453
Views
24
CrossRef citations to date
0
Altmetric
Original Articles

Hydrolysis of Sodium Borohydride and Ammonia Borane for Hydrogen Generation Using Highly Efficient Poly(N-Vinyl-2-Pyrrolidone)-Stabilized Ru–Pd Nanoparticles as Catalysts

References

  • Akdim, O., U.B. Demirci, and P. Miele. 2009. Acetic acid, a relatively green single-use catalyst for hydrogen generation from sodium borohydride. International Journal of Hydrogen Energy 34:7231–8.
  • Amendola, S.C., J.M. Janjua, N.C. Spencer, M.T. Kelly, P.J. Petillo, S.L. Sharp-Goldman, and M. Binder. 2000. A safe, portable, hydrogen gas generator using aqueous borohydride solution and Ru catalyst. International Journal of Hydrogen Energy 25:969–75.
  • Basu, S., A. Brockman, P. Gagare, Y. Zheng, P.V. Ramachandran, and W.N. Delgass. 2009. Chemical kinetics of Ru-catalyzed ammonia borane hydrolysis. Journal of Power Sources 188:238–43.
  • Brun, M., A. Berthet, and J.C. Bertolini. 1999. XPS, AES, and Auger parameter of Pd and PdO. Journal of Electron Spectroscopy and Related Phenomena 104:55–60.
  • Can, H., and Ö. Metin. 2012. A facile synthesis of nearly monodisperse ruthenium nanoparticles and their catalysis in the hydrolytic dehydrogenation of ammonia borane for chemical hydrogen storage. Applied Catalysis B: Environmental 125:304–10.
  • Chandra, M., and Q. Xu. 2006. A high-performance hydrogen generation system: Transition metal-catalyzed dissociation and hydrolysis of ammonia borane. Journal of Power Sources 156:190–4.
  • Chandra, M., and Q. Xu. 2007. Room temperature hydrogen generation from aqueous ammonia borane using noble metal nano-clusters as highly active catalysts. Journal of Power Sources 168:135–42.
  • Cheng, F., H. Ma, Y. Li, and J. Chen. 2007. Ni1-xPtx (x = 0–0.12) hollow spheres as catalysts for hydrogen generation from ammonia-borane. Inorganic Chemistry 46:788–94.
  • Clark, T.J., G.R. Whittell, and I. Manners. 2007. Highly efficient colloidal cobalt- and rhodium-catalyzed hydrolysis of H3NBH3 in air. Inorganic Chemistry 46:7522–7.
  • Dai, H.B., Y. Liang, P. Wang, and H.M. Cheng. 2008a. Amorphous cobalt-boron/nickel foam as an effective catalyst for hydrogen generation from alkaline sodium borohydride solution. Journal of Power Sources 177:17–23.
  • Dai, H.B., Y. Liang, P. Wang, X.D. Yao, T. Rufford, M. Lu, and H.M. Cheng. 2008b. High-performance cobalt-tungsten-boron catalyst supported on Ni foam for hydrogen generation from alkaline sodium borohydride solution. International Journal of Hydrogen Energy 33:4405–12.
  • Dai, H.B., L.L. Gao, Y. Liang, X.D. Kang, and P. Wang. 2010. Promoted hydrogen generation from ammonia-borane aqueous solution using cobalt-molybdenum-boron/nickel foam catalyst. Journal of Power Sources 195:307–12.
  • Demirci, U.B., and F. Garin. 2008. Kinetics of Ru-promoted sulphated zirconia catalysed hydrogen generation by hydrolysis of sodium tetrahydroborate. Journal of Molecular Catalysis A: Chemical 279:57–62.
  • Dinç, M., Ö. Metin, and S. Özkar. 2012. Water soluble polymer stabilized iron(0) nanoclusters: A cost-effective and magnetically recoverable in hydrogen generation from the hydrolysis of sodium borohydride and ammonia borane. Catalysis Today 183:10–6.
  • Ding, X.L., X. Yuan, C. Jia, and Z.F. Ma. 2010. Hydrogen generation from catalytic hydrolysis of sodium borohydride solution using cobalt–copper–boride (Co–Cu–B) catalysts. International Journal of Hydrogen Energy 35:11077–84.
  • Durap, F., M. Zahmakıran, and S. Özkar. 2009a. Water soluble laurate-stabilized rhodium(0) nanoclusters catalyst with unprecedented catalytic lifetime in the hydrolytic dehydrogenation of ammonia-borane. Applied Catalysis A: General 369:53–9.
  • Durap, F., M. Zahmakıran, and S. Özkar. 2009b. Water soluble laurate-stabilized ruthenium(0) nanoclusters catalyst for hydrogen generation from the hydrolysis of ammonia–borane: High activity and long lifetime. International Journal of Hydrogen Energy 34:7223–30.
  • Eom, K.S., K.W. Cho, and H.S. Kwon. 2008. Effects of electroless deposition conditions on microstructures of cobalt–phosphorus catalysts and their hydrogen generation properties in alkaline sodium borohydride solution. Journal of Power Sources 180:484–90.
  • Eom, K.S., K.W. Cho, and H.S. Kwon. 2010. Hydrogen generation from hydrolysis of NH3BH3 by an electroplated Co–P catalyst. International Journal of Hydrogen Energy 35:181–6.
  • Fernandes, R., N. Patel, and A. Miotello. 2009. Hydrogen generation by hydrolysis of alkaline NaBH4 solution with Cr-promoted Co–B amorphous catalyst. Applied Catalysis B: Environmental 92:68–74.
  • Fernandes, R., N. Patel, A. Miotello, and L. Calliari. 2012. Co–Mo–B–P alloy with enhanced catalytic properties for H2 production by hydrolysis of ammonia borane. Topics in Catalysis 55:1032–9.
  • Fernandes, R., N. Patel, A. Miotello, and M. Filippi. 2009. Studies on catalytic behavior of Co–Ni–B in hydrogen production by hydrolysis of NaBH4. Journal of Molecular Catalysis A: Chemical 298:1–6.
  • Guella, G., C. Zanchetta, B. Patton, and A. Miotello. 2006. New insights on the mechanism of palladium-catalyzed hydrolysis of sodium borohydride from 11B NMR measurements. Journal of Physical Chemistry B 110:17024–33.
  • Hsueh, C.L., C.Y. Chen, J.R. Ku, S.F. Tsai, Y.Y. Hsu, F. Tsau, and M.S. Jeng. 2008. Simple and fast fabrication of polymer template-Ru composite as a catalyst for hydrogen generation from alkaline NaBH4 solution. Journal of Power Sources 177:485–92.
  • Hu, L., R. Ceccato, and R. Raj. 2011. Ultrahigh figure-of-merit for hydrogen generation from sodium borohydride using ternary metal catalysts. Journal of Power Sources 196:69–75.
  • Hua, D., Y. Hanxi, A. Xinping, and C. Chuansin. 2003. Hydrogen production from catalytic hydrolysis of sodium borohydride solution using nickel boride catalyst. International Journal of Hydrogen Energy 28:1095–100.
  • Huang, Y., Y. Wang, R. Zhao, P.K. Shen, and Z. Wei. 2008. Accurately measuring the hydrogen generation rate for hydrolysis of sodium borohydride on multi-walled carbon nanotubes/Co–B catalysts. International Journal of Hydrogen Energy 33:7110–15.
  • Ingersoll, J.C., N. Mani, J.C. Thenmozhiyal, and A. Muthaiah. 2007. Catalytic hydrolysis of sodium borohydride by a novel nickel–cobalt–boride catalyst. Journal of Power Sources 173:450–7.
  • Jiang, H.L., T. Umegaki, T. Akita, X.B. Zhang, M. Haruta, and Q. Xu. 2010. Bimetallic Au-Ni nanoparticles embedded in SiO2 nanospheres: Synergetic catalysis in hydrolytic dehydrogenation of ammonia borane. Chemistry A European Journal 16:3132–7.
  • Kalidindi, S.B., U. Sanyal, and B.R. Jagirdar. 2008. Nanostructured Cu and Cu@Cu2O core shell catalysts for hydrogen generation from ammonia-borane. Physical Chemistry Chemical Physics 10:5870–4.
  • Kılıç, B., S. Şencanlı, and Ö. Metin. 2012. Hydrolytic dehydrogenation of ammonia borane catalyzed by reduced graphene oxide supported monodisperse palladium nanoparticles: High activity and detailed reaction kinetics. Journal of Molecular Catalysis A: Chemical 361–362:104–10.
  • Lee, J., K.Y. Kong, C.R. Jung, E. Cho, S.P. Yoon, J. Han, T.G. Lee, and S.W. Nam. 2007. A structured Co–B catalyst for hydrogen extraction from NaBH4 solution. Catalysis Today 120:305–10.
  • Li, P.Z., K. Aranishi, and Q. Xu. 2012. ZIF-8 immobilized nickel nanoparticles: Highly effective catalyst for hydrogen generation from hydrolysis of ammonia borane. Chemical Communications 48:3173–5.
  • Liang, Y., P. Wang, and H.B. Dai. 2010. Hydrogen bubbles dynamic template preparation of a porous Fe-Co-B/Ni foam catalyst for hydrogen generation from hydrolysis of alkaline sodium borohydride solution. Journal of Alloys and Compounds 491:359–65.
  • Liu, C.H., B.H. Chen, C.L. Hsueh, J.R. Ku, M.S. Jeng, and F. Tsau. 2009. Hydrogen generation from hydrolysis of sodium borohydride using Ni–Ru nanocomposite as catalysts. International Journal of Hydrogen Energy 34:2153–63.
  • Liu, B.H., Z.P. Li, and S. Suda. 2006. Nickel- and cobalt-based catalysts for hydrogen generation by hydrolysis of borohydride. Journal of Alloys and Compounds 415:288–93.
  • Loghmani, M.H., and A.F. Shojaei. 2013. Synthesis and characterization of Co–La–Zr–B quaternary amorphous nano-alloy: Kinetic study for hydrogen generation from hydrolysis of sodium borohydride. Journal of Alloys and Compounds 580:61–6.
  • Lu, A., Y. Chen, J. Jin, G.H. Yue, and D.L. Peng. 2012. CoO nanocrystals as a highly active catalyst for the generation of hydrogen from hydrolysis of sodium borohydride. Journal of Power Sources 220:391–8.
  • Lu, Z.H., J. Li, A. Zhu, Q. Yao, W. Huang, R. Zhou, R. Zhou, and X. Chen. 2013. Catalytic hydrolysis of ammonia borane via magnetically recyclable copper iron nanoparticles for chemical hydrogen storage. International Journal of Hydrogen Energy 38:5330–7.
  • Metin, Ö., E. Kayhan, S. Özkar, and J.J. Schneider. 2012. Palladium nanoparticles supported on chemically derived graphene: An efficient and reusable catalyst for the dehydrogenation of ammonia borane. International Journal of Hydrogen Energy 37:8161–9.
  • Metin, Ö., and S. Özkar. 2008. Synthesis and characterization of poly(N-vinyl-2-pyrrolidone)-stabilized water-soluble nickel(0) nanoclusters as catalyst for hydrogen generation from the hydrolysis of sodium borohydride. Journal of Molecular Catalysis A: Chemical 295:39–46.
  • Metin, Ö., and S. Özkar. 2009. Hydrogen generation from the hydrolysis of ammonia-borane and sodium borohydride using water-soluble polymer-stabilized cobalt(0) nanoclusters catalyst. Energy and Fuels 23:3517–26.
  • Metin, Ö., and S. Özkar. 2011. Water soluble nickel(0) and cobalt(0) nanoclusters stabilized by poly(4-styrenesulfonic acid-co-maleic acid): Highly active, durable and cost effective catalysts in hydrogen generation from the hydrolysis of ammonia borane. International Journal of Hydrogen Energy 36:1424–32.
  • Metin, Ö., S. Özkar, and S. Sun. 2010. Monodisperse nickel nanoparticles supported on SiO2 as an effective catalyst for the hydrolysis of ammonia-borane. Nano Research 3:676–84.
  • Metin, Ö., Ş. Şahin, and S. Özkar. 2009. Water-soluble poly(4-styrenesulfonic acid-co-maleic acid) stabilized ruthenium(0) and palladium(0) nanoclusters as highly active catalysts in hydrogen generation from the hydrolysis of ammonia-borane. International Journal of Hydrogen Energy 34: 6304–13.
  • Mitov, M., R. Rashkov, N. Atanassov, and A. Zielonka. 2007. Effects of nickel foam dimensions on catalytic activity of supported Co-Mn-B nanocomposites for hydrogen generation from stabilized borohydride solutions. Journal of Materials Science 42:3367–72.
  • Mohajeri, N., A.T-Raissi, and O. Adebiyi. 2007. Hydrolytic cleavage of ammonia-borane complex for hydrogen production. Journal of Power Sources 167:482–5.
  • Oh, T.H., and S. Kwon. 2012. Effect of bath composition on properties of electroless deposited Co–P/Ni foam catalyst for hydrolysis of sodium borohydride solution. International Journal of Hydrogen Energy 37:17027–39.
  • Patel, N., R. Fernandes, N. Bazzanella, and A. Miotello. 2010a. Co–P–B catalyst thin films prepared by electroless and pulsed laser deposition for hydrogen generation by hydrolysis of alkaline sodium borohydride: A comparison. Thin Solid Films 518:4779–85.
  • Patel, N., R. Fernandes, G. Guella, and A. Miotello. 2010b. Nanoparticle-assembled Co-B thin film for the hydrolysis of ammonia borane: A highly active catalyst for hydrogen production. Applied Catalysis B: Environmental 95:137–43.
  • Patel, N., G. Guella, A. Kale, A. Miotello, B. Patton, C. Zanchetta, and R. Fernandes. 2008a. Structured and nanoparticle assembled Co-B thin films prepared by pulsed laser deposition: A very efficient catalyst for hydrogen production. Journal of Physical Chemistry C 112:6968–76.
  • Patel, N., B. Patton, C. Zanchetta, R. Fernandes, G. Guella, A. Kale, and A. Miotello. 2008b. Pd-C powder and thin film catalysts for hydrogen production by hydrolysis of sodium borohydride. International Journal of Hydrogen Energy 33:287–92.
  • Qiu, F., L. Li, G. Liu, Y. Wang, Y. Wang, C. An, Y. Xu, C. Xu, Y. Wang, L. Jiao, and H. Yuan. 2013. In situ synthesized Fe–Co/C nano-alloys as catalysts for the hydrolysis of ammonia borane. International Journal of Hydrogen Energy 38:3241–9.
  • Rakap, M., E.E. Kalu, and S. Özkar. 2011a. Cobalt–nickel–phosphorus supported on Pd-activated TiO2 (Co–Ni–P/Pd-TiO2) as cost-effective and reusable catalyst for hydrogen generation from hydrolysis of alkaline sodium borohydride solution. Journal of Alloys Compounds 509:7016–21.
  • Rakap, M., E.E. Kalu, and S. Özkar. 2011b. Hydrogen generation from the hydrolysis of ammonia borane using cobalt-nickel-phosphorus (Co-Ni-P) catalyst supported on Pd-activated TiO2 by electroless deposition. International Journal of Hydrogen Energy 36:254–61.
  • Rakap, M., E.E. Kalu, and S. Özkar. 2011c. Polymer-immobilized palladium supported on TiO2 (Pd–PVB–TiO2) as highly active and reusable catalyst for hydrogen generation from the hydrolysis of unstirred ammonia–borane solution. International Journal of Hydrogen Energy 36:1448–55.
  • Rakap, M., and S. Özkar. 2009. Intrazeolite cobalt(0) nanoclusters as low-cost and reusable catalyst for hydrogen generation from the hydrolysis of sodium borohydride. Applied Catalysis B: Environmental 91:21–9.
  • Rakap, M., and S. Özkar. 2011. Hydroxyapatite-supported palladium(0) nanoclusters as effective and reusable catalyst for hydrogen generation from the hydrolysis of ammonia-borane. International Journal of Hydrogen Energy 36:7019–27.
  • Rakap, M., and S. Özkar. 2012. Hydroxyapatite-supported cobalt(0) nanoclusters as efficient and cost-effective catalyst for hydrogen generation from the hydrolysis of both sodium borohydride and ammonia-borane. Catalysis Today 183:17–25.
  • Ramachandran, P.V., and P.D. Gagare. 2007. Preparation of ammonia-borane in high yield and purity, methanolysis, and regeneration. Inorganic Chemistry 46:7810–7.
  • Shih, Y.J., C.C. Su, Y.H. Huang, and M.C. Lu. 2013. SiO2-supported ferromagnetic catalysts for hydrogen generation from alkaline NaBH4 (sodium borohydride) solution. Energy 54:263–70.
  • Sun, D., V. Mazumder, Ö. Metin, and S. Sun. 2011. Catalytic hydrolysis of ammonia borane via cobalt palladium nanoparticles. ACS Nano 5:6458–64.
  • Tian, H., Q. Guo, and D. Xu. 2010. Hydrogen generation from catalytic hydrolysis of alkaline sodium borohydride solution using attapulgite clay-supported Co-B catalyst. Journal of Power Sources 195:2136–42.
  • Tong, D.G., X.L. Zeng, W. Chu, D. Wang, and P. Wu. 2010. Magnetically recyclable hollow Co-B nanospindles as catalyst for hydrogen generation from ammonia borane. Journal of Materials Science 45:2862–7.
  • Toshima, N., and K. Hirakawa. 1997. Polymer-protected PtRu bimetallic cluster catalysts for visible-light-induced hydrogen generation from water and electron transfer dynamics. Applied Surface Science 121–122:534–7.
  • Umegaki, T., J.M. Yan, X.B. Zhang, H. Shioyama, N. Kuriyama, and Q. Xu. 2009a. Hollow Ni-SiO2 nanosphere-catalyzed hydrolytic dehydrogenation of ammonia borane for chemical hydrogen storage. Journal of Power Sources 191:209–16.
  • Umegaki, T., J.M. Yan, X.B. Zhang, H. Shioyama, N. Kuriyama, and Q. Xu. 2009b. Preparation and catalysis of poly(N-vinyl-2-pyrrolidone) (PVP) stabilized nickel catalyst for hydrolytic dehydrogenation of ammonia borane. International Journal of Hydrogen Energy 34:3816–22.
  • Umegaki, T., J.M. Yan, X.B. Zhang, H. Shioyama, N. Kuriyama, and Q. Xu. 2010. Co-SiO2 nanosphere-catalyzed hydrolytic dehydrogenation of ammonia borane for chemical hydrogen storage. Journal of Power Sources 195:8209–14.
  • Wagner, C.D., W.M. Riggs, L.E. Davis, J.F. Moulder, and M.E. Muilenberg. 1979. Handbook of X-ray photoelectron spectroscopy. Eden Prairie, MN: Perkin-Elmer Physical Electronics Division, 106 pp.
  • Wang, X., D. Liu, S. Song, and H. Zhang. 2012. Synthesis of highly active Pt–CeO2 hybrids with tunable secondary nanostructures for the catalytic hydrolysis of ammonia borane. Chemical Communications 48:10207–9.
  • Wang, H.L., J.M. Yan, Z.L. Wang, and Q. Jiang. 2012. One-step synthesis of Cu@FeNi core–shell nanoparticles: Highly active catalyst for hydrolytic dehydrogenation of ammonia borane. International Journal of Hydrogen Energy 37:10229–35.
  • Wen, M., S. Zhou, Q. Wu, J. Zhang, Q. Wu, C. Wang, and Y. Sun. 2013. Construction of NiCo–Pt nanopolyhedron inlay-structures and their highly efficient catalysis hydrolytic dehydrogenation toward ammonia borane. Journal of Power Sources 232:86–92.
  • Xia, Z.T., and S.H. Chan. 2005. Feasibility study of hydrogen generation from sodium borohydride solution for micro fuel cell applications. Journal of Power Sources 152:46–9.
  • Xu, Q., and M. Chandra. 2007. A portable hydrogen generation system: Catalytic hydrolysis of ammonia-borane. Journal of Alloys and Compounds 446–447:729–32.
  • Xu, D., P. Dai, X. Liu, C. Cao, and Q. Guo. 2008. Carbon-supported cobalt catalyst for hydrogen generation from alkaline sodium borohydride solution. Journal of Power Sources 182:616–20.
  • Yamada, Y., K. Yano, Q. Xu, and S. Fukuzumi. 2010. Cu/Co3O4 nanoparticles as catalysts for hydrogen evolution from ammonia borane by hydrolysis. Journal of Physical Chemistry C 114:16456–62.
  • Yan, J.M., X.B. Zhang, S. Han, H. Shioyama, and Q. Xu. 2008. Iron nanoparticle-catalyzed hydrolytic dehydrogenation of ammonia borane for chemical hydrogen storage. Angewandte Chemie International Edition 47:2287–9.
  • Yan, J.M., X.B. Zhang, S. Han, H. Shioyama, and Q. Xu. 2009a. Magnetically recyclable Fe-Ni alloy catalyzed dehydrogenation of ammonia borane in aqueous solution under ambient atmosphere. Journal of Power Sources 194:478–81.
  • Yan, J.M., X.B. Zhang, S. Han, H. Shioyama, and Q. Xu. 2009b. Synthesis of longtime water/air-stable Ni nanoparticles and their high catalytic activity for hydrolysis of ammonia–borane for hydrogen generation. Inorganic Chemistry 48:7389–93.
  • Yan, J.M., X.B. Zhang, H. Shioyama, and Q. Xu. 2010a. Room temperature hydrolytic dehydrogenation of ammonia borane catalyzed by Co nanoparticles. Journal of Power Sources 195:1091–4.
  • Yan, J.M., X.B. Zhang, T. Akita, M. Haruta, and Q. Xu. 2010b. One-step seeding growth of magnetically recyclable Au@Co core-shell nanoparticles: Highly efficient catalyst for hydrolytic dehydrogenation of ammonia–borane. Journal of American Chemical Society 132:5326–7.
  • Yang, X., F. Cheng, J. Liang, Z. Tao, and J. Chen. 2009. PtxNi1-x nanoparticles as catalysts for hydrogen generation from hydrolysis of ammonia borane. International Journal of Hydrogen Energy 34:8785–91.
  • Zahmakıran, M., and S. Özkar. 2009. Zeolite framework stabilized rhodium(0) nanoclusters catalyst for the hydrolysis of ammonia-borane in air: Outstanding catalytic activity, reusability and lifetime. Applied Catalysis B: Environmental 89:104–10.
  • Zhang, Q., Y. Wu, X. Sun, and J. Ortega. 2007. Kinetics of catalytic hydrolysis of stabilized sodium borohydride solutions. Industrial and Engineering Chemistry Research 46:1120–4.
  • Zhu, J., R. Li, W. Niu, Y. Wu, and X. Gou. 2012. Facile hydrogen generation using colloidal carbon supported cobalt to catalyze hydrolysis of sodium borohydride. Journal of Power Sources 211:33–9.
  • Zhuang, D.W., Q. Kang, S.S. Muir, X. Yao, H.B. Dai, G.L. Ma, and P. Wang. 2013. Evaluation of a cobalt–molybdenum–boron catalyst for hydrogen generation of alkaline sodium borohydride solution–aluminum powder system. Journal of Power Sources 224:304–11.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.