510
Views
26
CrossRef citations to date
0
Altmetric
Reviews

Comparing Branched versus Straight-chained Monoamide Extractants for Actinide Recovery

, & ORCID Icon
Pages 49-65 | Received 01 Oct 2015, Accepted 08 Apr 2017, Published online: 10 Jul 2017

REFERENCES

  • Nash, K. L. and Braley, J. C. (2010) Chemistry of radioactive materials in the nuclear fuel cycle. In Advanced Separation Techniques for nuclear fuel reprocessing and radioactive waste treatment. Nash, K. L., Lumetta, G. J., Eds.; Woodhead Publishing Series in Energy: Cambridge, Vol. 1046, 1–22.
  • Braley, J. C., Lumetta, G. J., and Carter, J. C. (2013) The TRUSPEAK concept: Combining CMPO and HDEHP for separating trivalent lanthanides from the transuranic elements. Solvent Extr. Ion Exch., 31 (6): 567–577.
  • Lanham, W. B. and Runion, T. C. (1949) PUREX Process for Plutonium and Uranium Recovery; Oak Ridge National Laboratory: Oak Ridge, TN.
  • Oliver, J. R. (1958) THOREX Process: Third Uranium Cycle Studies; Oak Ridge National Laboratory: Oak Ridge, TN.
  • Siddall, T. H. (1960) Effects of structure of N,N-disubstituted amides on their extraction of actinide and zirconium nitrates and of nitric acid. J. Phys. Chem. 64: 1863–1866.
  • Gasparini, G. M. and Grossi, G. (1980) Application of N,N-dialkyl aliphatic amides in the separation of some actinides. Sep. Sci. Technol., 15 (4): 825–844.
  • Musikas, C. (1987) Solvent extraction for the chemical separations of the 5f elements*. Inorg. Chim. Acta, 140: 197–206.
  • Pathak, P. N. (2014) N,N-dialkyl amides as extractants for spent fuel reprocessing: An overview. J. Radioanal. Nucl. Chem., 300 (1): 7–15.
  • Manchanda, V. K. and Pathak, P. N. (2004) Amides and diamides as promising extractants in the back end of the nuclear fuel cycle: An overview. Sep. Purif. Technol., 35 (2): 85–103.
  • Gasparini, G. M. and Grossi, G. (1986) Long chain disubstituted aliphatic amides as extracting agents in industrial applications of solvent extraction. Solvent Extr. Ion Exch., 4 (6): 1233–1271.
  • Lanigan, R. M. and Sheppard, T. D. (2013) Recent developments in amide synthesis: Direct amidation of carboxylic acids and transamidation reactions. Eur. J. Org. Chem., 33: 7453–7465.
  • Lanigan, R. M., Starkov, P., and Sheppard, T. D. (2013) Direct synthesis of amides from carboxylic acids and amines using B(OCH2CF3)3. J. Org. Chem., 78: 4512–4523.
  • Gooßen, L. J., Ohlmann, D. M., and Lange, P. P. (2009) The thermal amidation of carboxylic acids revisited. Synthesis (Stuttg)., 1: 160–164.
  • Thiollet, G. and Musikas, C. (1989) Synthesis and uses of the amides extractants. Solvent Extr. Ion Exch., 7 (5): 813–827.
  • Condamines, N. and Musikas, C. (1992) The extraction by N,N-dialkylamides II. Extraction of actinide cations. Solvent Extr. Ion Exch., 10 (1): 69–100.
  • Pathak, P. N., Veeraraghavan, R., Prabhu, D. R., Mahajan, G. R., and Manchanda, V. K. (1999) Separation studies of uranium and thorium using di-2-ethylhexyl isobutyramide (D2EHIBA). Sep. Sci. Technol., 34 (13): 2601–2614.
  • Pathak, P. N., Kumbhare, L. B., and Manchanda, V. K. (2001) Structural effects in N,N-dialkyl amides on their extraction behavior toward uranium and thorium. Solvent Extr. Ion Exch., 19 (1): 105–126.
  • Ardois, C., Mokili, M. B., Musikas, C., and Abb, J. C. (1999) The use of the N, N-diethyldodecanamide for actinide extraction in conjunction with liquid scintillation counting. J. Radioanal. Nucl. Chem., 240 (3): 751–761.
  • Gupta, K. K., Manchanda, V. K., Subramanian, M. S., and Singh, R. K. (2000) N'N-dihexyl hexanamide: A promising extractant for nuclear fuel reprocessing. Sep. Sci. Technol., 35 (10): 1603–1617.
  • Sato, T. (1958) The extraction of uranyl nitrate from nitric acid solutions by tributyl phosphate. J. Inorg. Nucl. Chem., 6 (1956): 1955–1958.
  • Condamines, N. and Musikas, C. (1988) The extraction by N,N-dialkylamides. I. HNO3 and other inorganic acids. Solvent Extr. Ion Exch., 6 (6): 1007–1034.
  • Chaiko, D. J. and Vandegrift, G. F. (1988) A thermodynamic model of nitric acid extraction by tri-​n-​butyl phosphate. Nucl. Technol., 82 (1): 52–59.
  • Yu, B. C., Guoxin, S., Zhenwei, Z., Yexin, L., and Sixiu, S. (2005) Extraction of U (VI) with unsymmetrical N-methyl-N-decylalkylamide in toluene. Radiochim. Acta, 290: 287–290.
  • Rodrigues, F., Ferru, G., Berthon, L., Boubals, N., Guilbaud, P., Sorel, C., Diat, O., Bauduin, P., Simonin, J. P., Morel, J. P., and Morel-Desrosiers, N. (2014) New Insights into the Extraction of uranium(VI) by an N,N-Dialkylamide. Mol. Phys., 112 (9–10): 1362–1374.
  • Shafer, J. C., Sulakova, J., Ogden, M. D., and Nash, K. L. (2010) Partitioning of U, Np, Th, and Eu between acidic aqueous Al(NO3)3 solutions and various TOPO extraction chromatographic materials. IOP Conf. Ser. Mater. Sci. Eng., 9 (12012).
  • Shafer, J. C., Harrington, R. C., and Nash, K. L. (2008) Partitioning of U(VI) and Eu(III) between acidic aqueous Al(NO3)3 and trioctyl phosphine oxide in N-dodecane. Proc. 18th Solvent Extr. Conf., (593–598).
  • Musikas, C. (1999) Review of Possible Technologies for Actinide Separations Using Other Extractants than TBP; Choppin, G. R., Khankhasayev, M. K., Eds.; Kluwer Academic Publishers: Dordrecht, Netherlands.
  • Gupta, K. K., Manchanda, V. K., Subramanian, M. S., and Singh, R. K. (1999) Thermodynamics of extraction of uranium(VI) and plutonium(IV) with some long-chain aliphatic amides. Radiochim. Acta, 85: 103–106.
  • Sun, G.-X., Han, J.-T., Bao, B.-R., and Sun, S.-X. (1998) Structural effect of N,N-dialkylamide in toluene on the extraction of uranium(VI). J. Radioanal. Nucl. Chem., 232 (1–2): 245–247.
  • Pathak, P. N., Prabhu, D. R., Kanekar, A. S., and Manchanda, V. K. (2006) Distribution studies on Th(IV), U(VI) and Pu(IV) using tri-N-butylphosphate and N,N-dialkyl amides. Radiochim. Acta, 94: 193–198.
  • Prabhu, D. R., Kumari, N., Kanekar, A. S., and Pathak, P. N. (2013) Biphasic kinetic investigations on the evaluation of non-salt forming reductants for Pu(IV) stripping from tributyl phosphate and N,N-dihexyl octanamide solutions in N-dodecane. J. Radioanal. Nucl. Chem., 298 (1): 691–698.
  • Gupta, K. K., Manchanda, V. K., Subramanian, M. S., and Singh, R. K. (2000) Solvent extraction studies on U(VI), Pu(IV), and fission products using DHOA. Solvent Extr. Ion Exch., 18: 273–292.
  • Verma, P. K., Kumari, N., Pathak, P. N., Sadhu, B., Sundararajan, M., Aswal, V. K., and Mohapatra, P. K. (2014) Investigations on preferential Pu(IV) extraction over U(VI) by N,N-dihexyloctanamide versus tri-N-butyl phosphate: Evidence through small angle neutron scattering and DFT studies. J. Phys. Chem. A, 118 (22): 3996–4004.
  • Pathak, P. N., Prabhu, D. R., Kanekar, A. S., and Manchanda, V. K. (2009) Recent R&D studies related to coprocessing of spent nuclear fuel using N,N-dihexyloctanamide. Sep. Sci. Technol., 44 (15): 3650–3663.
  • Musikas, C. (1988) Potentiality of nonorganophosphorus extractants in chemical separations of actinides. Sep. Purif. Technol., 23 (12): 1211–1226.
  • Vidyalakshmi, V., Subramanian, M. S., Srinivasan, T. G., and Vasudeva Rao, P. R. (2001) Effect of extractant structure on third phase formation in the extraction of uranium and nitric acid by dialkyl amides. Solvent Extr. Ion Exch., 19: 37–49.
  • Vidyalakshmi, V., Subramanian, M. S., Rajeswari, S., Srinivasan, T. G., and Vasudeva Rao, P. R. (2003) Interfacial tension studies of N,N-dialkyl amides. Solvent Extr. Ion Exch., 21: 399–412.
  • Gupta, K. K., Manchanda, V. K., Sriram, S., Thomas, G., Kulkarni, P. G., and Singh, R. K. (2000) Third phase formation in the extraction of uranyl nitrate by N,N-dialkyl aliphatic amides. Solvent Extr. Ion Exch., 18: 421–439.
  • Jha, R. K., Gupta, K. K., Kulkarni, P. G., Gurba, P. B., Janardan, P., Changarani, R. D., Dey, P. K., Pathak, P. N., and Manchanda, V. K. (2008) Third phase formation studies in the extraction of Th(IV) and U(VI) by N,N-dialkyl aliphatic amides. Desalination, 232 (1–3): 225–233.
  • Vasudeva Rao, P. R., Dhamodaran, R., Srinivasan, T. G., and Mathews, C. K. (1993) The effect of diluent on third phase formation in thorium nitrate - TBP system: Some novel empirical correlations. Solvent Extr. Ion Exch., 11 (4): 645–662.
  • Verma, P. K., Pathak, P. N., Mohapatra, P. K., Aswal, V. K., Sadhu, B., and Sundararajan, M. (2013) An Insight into third-phase formation during the extraction of thorium nitrate: Evidence for aggregate formation from small-angle neutron scattering and validation by computational studies. J. Phys. Chem. B, 117: 9821–9828.
  • Prabhu, D. R., Mahajan, G. R., and Nair, G. M. (1997) Di(2-ethyl hexyl) butyramide and di(2-ethyl hexyl)isobutyramide as extractants for uranium(VI) and plutonium(IV). J. Radioanal. Nucl. Chem., 224 (1–2): 113–117.
  • Pathak, P. N., Veeraraghavan, R., Ruikar, P. B., and Manchanda, V. K. (1999) Solvent extraction studies on Th(IV), Pa(V), and U(VI) from nitric acid medium using D2EHiBA. Radiochim. Acta, 86: 129–134.
  • Pathak, P. N., Prabhu, D. R., Ruikar, P. B., and Manchanda, V. K. (2002) Evaluation of di(2-ethylhexyl)isobutyramide as a process extractant for recovery U from irradiated Th. Solvent Extr. Ion Exch., 20 (3): 293–311.
  • Pathak, P. N., Prabhu, D. R., and Manchanda, V. K. (2003) The role of oxidants in Pu-Th separation studies employing di(2-ethylhexyl)isobutyramide (D2EHIBA) as extractant. Radiochim. Acta, 91 ( 3–2003): 141–146.
  • Pathak, P. N., Prabhu, D. R., Rizvi, G. H., Ruikar, P. B., Kumbhare, L. B., Mohapatra, P. K., and Manchanda, V. K. (2003) Pu-Th separation studies employing di(2-ethylhexyl) isobutyramide (D2EHIBA) as extractant from nitric acid medium. Radiochim. Acta, 91: 379–384.
  • Manchanda, V. K., Pathak, P. N., and Rao, A. K. (2004) Di(2-ethylhexyl) pivalamide (D2EHPVA): A promising extractant for selective removal of uranium from high level nuclear waste solutions. Solvent Extr. Ion Exch., 22 (3): 353–375.
  • Ban, Y., Hotoku, S., and Morita, Y. (2012) Application DEHiBA for mutual separation of U and Pu by continuous counter-current extraction with mixer-settler extractors. J. Nucl. Sci. Technol., 49 (6): 588–594.
  • Nair, G. M., Prabhu, D. R., and Mahajan, G. R. (1994) Extraction of uranium(VI) and plutonium(IV) with dihexylbutyramide and dihexylisobutyramide from nitric acid medium. J. Radioanal. Nucl. Chem., 182 (2): 393–399.
  • Nair, G. M., Mahajan, G. R., and Prabhu, D. R. (1996) Dioctyl butyramide and dioctyl isobutyramide as extractans for uranium(VI) and plutonium(IV). J. Radioanal. Nucl. Chem., 204 (1): 103–111.
  • Suzuki, S., Sasaki, Y., Yaita, T., and Kimura, T. (2004) Study on selective separation of uranium by N,N-dialkylamide in ARTIST process. Proc. ATALANTA 2004, P1–63.
  • Pathak, P. N., Kumbhare, L. B., and Manchanda, V. K. (2001) Effect of structure of N,N dialkyl amides on the extraction of U and Th thermodynamic study. Radiochim. Acta, 89: 447–452.
  • Rodrigues, F., Boubals, N., Charbonnel, M.-C., and Morel-Desrosiers, N. (2012) Thermodynamic approach of uranium(VI) extraction by N,N-(2–ethylhexyl)isobutyramide. Proc. Chem., 7: 59–65.
  • Acher, E., Hacene Cherkaski, Y., Dumas, T., Tamain, C., Guillaumont, D., Boubals, N., Javierre, G., Hennig, C., Solari, P. L., and Charbonnel, M.-C. (2016) Structures of plutonium(IV) and uranium(VI) with N, N-dialkyl amides from crystallography, X-ray absorption spectra, and theoretical calculations. Inorg. Chem., 55 (11): 5558–5569.
  • Mowafy, E. A., and Aly, H. F. (2001) Extraction of actinides and selected fission products from nitric acid medium using long chain monoamides. Solvent Extr. Ion Exch., 19 (4): 629–641.
  • Pathak, P. N., Prabhu, D. R., Kanekar, A. S., and Manchanda, V. K. (2010) Evaluation of N,N-dialkylamides as promising process extractants. IOP Conf. Ser. Mater. Sci. Eng., 9: 12082.
  • Pathak, P. N., Prabhu, D. R., Kanekar, A. S., Ruikar, P. B., Bhattacharyya, A., Mohapatra, P. K., and Manchanda, V. K. (2004) Distribution behavior of U(VI), Th(IV), and fission products with di(2-ethylhexyl) isobutyramide under process conditions. Ind. Eng. Chem. Res., 43 (15): 4369–4375.
  • Moeyaert, P., Dumas, T., Guillaumont, D., Kvashnina, K., Sorel, C., Miguirditchian, M., Moisy, P., and Dufrêche, J.-F. (2016) Modeling and speciation study of uranium(VI) and technetium(VII) coextraction with DEHiBA. Inorg. Chem., 55: 6511–6519.
  • Dagnac, T., Guillot, J.-M., and Le Cloirec, P. (1997) Investigation of the thermal decomposition of selected N,N-dialkylamides at low temperature. J. Anal. Appl. Pyrolysis, 42 (1): 53–71.
  • Parikh, K. J., Pathak, P. N., Misra, S. K., Tripathi, S. C., Dakshinamoorthy, A., and Manchanda, V. K. (2009) Radiolytic degradation studies on N,N-dihexyloctanamide (DHOA) under PUREX process conditions. Solvent Extr. Ion Exch., 27: 244–257.
  • Pathak, P. N., Prabhu, D. R., Bindu, M., Tripathi, S. C., and Manchanda, V. K. (2011) Alpha radiolytic degradation of N,N-dihexyl octanamide. J. Radioanal. Nucl. Chem., 288 (1): 137–142.
  • Kulkarni, P. G., Gupta, K. K., Gurba, P. B., Janardan, P., Changrani, R. D., Dey, P. K., and Manchanda, V. K. (2006) Solvent extraction behaviour of some fission product elements with DHOA and TBP under simulated PUREX process conditions. Radiochim. Acta, 94: 325–329

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.