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Original Articles

Physico-Chemical Properties of New Liquid Crystals Incorporating a Lactone Ring

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Pages 209/[2075]-220/[2086] | Published online: 31 Aug 2006

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  • 4-Octyloxybiphenyl-4′-yl 4-cyanobenzoate (8OBCB) has a phase sequence of C•129•SmC•125•SmA•153•SmA•160•N•235•I (T/°C). The layer spacing of the SmA phase at high temperature region is 39.9 and 40.0 Å at 160 and 155°C, respectively, and those at low temperature region are 27.2 Å in the range between 151 and 125°C, and 27.5 Å at 120°C. Both reflection peaks co-exist in the temperature range between 140 and 160°C, and the relative intensity of both peaks notably varies without changing their positions. The layer spacings of 40.0 and 27.2 Å correspond to 1.48 and 1.0 times of the calculated molecular length (26.9 Å) . [CSA]
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