A Comparison of Two Sampling Methods for the Detection of Airborne Methylene Bisphenyl Diisocyanate

REFERENCES

• Woolrich , P. F. 1982 . Toxicology, industrial hygiene and medical control of TDI, MDI and PMPPI . Am. Ind. Hyg. Assoc. J , 43 : 89 – 98 .
   PubMed Web of Science ®Google Scholar
• Weyel , D. A. and Schaffer , R. B. 1985 . Pulmonary and sensory irritation of diphenylmethane-4,4′- and dicyclohexylmethane-4,4′-diisocyanate . Toxicol. Appl. Pharmacol , 77 : 427 – 433 .
   PubMed Web of Science ®Google Scholar
• Nakashima , K. , Takeshita , T. and Morimoto , K. 2002 . Review of the occupational exposures to isocyanates: Mechanisms of action . Environ. Health Prev. Med , 7 : 1 – 6 .
   PubMedGoogle Scholar
• Deschamps , F. , Prevost , A. , Lavaud , F. and Kochman , S. 1998 . Mechanisms of occupational asthma induced by isocyanates . Ann. Occup. Hyg , 42 : 33 – 36 .
   PubMed Web of Science ®Google Scholar
• Streicher , R. , Reh , C. , Key-Schwartz , R. , Schlecht , P. , Cassinelli , M. and Connor , P. 2000 . Determination of airborne isocyanate exposure: Considerations in method selection . Am. Ind. Hyg. Assoc. J. , 61 : 544 – 556 .
   Web of Science ®Google Scholar
• Allport , D. , Gilbert , D. and Outterside , S. 2003 . MDI & TDI: Safety, Health, and the Environment , Chichester , , U.K : John Wiley & Sons Ltd .
   Google Scholar
• Ashida , K. 2007 . Polyurethane and Related Foams (Chemistry and Technology) , Boca Raton , Fla : Taylor & Francis Group .
   Google Scholar
• Ulrich , H. 1996 . Chemistry and Technology of Isocyanates , Chichester , , U.K : John Wiley & Sons Ltd .
   Google Scholar
• Henneken , H. , Vogel , M. and Karst , U. 2007 . Determination of airborne isocyanates . Bioanal. Chem , 387 ( 1 ) : 219 – 236 .
   PubMed Web of Science ®Google Scholar
• Bello , D. , Woskie , S. R. Streicher , R. P. 2004 . Isocyanates in occupational environments: A critical review of exposure limits and metrics . Am. J. Ind. Med , 46 ( 5 ) : 480 – 491 .
   PubMed Web of Science ®Google Scholar
• Raulf-Heimsoth , M. and Baur , X. 1998 . Pathomechanisms and pathophysiology of isocyanate-induced diseases—Summary of present knowledge . Am. J. Ind. Med , 34 ( 2 ) : 137 – 143 .
   PubMedGoogle Scholar
• Cummings , B. J. and Booth , K. S. 2002 . Industrial hygiene sampling for airborne TDI in six flexible slabstock foam manufacturing facilities in the United States: A comparison of the short-term and long-term sampling data . Appl. Occup. Environ. Hyg , 17 : 863 – 871 .
   PubMedGoogle Scholar
• Kim , S. H. , Kim , B. K. and Lim , H. 2008 . Effect of isocyanate Index on the Properties of Rigid Polyurethane Foams by HFC 365mfc . Macromolec. Res , 16 ( 5 ) : 467 – 472 .
   Google Scholar
• Chester , D. , Hanna , E. Pickelman , B. 2005 . Asthma death after spraying polyeurethane truck bedliner . Am. J. Ind. Med , 48 : 78 – 84 .
   PubMed Web of Science ®Google Scholar
• Brooks , E. 2006 . OSHA Compliance Issues—Isocyanate exposure in an autobody repair and collision center . J. Occup. Environ. Hyg , 3 : D24 – D27 .
   PubMedGoogle Scholar
• Lofgren , D. , Walley , T. , Peters , P. and Weis , M. 2003 . MDI exposure for spray-on truck bed lining . Appl. Occup. Environ. Hyg , 18 : 772 – 779 .
   PubMedGoogle Scholar
• Kang , M. J. , Kim , Y. H. , Park , G. P. , Han , M. S. , Kim , W. N. and Park , S. D. 2010 . Liquid nucleating additives for improving thermal insulating properties and mechanical strength of polyisocyanurate foams . J. Mater. Sci , 45 : 5412 – 5419 .
   Web of Science ®Google Scholar
• Toluene Diisocyanates . Available at http://ntp.niehs.nih.gov/ntp/roc/twelfth/profiles/Toluenediisocyanates.pdf (accessed September 12, 2012)
   Google Scholar
• Pronk , A. , Preller , L. Raulf-Heimsoth , M. 2007 . Respiratory symptoms, sensitization, and exposure response relationships in spray painters exposed to isocyanates . Am. J. Respir. Crit. Care Med , 176 ( 11 ) : 1090 – 1097 .
   PubMed Web of Science ®Google Scholar
• Lushniak , B. , Reh , C. , Bernstein , D. and Gallagher , J. 1998 . Indirect assessment of 4,4′-diphenylmethane diisocyanate (MDI) exposure by evaluation of specific humoral immune responses to MDI conjugated to human serum albumin . Am. J. Ind. Med , 33 : 471 – 477 .
   PubMed Web of Science ®Google Scholar
• Toxic and Hazardous Substances . Code of Federal Regulations Title 29 , Part 1910. Subpart Z
   Google Scholar
• ACGIH . 2006 . Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices , Cincinnati , Ohio : ACGIH .
   Google Scholar
• National Institute for Occupational Safety and Health (NIOSH) . 2005 . NIOSH Pocket Guide to Chemical Hazards , Cincinnati , Ohio : NIOSH . Pub. No. 2005-149
   Google Scholar
• Streicher , R. P. , Reh , C. M. , Key-Schwartz , R. J. , Schlecht , P. C. and Cassinelli , M. E. 1994 . “ Determination of airborne isocyanates ” . In NIOSH Manual of Analytical Methods , Edited by: Schlecht , P. C. and O’Connor , P. F. Cincinnati , Ohio : DHHS, NIOSH . DHHS (NIOSH) Pub. 94-113
   Google Scholar
• Lesage , J. , Stanley , J. , Karoly , W. and Lichtenberg , F. W. 2007 . Airborne methylene diphenyl diisocyanate (MDI) concentrations associated with the application of polyurethane spray foam in residential construction . J. Occup. Environ. Hyg , 4 : 145 – 155 .
   PubMedGoogle Scholar
• Total Isocyanates, Method 5525 . Available at http://www.cdc.gov/niosh/docs/2003-154/pdfs/5525.pdf (accessed September 12, 2012)
   Google Scholar
• ISO-CHEK. Simultaneous and Separate Collection of Isocyanate . Available at http://www.skcinc.com/prod/225-9022.asp (accessed Sep- tember 12, 2012)
   Google Scholar
• Isocyanates (Organic Methods #47) . Available at http://www.osha.gov/dts/sltc/methods/organic/org047/org047.html (accessed September 12, 2012)
   Google Scholar
• Isocyanates (Organic Methods #42) . Available at http://www.osha.gov/dts/sltc/methods/organic/org042/org042.html (accessed September 12, 2012)
   Google Scholar
• Tremblay , P. , Lesage , J. , Ostiguy , C. and Tra , H. V. 2003 . Investigation of the competitive rate of derivatization of several secondary amines with phenylisocyanate (PHI), hexamethylene-1,6-diisocyanate (HDI), 4,4′-methylenebis(phenyl isocyanate) (MDI) and toluene diisocyanate (TDI) in liquid medium . Analyst , 128 ( 2 ) : 142 – 149 .
   PubMed Web of Science ®Google Scholar
• Streicher , R. P. , Arnold , J. E. , Ernst , M. K. and Cooper , C. V. 1996 . Development of a novel derivatization reagent for the sampling and analysis of total isocyanate group in air and comparison of its performance with that of several established reagents . Am. Ind. Hyg. Assoc. J , 57 : 905 – 913 .
   PubMed Web of Science ®Google Scholar
• Levine , S. P. , Hillig , K. J.D. , Dharmarajan , V. , Spence , M. W. and Baker , M. D. 1995 . Critical review of methods of sampling, analysis, and monitoring for TDI and MDI . Am. Ind. Hyg. Assoc. J , 56 : 581 – 589 .
   Web of Science ®Google Scholar
• Karoly , W. J. 1998 . Stability of diphenylmethane diisocyanate (MDI) on glass fiber filters . Am. Ind. Hyg. Assoc. J , 59 : 645 – 647 .
   Web of Science ®Google Scholar
• Booth , K. , Cummings , B. Karoly , W. J. 2009 . Measurements of airborne methylene diphenyl diisocyanate (MDI) concentration in the U.S. workplace . J. Occup. Environ. Hyg , 6 : 228 – 238 .
   PubMed Web of Science ®Google Scholar
• Bell , J. 1994 . “Evaluation of the OSHA 42 and NIOSH 5521 Methods in Determining the Free Isocyanate Concentration in Aerosols and Vapor Phases During Application of Two Component 1, 6-Hexamethylene Diisocyanate Paints , Texas : Master's thesis, Texas A&M University, College Station .
   Google Scholar