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Materials Research Innovations Volume 24, 2020 - Issue 7
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Research Article

Preparation of branched polystyrene via atom transfer radical polymerisation using diene with electron-rich double bond

Wenyan Huanga Jiangsu Key Laboratory of Environmentally Friendly Polymeric Materials, School of Materials Science and Engineering, Jiangsu Collaborative Innovation Center of Photovolatic Science and Engineering, Changzhou University, Changzhou, ChinaORCID Iconhttps://orcid.org/0000-0003-2809-3774View further author information
ORCID Icon,
Haiyan Wua Jiangsu Key Laboratory of Environmentally Friendly Polymeric Materials, School of Materials Science and Engineering, Jiangsu Collaborative Innovation Center of Photovolatic Science and Engineering, Changzhou University, Changzhou, ChinaView further author information
,
Yi Fana Jiangsu Key Laboratory of Environmentally Friendly Polymeric Materials, School of Materials Science and Engineering, Jiangsu Collaborative Innovation Center of Photovolatic Science and Engineering, Changzhou University, Changzhou, ChinaView further author information
,
Xiaoqiang Xuea Jiangsu Key Laboratory of Environmentally Friendly Polymeric Materials, School of Materials Science and Engineering, Jiangsu Collaborative Innovation Center of Photovolatic Science and Engineering, Changzhou University, Changzhou, ChinaView further author information
,
Hongjun Yanga Jiangsu Key Laboratory of Environmentally Friendly Polymeric Materials, School of Materials Science and Engineering, Jiangsu Collaborative Innovation Center of Photovolatic Science and Engineering, Changzhou University, Changzhou, ChinaView further author information
,
Li Jianga Jiangsu Key Laboratory of Environmentally Friendly Polymeric Materials, School of Materials Science and Engineering, Jiangsu Collaborative Innovation Center of Photovolatic Science and Engineering, Changzhou University, Changzhou, ChinaView further author information
,
Qimin Jianga Jiangsu Key Laboratory of Environmentally Friendly Polymeric Materials, School of Materials Science and Engineering, Jiangsu Collaborative Innovation Center of Photovolatic Science and Engineering, Changzhou University, Changzhou, ChinaView further author information
&
Bibiao Jianga Jiangsu Key Laboratory of Environmentally Friendly Polymeric Materials, School of Materials Science and Engineering, Jiangsu Collaborative Innovation Center of Photovolatic Science and Engineering, Changzhou University, Changzhou, China;b Changzhou University Huaide College, Jingjiang, ChinaCorrespondence[email protected]
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Pages 447-451 | Received 26 Aug 2020, Accepted 07 Sep 2020, Published online: 16 Sep 2020

References

  • VoitandA Lederer: BI. Hyperbranched and highly branched polymer architectures – synthetic strategies and major characterization aspects. Chem Rev. 2009;109:5924–5973.
  • Haidan G, Wenyan H, Dongliang Z, et al. Studies on the development of branching in ATRP of styrene and acrylonitrile in the presence of divinylbenzene. Polymer. 2008;49:4101–4108.
  • Ren Q, Gong F, Liu C, et al. Synthesis of branched polystyrene by ATRP exploiting divinylbenzene as branching comonomer. Eur Polym J. 2006;42:2573–2580.
  • Gong F, Tang H, Liu C, et al. Preparation of hyperbranched polymers through ATRP of in situ formed AB* monomer. J Appl Polym Sci. 2006;101:850–856.
  • Huang W, Sun P, Xue X, et al. Studies on the branching atom transfer radical polymerization using different divinyl monomers as the branching agent. Acta Polymerica Sinica. 2011;011:1253–1257.
  • Fréchet J, Henmi M, Gitsov I, et al. Self-condensing vinyl polymerization: an approach to dendritic materials. Science. 1995;269:1080–1083.
  • Gaynor S, Edelman S, Matyjaszewski K. Synthesis of branched and hyperbranched polystyrenes. Macromolecules. 1996;29:1079–1081.
  • Matyjaszewski K, Gaynor SG, Kulfan A, et al. Preparation of hyperbranched polyacrylates by atom transfer radical polymerization. 1. Acrylic AB* Monomers in “Living” Radical Polymerizations. Macromolecules. 1997;30:5192–5194.
  • Alfurhood J, Sun H, Bachler P, et al. Hyperbranched poly(N-(2-hydroxypropyl) methacrylamide) via RAFT self-condensing vinyl polymerization. Polym Chem. 2016;7:2099–2104.
  • Baskaran D. Hyperbranched polymers from divinylbenzene and 1,3-diisopropenylbenzene through anionic self-condensing vinyl polymerization. Polymer. 2003;44:2213–2220.
  • Burchard W. Solution properties of branched macromolecules. Adv Polym Sci. 1999;143:114–194.
  • Saunders G, Cormack P, Graham S, et al. Use of rapid triple detection size exclusion chromatography to evaluate the evolution of molar mass and branching architecture during free radical branching copolymerization of methyl methacrylate and ethylene glycol dimethacrylate. Macromolecules. 2005;38:6418–6422.
  • Burchard W, Schmidt M, Stockmayer W. Information on polydispersity and branching from combined quasi-elastic and integrated scattering. Macromolecules. 1980;13:1265–1272.
  • Huang W, Yang H, Xue X, et al. Polymerization behaviors and polymer branching structures in ATRP of monovinyl and divinyl monomers. Polym Chem. 2013;4:3204–3211.
  • Huang W, Gu W, Yang H, et al. Preparation and properties of branched polystyrene through radical suspension polymerization. Polymers. 2017;9:14.
  • Nikos H, Xenidou M, Iatrou H, et al. Well-defined, model long chain branched polyethylene. 1. synthesis and characterization. Macromolecules. 2000;33:2424–2436.
  • ScholteandN TG, Meijerink LJ. Gel permeation chromatography on branched polymers. Br Polym J. 1977;9:133–139.
  • TackxandJ P, Tacx CJF. Chain architecture of LDPE as a function of molar mass using size exclusion chromatography and multi-angle laser light scattering (SEC-MALLS). Polymer. 1998;39:3109–3113.

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