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Original Articles

Thermal Reduction of Graphene Oxide in Organic Solvents for Producing Colloidal Suspensions of Reduced Graphene Oxide Sheets

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Pages 901-915 | Published online: 05 Nov 2013

References

  • Geim , A.K. and Novoselov , K.S. 2007 . The rise of graphene . Nat. Mater. , 6 : 183 – 191 .
  • Lee , C. , Wei , X.D. , Kysar , J.W. and Hone , J. 2008 . Measurement of the elastic properties and intrinsic strength of monolayer graphene . Science , 321 : 385 – 388 .
  • Zhang , Y. , Tan , Y.W. , Stormer , H.L. and Kim , P. 2005 . Experimental observation of the quantum Hall effect and Berry's phase in graphene . Nature , 438 : 201 – 204 .
  • Balandin , A.A. , Ghosh , S. , Bao , W. , Calizo , I. , Teweldebrhan , D. , Miao , F. and Lau , C.N. 2008 . Superior thermal conductivity of single-layer graphene . Nano Lett. , 8 : 902 – 907 .
  • Dikin , D.A. , Stankovich , S. , Zimney , E.J. , Piner , R.D. , Dommett , G.H. , Evmenenko , G. , Nguyen , S.T. and Ruoff , R.S. 2007 . Preparation and characterization of graphene oxide paper . Nature , 448 : 457 – 460 .
  • Li , D. , Muller , M.B. , Gilje , S. , Kaner , R.B. and Wallace , G.G. 2008 . Processable aqueous dispersions of graphene nanosheets . Nat. Nanotechnol. , 3 : 101 – 105 .
  • Watcharotone , S. , Dikin , D.A. Stankovich , S. 2007 . Graphene-silica composite thin films as transparent conductors . Nano Lett. , 7 : 1888 – 1892 .
  • Wang , X. , Zhi , L.J. and Mullen , K. 2008 . Transparent, conductive graphene electrodes for dye-sensitized solar cells . Nano Lett. , 8 : 323 – 327 .
  • Park , S. , Lee , K.S. , Bozoklu , G. , Cai , W. , Nguyen , S.T. and Ruoff , R.S. 2008 . Graphene oxide papers modified by divalent ions-enhancing mechanical properties via chemical cross-linking . ACS Nano. , 2 : 572 – 578 .
  • Stankovich , S. , Piner , R.D. , Nguyen , S.T. and Ruoff , R.S. 2006 . Synthesis and exfoliation of isocyanate-treated graphene oxide nanoplatelets . Carbon , 44 : 3342 – 3347 .
  • Stankovich , S. , Piner , R.D. , Chen , X. , Wu , N. , Nguyen , S.T. and Ruoff , R.S. 2006 . Stable aqueous dispersions of graphitic nanoplatelets via the reduction of exfoliated graphite oxide in the presence of poly(sodium 4-styrenesulfonate) . J. Mater. Chem. , 16 : 155 – 158 .
  • Paredes , J.I. , Villar-Rodil , S. , Martinez-Alonso , A. and Tascon , J.M.D. 2008 . Graphene oxide dispersions in organic solvents . Langmuir , 24 : 10560 – 10564 .
  • Stankovich , S. , Dikin , D.A. , Piner , R.D. , Kohlhaas , K.A. , Kleinhammes , A. , Jia , Y. , Wu , Y. , Nguyen , S.T. and Ruoff , R.S. 2007 . Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide . Carbon , 45 : 1558 – 1565 .
  • Park , S. , An , J. , Jung , I. , Piner , R.D. , An , S.J. , Li , X. , Velamakanni , A. and Ruoff , R.S. 2009 . Colloidal suspensions of highly reduced graphene oxide in a wide variety of organic solvents . Nano Lett. , 9 : 1593 – 1597 .
  • Lomeda , J.R. , Doyle , C.D. , Kosynkin , D.V. , Hwang , W.F. and Tour , J.M. 2008 . Diazonium functionalization of surfactant-wrapped chemically converted graphene sheets . J. Am. Chem. Soc. , 130 : 16201 – 16206 .
  • Tung , V.C. , Allen , M.J. , Yang , Y. and Kaner , R.B. 2009 . High-throughput solution processing of large-scale graphene . Nat. Nanotechnol. , 4 : 25 – 29 .
  • Stankovich , S. , Dikin , D.A. , Dommett , G.H. , Kohlhass , K.M. , Zimney , E.J. , Stach , E.A. , Piner , R.D. , Nguyen , S.T. and Ruoff , R.S. 2006 . Graphene-based composite materials . Nature , 442 : 282 – 286 .
  • Wang , G.X. , Yang , J. , Park , J. , Gou , X. , Wang , B. , Liu , H. and Yao , J. 2008 . Facile synthesis and characterization of graphene nanosheets . J. Phys. Chem. C , 112 : 8192 – 8195 .
  • Si , Y. and Samulski , E.T. 2008 . Synthesis of water soluble graphene . Nano Lett. , 8 : 1679 – 1682 .
  • Muszynski , R. , Seger , B. and Kamat , P.V. 2008 . Decorating graphene sheets with gold nanoparticles . J. Phys. Chem. C , 112 : 5263 – 5266 .
  • Schniepp , H.C. , Li , J.L. , McAllister , M.J. , Sai , H. , Herrera-Alonso , M. , Adamson , D.H. , Prud'homme , R.K. , Car , R. , Saville , D.A. and Aksay , I.A. 2006 . Functionalized single graphene sheets derived from splitting graphite oxide . J. Phys. Chem. B , 110 : 8535 – 8539 .
  • McAllister , M.J. , Li , J.L. , Adamson , D.H. , Schniepp , H.C. , Abdala , A.A. , Liu , J. Herrera-Alonso , M. 2007 . Single sheet functionalized graphene by oxidation and thermal expansion of graphite . Chem. Mat. , 19 : 4396 – 4404 .
  • Jeong , H.H. , Lee , Y.P. , Jin , M.H. , Kim , E.S. , Bae , J.J. and Lee , Y.H. 2009 . Thermal stability of graphite oxide . Chem. Phys. Lett. , 470 : 255 – 258 .
  • Yang , D.X. , Velamakanni , A. , Bozoklu , G. , Park , S. , Stoller , M. , Piner , R.D. Stankovich , S. 2009 . Chemical analysis of graphene oxide films after heat and chemical treatments by X-ray photoelectron and Micro-Raman spectroscopy . Carbon , 47 : 145 – 152 .
  • Barroso-Bujans , F. , Cerveny , S. , Verdejo , R. , del Val , J.J. , Alberdi , J.M. , Alegria , A. and Colmenero , J. 2010 . Permanent adsorption of organic solvents in graphite oxide and its effect on the thermal exfoliation . Carbon , 48 : 1079 – 1087 .
  • Hummers , W.S. and Offeman , R.E. 1958 . Preparation of graphitic oxide . J. Am. Chem. Soc. , 80 : 1339 – 1339 .
  • Gu , W. , Zhang , W. , Li , X. , Zhu , H. , Wei , J. , Li , Z. Shu , Q. 2009 . Graphene sheets from worm-like exfoliated graphite . J. Mater. Chem. , 19 : 3367 – 3369 .
  • Park , S. , An , J. , Piner , R.D. , Jung , I. , Yang , D. , Velamakanni , A. , Nguyen , S.T. and Ruoff , R.S. 2008 . Aqueous suspension and characterization of chemically modified graphene sheets . Chem. Mat. , 20 : 6592 – 6594 .
  • Chen , H. , Muller , M.B. , Gilmore , K.J. , Wallace , G.G. and Li , D. 2008 . Mechanically strong, electrically conductive and biocompatible graphene paper . Adv. Mater. , 20 : 3557 – 3561 .
  • Hernandez , Y. , Nicolosi , V. , Lotya , M. , Blighe , F.M. , Sun , Z. , De , S. McGovern , I.T. 2008 . High-yield production of graphene by liquid-phase exfoliation of graphite . Nat. Nanotechnol. , 3 : 563 – 568 .
  • Akhavan , O. 2010 . The effect of heat treatment on formation of graphene thin films from graphene oxide nanosheets . Carbon , 48 : 509 – 519 .
  • Ferrarri , A.C. , Meyer , J.C. , Scardaci , V. , Casiraghi , C. , Lazzeri , M. , Mauri , F. Piscanec , S. 2006 . Raman spectrum of graphene and graphene layers . Phys. Rev. Lett. , 97 : 1 – 4 .
  • Wang , H. , Robinson , J.T. , Li , X. and Dai , H. 2009 . Solvothermal reduction of chemically exfoliated graphene sheets . J. Am. Chem. Soc. , 131 : 9910 – 9911 .
  • Ruoff , R.S. , Tse , D.S. , Malhotra , R. and Lorents , D.C. 1993 . Solubility of fullerene (C60) in a variety of solvents . J. Phys. Chem. , 97 : 3379 – 3383 .
  • Ausman , K.D. , Piner , R. , Lourie , O. , Ruoff , R.S. and Korobov , M. 2000 . Organic solvent dispersions of single-walled carbon nanotubes: toward solutions of pristine nanotubes . J. Phys. Chem. B , 104 : 8911 – 8915 .
  • Hansen , C.M. 2007 . Hansen Solubility Parameters: A User's Handbook , NJ : CRC Press: Hoboken .
  • Hernandez , Y. , Lotya , M. , Rickard , D. , Bergin , S.D. and Coleman , J.N. 2009 . Measurement of multicomponent solubility parameters for graphene facilitates solvent discovery . Langmuir , 26 : 3208 – 3213 .
  • Mkhoyan , K.A. , Contryman , A.W. , Silcox , J. , Stewart , D.A. , Eda , G. , Mattevi , C. , Miller , S. and Chhowalla , M. 2009 . Atomic and electronic structure of graphene-oxide . Nano Lett. , 9 : 1058 – 1063 .

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