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Reviews

Progress in Toughening Poly(Lactic Acid) with Renewable Polymers

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References

  • Yu, L.; Dean, K.; Li, L. “Polymer blends and composites from renewable resources”, Prog. Polym. Sci. 2006, 31, 576–602.
  • Reddy, M. M.; Vivekanandhan, S.; Misra, M.; Bhatia, S. K.; Mohanty, A. K. “Biobased plastics and bionanocomposites: Current status and future opportunities”, Prog. Polym. Sci. 2013, 38, 1653–1689.
  • Zeng, J. B.; Jiao, L.; Li, Y. D.; Srinivasan, M.; Li, T.; Wang, Y. Z. “Bio-based blends of starch and poly(butylene succinate) with improved miscibility, mechanical properties, and reduced water absorption”, Carbohydr. Polym. 2011, 83, 762–768.
  • Zeng, J. B.; Zhu, Q. Y.; Lu, X.; He, Y. S.; Wang, Y. Z. “From miscible to partially miscible biodegradable double crystalline poly (ethylene succinate)-b-poly(butylene succinate) multiblock copolymers”, Polym. Chem. 2012, 3, 399–408.
  • Zeng, J. B.; Wu, F.; Huang, C. L.; He, Y. S.; Wang, Y. Z. “Urethane ionic groups induced rapid crystallization of biodegradable poly(ethylene succinate)”, ACS Macro Lett. 2012, 1, 965–968.
  • Xu, J.; Guo, B. H. “Poly(butylene succinate) and its copolymers: Research, development and industrialization”, Biotechnol. J. 2010, 5, 1149–1163.
  • Li, Y. D.; Zeng, J. B.; Wang, X. L.; Yang, K. K.; Wang, Y. Z. “Structure and properties of soy protein/poly(butylene succinate) blends with improved compatibility”, Biomacromolecules 2008, 9, 3157–3164.
  • Fang, H.; Jiang, F.; Wu, Q.; Ding, Y.; Wang, Z. “Supertough polylactide materials prepared through in situ reactive blending with PEG-based diacrylate monomer”, ACS Appl. Mater. Interfaces 2014, 6, 13552–13563.
  • Dong, W.; He, M.; Wang, H.; Ren, F.; Zhang, J.; Zhao, X.; Li, Y. “PLLA/ABS blends compatibilized by reactive comb polymers: double Tg depression and significantly improved toughness”, ACS Sustain. Chem. Eng. 2015, 3, 2542–2550.
  • Liu, Z.; Luo, Y.; Bai, H.; Zhang, Q.; Fu, Q. “Remarkably enhanced impact toughness and heat resistance of poly(L-Lactide)/thermoplastic polyurethane blends by constructing stereocomplex crystallites in the matrix”, ACS Sustain. Chem. Eng. 2016, 4, 111–120.
  • Garlotta, D. “A literature review of poly(Lactic Acid)”, J. Polym. Environ. 2001, 9, 63–84.
  • Datta, R.; Henry, M. “Lactic acid: recent advances in products, processes and technologies: A review”, J. Chem. Technol. Biotechnol. 2006, 81, 1119–1129.
  • Drumrigh, R. E.; Grube, P. R.; Henton, D. E. “Polylactic acid technology”, Adv. Mater. 2000, 12, 1841–1846.
  • Hiraoa, K.; Ohara, H. “Synthesis and recycle of poly(L-lactic acid) using microwave irradiation”, Polym. Rev. 2011, 51, 1–22.
  • Narayan, R. Degradation of polymeric materials, in ccience and engineering of composting: Design, environmental, microbiological and utilization aspects (H. A. Hoitink, H. N. Keener; Eds.) OARDC, OH, 1993.
  • Rasal, R. M.; Janorkar, A. V.; Hirt, D. E. “Poly(lactic acid) modifications”, Prog. Polym. Sci. 2010, 35, 338–356.
  • Gupta, B.; Revagade, N.; Hilborn, J. “Poly(lactic acid) fiber: An overview”, Prog. Polym. Sci. 2007, 32, 455–482.
  • Lim, L. T.; Auras, R.; Rubino, M. “Processing technologies for poly(lactic acid)”, Prog. Polym. Sci. 2008, 33, 820–852.
  • Zeng, J. B.; Li, K. A.; Du, A. K. “Compatibilization strategies in poly(lactic acid)-based blends”, RSC Adv. 2015, 5, 32546–32565.
  • Bai, H.; Xiu, H.; Gao, J.; Deng, H.; Zhang, Q.; Yang, M.; Fu, Q. “Tailoring impact toughness of poly(L-lactide)/poly(epsilon-caprolactone) (PLLA/PCL) blends by controlling crystallizatior of PLLA matrix”, ACS Appl. Mater. Interfaces 2012, 4, 897–905.
  • Liu, H.; Zhang, J. “Research progress in toughening modification of poly(lactic acid)”, J. Polym. Sci. Part B-Polym. Phys. 2011, 49, 1051–1083.
  • Yin, H. Y.; Wei, X. F.; Bao, R. Y.; Dong, Q. X.; Liu, Z. Y.; Yang, W.; Xie, B. H.; Yang, M. B. “Enhancing thermomechanical properties and heat distortion resistance of poly(l-lactide) with high crystallinity under high cooling rate”, ACS Sustain. Chem. Eng. 2015, 3, 654–661.
  • Nagarajan, V.; Mohanty, A. K.; Misra, M. “Perspective on polylactic acid (PLA) based sustainable materials for durable applications: Focus on toughness and heat resistance”, ACS Sustain. Chem. Eng. 2016, 4, 2899–2916.
  • Liang, Y. Y.; Yang, S.; Jiang, X.; Zhong, G. J.; Xu, J. Z.; Li, Z. M. “Nucleation ability of thermally reduced graphene oxide for polylactide: Role of size and structural integrity”, J. Phys. Chem. B 2015, 119, 4777–4787.
  • Xu, J. Z.; Chen, T.; Yang, C. L.; Li, Z. M.; Mao, Y. M.; Zeng, B. Q.; Hsiao, B. S. “Isothermal crystallization of poly(l-lactide) induced by graphene nanosheets and carbon nanotubes: A comparative study”, Macromolecules 2010, 43, 5000–5008.
  • Bai, H.; Zhang, W.; Deng, H.; Zhang, Q.; Fu, Q. “Control of crystal morphology in poly(l-lactide) by adding nucleating agent”, Macromolecules 2011, 44, 1233–1237.
  • Anderson, K. S.; Schreck, K. M.; Hillmyer, M. A. “Toughening polylactide”, Polym. Rev. 2008, 48, 85–108.
  • Zeng, J. B.; Li, Y. D.; Zhu, Q. Y.; Yang, K. K.; Wang, X. L.; Wang, Y. Z. “A novel biodegradable multiblock poly(ester urethane) containing poly(L-lactic acid) and poly(butylene succinate) blocks”, Polymer 2009, 50, 1178–1186.
  • Zeng, J. B.; Li, Y. D.; Li, W. D.; Yang, K. K.; Wang, X. L.; Wang, Y. Z. “Synthesis and properties of poly(Ester Urethane)s consisting of poly(L-Lactic Acid) and poly(ethylene succinate) segments”, Ind. Eng. Chem. Res. 2009, 48, 1706–1711.
  • Li, W. D.; Zeng, J. B.; Li, Y. D.; Wang, X. L.; Wang, Y. Z. “Synthesis of high-molecular-weight aliphatic-aromatic copolyesters from poly(ethylene-co-1,6-hexene terephthalate) and poly(L-lactic acid) by chain extension”, J. Polym. Sci. Part A-Polym. Chem. 2009, 47, 5898–5907.
  • Labrecque, L. V.; Kumar, R. A.; Dave, V.; Gross, R. A.; McCarthy, S. P. “Citrate esters as plasticizers for poly(lactic acid)”, J. Appl. Polym. Sci. 1997, 66, 1507–1513.
  • Lemmouchi, Y.; Murariu, M.; Dos Santos, A. M.; Amass, A. J.; Schacht, E.; Dubois, P. “Plasticization of poly(lactide) with blends of tributyl citrate and low molecular weight poly(D,L-lactide)-b-poly(ethylene glycol) copolymers”, Eur. Polym. J. 2009, 45, 2839–2848.
  • Roberto, A.; Rachele, C.; Gennaro, G.; Veronica, A.; Stefano, F.; Maurizio, A.; Mariacristina, C.; Emanuela, E. M. “Plasticization of poly(lactic acid) through blending, with oligomers of lactic acid: Effect of the physical aging on properties”, Eur. Polym. J. 2015, 66, 533–542.
  • Ali, F.; Chang, Y.-W.; Kang, S. C.; Yoon, J. Y. “Thermal, mechanical and rheological properties of poly (lactic acid)/epoxidized soybean oil blends”, Polym. Bull. 2009, 62, 91–98.
  • Santos, E. F.; Oliveira, R. V. B.; Reiznautt, Q. B.; Samios, D.; Nachtigall, S. M. B. “Sunflower-oil biodiesel-oligoesters/polylactide blends: Plasticizing effect and ageing”, Polym. Test. 2014, 39, 23–29.
  • Wang, Y. B.; Hillmyer, M. A. “Polyethylene-poly(L-lactide) diblock copolymers: Synthesis and compatibilization of poly(L-lactide)/polyethylene blends”, J. Polym. Sci. Part A-Polym. Chem. 2001, 39, 2755–2766.
  • Anderson, K. S.; Lim, S. H.; Hillmyer, M. A. “Toughening of polylactide by melt blending with linear low-density polyethylene”, J. Appl. Polym. Sci. 2003, 89, 3757–3768.
  • Noda, I.; Satkowski, M. M.; Dowrey, A. E.; Marcott, C. “Polymer alloys of nodax copolymers and poly(lactic acid)”, Macromol. Biosci. 2004, 4, 269–275.
  • Jiang, L.; Liu, B.; Zhang, J. “Properties of poly(lactic acid)/poly(butylene adipate-co-terephthalate)/nanoparticle ternary composites”, Ind. Eng. Chem. Res. 2009, 48, 7594–7602.
  • Li, Y.; Shimizu, H. “Improvement in toughness of poly(l-lactide) (PLLA) through reactive blending with acrylonitrile–butadiene–styrene copolymer (ABS): Morphology and properties”, Eur. Polym. J. 2009, 45, 738–746.
  • Oyama, H. I. “Super-tough poly(lactic acid) materials: Reactive blending with ethylene copolymer”, Polymer 2009, 50, 747–751.
  • Wang, R.; Wang, S.; Zhang, Y.; Wan, C.; Ma, P. “Toughening modification of PLLA/PBS blends via in situ compatibilization”, Polym. Eng. Sci. 2009, 49, 26–33.
  • Afrifah, K. A.; Matuana, L. M. “Impact modification of polylactide with a biodegradable ethylene/acrylate copolymer”, Macromol. Mater. Eng. 2010, 295, 802–811.
  • Zeng, J. B.; Li, Y. D.; He, Y. S.; Li, S. L.; Wang, Y. Z. “Improving flexibility of poly(L-lactide) by blending with poly(L-lactic acid) based poly(ester-urethane): morphology, mechanical properties, and crystallization behaviors”, Ind. Eng. Chem. Res. 2011, 50, 6124–6131.
  • Jiao, L.; Huang, C. L.; Zeng, J. B.; Wang, Y. Z.; Wang, X. L. “Miscibility, crystallization and mechanical properties of biodegradable blends of poly(L-lactic acid) and poly(butylene succinate-b-ethylene succinate) multiblock copolymer”, Thermochim. Acta 2012, 539, 16–22.
  • Liu, H.; Chen, F.; Liu, B.; Estep, G.; Zhang, J. “Super toughened poly(lactic acid) ternary blends by simultaneous dynamic vulcanization and interfacial compatibilization”, Macromolecules 2010, 43, 6058–6066.
  • Liu, H.; Song, W.; Chen, F.; Guo, L.; Zhang, J. “Interaction of microstructure and interfacial adhesion on impact performance of polylactide (PLA) ternary blends”, Macromolecules 2011, 44, 1513–1522.
  • Lebarbe, T.; Grau, E.; Alfos, C.; Cramail, H. “Fatty acid-based thermoplastic poly(ester-amide) as toughening and crystallization improver of poly(L-lactide)”, Eur. Polym. J. 2015, 65, 276–285.
  • Lebarbe, T.; Grau, E.; Gadenne, B.; Alfos, C.; Cramail, H. “Synthesis of fatty acid-based polyesters and their blends with poly(L-lactide) as a way to tailor PLLA toughness”, ACS Sustain. Chem. Eng. 2015, 3, 283–292.
  • Notta-Cuvier, D.; Murariu, M.; Odent, J.; Delille, R.; Bouzouita, A.; Raquez, J. M.; Lauro, F.; Dubois, P. “Tailoring polylactide properties for automotive applications: Effects of co-addition of halloysite nanotubes and selected plasticizer”, Macromol. Mater. Eng. 2015, 300, 684–698.
  • Wang, Y.; Chen, K.; Xu, C.; Chen, Y. “Supertoughened biobased poly(lactic acid)-epoxidized natural rubber thermoplastic vulcanizates: Fabrication, co-continuous phase structure, interfacial in situ compatibilization, and toughening mechanism”, J. Phys. Chem. B 2015, 119, 12138–12146.
  • Yang, X.; Clenet, J.; Xu, H.; Odelius, K.; Hakkarainen, M. “Two step extrusion process: from thermal recycling of PHB to plasticized PLA by reactive extrusion grafting of PHB degradation products onto PLA chains”, Macromolecules 2015, 48, 2509–2518.
  • Yuan, D.; Chen, Z.; Xu, C.; Chen, K.; Chen, Y. “Fully biobased shape memory material based on novel cocontinuous structure in poly(Lactic Acid)/natural rubber TPVs fabricated via peroxide-induced dynamic vulcanization and in situ interfacial compatibilization”, ACS Sustain. Chem. Eng. 2015, 3, 2856–2865.
  • Coativy, G.; Misra, M.; Mohanty, A. K. “Microwave synthesis and melt blending of glycerol based toughening agent with poly(lactic acid)”, ACS Sustain. Chem. Eng. 2016, 4, 2142–2149.
  • Mauck, S. C.; Wang, S.; Ding, W.; Rohde, B. J.; Fortune, C. K.; Yang, G.; Ahn, S. K.; Robertson, M. L. “Biorenewable tough blends of polylactide and acrylated epoxidized soybean oil compatibilized by a polylactide star polymer”, Macromolecules 2016, 49, 1605–1615.
  • Zhang, X.; Zhang, Y. “Reinforcement effect of poly(butylene succinate) (PBS)-grafted cellulose nanocrystal on toughened PBS/polylactic acid blends”, Carbohydr. Polym. 2016, 140, 374–382.
  • Zhao, T. H.; He, Y.; Li, Y. D.; Wang, M.; Zeng, J. B. “Dynamic vulcanization of castor oil in a polylactide matrix for toughening”, RSC Adv. 2016, 6, 79542–79553.
  • Martin, O.; Avérous, L. “Poly(lactic acid): Plasticization and properties of biodegradable multiphase systems”, Polymer 2001, 42, 6209–6219.
  • Sinclaira, R. G. “The case for polylactic acid as a commodity packaging plastic”, J. Macromol. Sci., Part A: Pure Appl. Chem. 1996, 33, 585–597.
  • Baiardo, M.; Frisoni, G.; Scandola, M.; Rimelen, M.; Lips, D.; Ruffieux, K.; Wintermantel, E. “Thermal and mechanical properties of plasticized poly(L-lactic acid)”, J. Appl. Polym. Sci. 2003, 90, 1731–1738.
  • Courgneau, C.; Domenek, S.; Guinault, A.; Averous, L.; Ducruet, V. “Analysis of the structure-properties relationships of different multiphase systems based on plasticized poly(lactic acid)”, J. Polym. Environ. 2011, 19, 362–371.
  • Pillin, I.; Montrelay, N.; Grohens, Y. “Thermo-mechanical characterization of plasticized PLA: Is the miscibility the only significant factor?”, Polymer 2006, 47, 4676–4682.
  • Murariu, M.; Ferreira, A. D. S.; Alexandre, M.; Dubois, P. “Polylactide (PLA) designed with desired end-use properties: 1. PLA compositions with low molecular weight ester-like plasticizers and related performances”, Polym. Adv. Tech. 2008, 19, 636–646.
  • Vijayarajan, S.; Selke, S. E. M.; Matuana, L. M. “Continuous blending approach in the manufacture of epoxidized soybean oil plasticized poly(lactic acid) sheets and films”, Macromol. Mater. Eng. 2014, 299, 622–630.
  • Azwar, E.; Yin, B.; Hakkarainen, M. “Liquefied biomass derived plasticizer for polylactide”, J. Chem. Tech. Biotech. 2013, 88, 897–903.
  • Ljungberg, N.; Wesslen, B. “Tributyl citrate oligomers as plasticizers for poly (lactic acid): Thermo-mechanical film properties and aging”, Polymer 2003, 44, 7679–7688.
  • Zhang, H.; Fang, J.; Ge, H.; Han, L.; Wang, X.; Hao, Y.; Han, C.; Dong, L. “Thermal, mechanical, and rheological properties of polylactide/poly(1,2-propylene glycol adipate)”, Polym. Eng. Sci. 2013, 53, 112–118.
  • Ruellan, A.; Guinault, A.; Sollogoub, C.; Ducruet, V.; Domenek, S. “Solubility factors as screening tools of biodegradable toughening agents of polylactide”, J. Appl. Polym. Sci. 2015, 132, 42476.
  • Martin, O.; Averous, L. “Poly(lactic acid): plasticization and properties of biodegradable multiphase systems”, Polymer 2001, 42, 6209–6219.
  • Burgos, N.; Martino, V. P.; Jimenez, A. “Characterization and ageing study of poly(lactic acid) films plasticized with oligomeric lactic acid”, Polym. Degrad. Stab. 2013, 98, 651–658.
  • Jacobsen, S.; Fritz, H. G. “Plasticizing polylactide: The effect of different plasticizers on the mechanical properties”, Polym. Sci. Eng. 1999, 39, 1303–1310.
  • Xing, C.; Matuana, L. M. “Epoxidized soybean oil-plasticized poly(lactic acid) films performance as impacted by storage”, J. Appl. Polym. Sci. 2016, 133, article no. 43201.
  • Liu, G. C.; He, Y. S.; Zeng, J. B.; Li, Q. T.; Wang, Y. Z. “Fully biobased and supertough polylactide-based thermoplastic vulcanizates fabricated by peroxide-induced dynamic vulcanization and interfacial compatibilization”, Biomacromolecules 2014, 15, 4260–4271.
  • Liu, G. C.; He, Y. S.; Zeng, J. B.; Xu, Y.; Wang, Y. Z. “In situ formed crosslinked polyurethane toughened polylactide”, Polym. Chem. 2014, 5, 2530–2539.
  • Anderson, K. S.; Hillmyer, M. A. “The influence of block copolymer microstructure on the toughness of compatibilized polylactide/polyethylene blends”, Polymer 2004, 45, 8809–8823.
  • Su, Z.; Li, Q.; Liu, Y.; Hu, G. H.; Wu, C. “Compatibility and phase structure of binary blends of poly(lactic acid) and glycidyl methacrylate grafted poly(ethylene octane)”, Eur. Polym. J. 2009, 45, 2428–2433.
  • Ho, C. H.; Wang, C. H.; Lin, C. I.; Lee, Y. D. “Synthesis and characterization of TPO–PLA copolymer and its behavior as compatibilizer for PLA/TPO blends”, Polymer 2008, 49, 3902–3910.
  • Liu, H.; Guo, L.; Guo, X.; Zhang, J. “Effects of reactive blending temperature on impact toughness of poly(lactic acid) ternary blends”, Polymer 2012, 53, 272–276.
  • Hashima, K.; Nishitsuji, S.; Inoue, T. “Structure-properties of super-tough PLA alloy with excellent heat resistance”, Polymer 2010, 51, 3934–3939.
  • Chen, C. C.; Chueh, J. Y.; Tseng, H.; Huang, H. M.; Lee, S. Y. “Preparation and characterization of biodegradable PLA polymeric blends”, Biomaterials 2003, 24, 1167–1173.
  • Ishiaku, U. S.; Yang, X. Y.; Leong, Y. W.; Hamada, H.; Semba, T.; Kitagawa, K. “Effects of fiber content and alkali treatment on the mechanical and morphological properties of poly(lactic acid)/poly(caprolactone) blend jute fiber-filled biodegradable composites”, J. Biobased Mater. Bio. 2007, 1, 78–86.
  • Bai, H.; Huang, C.; Xiu, H.; Gao, Y.; Zhang, Q.; Fu, Q. “Toughening of poly(L-lactide) with poly(epsilon-caprolactone): Combined effects of matrix crystallization and impact modifier particle size”, Polymer 2013, 54, 5257–5266.
  • Jiang, L.; Wolcott, M. P.; Zhang, J. W. “Study of biodegradable polyactide/poly(butylene adipate-co-terephthalate) blends”, Biomacromolecules 2006, 7, 199–207.
  • Zhang, N.; Wang, Q.; Ren, J.; Wang, L. “Preparation and properties of biodegradable poly(lactic acid)/poly(butylene adipate-co-terephthalate) blend with glycidyl methacrylate as reactive processing agent”, J. Mater. Sci. 2009, 44, 250–256.
  • Ma, P.; Cai, X.; Zhang, Y.; Wang, S.; Dong, W.; Chen, M.; Lemstra, P. J. “In-situ compatibilization of poly(lactic acid) and poly(butylene adipate-co-terephthalate) blends by using dicumyl peroxide as a free-radical initiator”, Polym. Degrad. Stab. 2014, 102, 145–151.
  • Li, Y.; Shimizu, H. “Toughening of polylactide by melt blending with a biodegradable poly(ether)urethane elastomer”, Macromol. Biosci. 2007, 7, 921–928.
  • Yuan, Y. M.; Ruckenstein, E. “Polyurethane toughened polylactide”, Polym. Bull. 1998, 40, 485–490.
  • Han, J. J.; Huang, H. X. “Preparation and characterization of biodegradable polylactide/thermoplastic polyurethane elastomer blends”, J. Appl. Polym. Sci. 2011, 120, 3217–3223.
  • Feng, L.; Bian, X.; Cui, Y.; Chen, Z.; Li, G.; Chen, X. “Flexibility improvement of poly(L-lactide) by reactive blending with poly(ether urethane) containing poly(ethylene glycol) blocks”, Macromol. Chem. Phys. 2013, 214, 824–834.
  • Shi, Y. Y.; Zhang, W. B.; Yang, J. H.; Huang, T.; Zhang, N.; Wang, Y.; Yuan, G. P.; Zhang, C. L. “Super toughening of the poly(L-lactide)/thermoplastic polyurethane blends by carbon nanotubes”, RSC Adv. 2013, 3, 26271–26282.
  • Chang, K.; Robertson, M. L.; Hillmyer, M. A. “Phase inversion in polylactide/soybean oil blends compatibilized by poly(isoprene-b-lactide) block copolymers”, ACS Appl. Mater. Interfaces 2009, 1, 2390–2399.
  • Gramlich, W. M.; Robertson, M. L.; Hillmyer, M. A. “Reactive compatibilization of poly(L-lactide) and conjugated soybean oil”, Macromolecules 2010, 43, 2313–2321.
  • Stoclet, G.; Seguela, R.; Lefebvre, J. M. “Morphology, thermal behavior and mechanical properties of binary blends of compatible biosourced polymers: Polylactide/polyamide11”, Polymer 2011, 52, 1417–1425.
  • Ma, P.; Spoelstra, A. B.; Schmit, P.; Lemstra, P. J. “Toughening of poly (lactic acid) by poly (beta-hydroxybutyrate-co-beta-hydroxyvalerate) with high beta-hydroxyvalerate content”, Eur. Polym. J. 2013, 49, 1523–1531.
  • Schreck, K. M.; Hillmyer, M. A. “Block copolymers and melt blends of polylactide with Nodax™ microbial polyesters: Preparation and mechanical properties”, J. Biotech. 2007, 132, 287–295.
  • Chen, Y.; Yuan, D.; Xu, C. “Dynamically vulcanized biobased polylactide/natural rubber blend material with continuous cross-linked rubber phase”, ACS Appl. Mater. Interfaces 2014, 6, 3811–3816.
  • Zhang, C.; Wang, W.; Huang, Y.; Pan, Y.; Jiang, L.; Dan, Y.; Luo, Y.; Peng, Z. “Thermal, mechanical and rheological properties of polylactide toughened by expoxidized natural rubber”, Mater. Design 2013, 45, 198–205.
  • Kang, H.; Qiao, B.; Wang, R.; Wang, Z.; Zhang, L.; Ma, J.; Coates, P. “Employing a novel bioelastomer to toughen polylactide”, Polymer 2013, 54, 2450–2458.
  • Xie, L.; Xu, H.; Niu, B.; Ji, X.; Chen, J.; Li, Z. M.; Hsiao, B. S.; Zhong, G. J. “Unprecedented access to strong and ductile poly(lactic acid) by introducing in situ nanofibrillar poly(butylene succinate) for green packaging”, Biomacromolecules 2014, 15, 4054–4064.
  • Deng, Y.; Thomas, N. L. “Blending poly(butylene succinate) with poly(lactic acid): Ductility and phase inversion effects”, Eur. Polym. J. 2015, 71, 534–546.
  • Persenaire, O.; Quintana, R.; Lemmouchi, Y.; Sampson, J.; Martin, S.; Bonnaud, L.; Dubois, P. “Reactive compatibilization of poly(L-lactide)/poly(butylene succinate) blends through polyester maleation: From materials to properties”, Polym. Int. 2014, 63, 1724–1731.
  • Ojijo, V.; Ray, S. S. “Super toughened biodegradable polylactide blends with non-linear copolymer interfacial architecture obtained via facile in-situ reactive compatibilization”, Polymer 2015, 80, 1–17.
  • Wu, S. “Control of intrinsic brittleness and toughness of polymers and blends by chemical structure: A review”, Polym. Int. 1992, 29, 229–247.
  • Wellinghoff, S. T.; Baer, E. “Microstructure and its relationship to deformation processes in amorphous polymer glasses”, J. Appl. Polym. Sci. 1978, 22, 2025–2045.
  • Wu, S. “Chian structure, phase morphology, and toughness relationships in polymers and blends”, Polym. Eng. Sci. 1990, 30, 753–761.
  • Merz, E. H.; Claver, G. C. M., B. “Studies on heterogeneous polymeric systems”, J. Polym. Sci. 1956, 22, 325–341.
  • Wu, S. “Phase structure and adhesion in polymer blends: A criterion for rubber toughening”, Polymer 1985, 26, 1855–1863.
  • Borggreve, R. J. M.; Gaymans, R. J.; Eichenwald, H. M. “Impact behaviour of nylon-rubber blends: 6. Influence of structure on voiding processes, toughening mechanism”, Polymer 1989, 30, 78–83.
  • Dompas, D.; Groeninckx, G.; Isogawa, M.; Hasegawa, T.; Kadokura, M. “Cavitation versus debonding during deformation of rubber-modified poly(vinyl chloride)”, Polymer 1995, 36, 437–441.
  • Piorkowska, E.; Argon, A. S.; Cohen, R. E. “Size effect of compliant rubbery particles on craze plasticity in polystyrene”, Macromolecules 1990, 23, 3838–3848.
  • Okamoto, Y.; Miyagi, H.; Mitsui, S. “New cavitation mechanism of rubber dispersed polystyrene”, Macromolecules 1993, 26, 6547–6551.
  • Gao, G.; Zhang, J.; Yang, H.; Zhou, C.; Zhang, H. “Deformation mechanism of polystyrene toughened with sub-micrometer monodisperse rubber particles”, Polym. Int. 2006, 55, 1215–1221.
  • Pecorini, T. J.; Calvert, D. “The role of impact modifier particle size and adhesion on the toughness of PET. in toughening of plastics”, ACS Symposium Series 2000, 759, 141–158.
  • Deblieck, R. A. C.; van Beek, D. J. M.; Remerie, K.; Ward, I. M. “Failure mechanisms in polyolefines: The role of crazing, shear yielding and the entanglement network”, Polymer 2011, 52, 2979–2990.
  • Panda, B. P.; Mohanty, S.; Nayak, S. K. “Mechanism of toughening in rubber toughened polyolefin: A review”, Polym.-Plast. Techn. Eng. 2015, 54, 462–473.
  • Liang, J. Z.; Li, R. K. Y. “Rubber toughening in polypropylene: A review”, J. Appl. Polym. Sci. 2000, 77, 409–417.
  • Wu, J.; Mai, Y. W.; Yee, A. F. “Fracture toughness and fracture mechanisms of polybutylene-terephthalate/polycarbonate/impact-modifier blends”, J. Mater. Sci. 1994, 29, 4510–4522.
  • Cho, K.; Yang, J. H.; Chan, E. P. “The effect of interfacial adhesion on toughening behavior of rubber modified poly(methyl methacrylate)”, Polymer 1997, 38, 5161–5167.
  • Liu, Z.; Zhu, X.; Wu, L.; Li, Y.; Qi, Z.; Choy, C.; Wang, F. “Effects of interfacial adhesion on the rubber toughening of poly(vinyl chloride) Part 1. Impact tests”, Polymer 2001, 42, 737–746.
  • Koning, C.; Duin, M. V.; Pagnoulle, C.; Jerome, R. “Strategies for compatibilization of polymer blends”, Prog. Polym. Sci. 1998, 23, 707–757.
  • He, Y. S.; Zeng, J. B.; Liu, G. C.; Li, Q. T.; Wang, Y. Z. “Super-tough poly(L-lactide)/crosslinked polyurethane blends with tunable impact toughness”, RSC Adv. 2014, 4, 12857–12866.
  • Yuan, D.; Xu, C.; Chen, Z.; Chen, Y. “Crosslinked bicontinuous biobased polylactide/natural rubber materials: Super toughness, “net-like”-structure of NR phase and excellent interfacial adhesion”, Polym. Test. 2014, 38, 73–80.
  • Ding, C.; Shuttleworth, P. S.; Makin, S.; Clark, J. H.; Matharu, A. S. “New insights into the curing of epoxidized linseed oil with dicarboxylic acids”, Green Chem. 2015, 17, 4000–4008.
  • Mochizuki, M.; Mukai, K.; Yamada, K.; Ichise, N.; Murase, S.; Iwaya, Y. “Structural effects upon enzymatic hydrolysis of poly(butylene succinate-co-ethylene succinate)s”, Macromolecules 1997, 30, 7403–7407.
  • Zeng, J. B.; Huang, C. L.; Jiao, L.; Lu, X.; Wang, Y. Z.; Wang, X. L. “Synthesis and properties of biodegradable poly(butylene succinate-co-diethylene glycol succinate) copolymers”, Ind. Eng. Chem. Res. 2012, 51, 12258–12265.
  • Meng, F.; Qiu, Z. “Enhanced crystallization rate of biodegradable poly(butylene succinate-co-ethylene succinate) by poly(butylene fumarate) as an efficient polymeric nucleating agent”, RSC Adv. 2015, 5, 96290–96296.
  • Wang, C.; Ming, W.; Yan, D.; Zhang, C.; Yang, M.; Liu, Y.; Zhang, Y.; Guo, B.; Wan, Y.; Xing, J. “Novel membrane-based biotechnological alternative process for succinic acid production and chemical synthesis of bio-based poly (butylene succinate)”, Bioresource Technol. 2014, 156, 6–13.
  • Lv, L.; Wu, F.; Chen, S. C.; Wang, Y. Z.; Zeng, J. B. “Properties regulation of poly(butylene succinate) ionomers through their ionic group distribution”, Polymer 2015, 66, 148–159.
  • Wu, F.; Huang, C. L.; Zeng, J. B.; Li, S. L.; Wang, Y. Z. “Composition dependence of physical properties of biodegradable poly(ethylene succinate) urethane ionenes”, RSC Adv. 2014, 4, 54175–54186.
  • Wu, F.; Huang, C. L.; Zeng, J. B.; Li, S. L.; Wang, Y. Z. “Synthesis and characterization of segmented poly(butylene succinate) urethane ionenes containing secondary amine cation”, Polymer 2014, 55, 4358–4368.
  • Nikolic, M. S.; Djonlagic, J. “Synthesis and characterization of biodegradable poly(butylene succinate-co-butylene adipate)s”, Polym. Degrad. Stab. 2001, 74, 263–270.
  • Ojijo, V.; Ray, S. S.; Sadiku, R. “Role of specific interfacial area in controlling properties of immiscible blends of biodegradable polylactide and pol (butylene succinate)-co-adipate”, ACS Appl. Mater. Interfaces 2012, 4, 6689–6700.
  • Ojijo, V.; Ray, S. S.; Sadiku, R. “Toughening of biodegradable polylactide/poly(butylene succinate-co-adipate) blends via in situ reactive compatibilization”, ACS Appl. Mater. Interfaces 2013, 5, 4266–4276.
  • Tachibana, Y.; Kimura, S.; Kasuya, K. I. “Synthesis and verification of biobased terephthalic acid from furfural”, Sci. Rep. 2015, 5, article no. 8249.
  • Kumar, M.; Mohanty, S.; Nayak, S. K.; Parvaiz, M. R. “Effect of glycidyl methacrylate (GMA) on the thermal, mechanical and morphological property of biodegradable PLA/PBAT blend and its nanocomposites”, Bioresource Technol. 2010, 101, 8406–8415.
  • Signori, F.; Boggioni, A.; Righetti, M. C.; Escrig Rondan, C.; Bronco, S.; Ciardelli, F. “Evidences of transesterification, chain branching and cross-linking in a biopolyester commercial blend upon reaction with dicumyl peroxide in the melt”, Macromol. Mater. Eng. 2015, 300, 153–160.
  • Eyiler, E.; Chu, I. W.; Walters, K. B. “Toughening of poly(lactic acid) with the renewable bioplastic poly(trimethylene malonate)”, J. Appl. Polym. Sci. 2014, 131, 40888.
  • Gui, Z.; Xu, Y.; Cheng, S.; Gao, Y.; Lu, C. “Preparation and characterization of polylactide/poly(polyethylene glycol-co-citric acid) blends”, Polym. Bull. 2013, 70, 325–342.
  • Hu, X.; Kang, H.; Li, Y.; Li, M.; Wang, R.; Xu, R.; Qiao, H.; Zhang, L. “Direct copolycondensation of biobased elastomers based on lactic acid with tunable and versatile properties”, Polym. Chem. 2015, 6, 8112–8123.
  • Sheth, J. P.; Xu, J.; Wilkes, G. L. “Solid state structure–property behavior of semicrystalline poly(ether-block-amide) PEBAX® thermoplastic elastomers”, Polymer 2003, 44, 743–756.
  • Zhang, W.; Chen, L.; Zhang, Y. “Surprising shape-memory effect of polylactide resulted from toughening by polyamide elastomer”, Polymer 2009, 50, 1311–1315.
  • Han, L.; Han, C.; Dong, L. “Effect of crystallization on microstructure and mechanical properties of poly (ethylene oxide)-block-(amide-12) toughened poly(lactic acid) blend”, Polym. Int. 2013, 62, 295–303.
  • Han, L.; Han, C.; Dong, L. “Morphology and properties of the biosourced poly(lactic acid)/poly(ethylene oxide-b-amide-12) blends”, Polym. Compos. 2013, 34, 122–130.
  • Bugnicourt, E.; Cinelli, P.; Lazzeri, A.; Alvarez, V. “Polyhydroxyalkanoate (PHA): Review of synthesis, characteristics, processing and potential applications in packaging”, Express Polym. Lett. 2014, 8, 791–808.
  • Takagi, Y.; Yasuda, R.; Yamaoka, M.; Yamane, T. “Morphologies and mechanical properties of polylactide blends with medium chain length poly(3-hydroxyalkanoate) and chemically modified poly(3-hydroxyalkanoate)”, J. Appl. Polym. Sci. 2004, 93, 2363–2369.
  • Yoon, J. S.; Lee, W. S.; Kim, K. S.; Chin, I. J.; Kim, M. N.; Kim, C. “Effect of poly(ethylene glycol)-block-poly(L-lactide) on the poly[(R)-3-hydroxybutyrate]/poly(L-lactide) blends”, Eur. Polym. J. 2000, 36, 435–442.
  • Bartczak, Z.; Galeski, A.; Kowalczuk, M.; Sobota, M.; Malinowski, R. “Tough blends of poly(lactide) and amorphous poly( R,S-3-hydroxy butyrate)- morphology and properties”, Eur. Polym. J. 2013, 49, 3630–3641.
  • Noda, I.; Green, P. R.; Satkowski, M. M.; Schechtman, L. A. “Preparation and properties of a novel class of polyhydroxyalkanoate copolymers”, Biomacromolecules 2005, 6, 580–586.
  • Saito, Y.; Nakamura, S.; Hiramitsu, M.; Doi, Y. “Microbial synthesis and properties of poly(3-hydroxybutyrate-co-4-hydroxybutyrate)”, Polym. Int. 1996, 39, 169–174.
  • Bian, Y.; Han, C.; Han, L.; Lin, H.; Zhang, H.; Bian, J.; Dong, L. “Toughening mechanism behind intriguing stress-strain curves in tensile tests of highly enhanced compatibilization of biodegradable poly(lactic acid)/poly(3-hydroxybutyrate-co-4-hydroxybutyrate)blends”, RSC Adv. 2014, 4, 41722–41733.
  • Odent, J.; Leclere, P.; Raquez, J. M.; Dubois, P. “Toughening of polylactide by tailoring phase-morphology with P CL-co-LA random copolyesters as biodegradable impact modifiers”, Eur. Polym. J. 2013, 49, 914–922.
  • Rathi, S.; Chen, X.; Coughlin, E. B.; Hsu, S. L.; Golub, C. S.; Tzivanis, M. J. “Toughening semicrystalline poly(lactic acid) by morphology alteration”, Polymer 2011, 52, 4184–4188.
  • Rathi, S. R.; Coughlin, E. B.; Hsu, S. L.; Golub, C. S.; Ling, G. H.; Tzivanis, M. J. “Effect of midblock on the morphology and properties of blends of ABA triblock copolymers of PDLA-mid-block-PDLA with PLLA”, Polymer 2012, 53, 3008–3016.
  • Sun, Y.; He, C. “Biodegradable “core-shell” rubber nanoparticles and their toughening of poly(lactides)”, Macromolecules 2013, 46, 9625–9633.
  • Qi, F.; Tang, M.; Chen, X.; Chen, M.; Guo, G.; Zhang, Z. “Morphological structure, thermal and mechanical properties of tough poly(lactic acid) upon stereocomplexes”, Eur. Polym. J. 2015, 71, 314–324.
  • Feng, L.; Bian, X.; Li, G.; Chen, Z.; Chen, X. “Compatibility, mechanical properties and stability of blends of polylactide and polyurethane based on poly(ethylene glycol)-b-polylactide copolymers by chain extension with diisocyanate”, Polym. Degrad. Stab. 2016, 125, 148–155.
  • Rose, K.; Steinbuchel, A. “Biodegradation of natural rubber and related compounds: Recent insights into a hardly understood catabolic capability of microorganisms”, Appl. Environ. Microbiol. 2005, 71, 2803–2812.
  • Bitinis, N.; Verdejo, R.; Cassagnau, P.; Lopez-Manchado, M. A. “Structure and properties of polylactide/natural rubber blends”, Mater. Chem. Phys. 2011, 129, 823–831.
  • Huang, Y.; Zhang, C.; Pan, Y.; Wang, W.; Jiang, L.; Dan, Y. “Study on the effect of dicumyl peroxide on structure and properties of poly(lactic acid)/natural rubber blend”, J. Polym. Environ. 2013, 21, 375–387.
  • Zhang, C.; Huang, Y.; Luo, C.; Jiang, L.; Dan, Y. “Enhanced ductility of polylactide materials: Reactive blending with pre-hot sheared natural rubber”, J. Polym. Res. 2013, 20, 121.
  • Jaratrotkamjorn, R.; Khaokong, C.; Tanrattanakul, V. “Toughness enhancement of poly(lactic acid) by melt blending with natural rubber”, J. Appl. Polym. Sci. 2012, 124, 5027–5036.
  • Zhang, C.; Man, C.; Pan, Y.; Wang, W.; Jiang, L.; Dan, Y. “Toughening of polylactide with natural rubber grafted with poly(butyl acrylate)”, Polym. Int. 2011, 60, 1548–1555.
  • Chumeka, W.; Pasetto, P.; Pilard, J. F.; Tanrattanakul, V. “Bio-based triblock copolymers from natural rubber and poly(lactic acid): Synthesis and application in polymer blending”, Polymer 2014, 55, 4478–4487.
  • Nghia, P. T.; Siripitakchai, N.; Klinklai, W.; Saito, T.; Yamamoto, Y.; Kawahara, S. “Compatibility of liquid deproteinized natural rubber having epoxy group (LEDPNR)/poly (l-lactide) blend”, J. Appl. Polym. Sci. 2008, 108, 393–399.
  • Saito, T.; Klinklai, W.; Yamamoto, Y.; Kawahara, S.; Isono, Y.; Ohtake, Y. “Quantitative analysis for reaction between epoxidized natural rubber and poly (l-Lactide) through 1H NMR spectroscopy”, J. Appl. Polym. Sci. 2010, 115, 3598–3604.
  • Chen, Y.; Chen, K.; Wang, Y.; Xu, C. “Biobased heat-triggered shape-memory polymers based on polylactide/epoxidized natural rubber blend system fabricated via peroxide-induced dynamic vulcanization: Co-continuous phase structure, shape memory behavior, and interfacial compatibilization”, Ind. Eng. Chem. Res. 2015, 54, 8723–8731.
  • Tham, W. L.; Poh, B. T.; Ishak, Z. A. M.; Chow, W. S. “Epoxidized natural rubber toughened poly(lactic acid)/halloysite nanocomposites with high activation energy of water diffusion”, J. Appl. Polym. Sci. 2016, 133, 42850.
  • Guner, F. S.; Yagci, Y.; Erciyes, A. T. “Polymers from triglyceride oils”, Prog. Polym. Sci. 2006, 31, 633–670.
  • Robertson, M. L.; Chang, K.; Gramlich, W. M.; Hillmyer, M. A. “Toughening of polylactide with polymerized soybean oil”, Macromolecules 2010, 43, 1807–1814.
  • Robertson, M. L.; Paxton, J. M.; Hillmyer, M. A. “Tough blends of polylactide and castor oil”, ACS Appl. Mater. Interfaces 2011, 3, 3402–3410.
  • Gurunathan, T.; Mohanty, S.; Nayak, S. K. “Preparation and performance evaluation of castor oil-based polyurethane prepolymer/polylactide blends”, J. Mater. Sci. 2014, 49, 8016–8030.
  • Huang, S.; Sun, H.; Sun, J.; Li, G.; Chen, X. “Biodegradable tough blends of poly(L-lactide) and poly(castor oil)-poly(L-lactide) copolymer”, Mater. Lett. 2014, 133, 87–90.
  • Lao, S. C.; Yong, W.; Nguyen, K.; Moon, T. J.; Koo, J. H.; Pilato, L.; Wissler, G. “Flame-retardant polyamide 11 and 12 nanocomposites: Processing, morphology, and mechanical properties”, J. Compos. Mater. 2010, 44, 2933–2951.
  • Dong, W.; Cao, X.; Li, Y. “High-performance biosourced poly(lactic acid)/polyamide 11 blends with controlled salami structure”, Polym. Int. 2014, 63, 1094–1100.
  • Yu, R. L.; Zhang, L.S.; Feng, Y. H.; Zhang, R. Y.; Zhu, J. “Improvement in toughness of polylactide by melt blending with bio-based poly(ester)urethane”, Chin. J. Polym. Sci. 2014, 32, 1099–1110.
  • Zhang, L.; Xiong, Z.; Shams, S. S.; Yu, R.; Huang, J.; Zhang, R.; Zhu, J. “Free radical competitions in polylactide/bio-based thermoplastic polyurethane/free radical initiator ternary blends and their final properties”, Polymer 2015, 64, 69–75.
  • Zhang, X.; Koranteng, E.; Wu, Z.; Wu, Q. “Structure and properties of polylactide toughened by polyurethane prepolymer”, J. Appl. Polym. Sci. 2016, 133, article no. 42983.

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