112
Views
6
CrossRef citations to date
0
Altmetric
Articles

Mechanical properties, morphology, Mullins effect and its reversibility of thermoplastic vulcanizates based on ethylene-acrylic acid copolymer/chloroprene rubber blends

, & ORCID Icon
Pages 400-409 | Received 28 Jan 2019, Accepted 23 Apr 2019, Published online: 06 May 2019

References

  • Paran, S.M.R., Naderi, G., and Ghoreishy, M.H.R. (2016) Effect of halloysite nanotube on microstructure, rheological and mechanical properties of dynamically vulcanized PA6/NBR thermoplastic vulcanizates. Soft Materials, 14(3):127–139. doi:10.1080/1539445X.2016.1157694
  • Riahi, F., Benachour, D., and Douibi, A. (2004) Dynamically vulcanized thermoplastic elastomer blends of natural rubber and polypropylene. International Journal of Polymeric Materials and Polymeric Biomaterials, 53(2):143–156. doi:10.1080/00914030490267564
  • Ismail, H., Galpaya, D., and Ahmad, Z. (2009) Effects of dynamic vulcanization on tensile properties, morphology and natural weathering of polypropylene/recycled acrylonitrile butadiene rubber (PP/NBR) blends. Polymer-Plastics Technology and Engineering, 49(1):110–119. doi:10.1080/03602550903159077
  • Gessler, A.M., and Haslett, W.H. (1962) Process for preparing a vulcanized blend of crystalline polypropylene and chlorinated butyl rubber. U.S, Pat: 3,037,954.
  • Fisher, K. (1973) Thermoplastic blend of partially cured monoolefin copolymer rubber and polyolefin plastic. U.S, Pat: 3,758,643.
  • Coran, A.Y., and Patel, R.P. (1980) Rubber-thermoplastic compositions: part I EPDM-polypropylene thermoplastic vulcanizates. Rubber Chemistry and Technology, 53(1):141–150. doi:10.5254/1.3535023
  • Coran, A.Y., Patel, R.P., and Williams, D. (1982) Rubber-thermoplastic compositions, Part V: selecting polymers for thermoplastic vulcanizates. Rubber Chemistry and Technology, 55(5):116–136. doi:10.5254/1.3535861
  • Kim, J.K., Lee, S.H., and Wang, S.H. (2003) Study on the thermoplastic vulcanizate using ultrasonically treated rubber powder. Journal of Applied Polymer Science, 90(9):2503–2507. doi:10.1002/(ISSN)1097-4628
  • Van Duin, M. (2006) Recent developments for EPDM-based thermoplastic vulcanizates. Macromolecular Symposia, 233(1):11–16. doi:10.1002/masy.200690006
  • Wang, Z.B., Yu, W.J., and Cheng, X.K. (2013) Mechanical and morphological properties of thermoplastic vulcanizates based on ethylene vinyl acetate copolymer and styrene butadiene rubber. Plastics Rubber and Composites, 40(5):229–233. doi:10.1179/1743289810Y.0000000029
  • Han, D.H., Choi, M.C., Jeong, G.H., and Kim, H.S. (2016) Properties of acrylonitrile butadiene rubber (NBR)/poly(lactic acid) (PLA) blends and their foams. Composite Interfaces, 23(8):1–10. doi:10.1080/09276440.2016.1170518
  • Ryu, S.R., and Lee, D.J. (2006) Effects of interphase on the mechanical properties of short-fiber reinforced rubber. Composite Interfaces, 13(2–3):173–187. doi:10.1163/156855406775997024
  • Scaffaro, R., La Mantia, F.P., and Castronovo, C. (2004) Reactive compatibilization of PBT/EVA blends with an ethylene–acrylic acid copolymer and a low molar mass bis-oxazoline. Macromolecular Chemistry and Physics, 205(10):1402–1409. doi:10.1002/(ISSN)1521-3935
  • Scaffaro, R., La Mantia, F.P., and Canfora, L. (2003) Reactive compatibilization of PA6/LDPE blends with an ethylene-acrylic acid copolymer and a low molar mass bis-oxazoline. Macromolecular Chemistry and Physics, 44(22):6951–6957.
  • Liu, J.J., and Zhang, Y. (2011) Effect of ethylene-acrylic acid copolymer on flame retardancy and properties of LDPE/EAA/MH composites. Polymer Degradation and Stability, 96(12):2215–2220. doi:10.1016/j.polymdegradstab.2011.09.010
  • Kim, B., Lee, S.B., Lee, J., Cho, S., Park, H., and Yeom, S. (2012) A comparison among neo-hookean model, mooney-rivlin model, and ogden model for chloroprene rubber. International Journal of Precision Engineering and Manufacturing, 13(5):759–764. doi:10.1007/s12541-012-0099-y
  • Kuahara, H., Sudo, S., and Iijima, M. (2010) Dielectric properties of thermally degraded chloroprene rubber. Polymer Degradation and Stability, 95(12):2461–2466. doi:10.1016/j.polymdegradstab.2010.08.003
  • Qian, B.Z. (2010) Analysis of global CR market current situation. China Rubber, 26(4):10–13.
  • Zuo-Hua, L., Feng-Juan, Z., Jun, D.U., Xing, F., Zhao-Hong, Z., and Chang-Yuan, T. (2013) Experimental investigation on curing performance of neoprene rubber modified by BBr3. Journal of Functional Materials, 44(16):2393–2396.
  • Diani, J., Fayolle, B., and Gilormini, P. (2009) A review on the Mullins effect. European Polymer Journal, 45(3):601–612. doi:10.1016/j.eurpolymj.2008.11.017
  • Wang, C.C., Zhang, Y.F., and Wang, Z.B. (2015) Mechanical properties, morphology, and Mullins effect of thermoplastic vulcanizates based on ethylene–vinyl acetate copolymer/ethylene–vinyl acetate rubber. Journal of Thermoplastic Composite Materials, 30(6):1–13.
  • Mullins, L., and Tobin, N. (1957) Theoretical model for the elastic behavior of filler-reinforced vulcanized rubbers. Rubber Chemistry and Technology, 30(2):555–571. doi:10.5254/1.3542705
  • Boyce, M.C. (2001) Micro-mechanisms of deformation and recovery in thermoplastic vulcanizate. Journal of the Mechanics & Physics of Solids, 49(6):1323–1342. doi:10.1016/S0022-5096(00)00075-2
  • Oderkerk, J., and Groeninckx, G. (2002) Investigation of the deformation and recovery behavior of nylon-6/rubber thermoplastic vulcanizates on the molecular level by infrared-strain recovery measurements. Macromolecules, 35(10):3946–3954. doi:10.1021/ma010651v
  • Shi, Y.J., and Liu, F.F. (2018) Mullins effect and its reversibility for compatibilised thermoplastic elastomers based on high-density polyethylene/waste ground rubber tyre powder under compression mode. Plastics Rubber and Composites, 47(8):373–380. doi:10.1080/14658011.2018.1509041
  • Wang, Z.B., Zhao, H.L., Zhao, J., and Wang, X. (2011) Dynamically vulcanized styrene-butadiene rubber/ethylene-vinyl acetate copolymer/high impact polystyrene blends compatibilized by styrene-butadiene-styrene block copolymer. Journal of Macromolecular Science, 50(1):51–61. doi:10.1080/00222341003609468
  • Zhang, K., Zhao, J., Zhang, J.K., and Wang, Z.B. (2015) Compression Mullins effect and its reversibility of HDPM/EPDM thermoplastic vulcanizate. Special Purpose Rubber Products, 36(2):6–11.
  • Marckmann, G., Verron, E., Gornet, L., Chagnon, G., Charrier, P., and Fort, P. (2002) A theory of network alteration for the Mullins effect. Journal of the Mechanics & Physics of Solids, 50(9):2011–2028. doi:10.1016/S0022-5096(01)00136-3

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.