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Original Articles

Recovery and Utilization of Chromium-Tanned Proteinous Wastes of Leather Making: A Review

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Pages 2048-2075 | Published online: 29 Sep 2011

REFERENCES

  • Abreu , M. A. and Toffoli , S. M. 2009 . Characterization of a chromium-rich tannery waste and its potential use in ceramics . Ceramics International , 35 : 2225 – 2234 .
  • Afsar , A. , Gulumser , G. , Aslan , A. and Ocak , B. 2009 . A study on usability of collagen hydrolysate along with oxazolidine in leather processing Paper presented at the International Leather Engineering Symposium, Turkey, April 29–May 1
  • Amir , S. , Benlboukht , F. , Cancian , N. , Winterton , P. and Hafidi , M. 2008 . Physico-chemical analysis of tannery solid waste and structural characterization of its isolated humic acids after composting . J. Hazard. Mater., , 160 : 448 – 455 .
  • Aslan , A. , Gulumser , G. and Ocak , B. 2006 . Increased chromium tanning efficiency with collagen hydrolysates . J. Soc. Leather Technol. Chem. , 90 : 201 – 204 .
  • Aslan , A. , Karavana , H. A. , Gulumser , G. , Yasa , I. and Cadirci , B. H. 2007 . Utilization of collagen hydrolysate in keratinase production from Bacillus subtilis ATCC 6633 . J. Am. Leather Chemical. Assoc. , 102 : 129 – 134 .
  • Babanas , K. , Tarantili , P. A. and Andreopoulos , A. G. 2001 . Plasticized poly (vinyl chloride) filled with waste leather particles . J. Elast. Plast. , 33 : 72 – 85 .
  • Basak , N. and Vibhavari , S. 2003 . Isolation of protein products from chrome shavings by acidic treatment: A study . J. Indian Leather Technol. Assoc. , 53 : 935 – 940 .
  • Basegio , T. , Haas , C. , Pokorny , A. , Bernardes , A. M. and Bergmann , C. P. 2006 . Production of materials with alumina and ashes from incineration of chromium tanned leather shavings: Environmental and technical aspects . J. Hazard. Mater. , B137 : 1156 – 1164 .
  • Basegio , T. , Leao , A. P.B. , Bernardes , A. M. and Bergmann , C. P. 2009 . Vitrification: An alternative to minimize environmental impact caused by leather industry wastes . J. Hazard. Mater. , 165 : 604 – 611 .
  • Bataille , P. , Gagnon , F. and Smith , W. E. 1983 . Upgrading leather and felt scrap into proteins . J. Am. Leather Chemical. Assoc. , 78 : 328 – 337 .
  • Berry , F. J. , Costantini , N. and Smart , L. E. 2001 . Recovery and reuse of chromium from leather shavings: Formation of chromium-containing ceramic pigments . J. Am. Leather Chemical. Assoc. , 96 : 46 – 53 .
  • Berry , F. J. , Costantini , N. and Smart , L. E. 2002 . Synthesis of chromium pigments from chromium recovered from leather waste . Waste Manage. , 22 : 761 – 772 .
  • Bulewicz , E. M. , Kozak , A. and Kowalski , Z. 1997 . Treatment of chrome tannery wastes using coal ashes from fluidized bed combustion of coal . Ind. Eng. Chem. Res. , 36 : 4381 – 4384 .
  • Boushy , A. R.E. , Poel , A. F.B.V. , Koene , J. I.A. and Dieleman , S. H. 1991 . Tanning waste by-product from cattle hides, its suitability as a feedstuff . Bioresource Technology , 35 : 321 – 323 .
  • Bowden , W. 2003 . Gasification: Achieving zero waste . J. Am. Leather Chemical. Assoc. , 98 : 19 – 26 .
  • Brasack , I. , Bottcher , H. and Hempel , U. 2000 . Biocompatibility of modified silica-protein composite layers . J. Sol-Gel Sci. Techn. , 19 : 479 – 482 .
  • Brown , E. M. and Taylor , M. M. 2003 . Essential chromium? . J. Am. Leather Chemical. Assoc. , 98 : 408 – 414 .
  • Brown , E. M. , Taylor , M. M. and Marmer , W. N. 1996 . Production and potential uses of co-products from solid tannery waste . J. Am. Leather Chemical. Assoc. , 91 : 270 – 276 .
  • Brown , E. M. , Thompson , C. J. and Taylor , M. M. 1994 . Molecular size and conformation of protein recovered from chrome shavings . J. Am. Leather Chem. Assoc. , 89 : 215 – 220 .
  • Buljan , J. , Reich , G. and Ludvik , J. 1999 . Mass balance in leather processing . World Leather , 12 : 34 – 46 .
  • Cabeza , L. F. , Clauson , S. M. , Taylor , M. M. , Brown , E. M. , Marmer , W. N. and Merck , K. B. 1999a . The effect of surfactants on the isolation of protein products from chromium-containing solid tannery waste. Influence on the process and on the chemical, physical and functional properties of the resultant gelatin . J. Am. Leather Chem. Assoc. , 94 : 190 – 198 .
  • Cabeza , L. F. , McAloon , A. J. , Yee , W. C. , Taylor , M. M. , Brown , E. M. and Marmer , W. N. 1998a . Process simulation and cost estimation of treatment of chromium-containing leather waste . J. Am. Leather Chem. Assoc. , 93 : 299 – 315 .
  • Cabeza , L. F. , Taylor , M. M. , Brown , E. M. and Marmer , W. N. 1999b . Potential applications for Gelatin isolated from chromium-containing solid tannery waste: Microencapsulation . J. Am. Leather Chem. Assoc. , 94 : 182 – 189 .
  • Cabeza , L. F. , Taylor , M. M. , Brown , E. M. and Marmer , W. N. 1997 . Influence of pepsin and trypsin on chemical and physical properties of isolated gelatin from chrome shavings . J. Am. Leather Chem. Assoc. , 92 : 200 – 207 .
  • Cabeza , L. F. , Taylor , M. M. , Brown , E. M. and Marmer , W. N. 1998b . Chemical and physical properties of protein products isolated from chromium-containing leather waste using two consecutive enzymes . J. Soc. Leather Technol. Chem. , 82 : 173 – 179 .
  • Cabeza , L. F. , Taylor , M. M. , Brown , E. M. and Marmer , W. N. 1999c . Isolation of protein products from chromium-containing leather waste using two consecutive enzymes and purification of final chromium product: Pilot plant studies . J. Soc. Leather Technol. Chem. , 83 : 14 – 19 .
  • Cabeza , L. F. , Taylor , M. M. , Brown , E. M. , Marmer , W. N. , Carrio , R. , Grau , E. , Celma , P. J. , Cot , J. and Manich , M. 1999d . Treatment of sheep skin chrome shavings. Isolation of high value protein products and reuse of chromium in the tanning process . J. Am. Leather Chemical. Assoc. , 94 : 268 – 287 .
  • Cabeza , L. F. , Taylor , M. M. , DiMaio , G. L. , Brown , E. M. , Marmer , W. N. , Carrio , R. , Celma , P. J. and Cot , J. 1998c . Processing of leather waste: Pilot scale studies on chrome shavings. Isolation of potentially valuable protein products and chromium . Waste Manage. , 18 : 211 – 218 .
  • Cabeza , L. F. , Taylor , M. M. , DiMaio , G. L. , Brown , E. M. , Marmer , W. N. , Carrio , R. , Celma , P. J. and Cot , J. 1998d . Processing of leather waste: Pilot scale studies on chrome shavings. Part II. Purification of chrome cake and tanning trials . J. Am. Leather Chemical. Assoc. , 93 : 83 – 98 .
  • Cabeza , L. F. , Taylor , M. M. , DiMaio , G. L. , Brown , E. L. , Marmer , W. N. , Carrio , R. , Celma , P. J. and Cot , J. 1999e . Cost effective processing of leather waste: Pilot scale studies on chrome shavings from cattle hides and sheepskins isolation of potentially valuable protein products and utilization of recovered chromium Proc. of XXV IULTCS Congress held in Chennai, Waste Management Technologies., 465–472
  • Cakl , J. , Sir , J. , Medvedikova , L. and Blaha , A. 1998 . Demineralization of protein hydrolysates from enzymatic hydrolysis of leather shavings using membrane diafilteration . Separation Sci., and Technol. , 33 : 1271 – 1281 .
  • Cantera , C. S. 2003 . Adding value to chrome shavings: Hydrolysates as retanning materials . World Leather , 16 : 27 – 29 .
  • Cantera , C. S. , De Giuste , M. and Sofia , A. 1997 . Hydrolysis of chrome shavings: Application of collagen hydrolysate and “acrylic–protein” in post tanning operations . J. Soc. Leather Technol. Chem. , 81 : 183 – 191 .
  • Cantera , C. S. , Goya , L. and Mingo , R. 1999 . Collagen hydrolysate: ‘Soluble skin’ applied in post tanning processes Part 1: Characterisation . J. Soc. Leather Technol. Chem. , 84 : 29 – 37 .
  • Cantera , C. S. , Martegani , J. , Esterelles , G. and Vergara , J. 2002 . Collagen hydrolysate: ‘Soluble skin’ applied in post tanning processes Part 2: Interaction with acrylic retanning agents . J. Soc. Leather Technol. Chem. , 86 : 195 – 202 .
  • Cao , J. , Lu , Y. , Chang , G. and Tang , K. 2005 . Glutaraldehyde modification of collagen hydrolysate obtained from chrome shavings . J. Am. Leather Chemical. Assoc. , 100 : 265 – 272 .
  • Carneiro , S. , Almeida , M. F. and Ferreira , M. J. 2003 . Factors influencing chromium recovery from chromium sulphate tanned leather scrap ashes . J. Soc. Leather Technol. Chem. , 87 : 1 – 10 .
  • Chagne , C. , Silvestre , F. and Gaset , A. 1996 . Review of chrome tanning. Part 1 . Leather , 198 : 17 – 26 .
  • Chakraborty , R. 2003 . Ecofriendly solid waste management in the leather industry , Vol. 3 , 2 India : Environmental biotechnology newsletter, University of Kalyani .
  • Chakraborty , R. 2004 . Optimization of hydrolysis of chrome shavings by enzyme from P. Lilacinus . J. Am. Leather Chemical. Assoc. , 99 : 103 – 109 .
  • Chakraborty , R. and Sarkar , S. K. 1999 . Eco-friendly biofertilizer from solid waste Proc. XXV IULTCS Congress held in Chennai, Waste Management Technologies, 481–483
  • Chen , W. , Cooke , P. H. , DiMaio , G. , Taylor , M. M. and Brown , E. M. 2001 . Modified collagen hydrolysate, potential for use as a filler for leather . J. Am. Leather Chemical. Assoc. , 96 : 262 – 267 .
  • Chronska , K. and Przepiorkowska , A. 2008 . Buffing dust as a filler of carboxylated butadiene-acrylonitrile rubber and butadiene-acrylonitrile rubber . J. Hazard. Mater. , 151 : 348 – 355 .
  • Cot , J. , Aramon , C. , Baucells , M. , Lacort , G. and Roura , M. 1986 . Waste processing in the tannery: Production of gelatin, Reconstituted collagen and glue from chrome-tanned leather splits and trimmings subjected to a modified detanning process . J. Soc. Leather Technol. Chem. , 70 : 69 – 76 .
  • Cot , J. , Manich , A. M. , Marsal , A. , Fort , M. , Celma , P. J. , Carrio , R. , Choque , R. and Cabeza , L. F. 1999 . Processing of collagenic residues isolation of gelatin by the action of peroxochromates . J. Am. Leather Chemical. Assoc. , 94 : 115 – 128 .
  • Cot , J. , Manich , A. M. , Marsal , A. , Fort , M. , Celma , P. J. , Carrio , R. , Choque , R. and Cabeza , L. F. 1999 . Processing of collagenic residues isolation of gelatin by the action of peroxochromates Proc. XXV IULTCS Congress held in Chennai, Process Innovations, 135–145
  • Cot , J. , Marsal , A. , Manich , A. , Celma , P. , Choque , R. , Cabeza , L. , Labastida , L. , Lopez , J. and Salmeron , J. 2003 . Minimization of industrial wastes: Adding value to collagenic materials Proctor Memorial Lecture . J. Soc. Leather Technol. Chem. , 87 : 91 – 97 .
  • Crispim , A. and Mota , M. 2003 . Leather shavings treatment: An enzymatic approach . J. Soc. Leather Technol. Chem. , 87 : 203 – 207 .
  • Deng , D. , Liao , X. and Shi , B. 2008 . Synthesis of porous carbon fibers from collagen fiber . Chem. Sus. Chem. , 1 : 298 – 301 .
  • Dvorackova , M. , Julinova , M. , Mikulcakova , H. and Kupec , J. 2007 . Testing aerobic degradation of the protein portion of filter cake after filtration of chrome tanned waste . J. Am. Leather Chemical. Assoc. , 102 : 77 – 84 .
  • Erdem , M. 2006 . Chromium recovery from chrome shaving generated in tanning process . J. Hazard. Mater. , B129 : 143 – 146 .
  • Erdem , M. and Ozverdi , A. 2008 . Leaching behavior of chromium in chrome shaving generated in tanning process and its stabilization . J. Hazard. Mater. , 156 : 51 – 55 .
  • Fathima , N. N. , Aravindhan , R. , Rao , J. R. and Nair , B. U. 2005 . Solid waste removes toxic liquid waste: Adsorption of chromium (VI) by iron complexed protein waste . Environ. Sci. Technol. , 39 : 2804 – 2810 .
  • Fengxia , C. , Hanbo , Z. , Yahong , Z. , Weihua , L. and Xianyong , J. 2005 . Preparation of chrome liquor using chrome shavings as reducing agent . J. Am. Leather Chemical. Assoc. , 100 : 217 – 224 .
  • Gaidau , C. , Niculescu , M. , Stepan , E. , Taloi , D. and Filipescu , L. 2009 . Additives and advanced biomaterials obtained from leather industry by-products . Rev. De Chim. , 60 : 501 – 507 .
  • Gammoun , A. , Tahiri , S. , Albizane , A. , Azzi , M. and Guardia , M. D.L. 2007b . Decontamination of water polluted with oil through the use of tanned solid wastes . J. Environ. Eng. Sci. , 6 : 553 – 559 .
  • Gammoun , A. , Tahiri , S. , Albizane , A. , Azzi , M. , Moros , J. , Garrigues , S. and Guardia , M. D.L. 2007a . Separation of motor oils, oily wastes and hydrocarbons from contaminated water by sorption on chrome shavings . J. Hazard Mater. , 145 : 148 – 153 .
  • Gauglhofer , J. 1986 . Environmental aspects of tanning with chromium . J. Soc. Leather Technol. Chem. , 70 : 11 – 13 .
  • Gish , A. J. 1999 . Leather board, a practical use of tannery offal . J. Am. Leather Chemical. Assoc. , 94 : 43 – 47 .
  • Groenestijn , J. W.V. , Langerwerf , J. S.A. and Lucas , M. 2002 . Reducing environmental emissions in tanneries . J. Environ. Sci. Health. , A37 : 737 – 743 .
  • Hauck , R. A. 1974 . Some notes on utilization of fleshings and blue shavings . J. Am. Leather Chemical. Assoc. , 69 : 195 – 203 .
  • Heidemann , E. 1991 . Disposal and recycling of chrome-tanned materials . J. Am. Leather Chemical. Assoc. , 86 : 331 – 333 .
  • Hrncirik , J. , Dvorackova , M. , Hruska , F. , Kupec , J. and Kolomaznik , K. 2005 . Kinetics of alkaline hydrolysis of the insoluble protein fraction following enzymatic hydrolysis of chrome-tanned shavings . J. Am. Leather Chemical. Assoc. , 100 : 1 – 7 .
  • Huang , X. , Liao , X. and Shi , B. 2009 . Adsorption removal of phosphate in industrial wastewater by using metal-loaded skin split waste . J. Hazard. Mater. , 166 : 1261 – 1265 .
  • Imai , T. and Okamura , H. 1991 . Studies on incineration of chrome leather waste . J. Am. Leather Chemical. Assoc. , 86 : 281 – 294 .
  • Jiao , L. , Liao , X. and Shi , B. 2009 . Adsorptive removal of As(V) from aqueous solution by Zr(IV) loaded skin shavings . J. Am. Leather Chemical. Assoc. , 104 : 308 – 315 .
  • Kasparkova , V. , Kolomaznik , K. , Burketova , L. , Sasek , V. and Simek , L. 2009 . Characterization of low-molecular weight collagen hydrolysates prepared by combination of enzymatic and acid hydrolysis . J. Am. Leather Chemical. Assoc. , 104 : 46 – 51 .
  • Katsifas , E. A. , Giannoutsou , E. , Lambraki , M. , Barla , M. and Karagouni , A. D. 2004 . Chromium recycling of tannery waste through microbial fermentation . J. Ind. Microbial Biotechnol. , 31 : 57 – 62 .
  • Kolomaznik , K. , Adamek , M. , Andel , I. and Uhlirova , M. 2008 . Leather waste: Potential threat to human health, and a new technology of its treatment . J. Hazard Mater. , 160 : 514 – 520 .
  • Kolomaznik , K. , Mladek , M. , Langmaier , F. , Janacova , D. and Taylor , M. M. 1999 . Expereince in industrial practice of enzymatic dechromation of chrome shavings . J. Am. Leather Chemical. Assoc. , 94 : 55 – 63 .
  • Kosmac , V. S.E. , Gantar , A. and Anzur , I. 1995 . Modification of collagen hydrolysates . Resour. Conserv., and Recycle. , 13 : 97 – 104 .
  • Kowalski , Z. and Walawska , B. 2001 . Utilization of tannery wastes for the production of sodium chromate (VI) . Ind. Eng. Chem. Res. , 40 : 826 – 832 .
  • Kresalkova , M. , Hnanickova , L. , Kupec , J. , Kolomaznik , K. and Alexy , P. 2002 . Application of protein hydrolysate from chrome shavings for polyvinyl alcohol-based biodegradable material . J. Am. Leather Chemical. Assoc. , 97 : 143 – 149 .
  • Krncirik , J. H. , Pseja , J. , Kupec , J. , Noskova , R. and Olsak , J. 2009 . Anaerobic biological degradation of protein hydrolysate cross-linked with higher-molecular weight diepoxides . J. Am. Leather Chemical. Assoc. , 104 : 36 – 45 .
  • Krummenauer , K. and Andrade , J. J.D.O. 2009 . Incorporation of chromium tanned leather residue to asphalt micro-surface layer . Constr. Build. Mater. , 23 : 574 – 581 .
  • Kupec , J. , Dvorackova , M. , Rudlova , S. , Ruicka , J. and Kolomaznik , K. 2002 . Deproteination of chrome waste by washing and enzymatic hydrolysis . J. Am. Leather Chemical. Assoc. , 97 : 349 – 354 .
  • Langmaier , F. , Kolomaznik , K. and Mladek , M. 2003 . Modifying products of enzymatic breakdown of chrome-tanned leather wastes with glutaraldehyde . J. Soc. Leather Technol. Chem. , 87 : 55 – 61 .
  • Langmaier , F. , Kolomaznik , K. , Sukop , S. and Mladek , M. 1999 . Products of enzymatic decomposition of chrome-tanned leather waste . J. Soc. Leather Technol. Chem. , 83 : 187 – 195 .
  • Langmaier , F. , Mladek , M. , Kolomaznik , K. , Sivarova , J. and Sukop , S. 2002 . Calorimetry of the reactions of hydrolysates of chromed shavings with aldehydes . J. Therm. Anal. Cal. , 67 : 659 – 666 .
  • Langmaier , F. , Mokrejs , P. , Karnas , R. , Mladek , M. and Kolomaznik , K. 2006 . Modification of chrome-tanned leather waste hydrolysate with epichlorhydrin . J. Soc. Leather Technol. Chem. , 90 : 29 – 34 .
  • Langmaier , F. , Mokrejs , P. , Kolomaznik , K. and Mladek , M. 2008 . Plasticizing collagen hydrolysate with glycerol and low-molecular weight poly (ethylene glycols) . Thermochim. Acta. , 469 : 52 – 58 .
  • Langmaier , F. , Mokrejs , P. , Kolomaznik , K. , Mladek , M. and Karnas , R. 2007 . Cross-linking epoxide resins with hydrolysates of chrome-tanned leather waste . J. Therm. Anal. Cal. , 88 : 857 – 862 .
  • Langmaier , F. , Sivarova , J. , Kolomaznik , K. and Mladek , M. 2004a . Curing of urea-formaldehyde adhesives with collagen type hydrolysates under acid condition . J. Therm. Anal. Cal. , 76 : 1015 – 1023 .
  • Langmaier , F. , Sivarova , J. , Mladek , M. and Kolomaznik , K. 2004b . Curing adhesives of urea: Formaldehyde type with collagen hydrolysates of chrome-tanned leather waste . J. Therm. Anal. Cal. , 75 : 205 – 219 .
  • Langmaier , F. , Stibora , M. , Mladek , M. and Kolomaznik , K. 2001 . Gel-sol transitions of chrome tanned leather waste hydrolysate . J. Soc. Leather Technol. Chem. , 85 : 100 – 105 .
  • Lazau , R. I. , Pacurariu , C. , Becherescu , D. and Ianos , R. 2007 . Ceramic pigments with chromium content from leather wastes . J. Europe Ceramic Soc. , 27 : 1899 – 1903 .
  • Lipsett , V. A. 1982 . Offal blue: Sources and current deposition of chrome offals . J. Am. Leather Chemical. Assoc. , 77 : 291 – 301 .
  • Liu , Y. and Yang , Z. 2006 . Uses for chrome leather waste: Chromium-enriched brewers yeast . J. Soc. Leather Technol. Chem. , 90 : 14 – 18 .
  • Lollar , R. M. 1981 . Potential uses of tanned collagen . J. Am. Leather Chemical. Assoc. , 76 : 192 – 193 .
  • Malek , A. , Hachemi , M. and Didier , V. 2009 . New approach of depollution of solid chromium leather waste by the use of organic chelates: Economical and environmental impacts . J. Hazard Mater. , 170 : 156 – 162 .
  • Martinelango , K. and Shelly , D. C. 2004 . Multidimensional analysis of magnesium oxide hydrolysis of wet-blue shavings . J. Am. Leather Chemical. Assoc. , 99 : 258 – 268 .
  • Montoneri , E. , Rizzi , G. , Rizzi , A. , Mordenti , A. , Bauli , A. , Riolfatti , M. and Pellegrini , L. 1994 . Hydrolysis of tannery wastes to protein meal for animal feedstuffs: A process and product evaluation . J. Chem. Tech. Biotechnol. , 59 : 91 – 99 .
  • Mu , C. , Lin , W. , Zhang , M. and Zhu , Q. 2003 . Towards zero discharge of chromium-containing leather waste through improved alkali hydrolysis . Waste Manage. , 23 : 835 – 843 .
  • Mukherjee , G. , Chakraborty , S. , Biswas , G. K. and Basu , S. K. 2005 . Chromium tanned leather and its environmental impact . J. Indian Leather Technol. Assoc. , 55 : 239 – 246 .
  • Munoz , J. M. , Maldonado , M. V. and Rangel , A. S. 2002 . Development of a tanning process based on using hydrolyzated material collected from leather scrap . J. Am. Leather Chemical. Assoc. , 97 : 83 – 87 .
  • Munz , K. H. , Sundar , V. J. , Muralidharan , C. and Parthasarathy , K. 1997 . Chrome tannage without pickling . Das Leder , 48 : 128 – 132 .
  • Muralidharan , C. , Sundar , V. J. , Rao , V. S.S. and Ramasami , T. 2001 . Two-stage tanning: A new approach for chrome management . J. Am. Leather Chemical. Assoc. , 96 : 61 – 66 .
  • Na , Z. M. , Pin , L. X. and Bi , S. 2006 . Adsorption of surfactants on chromium leather waste . J. Soc. Leather Technol. Chem. , 90 : 1 – 6 .
  • Narasimhan , K. , Sehgal , P. K. and Joseph , K. T. 1980 . Condensation of aromatic sulfonic acid with hydrolysates from leather wastes . J. Am. Leather Chemical. Assoc. , 75 : 211 – 215 .
  • Nogami , E. M. , Kimura , C. C.M. , Malagutti , A. R. , Galli , D. , Gallo , D. , Castilho , T. J. , Rodrigues , C. and Nozaki , J. 2000 . Recovery of protein from chrome shavings and application as a food supplement for Tilapia Oreochromis Niloticus . J. Am. Leather Chemical. Assoc. , 95 : 119 – 124 .
  • Okamura , H. and Shirai , K. 1972 . Basic studies on the manufacture of leatherboard from chrome collagen fiber . J. Am. Leather Chemical. Assoc. , 67 : 148 – 162 .
  • Okamura , H. and Shirai , K. 1976 . Recovery of chromium from shavings by wet air oxidation . J. Am. Leather Chemical. Assoc. , 71 : 173 – 179 .
  • Oliveira , D. Q.L. , Goncalves , M. , Oliveira , L. C.A. and Guilherme , L. R.G. 2008a . Removal of As (V) and Cr (VI) from aqueous solutions using solid waste from leather industry . J. Hazard Mater. , 151 : 280 – 284 .
  • Oliveira , L. C.A. , Goncalves , M. , Oliveira , D. Q.L. , Guerreiro , M. C. , Guilherme , L. R.G. and Dallago , R. M. 2007 . Solid waste from leather industry as adsorbent of organic dyes in aqueous–medium . J. Hazard Mater. , 141 : 344 – 347 .
  • Oliveira , L. C.A. , Guerreiro , M. C. , Concalves , M. , Oliveira , D. Q.L. and Costa , L. C.M. 2008b . Preparation of activated carbon from leather waste: A new material containing small particle of chromium oxide . Materials Letters , 62 : 3710 – 3712 .
  • Pearson , C. L. 1982 . Animal glue in industry and the use of chrome-tanned hide collagen in the production of animal glue . J. Am. Leather Chemical. Assoc. , 77 : 306 – 311 .
  • Popescu , C. , Budrugeac , P. , Wortmann , F. J. , Miu , L. , Demco , D. E. and Baius , M. 2008 . Assessment of collagen-based materials which are supports of cultural and historical objects . Poly. Degrad. Stability. , 93 : 976 – 982 .
  • Poulopoulou , V. G. , Katakis , D. and Vrachnou , E. 1998 . A method for the removal of chromium from tanned leather wastes . J. Air Waste Manage. Assoc. , 48 : 846 – 852 .
  • Przepiorkowska , A. , Chronska , K. , Prochon , M. and Zaborski , M. 2006 . New possibilities for managing the leather industry wastes . Przemysl Chemiczny. , 85 : 971 – 975 .
  • Przepiorkowska , A. , Chronska , K. and Zaborski , M. 2007 . Chrome tanned leather shavings as a filler of butadiene-acrylonitrile rubber . J. Hazard Mater. , 141 : 252 – 257 .
  • Przepiorkowska , A. , Janowska , G. , Slusarski , L. and Wolniak , S. 2003 . Leather powder as an agent for removing environmentally hazardous organic compounds . J. Soc. Leather Technol. Chem. , 87 : 223 – 226 .
  • Przepiorkowska , A. , Prochon , M. and Zaborski , M. 2004 . Use of waste collagen as a filler for rubber compounds . J. Soc. Leather Technol. Chem. , 88 : 223 – 227 .
  • Przepiorkowska , A. , Prochon , M. , Zaborski , M. , Zakowska , Z. and Piotrowska , M. 2005 . Biodegradable protein-containing elastomeric vulcanizates . Rubber Chem. Technol. , 78 : 868 – 878 .
  • Ramaraj , B. 2006 . Mechanical and thermal properties of ABS and leather waste composites . J. Applied Polymer Science. , 101 : 3062 – 3066 .
  • Ramasami , T. , Sreeram , K. J. and Gayatri , R. 1998 . Emerging leather processing options for waste minimization UNIDO Report, Regional Workshop on Cleaner Tanning Technologies
  • Rao , J. R. , Thanikaivelan , P. , Sreeram , K. J. and Nair , B. U. 2002 . Green route for the utilization of chrome shavings (chromium-containing solid waste) in tanning industry . Environ. Sci. Technol. , 36 : 1372 – 1376 .
  • Rao , J. R. , Thanikaivelan , P. , Sreeram , K. J. and Nair , B. U. 2004 . Tanning studies with basic chromium sulfate prepared using chrome shavings as a reductant: A call for ‘wealth from waste’ approach to the tanning industry . J. Am. Leather Chemical. Assoc. , 99 : 170 – 176 .
  • Rutland , F. H. 1991 . Environmental compatibility of chromium-containing tannery and other leather product wastes at land disposal site . J. Am. Leather Chemical. Assoc. , 86 : 364 – 375 .
  • Reis , M. A.D. and Beleza , V. 1991 . Utilization of leather waste: Animal feedstuff from chrome shavings. Part 1: Pilot plant study . J. Soc. Leather Technol. Chem. , 75 : 15 – 19 .
  • Saha , N. , Kresalkova , M. , Saha , L. and Kolomaznik , K. 2003 . The effect of anaerobic digestion on chrome sludge: A by-product of tanned leather waste . J. Am. Leather Chemical. Assoc. , 98 : 256 – 262 .
  • Saha , N. , Zatloukal , M. and Saha , P. 2003 . Modification of polymers by protein hydrolysate: A way to biodegradable materials . Polym. Adv. Technol. , 14 : 854 – 860 .
  • Santana , T. J.M. , Torres , A. C. and Lucero , A. M. 1998 . Extrusion and Mechanical characterization of PVC-leather fiber composites . Polym. Compos. , 19 : 431 – 439 .
  • Santana , T. J.M. , Vega , M. J.A. , Lucero , A. M. and Moreno , F. V. 2002 . Production of leather like composites using chemically modified short leather fibers. I: Chemical modification by emulsion polymerization . Polym. Compos. , 23 : 49 – 60 .
  • Saravanabhavan , S. , Sreeram , K. J. , Rao , J. R. and Nair , B. U. 2004 . The three pot solution for chromium, tannins and solid wastes: Recovery and reuse technique for spent semi-chrome liquor and chrome shavings . J. Soc. Leather Technol. Chem. , 88 : 202 – 207 .
  • Saravanabhavan , S. , Sreeram , K. J. , Rao , J. R. and Nair , B. U. 2007 . The use of toxic solid waste for the adsorption of dyes from waste streams . J. Chem. Technol. Biotechnol. , 82 : 407 – 413 .
  • Sarkar , K. T. 2005 . Theory and practice of leather manufacture , Rev. Ed. , Calcutta, , India : Sarkar Publications .
  • Sastry , T. P. , Ranganayaki , M. D. , Rose , C. and Rajini , R. 1999 . Extraction of gelatin from chrome shavings using pancreatic enzymes Proc. XXV IULTCS Congress, held in Chennai, Waste Management Technologies, 513–519
  • Sekaran , G. , Shanmugasundaram , K. A. and Mariappan , M. 1998 . Characterization and utilization of buffing dust generated by the leather industry . J. Hazard Mater. , 63 : 53 – 68 .
  • Sempere , J. F. , Martinez , M. L.B. , Montesinos , R. F. and Lillo , M. C.S. 1997 . Characterization of tannery wastes comparison of three leachability tests . J. Hazard. Mater. , 54 : 31 – 45 .
  • Shanthi , C. and Shelly , D. C. 2003 . Immobilization of degradative enzyme onto collagen hydrolysate films . J. Am. Leather Chemical. Assoc. , 98 : 6 – 12 .
  • Shin , E. C. , Lee , S. C. , Kim , W. J. and Heo , J. S. 2007 . Development of regenerated protein fibers from a collagen-polyvinyl alcohol complex . J. Am. Leather Chemical. Assoc. , 102 : 315 – 321 .
  • Sivaparvathy, M., Suseela, K., and Nanda, S.C. (1986). Hydrolytic action of Pseudomonas Aerugihosa on chrome shavings. Leather Sci., 33(1), 8–11.
  • Smith , L. R. and Donovan , R. G. 1982 . Preparation of high quality gelatin with low chromium content from chrome-tanned stock . J. Am. Leather Chemical. Assoc. , 77 : 301 – 306 .
  • Sreeram , K. J. , Saravanabhavan , S. , Rao , J. R. and Nair , B. U. 2004 . Use of chromium-collagen wastes for the removal of tannins from wastewaters . Ind. Eng. Chem. Res. , 43 : 5310 – 5317 .
  • Stockman , G. 1996 . Practical considerations of the production scale hydrolysis of blue shavings . J. Am. Leather Chemical. Assoc. , 91 : 190 – 193 .
  • Sun , D. , Liao , X. and Shi , B. 2003 . Oxidative dechroming of leather shavings under ultrasound . J. Soc. Leather Technol. Chem. , 87 : 103 – 106 .
  • Sundar , V. J. , Haribabu , V. , Muralidharan , C. and Sadulla , S. 2008 . Turning to nature for eco benign stabilization of skin protein . J. Leather Sci. , 4 : 24 – 28 .
  • Sundar , V. J. , Ramesh , R. , Rao , P. S. , Saravanan , P. , Sridharnath , B. and Muralidharan , C. 2001 . Water management in leather industry . J. Sci. Ind. Res. , 60 : 443 – 450 .
  • Sundar , V. J. , Rangasamy , T. , Sivakumar , V. and Muralidharan , C. 2004 . A novel pickle free high exhaust chrome tanning method: An approach for total dissolved solids management . J. Soc. Leather Technol. Chem. , 88 : 252 – 255 .
  • Sundar , V. J. , Rao , J. R. and Muralidharan , C. 2002 . Cleaner chrome tanning: Emerging options . J. Clean. Prod. , 10 : 69 – 74 .
  • Sundar , V. J. , Vedaraman , N. , Balakrishnan , P. A. , Chakrabarti , S. and Muralidharan , C. 2006 . Sulphide free unhairing: Studies on ozone based depilation . J. Am. Leather Chemical. Assoc. , 101 : 231 – 234 .
  • Swarnalatha , S. , Ganesh Kumar , A. , Tandaiah , S. and Sekaran , G. 2009 . Efficient and safe disposal of chrome shavings discharged from leather industry using thermal combustion . J. Chem. Tech. Biotechnol. , 84 : 751 – 760 .
  • Swarnalatha , S. , Srinivasulu , T. , Srimurali , M. and Sekaran , T. 2008 . Safe disposal of toxic chrome buffing dust generated from leather industries . J. Hazard. Mater. , 150 : 290 – 299 .
  • Tahiri , S. , Albizane , A. , Abargues , M. R. and Guardia , M. D.L. 2006 . Recovery of proteinaceous materials from tanned solid wastes: Yields and characterization of isolated products . J. Solid Waste Technol. Manage. , 32 : 138 – 148 .
  • Tahiri , S. , Albizane , A. , Messaoudi , A. , Azzi , M. , Bennazha , J. , Younssi , S. A. and Bouhria , M. 2007 . Thermal behaviour of chrome shavings and of sludges recovered after digestion of tanned solid wastes with calcium hydroxide . Waste Manage. , 27 : 89 – 95 .
  • Tahiri , S. , Azzi , M. , Albizane , A. , Messaoudi , A. , Bouhria , M. and Sibari , A. 2001a . Processing of chrome tanned solid waste generated in the leather industry: Recovery of proteins and synthesis of a pigment for paint . J. Am. Leather Chemical. Assoc. , 96 : 1 – 8 .
  • Tahiri , S. , Azzi , M. , Albizane , A. , Messaoudi , A. , Bouhria , M. , Younssi , S. A. , Mourid , A. and Amrhar , J. 2001b . Study of quality of a pigment prepared by complexation of chromates recovered from treated chrome shavings and tanned splits . J. Am. Leather Chemical. Assoc. , 96 : 426 – 436 .
  • Tahiri , S. , Azzi , M. , Messaoudi , A. , Albizane , A. , Bouhria , M. , Younssi , S. A. and Mabrour , J. 2002 . Removal of methylene blue from aqueous solutions by adsorption on tanned solid wastes . J. Am. Leather Chemical. Assoc. , 97 : 261 – 266 .
  • Tahiri , S. , Bouhria , M. , Albizane , A. , Messaoudi , A. , Azzi , M. , Younssi , S. A. and Mabrour , J. 2004 . Extraction of proteins from chrome shavings with sodium hydroxide and reuse of chromium in the tanning process . J. Am. Leather Chemical. Assoc. , 99 : 16 – 25 .
  • Tahiri , S. , Messaoudi , A. , Albizane , A. , Azzi , M. , Bouhria , M. , Younssi , S. A. , Bennazha , J. and Mabrour , J. 2003 . Removal of dyes from aqueous solutions by adsorption on chrome tanned solid wastes generated in the leather industry . Water Qual. Res. J. Canada. , 38 : 393 – 411 .
  • Taotao , Q. , Xuechuan , W. and Longfang , R. 2009 . Recovery of collagen from phosphonium tanned leather shavings and application as formaldehyde scavenger . J. Am. Leather Chemical. Assoc. , 104 : 316 – 322 .
  • Taylor , M. M. , Cabeza , L. F. , DiMaio , G. L. , Brown , E. M. , Marmer , W. N. , Carrio , R. , Celma , P. J. and Cot , J. 1998 . Processing of leather waste: Pilot scale studies on chrome shavings. Part, I. Isolation and characterization of protein products and separation of chrome cake . J. Am. Leather Chemical. Assoc. , 93 : 61 – 82 .
  • Taylor , M. M. , Cabeza , L. F. , Marmer , W. N. and Brown , E. M. 1997a . Computer-assisted method to measure the adhesive properties of hydrolysis products from collagen . J. Am. Leather Chemical. Assoc. , 92 : 28 – 37 .
  • Taylor , M. M. , Cabeza , L. F. , Marmer , W. N. and Brown , E. M. 2000 . Use of tryptec enzyme preparations in treatment of chrome shavings . J. Am. Leather Chemical. Assoc. , 95 : 243 – 252 .
  • Taylor , M. M. , Cabeza , L. F. , Marmer , W. N. and Brown , E. M. 2001 . Enzymatic modification of hydrolysis products from collagen using a microbial transglutaminase. I. Physical properties . J. Am. Leather Chemical. Assoc. , 96 : 319 – 332 .
  • Taylor , M. M. , Cabeza , L. F. , Marmer , W. N. , Brown , E. M. and Kolomaznik , K. 1998 . Functional properties of hydrolysis products from collagen . J. Am. Leather Chemical. Assoc. , 93 : 40 – 50 .
  • Taylor , M. M. , Diefendorf , E. J. , Brown , E. M. and Marmer , W. N. 1992 . Characterization of products isolated by enzyme treatment of chromium containing leather waste . J. Am. Leather Chemical. Assoc. , 87 : 380 – 389 .
  • Taylor , M. M. , Diefendorf , E. J. and Marmer , W. N. 1991 . Efficiency of enzymic solubilization of chrome shavings as influenced by choice of alkalinity-inducing agents . J. Am. Leather Chemical. Assoc. , 86 : 199 – 208 .
  • Taylor , M. M. , Diefendorf , E. J. , Marmer , W. N. and Brown , E. M. 1994 . Effect of various alkalinity inducing agents on chemical and physical properties of protein products isolated from chromium containing leather waste . J. Am. Leather Chemical. Assoc. , 89 : 221 – 228 .
  • Taylor , M. M. , Diefendorf , E. J. , Marmer , W. N. and Brown , E. M. 1995 . Effect of deionization on physical properties of gelable protein products recovered from solid tannery waste . J. Am. Leather Chemical. Assoc. , 90 : 365 – 374 .
  • Taylor , M. M. , Diefendorf , E. S. and Na , G. C. 1990 . Enzymic treatment of chrome shavings . J. Am. Leather Chemical. Assoc. , 85 : 264 – 275 .
  • Taylor , M. M. , Diefendorf , E. J. , Thompson , C. J. , Brown , E. M. , Marmer , W. N. and Cabeza , L. F. 1997b . Extraction of value added byproducts from the treatment of chromium containing collagenous leather industry waste . J. Soc. Leather Technol. Chem. , 81 : 5 – 13 .
  • Taylor , M. M. , Liu , C. K. , Latona , N. , Marmer , W. N. and Brown , E. M. 2002 . Enzymatic modification of hydrolysis products from collagen using a microbial transglutaminase. II. Preparation of films . J. Am. Leather Chemical. Assoc. , 97 : 225 – 234 .
  • Taylor , M. M. , Liu , C. K. , Marmer , W. N. and Brown , E. M. 2003 . Enzymatic modification of hydrolysis products from collagen using a microbial transglutaminase. III. Preparation of films with improved mechanical properties . J. Am. Leather Chemical. Assoc. , 98 : 435 – 444 .
  • Taylor , M. M. , Marmer , W. N. and Brown , E. M. 2005 . Characterization of biopolymers prepared from gelatin and sodium caseinate for potential use in leather processing . J. Am. Leather Chemical. Assoc. , 100 : 149 – 159 .
  • Trezza , M. A. and Scian , A. N. 2007 . Waste with chrome in the Portland cement clinker production . J. Hazard Mater. , 147 : 188 – 196 .
  • Vedaraman , N. , Rangasamy , T. , Muralidharan , C. and Rao , P. G. 2002 . A process for preparation of leather like sheet and the sheet prepared thereby No.752 Del 2002
  • Veeger , L. 1993 . Ecological procedure to solve the tannery waste problems . J. Am. Leather Chemical. Assoc. , 88 : 326 – 329 .
  • Vieira , M. S. and Marcilio , N. R. 2005 . Recovery of chromium from chrome containing leather waste from the leather industry: The optimization of the process Paper presented at Second Mercosur Congress on Chemical Engineering Proceedings, Rio De Janeiro, Brazil, August 14–18
  • Walawska , B. and Kowalski , Z. 2000 . Selection of technological variants of sodium chromate (VI) production process with the use of chromic waste . J. Environmental Studies. , 9 : 103 – 111 .
  • Walawska , B. and Kowalski , Z. 2001 . Environmental evaluation of the effects of using chromic waste in the production of chromium compounds . J. Cleaner Production. , 9 : 219 – 226 .
  • Xuechuan , W. , Longfang , R. and Taotao , Q. 2009 . Novel way of transformation of tannery waste to environmentally friendly formaldehyde scavenger . Environmental Progress & Sustainable Energy , 28 : 285 – 290 .
  • Yilmaz , O. , Kantarli , C. I. , Yuksel , M. , Saglam , M. and Yanik , J. 2007 . Conversion of leather wastes to useful products . Resources Conservation and Recycling , 49 : 436 – 448 .
  • Zhao , S. , Zhang , M. , Li , G. and Liu , W. 2009 . Preparation and characterization of alkali-soluble collagen from pigskin shavings . J. Am. Leather Chemical. Assoc. , 104 : 344 – 351 .

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