Two 3-Amino-1,2,4-triazole-based Manganese(II) Complexes Incorporated With Different Dicarboxylate Coligands: Synthesis, Structure, and Magnetism

References

• (a) Leuenberger, M. N.; Loss, D. Quantum computing in molecular magnets. Nature 2001, 410, 789–793;
   PubMed Web of Science ®Google Scholar
  (b) Meng, Z.-S.; Yun, L.; Zhang, W.-X.; Hong, C.-G.; Herchel, R.; Ou, Y.-C.; Leng, J.-D.; Peng, M.-X.; Lin, Z.-J.; Tong, M.-L. Reactivity of 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole, structures and magnetic properties of polynuclear and polymeric Mn(II), Cu(II) and Cd(II) complexes. Dalton Trans. 2009, 10284−10295;
   PubMed Web of Science ®Google Scholar
  (c) Tong, M.-L.; Hong, C.-G.; Zheng, L.-L.; Peng, M.-X.; Gaita-Arińo, A.; Clemente-Juan, J. M. New reactivity of 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole: Synthesis and structure of a mononuclear species, a dinuclear species, and a novel tetranuclear nickel(II) rectangle box, and magnetic properties of the dinuclear and tetranuclear complexes. Eur. J. Inorg. Chem. 2007, 3710–3717.
   Web of Science ®Google Scholar
• (a) Wang, X. Y.; Wang, Z. M.; Gao, S. Constructing magnetic molecular solids by employing three-atom ligands as bridges. Chem. Commun. 2008, 281–294;
   PubMed Web of Science ®Google Scholar
  (b) Zeng, Y. F.; Hu, X.; Liu, F. C.; Bu, X. H. Azido-mediated systems showing different magnetic behaviors. Chem. Soc. Rev. 2009, 38, 469–480;
   PubMed Web of Science ®Google Scholar
  (c) Hu, T.-L.; Li, J.-R.; Liu, C.-S.; Shi, X.-S.; Zhou, J.-N.; Bu, X.-H.; Ribas, J. Syntheses, crystal structures, and magneto-structural correlations of novel CuII complexes containing a planar [Cu(μ-L1)]2 (HL1 = 3-(2-pyridyl)pyrazole) unit: From dinuclear to tetranuclear and then to one-dimensional compounds. Inorg. Chem. 2006, 45, 162−173;
   PubMed Web of Science ®Google Scholar
  (d) Han, S.-D.; Song, W.-C.; Zhao, J.-P.; Yang, Q.; Liu, S.-J.; Li, Y.; Bu, X.-H. Synthesis and ferrimagnetic properties of an unprecedented polynuclear cobalt complex composed of [Co24] macrocycles. Chem. Commun. 2013, 49, 871−873.
   PubMed Web of Science ®Google Scholar
• (a) Ouellette, W.; Galán-Mascarós, J. R.; Dunbar, K. R.; Zubieta, J. Hydrothermal synthesis and structure of a three-dimensional Cobalt(II) triazolate magnet. Inorg. Chem. 2006, 45, 1909–1911;
   PubMed Web of Science ®Google Scholar
  (b) Ouellette, W.; Jones, S.; Zubieta, J. Solid state coordination chemistry of metal-1,2,4-triazolates and the related metal-4-pyridyltetrazolates. CrystEngComm 2011, 13, 4457–4485;
   Web of Science ®Google Scholar
  (c) Ouellette, W.; Yu, M. H.; O'Connor, C. J.; Hagrman, D.; Zubieta, J. Hydrothermal chemistry of the copper–triazolate system: A microporous metal–organic framework constructed from magnetic {Cu3(μ3-OH)(triazolate)3}2+ building blocks, and related materials. Angew. Chem. Int. Ed. 2006, 45, 3497–3500.
   PubMed Web of Science ®Google Scholar
• (a)Yang, E. C.; Liu, Z. Y.; Wu, X. Y.; Zhao, X. J. A 3D CoIIframework with alternating vertex- and edge-sharing Δ-ribbons showing a two-step field-induced magnetic transition. Chem. Commun. 2011, 47, 8629–8631;
   PubMed Web of Science ®Google Scholar
  (b) Liu, Z. Y.; Ding, B.; Yang, E. C.; Zhao, X. J. A (3,4,14)-connected framework with various distorted triangular magnetic lattices exhibiting field-induced metamagnetism, spin competition and spin reorientation. Dalton Trans. 2012, 41, 9611–9614.
   PubMed Web of Science ®Google Scholar
• Zhang, J. P.; Zhang, Y. B.; Lin, J. B.; Chen, X. M. Metal azolate frameworks: from crystal engineering to functional materials. Chem. Rev. 2012, 112, 1001–1033.
   PubMed Web of Science ®Google Scholar
• Yang, E. C.; Liu, Z. Y.; Wang, X. G.; Batten, S. R.; Zhao, X. J. Three Zn(II)-triazole-H3btc complexes regulated by mixed ligands protonation upon stepwise crystallization. CrystEngComm 2008, 10, 1140–1143.
   Web of Science ®Google Scholar
• Liu, Z. Y.; Yang, E. C.; Li, L. L.; Zhao, X. J. A reversible SCSC transformation from a blue metamagnetic framework to a pink antiferromagnetic ordering layer exhibiting concomitant solvatochromic and solvatomagnetic effects. Dalton Trans. 2012, 41, 6827–6832.
   PubMed Web of Science ®Google Scholar
• Zhai, Q. G.; Lu, C. Z.; Wu, X. Y.; Batten, S. R. Coligand modulated six-, eight-, and ten-connected zn/cd-1,2,4-triazolate frameworks based on mono-, bi-, tri-, penta-, and heptanuclear cluster units. Cryst. Growth Des. 2007, 7, 2332–2342.
   Web of Science ®Google Scholar
• Gu, Z. G.; Xu, Y. F.; Zhou, X. H.; Zuo, J. L.; You, X. Z. Assembly of iron(ii)-triazole polymers from 1d chains to 3d interpenetrated frameworks: Syntheses, structures, and magnetic properties. Cryst. Growth Des. 2008, 8, 1306–1312.
   Web of Science ®Google Scholar
• Sarma, D.; Srivastava, V.; Natarajan, S. Aza-heterocyclic ligand assisted assembly of new cobalt MOFs with pcu and graphite related structures. Dalton Trans. 2012, 41, 4135–4145.
   PubMed Web of Science ®Google Scholar
• Liu, B.; Zhao, R. L.; Yue, K. F.; Shi, J. T.; Yu, Y.; Wang, Y. Y. New amine-functionalized cobalt cluster-based frameworks with open metal sites and suitable pore sizes: multipoint interactions enhanced CO2 sorption. Dalton Trans. 2013, 42, 13990–13996.
   PubMed Web of Science ®Google Scholar
• Zhang, X. Y.; Yang, E. C.; Wang, X. G.; Liu, Z. Y.; Zhao, X. J. Three 3-amino-1,2,4-triazole-based magnetic complexes incorporated with different carboxylate-containing coligands: synthesis, structures, and magnetic properties. Z. Anorg. Allg. Chem. 2013, 639, 974–981.
   Web of Science ®Google Scholar
• Zhang, P.; Li, B.; Zhao, Y.; Meng, X. G.; Zhang, T. L. A novel (3,36)-connected and self-interpenetrated metal-organic framework with high thermal stability and gas-sorption capabilities. Chem. Commun. 2011, 47, 7722–7724.
   PubMed Web of Science ®Google Scholar
• Chen, M.; Lu, Y.; Fan, J.; Lv, G. C.; Zhao, Y.; Zhang, Y.; Sun, W. Y. High structural diversity controlled by temperature and induction agent. CrytEngComm 2012, 14, 2015–2023.
   Web of Science ®Google Scholar
• Yang, E. C.; Zhang, X. Y.; Wang, X. G.; Liu, Z. Y.; Zhao, X. J. Four manganese(II) 3-amino-1,2,4-triazole complexes incorporated with different polycarboxylate coligands: Synthesis, structures and magnetism. Polyhedron 2013, 53, 208–214.
   Web of Science ®Google Scholar
• Liu, J. C.; Guo, G. C.; Huang, J. S.; You, X. Z. Different oxidation states of copper(I,I/II,II) thiocyanate complexes containing 1,2,4-triazole as a bridging ligand:  Syntheses, crystal structures, and magnetic properties of 2-D polymer CuI(admtrz)SCN, linear trinuclear [CuI2CuII(admtrz)6(SCN)2](ClO4)2, and triangular trinuclear [CuII3(admtrz)4(SCN)3(μ3-OH)(H2O)](ClO4)2·H2O (admtrz = 4-Amino-3,5-dimethyl-1,2,4-triazole). Inorg. Chem. 2003, 42, 235–243.
   PubMed Web of Science ®Google Scholar
• Liu, B.; Chen, Y. H.; Zhang, X. C. Synthesis, structure and fluorescence of a new 1,2,4-triazole-bridging manganese(II) 2D layered framework. Inorg. Chem. Commun. 2008, 11, 965–968.
   Web of Science ®Google Scholar
• Yin, P. X.; Li, Z. J.; Zhang, J.; Zhang, L.; Lin, Q. P.; Qin, Y. Y.; Yao, Y. G. Protonated 3-amino-1,2,4-triazole templated luminescent lanthanide isophthalates with a rare (3,6)-connected topology. CrystEngComm 2009, 11, 2734–2738.
   Web of Science ®Google Scholar
• Rueff, J. M.; Masciocchi, N.; Rabu, P.; Sironi, A.; Skoulios, A. Synthesis, structure and magnetism of homologous series of polycrystalline cobalt alkane mono- and dicarboxylate soaps. Chem. Eur. J. 2002, 8, 1813–1820.
   PubMed Web of Science ®Google Scholar
• Zhou, J. H.; Cheng, R. M.; Song, Y.; Li, Y. Z.; Yu, Z.; Chen, X. T.; Xue, Z. L.; You, X. Z. Syntheses, structures, and magnetic properties of unusual nonlinear polynuclear copper(II) complexes containing derivatives of 1,2,4-triazole and pivalate ligands. Inorg. Chem. 2005, 44, 8011–8022.
   PubMed Web of Science ®Google Scholar
• (a) Zhang, W. X.; Wei, X.; Zheng, Y. Z.; Chen, X. M. Two spin-competing manganese(II) coordination polymers exhibiting unusual multi-step magnetization jumps. Chem. Commun. 2009, 3804–3806;
   PubMed Web of Science ®Google Scholar
  (b) Lu, Y. B.; Wang, M. S.; Zhou, W. W.; Xu, G.; Guo, G. C. Novel 3-D PtS-like tetrazolate-bridged manganese(II) complex exhibiting spin-canted antiferromagnetism and field-induced spin-flop transition. Inorg. Chem. 2008, 47, 8935–8942.
   PubMed Web of Science ®Google Scholar
• Li, J. R.; Yu, Q.; Sañudo, E. C.; Tao, Y.; Bu, X.H. An azido–CuII–triazolate complex with utp-type topological network, showing spin-canted antiferromagnetism. Chem. Commun. 2007, 2602–2604.
   PubMed Web of Science ®Google Scholar
• Yang, E. C.; Liu, Z.Y.; Li, Y. L.; Wang, J. Y.; Zhao, X. J. A Kagomé layer-based 3D MnII framework showing coexistence of spin-canting, spin-frustration, field-induced metamagnetic and spin-flop transitions. Dalton Trans. 2011, 40, 8513–8516.
   PubMed Web of Science ®Google Scholar
• Sheldrick, G. M. SADABS: Program for Empirical Absorption Correction of Area Detector Data; University of Göttingen, Germany, 1996.
   Google Scholar
• Sheldrick, G. M. SHELXTL: Structure Determination Software Programs; Bruker, Madison, WI, 2001.
   Google Scholar