533
Views
240
CrossRef citations to date
0
Altmetric
Reviews

A critical review of Henry's law constants for environmental applications

&
Pages 205-297 | Published online: 09 Jan 2009

References

  • 1992 . CRC Handbook of Chemistry and Physics , 73rd ed. , Boca Raton, FL : CRC Press .
  • Abrams , D.S. and Prausnitz , J.M. 1975 . Statistical thermodynamics of liquid mixtures: a new expression for the excess Gibbs energy of partly or completely miscible systems . AIChE J. , 21 (1) : 116 – 128 .
  • Anderson , M.A. 1992 . Influence of surfactants on vapor‐liquid partitioning . Environ. Sci. Technol. , 26 (11) : 2186 – 2191 .
  • Arbuckle , W.B. 1983 . Estimating activity coefficients for use in calculating environmental parameters . Environ. Sci. Technol. , 17 (9) : 537 – 542 .
  • Ashworth , R.A. , Howe , G.B. , Mullins , M.E. and Rogers , T.N. 1988 . Air‐water partitioning coefficients of organics in dilute aqueous solutions . J. Hazard. Mater. , 18 : 25 – 36 .
  • Atkins , P.W. 1990 . Physical Chemistry , 4th ed. , New York : Freeman .
  • Atlas , E. , Foster , R. and Glam , C.S. 1982 . Air‐sea exchange of high molecular weight organic pollutants: laboratory studies . Environ. Sci. Technol. , 16 (5) : 283 – 286 .
  • Barr , R.S. and Newsham , D.M.T. 1987a . Phase equilibria in very dilute mixtures of water and chlorinated hydrocarbons. I. Experimental results . Fluid Phase Equil. , 35 : 189 – 205 .
  • Barr , R.S. and Newsham , D.M.T. 1987b . Phase equilibria in very dilute mixtures of water and chlorinated hydrocarbons, II. UNIFAC parameters . Fluid Phase Equil. , 35 : 207 – 215 .
  • Bastos , J.C. , Soares , M.E. and Medina , A.G. 1988 . Infinite dilution activity coefficients predicted by UNIFAC group contribution . Ind. Eng. Chem. Res. , 27 : 1269 – 1277 .
  • Betterton , E.A. and Hoffmann , M.R. 1988 . Henry's law constants of some environmentally important aldehydes . Environ. Sci. Technol. , 22 (12) : 1415 – 1418 .
  • Bissonette , E.M. , Westrick , J.J. and Morand , J.M. 1990 . Determination of Henry's coefficient for volatile organic compounds in dilute aqueous systems . Proceedings of the Annual Conference of the American Water Works Association . June 17–21 1990 , Cincinnati, OH. pp. 1913 – 1922 .
  • Brunner , S. , Hornung , E. , Santl , H. , Wolff , E. , Piringer , O.G. , Altschuh , J. and Bruggemann , R. 1990 . Henry's law constant for polychlorinated biphenyls: experimental determination and structure‐property relationships . Environ. Sci. Technol. , 24 (11) : 1751 – 1754 .
  • Burkhard , L.P. , Armstrong , D.E. and Andren , A.W. 1985 . Henry's law constant for the polychlorinated biphenyls . Environ. Sci. Technol. , 19 (7) : 590 – 596 .
  • Callaway , J.Y. , Gabbita , K.V. and Vilker , V.L. 1984 . Reduction of low molecular weight halocarbons in the vapor phase above concentrated humic acid solutions . Environ. Sci. Technol. , 18 (11) : 890 – 893 .
  • Chiou , C.T. , Kile , D.E. , Brinton , T.I. , Malcolm , R.L. , Leenheer , J.A. and MacCarthy , P.A. 1987 . Comparison of water solubility enhancements of organic solutes by aquatic humic materials and commerical humic acids . Environ. Sci. Technol. , 21 (12) : 1231 – 1234 .
  • Chiou , C.T. , Kile , D.E. and Rutherford , D.W. 1991 . The neutral oil in commerical linear alkylbenzenesulfonate and its effect on organic solute solubility in water . Environ. Sci. Technol. , 25 (4) : 660 – 665 .
  • Chiou , C.T. , Malcolm , R.L. , Brinton , T.I. and Kile , D.E. 1986 . Water solubility enhancement of some organic pollutants and pesticides by dissolved humic and fulvic acids . Environ. Sci. Technol. , 20 (5) : 502 – 508 .
  • Cooling , M.R. , Khalfaoui , B. and Newsham , D.M.T. 1992 . Phase equilibria in very dilute mixtures of water and unsaturated chlorinated hydrocarbons and of water and benzene . Fluid Phase Equil. , 81 : 217 – 229 .
  • Dean , J.A. 1992 . Lange's Handbook of Chemistry , 14th ed. , New York : McGraw‐Hill .
  • Dunnivant , F.M. , Coates , J.T. and Elzerman , A.W. 1988 . Experimentally determined Henry's law constants for 17 polychlorobiphenyl congeners . Environ. Sci. Technol. , 22 (4) : 448 – 453 .
  • Dunnivant , F.M. , Elzerman , A.W. , Jurs , P.C. and Hasan , M.N. 1992 . Quantitative structure‐property relationships for aqueous solubilities and Henry's law constants for polychlorinated biphenyls . Environ. Sci. Technol. , 26 (8) : 1567 – 1573 .
  • Ervin , A.L. , Mangone , M.A. and Singley , J.E. 1980 . Trace organics removal by air stripping . Proceedings of the Annual Conference of the American Water Works Association . 1980 . pp. 507 – 530 .
  • Fendinger , N.J. and Glotfelty , D.E. 1990 . Henry's law constants for selected pesticides, PAHs, and PCBs . Environ. Toxicol. Chem. , 9 : 731 – 735 .
  • Fendinger , N.J. , Glotfelty , D.E. and Freeman , H.P. 1989 . Comparison of two experimental techniques for determining air/water Henry's law constants . Environ. Sci. Technol. , 23 (12) : 1528 – 1532 .
  • Fredenslund , A. , Gmehling , J. and Rasmussen , P. 1977 . Vapor‐Liquid Equilibria Using UNIFAC , Amsterdam : Elsevier .
  • Fredenslund , A. , Jones , R.L. and Prausnitz , J.M. 1975 . Group‐contribution estimation of activity coefficients in nonideal liquid mixtures . AIChE J. , 21 (6) : 1086 – 1099 .
  • Gmehling , J. , Rasmussen , P. and Fredenslund , A. 1982 . Vapor‐liquid equilibria by UNIFAC group contribution. II. Revision and extension . Ind. Eng. Chem. Process Des. Dev. , 21 : 118 – 127 .
  • Gmehling , J. , Tiegs , D. and Knipp , U. 1990 . A comparison of the predictive capability of different group contribution methods . Fluid Phase Equil. , 54 : 147 – 165 .
  • Gossett , J.M. 1987 . Measurement of Henry's law constants for C1 and C2 chlorinated hydrocarbons . Environ. Sci. Technol. , 21 (2) : 202 – 208 .
  • Gossett , J.M. , Cameron , C.E. , Eckstrom , B.P. , Goodman , C. and Lincoff , A.H. 1985 . Mass Transfer Coefficients and Henry's Constants for Packed‐Tower Air Stripping of Volatile Organics: Measurements and Correlations , Final Report ESL‐TR‐85–18 Tyndall Air Force Base, FL : Engineering and Services Laboratory .
  • Gossett , J.M. and Lincoff , A.H. 1981 . “ Solute‐Gas Equilibria in Multiorganic Aqueous Systems ” . In Final Report: Air Force Office of Scientific Research grant AFOSR‐81–0074
  • Hansen , H.K. , Rasmussen , P. , Fredenslund , A. , Schiller , M. and Gmehling , J. 1991 . Vapor‐liquid equilibria by UNIFAC group contribution. V. Revision and extension . Ind. Eng. Chem. Res. , 30 : 2352 – 2355 .
  • Hansen , K.C. , Zhou , Z. , Yaws , C.L. and Aminabhavi , T.M. 1993 . Determination of Henry's law constants of organics in dilute aqueous solutions . J. Chem. Eng. Data , 38 (4) : 546 – 550 .
  • Hawker , D.W. 1989 . Vapor pressures and Henry's law constants of polychlorinated biphenyls . Environ. Sci. Technol. , 23 (10) : 1250 – 1253 .
  • Hine , J. and Mookerjee , P.K. 1975 . The intrinsic hydrophilic character of organic compounds: correlations in terms of structural contributions . J. Org. Chem. , 40 (3) : 292 – 298 .
  • ten Hulscher , Th.E.M. , Van der Velde , L.E. and Bruggeman , W.A. 1992 . Temperature dependence of Henry's law constants for selected chlorobenzenes, polychlorinated biphenyls and polycyclic aromatic hydrocarbons, Environ . Toxicol. Chem. , 11 : 1595 – 1603 .
  • Hunter‐Smith , R.J. , Balls , P.W. and Liss , P.S. 1983 . Henry's law constants and the air‐sea exchange of various low molecular weight halocarbon gases . Tellus , 35B (3) : 170 – 176 .
  • Janini , G.M. and Qaddora , L.A. 1986 . Determination of activity coefficients of oxygenated hydrocarbons by liquid‐liquid chromatography . J. Liq. Chromatogr. , 9 (1) : 39 – 53 .
  • Kames , J. , Schweighoefer , S. and Schurath , U. 1991 . Henry's law constant and hydrolysis of peroxyacetyl nitrat(PAN) . J. Atmos. Chem. , 12 : 169 – 180 .
  • Kavanaugh , M.C. and Trussell , R.R. 1980 . Design of aeration towers to strip volatile contaminants from drinking water . J Am. Water Works Assoc. , 72 (12) : 684 – 692 .
  • Kile , D.E. and Chiou , C.T. 1989 . Water solubility enhancement of DDT and trichlorobenzene by some surfactants below and above the critical micelle concentration . Environ. Sci. Technol. , 23 (7) : 832 – 838 .
  • Kile , D.E. , Chiou , C.T. and Helburn , R.S. 1990 . Effect of some petroleum sulfonate surfactants on the apparent water solubility of organic compounds . Environ. Sci. Technol. , 24 (2) : 205 – 208 .
  • Kucklick , J.R. , Hinckley , D.A. and Bidleman , T.F. 1991 . Determination of Henry's law constants for hexachlorocyclohexanes in distilled water and artificial seawater as a function of temperature . Marine Chem. , 34 : 197 – 209 .
  • Lalezary , S. , Pirbazari , M. , McGuire , M.J. and Krasner , S.W. 1984 . Air stripping of taste and odor compounds from water . J. Am. Water Works Assoc. , 76 (3) : 83 – 87 .
  • Lamarche , P. and Droste , R.L. 1989 . Air stripping mass transfer correlations for volatile organics . J. Am. Water Works Assoc. , 81 (1) : 78 – 89 .
  • Leighton , D.T. and Calo , J.M. 1981 . Distribution coefficients of chlorinated hydrocarbons in dilute air‐water systems for groundwater contamination applications . J. Chem. Eng. Data , 26 (4) : 382 – 385 .
  • Lincoff , A.H. and Gossett , J.M. 1984 . “ The determination of Henry's constant for volatile organics by equilibrium partitioning in closed systems ” . In Gas Transferal Water Surfaces , Edited by: Brutsaert , W. and Jirka , G.H. 17 – 25 . Boston : D. Reidel Publishing .
  • Lucius , J.E. , Olhoeft , G.R. , Hill , P.L. and Duke , S.K. 1992 . Properties and Hazards of 108 Selected Substances , 1992 ed. , U.S. Geological Survey Open File Report 92–527
  • Macedo , E.A. , Weidlich , U. , Gmehling , J. and Rasmussen , P. 1983 . Vapor‐liquid equilibria by UNIFAC group contribution. III. Revision and extension . Ind. Eng. Chem. Process Des. Dev. , 22 : 676 – 684 .
  • Mackay , D. 1991 . Multimedia Environmental Models: The Fugacity Approach , Chelsea, MI : Lewis Press .
  • Mackay , D. and Shiu , W.Y. 1981 . A critical review of Henry's law constants for chemicals of environmental interest . J. Phys. Chem. Ref. Data , 10 (4) : 1175 – 1199 .
  • Mackay , D. , Shiu , W.Y. and Sutherland , R.P. 1979 . Determination of air‐water Henry's law constants for hydrophobic pollutants . Environ. Sci. Technol. , 13 (3) : 333 – 337 .
  • Masterton , W.L. 1975 . Salting coefficients for gases in seawater from scaled‐particle theory . J. Solution Chem. , 4 (6) : 523 – 534 .
  • McAulife , C. 1971 . GC determination of solutes by multiple phase equilibration . Chem. Technol. , 1 : 46 – 51 .
  • Meylan , W.M. and Howard , P.H. 1991 . Bond contribution method for estimating Henry's law constants . Environ. Toxicol. Chem. , 10 : 1283 – 1293 .
  • Munz , C. 1985 . Air‐Water Phase Equilibria and Mass Transfer of Volatile Organic Solutes , California : Department of Civil Engineering, Stanford University . Ph.D. thesis
  • Munz , C. and Roberts , P.V. 1987 . Air‐water phase equilibria of volatile organic solutes . J. Am. Water Works Assoc. , 79 (5) : 62 – 69 .
  • Murphy , T.J. , Mullin , M.D. and Meyer , J.A. 1987 . Equilibration of polychlorinated biphenyls and toxaphene with air and water . Environ. Sci. Technol. , 21 (2) : 155 – 162 .
  • Nicholson , B.C. , Maguire , B.P. and Bursill , D.B. 1984 . Henry's law constants for the trihalomethanes: Effect of water composition and temperature . Environ. Sci. Technol. , 18 (3) : 518 – 521 .
  • Nirmalakhandan , N.N. and Speece , R.E. 1988 . QSAR model for predicting Henry's constant . Environ. Sci. Technol. , 22 (11) : 1349 – 1357 .
  • Orbey , H. and Sandier , S.I. 1991 . Relative measurements of activity coefficients at infinite dilution by gas chromatography . Ind. Eng. Chem. Res. , 30 : 2006 – 2011 .
  • Prausnitz , J.M. 1969 . Molecular Thermodynamics of Fluid‐Phase Equilibria , Englewood Cliffs, NJ : Prentice‐Hall .
  • Przyjazny , A. , Janicki , W. , Chrzanowski , W. and Staszewsji , R. 1983 . Headspace gas chromatographic determination of distribution coefficients of selected organosulphur compounds and their dependence on some parameters . J. Chromatogr. , 280 : 249 – 260 .
  • Reid , R.C. 1987 . The Properties of Gases and Liquids , 4th ed. , New York : McGraw‐Hill .
  • Robbins , G.A. , Wang , S. and Stuart , J.D. 1993 . Using the static headspace method to determine Henry's law constants . Anal. Chem. , 65 : 3113 – 3118 .
  • Russell , C.J. , Dixon , S.L. and Jurs , P.C. 1992 . Computer‐assisted study of the relationship between molecular structure and Henry's law constant . Anal. Chem. , 64 : 1350 – 1355 .
  • Sabljic , A. and Gusten , H. 1989 . Predicting Henry's law constants for polychlorinated biphenyls . Chemosphere , 19 (10/11) : 1503 – 1511 .
  • Sagebiel , J.C. , Seiber , J.N. and Woodrow , J.E. 1992 . Comparison of headspace and gas‐stripping methods for determining the Henry's law constant (H) for organic compounds of low to intermediate H . Chemosphere , 25 (12) : 1763 – 1768 .
  • Schwarzenbach , R.P. , Gschwend , P.M. and Imboden , D.M. 1993 . Environmental Organic Chemistry , New York : John Wiley & Sons, Inc. .
  • Schwarzenbach , R.P. , Stieril , R. , Folsom , B.R. and Zeyer , J. 1988 . Compound properties relevant for assessing the environmental partitioning of nitrophenols . Environ. Sci. Technol. , 22 (1) : 83 – 92 .
  • Shaffer , D.L. and Daubert , T.E. 1969 . Gas‐liquid chromatographic determination of solution properties of oxygenated compounds in water . Anal. Chem. , 41 (12) : 1585 – 1589 .
  • Shiu , W.Y. , Doucette , W. , Gobas , F.A.P.C. , Andren , A. and Mackay , D. 1988 . Physical‐chemical properties of chlorinated dibenzo‐p‐dioxins . Environ. Sci. Technol. , 22 (6) : 651 – 658 .
  • Shiu , W.Y. and Mackay , D. 1986 . A critical review of aqueous solubilities, vapor pressures, Henry's law constants, and octanol‐water partition coefficients of the polychlorinated biphenyls . J. Phys. Chem. Ref. Data , 15 (2) : 911 – 929 .
  • Skjold‐Jorgensen , S. , Kolbe , B. , Gmehling , J. and Rasmussen , P. 1979 . Vapor‐liquid equilibria by UNIFAC group contribution. Revision and extension . Ind. Eng. Chem. Process Des. Dev. , 18 (4) : 714 – 722 .
  • Smith , J.M. and VanNess , H.C. 1987 . Introduction to Chemical Engineering Thermodynamics , 4th ed. , New York : McGraw‐Hill .
  • Soave , G.S. , Bertucco , A. and Vecchiato , L. 1994 . Equation‐of‐state group contributions from infinite‐dilution activity coefficients . Ind. Eng. Chem. Res. , 33 : 975 – 980 .
  • Stelmachowski , M. and Ledakowicz , S. 1993 . Prediction of Henry's constants by the UNIFAC‐FV model for hydrocarbon gases and vapors in high‐boiling hydrocarbon solvents . Fluid Phase Equil. , 90 : 205 – 217 .
  • Suntio , L.R. , Shiu , W.Y. and Mackay , D. 1988a . A review of the nature and properties of chemicals present in pulp mill effluents . Chemosphere , 17 (7) : 1249 – 1290 .
  • Suntio , L.R. , Shiu , W.Y. , Mackay , D. , Seiber , J.N. and Glotfelty , D. 1988b . Critical review of Henry's law constants for pesticides . Rev. Environ. Contam. Toxicol. , 103 : 1 – 59 .
  • Suzuki , T. , Ohtaguchi , K. and Koide , K. 1992 . Application of principal components analysis to calculate Henry's constant from molecular structure . Comput. Chem. , 16 (1) : 41 – 52 .
  • Tancrede , M.V. and Yanagisawa , Y. 1990 . An analytical method to determine Henry's law constant for selected volatile organic compounds at concentrations and temperatures corresponding to tap water use . J. Air Waste Manage. Assoc. , 40 (12) : 1658 – 1663 .
  • Tiegs , D. , Gmehling , J. , Rasmussen , P. and Fredenslund , A. 1987 . Vapor‐liquid equilibria by UNIFAC group contribution. IV. Revision and extension . Ind. Eng. Chem. Res. , 26 : 159 – 161 .
  • Tse , G. , Orbey , H. and Sandier , S.I. 1992 . Infinite dilution activity coefficients and Henry's law coefficients of some priority water pollutants determined by a relative gas chromatographic method . Environ. Sci. Technol. , 26 (10) : 2017 – 2022 .
  • Tucker , E.E. and Christian , S.D. 1979 . A prototype hydrophobic interaction. The dimerization of benzene in water . J. Phys. Chem. , 83 (3) : 426 – 427 .
  • USEPA . 1982 . Air and Steam Stripping of Toxic Pollutants , Tech. Rep. EPA‐68–03–002 Cincinnati, OH : Industrial Environmental Research Laboratory .
  • Valsaraj , K.T. and Thibodeaux , L.J. 1989 . Relationships between micelle‐water and octanol‐water partition constants for hydrophobic organics of environmental interest . Water Res. , 23 (2) : 183 – 189 .
  • Weidlich , U. and Gmehling , J. 1987 . A modified UNIFAC model. Prediction of VLE, hE and . Ind. Eng. Chem. Res. , 26 : 1372 – 1381 .
  • Wright , D.A. , Sandier , S.I. and DeVoll , D. 1992 . Infinite dilution activity coefficients and solubilities of halogenated hydrocarbons in water at ambient temperatures . Environ. Sci. Technol. , 26 (9) : 1828 – 1831 .
  • Yalkowsky , S.H. 1979 . Estimation of entropies of fusion of organic compounds . Ind. Eng. Chem. Fundam. , 18 (2) : 108 – 111 .
  • Yaws , C. , Yang , H. and Pan , X. 1991 . Henry's law constants for 362 organic compounds in water . Chem. Eng. , 98 (11) : 179 – 185 .
  • Yin , C. and Hassett , J.P. 1986 . Gas‐partitioning approach for laboratory and field studies of mirex fugacity in water . Environ. Sci. Technol. , 20 (12) : 1213 – 1217 .
  • Yurteri , C. , Ryan , D.F. , Callow , J.J. and Gurol , M.D. 1987 . The effect of chemical composition of water on Henry's law constant . J. Water Pollut. Control Fed. , 59 (11) : 950 – 956 .
  • Zhou , X. and Mopper , K. 1990 . Apparent partition coefficients of 15 carbonyl compounds between air and seawater and between air and freshwater; implications for air‐sea exchange . Environ. Sci. Technol. , 24 (12) : 1864 – 1869 .

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.