References
- Koch, A. S.; Khemani, K. C.; Wudl, F. Preparation of Fullerenes with a Simple Benchtop Reactor. J. Org. Chem. 1991, 56, 4543–4545. DOI: https://doi.org/10.1021/jo00014a041.
- Craig, N. C.; Gee, G. C.; Johnson, A. R. C60 and C70 Made Simply. J. Chem. Educ. 1992, 69, 664–666. DOI: https://doi.org/10.1021/ed069p664.
- Bubnov, V. P.; Krainskii, I. S.; Laukhina, E. E.; Yagubskii, E. B. Production of Carbon Soot with a High Content of C60 and C70 Fullerenes by Electric Arc. Russ. Chem. Bull. 1994, 43, 746–750. DOI: https://doi.org/10.1007/BF00717331.
- Marković, Z. M.; Jokić, T. L.; Todorović-Marković, B. M.; Bianuša, J. L.; Nenadovic, T. M. Model of Improved Arc Generator for Fullerene Production. Fullerenes Nanot. Carbon Nanostruct. 1997, 5, 903–918. DOI: https://doi.org/10.1080/15363839708013306.
- Langer, J. J.; Golczak, S.; Żabiński, S.; Gibiński, T. Fullerenes and Carbon Nanotubes Formed in an Electric Arc at and above Atmospheric Pressure. Fullerenes Nanot. Carbon Nanostruct. 2004, 12, 593–602. DOI: https://doi.org/10.1081/FST-200026944.
- Dudnik, A. I.; Osipova, I. V.; Nikolaev, N. S.; Churilov, G. N. Comparative Analysis of Two Methods for Synthesis of Fullerenes at Different Helium Pressures. Fullerenes Nanot. Carbon Nanostruct. 2020, 28, 697–701. DOI: https://doi.org/10.1080/1536383X.2020.1746281.
- Churilov, G.; Popov, A.; Vnukova, N.; Dudnik, A.; Samoylova, N.; Glushenko, G. Controlled Synthesis of Fullerenes and Endohedral Metallofullerenes in High Frequency Arc Discharge. Fullerenes Nanot. Carbon Nanostruct. 2016, 24, 675–678. DOI: https://doi.org/10.1080/1536383X.2016.1207062.
- Harris, P. J. Carbon Nanotube Science: Synthesis, Properties and Applications. Cambridge University Press: Cambridge, UK, 2009.
- Roslan, M. S.; Chaudary, K. T.; Haider, Z.; Aziz, M. S.; Ali, J. Multi-Walled Carbon Nanotubes Grow under Low Pressure Hydrogen, Air, and Argon Ambient by Arc Discharge Plasma. Fullerenes Nanot. Carbon Nanostruct. 2017, 25, 269–272. DOI: https://doi.org/10.1080/1536383X.2017.1285287.
- Grebenyukov, V. V.; Obraztsova, E. D.; Pozharov, A. S.; Arutyunyan, N. R.; Romeikov, A. A.; Kozyrev, I. A. Arc‐Synthesis of Single‐Walled Carbon Nanotubes in Nitrogen Atmosphere. Fullerenes Nanot. Carbon Nanostruct. 2008, 16, 330–334. DOI: https://doi.org/10.1080/15363830802219849.
- Zhao, X.; Zhao, T.; Peng, X.; Hu, J.; Yang, W. Catalyst Effect on the Preparation of Single-Walled Carbon Nanotubes by a Modified Arc Discharge. Fullerenes Nanot. Carbon Nanostruct. 2019, 27, 52–57. DOI: https://doi.org/10.1080/1536383X.2018.1492560.
- Bystrzejewski, M.; Lange, H.; Huczko, A.; Ruemmeli, M.; Gemming, T.; Pichler, T. Synthesis of Heterogeneous Multi‐Walled Carbon Nanotubes in a Carbon Arc in Water. Fullerenes Nanot. Carbon Nanostruct. 2006, 14, 207–213. DOI: https://doi.org/10.1080/15363830600728066.
- Lange, H. Spectral Diagnostics of Helium-Carbon Arc Plasma during Carbon Nanostructure Formation. Fullerenes Nanot. Carbon Nanostruct. 1997, 5, 1177–1201. DOI: https://doi.org/10.1080/15363839708009605.
- Todorović‐Marković, B.; Marković, Z.; Nikolić, Z.; Ristić, Z.; Nenadović, T. Optical Emission Measurements of Rotational Temperature of C2 Radicals in Fullerene Processing. Fullerenes Nanot. Carbon Nanostruct. 2004, 12, 647–657. DOI: https://doi.org/10.1081/FST-200026952.
- Baskakova, K. I.; Sedelnikova, O. V.; Lobiak, E. V.; Plyusnin, P. E.; Bulusheva, L. G.; Okotrub, A. V. Modification of Structure and Conductivity of Nanohorns by Toluene Addition in Carbon Arc. Fullerenes Nanot. Carbon Nanostruct. 2020, 28, 342–347. DOI: https://doi.org/10.1080/1536383X.2019.1708737.
- Ruan, C.; Lian, Y. Purification of Carbon Nano-Onions Fabricated by Arc Discharge. Fullerenes Nanot. Carbon Nanostruct. 2015, 23, 488–493. DOI: https://doi.org/10.1080/1536383X.2013.863763.
- Li, Z.; Zhang, D.; Ruan, C.; Zhao, H.; Wang, Y.; Lian, Y. A Sector Deposition Mechanism of Carbon Onions Operated in a Large Discharge Furnace. Fullerenes Nanot. Carbon Nanostruct. 2021, 29, 156–162. DOI: https://doi.org/10.1080/1536383X.2020.1824184.
- Cataldo, F.; Valentini, F.; Cherubini, V.; Ursini, O.; Angelini, G. Synthesis of Expanded Graphite Flakes by the Submerged Carbon Arc in Oleum. Fullerenes Nanot. Carbon Nanostruct. 2012, 20, 152–162. DOI: https://doi.org/10.1080/1536383X.2010.533303.
- Kesarwani, A. K.; Panwar, O. S.; Dhakate, S. R.; Singh, V. N.; Rakshit, R. K.; Bisht, A.; Kumar, A. Determining the Number of Layers in Graphene Films Synthesized by Filtered Cathodic Vacuum Arc Technique. Fullerenes Nanot. Carbon Nanostruct. 2016, 24, 725–731. DOI: https://doi.org/10.1080/1536383X.2016.1168406.
- Cataldo, F. Soot and Other Products Formation from the Submerged Carbon Arc in Halogenated Solvents. Fullerenes Nanot. Carbon Nanostruct. 2005, 13, 239–257. DOI: https://doi.org/10.1081/FST-200056248.
- García-Hernández, D. A.; Manchado, A.; Gemmi, M.; Mugnaioli, E.; Fabbri, F.; Pascale, S.; Cataldo, F. Raman, FT-IR Spectroscopy and Morphology of Carbon Dust from Carbon Arc in Liquid Benzene. Fullerenes Nanot. Carbon Nanostruct. 2018, 26, 654–660. DOI: https://doi.org/10.1080/1536383X.2018.1461623.
- Cataldo, F.; García-Hernández, D. A.; Manchado, A. Submerged Carbon Arc in Liquid Benzene: GC-MS Analysis of the Products. Fullerenes Nanot. Carbon Nanostruct. 2017, 25, 576–584. DOI: https://doi.org/10.1080/1536383X.2017.1345885.
- Cataldo, F.; García-Hernández, D. A.; Manchado, A. Toluene Pyrolysis in an Electric Arc: Products Analysis. Fullerenes Nanot. Carbon Nanostruct. 2019, 27, 469–477. DOI: https://doi.org/10.1080/1536383X.2019.1576639.
- Schermann, G.; Grösser, T.; Hampel, F.; Hirsch, A. Dicyanopolyynes: A Homologuous Series of End‐Capped Linear sp Carbon. Chem. Eur. J. 1997, 3, 1105–1112. DOI: https://doi.org/10.1002/chem.19970030718.
- Cataldo, F. Synthesis of Polyynes in a Submerged Electric Arc in Organic Solvents. Carbon. 2004, 42, 129–142. DOI: https://doi.org/10.1016/j.carbon.2003.10.016.
- Cataldo, F. Polyynes Production in a Solvent‐Submerged Electric Arc between Graphite Electrodes. I. Synthesis and Spectroscopy. Fullerenes Nanot. Carbon Nanostruct. 2004, 12, 603–617. DOI: https://doi.org/10.1081/FST-200026947.
- Cataldo, F. Polyynes Production in a Solvent‐Submerged Electric Arc between Graphite Electrodes II. Analysis by Liquid Chromatography. Fullerenes Nanot. Carbon Nanostruct. 2004, 12, 619–631. DOI: https://doi.org/10.1081/FST-200026949.
- Cataldo, F. Polyynes Production in a Solvent‐Submerged Electric Arc between Graphite Electrodes. III. chemical Reactivity and Stability toward Air, Ozone, and Light. Fullerenes Nanot. Carbon Nanostruct. 2004, 12, 633–646. DOI: https://doi.org/10.1081/FST-200026951.
- Cataldo, F. Polyynes from Submerged Electric Arc. IV. Hydrogenation to Ene-Ynes. Fullerenes Nanot. Carbon Nanostruct. 2004, 12, 765–779. DOI: https://doi.org/10.1081/FST-200032890.
- Cataldo, F. Cyanopolyynes: Carbon Chains Formation in a Carbon Arc Mimicking the Formation of Carbon Chains in the Circumstellar Medium. Int. J. Astrobiol. 2004, 3, 237–246. DOI: https://doi.org/10.1017/S1473550404002149.
- Cataldo, F. Polyynes: A New Class of Carbon Allotropes. About the Formation of Dicyanopolyynes from an Electric Arc between Graphite Electrodes in Liquid Nitrogen. Polyhedron 2004, 23, 1889–1896. DOI: https://doi.org/10.1016/j.poly.2004.04.024.
- Cataldo, F. (Ed.). Polyynes: Synthesis, Properties, and Applications. CRC Press: Boca Raton, FL, 2005.
- Cataldo, F. Synthesis and Properties of Long Chains of sp‐Hybridized Carbon Atoms: Polyynes. Fullerenes Nanot. Carbon Nanostruct. 2005, 13, 77–82. DOI: https://doi.org/10.1081/FST-200039212.
- Cataldo, F. Synthesis of Polyynes with Electric Arc Part 5: Detection of PAHs as Minor Products. Fullerenes Nanot. Carbon Nanostruct. 2005, 13, 21–30. DOI: https://doi.org/10.1081/FST-200040750.
- Cataldo, F. Study of the Submerged Electric Arc in Hexane in Presence of C60 Fullerene. Fullerenes Nanot. Carbon Nanostruct. 2005, 13, 31–41. DOI: https://doi.org/10.1081/FST-200040752.
- Cataldo, F. Polyynes and Cyanopolyynes: Their Synthesis with the Carbon Arc Gives the Same Abundances Occurring in Carbon-Rich Stars. Orig. Life Evol. Biosph. 2006, 36, 467–475. DOI: https://doi.org/10.1007/s11084-006-9051-4.
- Cataldo, F.; Ursini, O.; Angelini, G. Kinetics of Polyynes Formation with the Submerged Carbon Arc. J. Electroanal. Chem. 2007, 602, 82–90. DOI: https://doi.org/10.1016/j.jelechem.2006.12.005.
- Cataldo, F. Synthesis of Polyynes from a Submerged Carbon Arc in Formamide: Some Implications on the Formation Mechanism. Fullerenes Nanot. Carbon Nanostruct. 2007, 15, 147–153. DOI: https://doi.org/10.1080/15363830601177834.
- Cataldo, F. Polyynes Formation from Electric Arc in Liquid Argon in Presence of Methane. Fullerenes Nanot. Carbon Nanostruct. 2007, 15, 291–301. DOI: https://doi.org/10.1080/15363830701423690.
- Cataldo, F. Storage Stability of Polyynes and Cyanopolyynes in Solution and the Effect of Ammonia or Hydrochloric Acid. Fullerenes Nanot. Carbon Nanostruct. 2007, 15, 155–166. DOI: https://doi.org/10.1080/15363830601179814.
- Cataldo, F. On the Action of Ozone on Polyynes and Monocyanopolyynes: Selective Ozonolysis of Polyynes. Fullerenes Nanot. Carbon Nanostruct. 2006, 14, 1–8. DOI: https://doi.org/10.1080/15363830500538607.
- Cataldo, F.; Keheyan, Y. Radiolysis of Polyynes in Heptane. Fullerenes Nanot. Carbon Nanostruct. 2006, 14, 83–91. DOI: https://doi.org/10.1080/15363830500538532.
- Cataldo, F.; Ursini, O.; Angelini, G.; Strazzulla, G. Polyynes Decomposition with γ Radiation. Fullerenes Nanot. Carbon Nanostruct. 2008, 16, 272–281. DOI: https://doi.org/10.1080/15363830802171859.
- Cataldo, F.; Strazzulla, G.; Iglesias-Groth, S. UV Photolysis of Polyynes at λ= 254 nm and at λ > 222 nm. Int. J. Astrobiol. 2008, 7, 107–116. DOI: https://doi.org/10.1017/S147355040800414X.
- Gruenberger, T. M.; Gonzalez‐Aguilar, J.; Fulcheri, L.; Okuno, H.; Charlier, J.‐C.; Fabry, F.; Grivei, E.; Probst, N.; Flamant, G. Tailor‐Made Carbon Nanomaterials for Bulk Applications via High‐Intensity Arc Plasma. Fullerenes Nanot. Carbon Nanostruct. 2005, 13, 67–75. DOI: https://doi.org/10.1081/FST-200039210.
- Rud, A. D.; Kuskova, N. I.; Ivaschuk, L. I.; Zelinskaya, G. M.; Biliy, N. M. Structure State of Carbon Nanomaterials Produced by High-Energy Electric Discharge Techniques. Fullerenes Nanot. Carbon Nanostruct. 2010, 19, 120–126. DOI: https://doi.org/10.1080/1536383X.2010.490129.
- Gillam, A. E.; Stern, E. S. 1954. An Introduction to Electronic Absorption Spectroscopy in Organic Chemistry. Edward Arnold Publishers: London; p 89.
- Georgieff, K. K.; Cave, W. T.; Blaikie, K. G. Acetylene Polymers: Preparation, Physical Properties, Infrared and Ultraviolet. Spectra 1. J. Am. Chem. Soc. 1954, 76, 5494–5499. DOI: https://doi.org/10.1021/ja01650a070.
- Cataldo, F. A Study on Ethylene and Acetylene Photoligomerization and Photopolymerization. J. Photochem. Photobiol. A Chem. 1996, 99, 75–81. DOI: https://doi.org/10.1016/1010-6030(96)04356-0.
- Petrov, A. A. Vinylacetylene and Its Homologues. Russ. Chem. Rev. 1960, 29, 489–509. DOI: https://doi.org/10.1070/RC1960v029n09ABEH001249.
- Dean, J. A. 1992. Lange's Handbook of Chemistry. McGraw-Hill: New York.
- Cataldo, F.; Casari, C. S. Synthesis, Structure and Thermal Properties of Copper and Silver Polyynides and Acetylides. J. Inorg. Organomet. Polym. 2007, 17, 641–651. DOI: https://doi.org/10.1007/s10904-007-9150-3.
- Cataldo, F. The Role of Raman Spectroscopy in the Research on sp‐Hybridized Carbon Chains: Carbynoid Structures Polyynes and Metal Polyynides. J. Raman Spectrosc. 2008, 39, 169–176. DOI: https://doi.org/10.1002/jrs.1830.
- Cataldo, F.; Compagnini, G.; Scandurra, A.; Strazzulla, G. Silver and Copper Polyynides: A Study with HPLC, FT‐IR and XPS Spectroscopy. Fullerenes Nanot. Carbon Nanostruct. 2008, 16, 126–141. DOI: https://doi.org/10.1080/15363830801888024.
- Hennion, G. F.; Price, C. C.; McKeon, T. F. Jr, The Preparation of Vinylacetylene. J. Am. Chem. Soc. 1954, 76, 5160–5160. DOI: https://doi.org/10.1021/ja01649a054.
- Perkampus, H. H. 1992. UV-VIS Atlas of Organic Compounds, 2nd ed. VCH: Weinheim, Spectrum A4/1.
- Doddipatla, S.; Galimova, G. R.; Wei, H.; Thomas, A. M.; He, C.; Yang, Z.; Morozov, A. N.; Shingledecker, C. N.; Mebel, A. M.; Kaiser, R. I. Low-Temperature Gas-Phase Formation of Indene in the Interstellar Medium. Sci. Adv. 2021, 7, eabd4044. DOI: https://doi.org/10.1126/sciadv.abd4044.
- Whitlock, H. W., Jr.; Wu, E. M.; Whitlock, B. J. Role of Solvent Hydrogens in the Dehydro Diels-Alder Reaction. J. Org. Chem. 1969, 34, 1857–1859. DOI: https://doi.org/10.1021/jo01258a072.
- Wessig, P.; Müller, G. The Dehydro-Diels-Alder Reaction. Chem. Rev. 2008, 108, 2051–2063. DOI: https://doi.org/10.1021/cr0783986.
- Mebel, A. M.; Landera, A.; Kaiser, R. I. Formation Mechanisms of Naphthalene and Indene: From the Interstellar Medium to Combustion Flames. J. Phys. Chem. A. 2017, 121, 901–926. DOI: https://doi.org/10.1021/acs.jpca.6b09735.
- Zhao, L.; Kaiser, R. I.; Xu, B.; Ablikim, U.; Ahmed, M.; Evseev, M. M.; Bashkirov, E. K.; Azyazov, V. N.; Mebel, A. M. Low-Temperature Formation of Polycyclic Aromatic Hydrocarbons in Titan’s Atmosphere. Nat. Astron. 2018, 2, 973–979. DOI: https://doi.org/10.1038/s41550-018-0585-y.
- Cataldo, F. Polyynes and Cyanopolyynes Synthesis from the Submerged Electric Arc: About the Role Played by the Electrodes and Solvents in Polyynes Formation. Tetrahedron 2004, 60, 4265–4274. DOI: https://doi.org/10.1016/j.tet.2004.03.033.
- Fridman, A. Plasma Chemistry. Cambridge University Press: Cambridge, 2008; pp 199 and 589–602.
- Pechuro, N. S. (Ed.). Organic Reactions in Electrical Discharges. Springer Science: New York, 1968; pp 114–135.
- Cullis, C. F.; Franklin, N. H. The Pyrolysis of Acetylene at Temperatures from 500 to 1000° C. Proc. Roy. Soc. London. Series A. Mathem. Phys. Sci. 1964, 280, 139–152.
- Back, M. H. Mechanism of the Pyrolysis of Acetylene. Can. J. Chem. 1971, 49, 2199–2204. DOI: https://doi.org/10.1139/v71-359.
- Ogura, H. Pyrolysis of Acetylene behind Shock Waves. BCSJ. 1977, 50, 1044–1050. DOI: https://doi.org/10.1246/bcsj.50.1044.
- Benson, S. W. The Mechanism of the Reversible-Reaction: 2 C2H2 ⇌ Vinyl Acetylene and the Pyrolysis of Butadiene. Int. J. Chem. Kinet. 1989, 21, 233–243. DOI: https://doi.org/10.1002/kin.550210403.
- Kiefer, J. H.; Von Drasek, W. A.; Von Drasek, W. A. The Mechanism of the Homogeneous Pyrolysis of Acetylene. Int. J. Chem. Kinet. 1990, 22, 747–786. DOI: https://doi.org/10.1002/kin.550220710.
- Zador, J.; Fellows, M. D.; Miller, J. A. Initiation Reactions in Acetylene Pyrolysis. J. Phys. Chem. A. 2017, 121, 4203–4217. DOI: https://doi.org/10.1021/acs.jpca.7b03040.
- Grziwa, R.; Rosskamp, G.; Schindler, R. N. Reaktionen in Elektrischen Entladungen, I./Reactions in Electrical Discharges, I.: Ein Neues Verfahren Zur Kontinuierlichen Synthese Von Diacetylen/a New Method for the Continuous Preparation of Diacetylene. Zeitsch. Naturforsch. B. 1974, 29, 442–444. DOI: https://doi.org/10.1515/znb-1974-5-636.
- Wheeler, S. E.; Houk, K. N.; Schleyer, P. V. R.; Allen, W. D. A Hierarchy of Homodesmotic Reactions for Thermochemistry. J. Am. Chem. Soc. 2009, 131, 2547–2560. DOI: https://doi.org/10.1021/ja805843n.
- Green, D. W.; Southard, M. Z. 2008. Perry's Chemical Engineers' Handbook, 8th ed. McGraw-Hill Education: New York.
- Stamm, R. F.; Halverson, F.; Whalen, J. J. Fundamental Vibrational Frequencies and Thermodynamic Functions for Vinylacetylene, Revised Thermodynamic Functions for Hydrogen Cyanide, and Thermodynamics of Two Reactions Involved in the Synthesis of Acrylonitrile. J. Chem. Phys. 1949, 17, 104–105. DOI: https://doi.org/10.1063/1.1747040.