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Articles

A novel approach to prepare large-scale and narrow-dispersed latex particles by emulsion polymerization based on particle coagulation mechanism

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Pages 119-127 | Received 25 Jun 2015, Accepted 22 Nov 2015, Published online: 22 Dec 2015

References

  • Zhang Q, Yu G, Wang WJ, et al. Preparation of CO2/N2-triggered reversibly coagulatable and redispersible polyacrylate latexes by emulsion polymerization using a polymeric surfactant. Macromol. Rapid Commun. 2012;33:916–921.10.1002/marc.201200033
  • Fowler CI, Muchemu CM, Miller RE, et al. Emulsion polymerization of styrene and methyl methacrylate using cationic switchable surfactants. Macromolecules 2011;44:2501–2509.10.1021/ma102936a
  • Behniafar H, Yousefzadeh D. Chemical synthesis of PEDOT/Ag nanocomposites via emulsion technique in silver colloid. Des. Monomers Polym. 2015;18:6–11.10.1080/15685551.2014.918018
  • Zhang Q, Wang WJ, Lu Y, et al. Reversibly coagulatable and redispersible polystyrene latex prepared by emulsion polymerization of styrene containing switchable amidine. Macromolecules 2011;44:6539–6545.10.1021/ma201056g
  • Jiang W, Li W, Chen L. Synthesis and characterization of novel acrylate emulsion containing phosphorus and silicon prepared via semi-continuous seeded emulsion polymerization. Des. Monomers Polym. 2015;18:180–184.10.1080/15685551.2014.971393
  • Carro S, Herrera-Ordonez J, Castillo-Tejas J. On the evolution of the rate of polymerization, number and size distribution of particles in styrene emulsion polymerization above CMC. J. Polym. Sci., Part A: Polym. Chem. 2010;48:3152–3160.10.1002/pola.v48:14
  • Kazantsev OA, Kamorin DM, Orekhov DV, et al. Study of amphiphilic properties of amine- and oligo(ethylene glycol)-containing (meth)acrylic monomers. Des. Monomers Polym. 2015;18:378–384.10.1080/15685551.2015.1012627
  • Ishii H, Ishii M, Nagao D, et al. Advanced synthesis for monodisperse polymer nanoparticles in aqueous media with sub-millimolar surfactants. Polymer 2014;55:2772–2779.10.1016/j.polymer.2014.04.011
  • Telford AM, Pham BT, Neto C, et al. Micron-sized polystyrene particles by surfactant-free emulsion polymerization in air: synthesis and mechanism. J. Polym. Sci., Part A: Polym. Chem. 2013;51:3997–4002.10.1002/pola.26841
  • Dobrowolska ME, van Esch JH, Koper GJM. Direct visualization of “coagulative nucleation” in surfactant-free emulsion polymerization. Langmuir 2013;29:11724–11729.10.1021/la4027927
  • Dobrowolska ME, Koper GJM. Optimal ionic strength for nonionically initiated polymerization. Soft Matter 2014;10:1151–1154.10.1039/c3sm51998h
  • Chou IC, Chiu WY. Novel synthesis of multi-scaled, surfactant-free monodisperse latexes via alcoholic dispersion polymerization in a mixed ionic/nonionic initiation system. Macromolecules 2013;46:3561–3569.10.1021/ma400277s
  • Chern CS, Lee C. Emulsion polymerization of styrene stabilized with an amphiphilic PEG-containing graft copolymer. Macromol. Chem. Phys. 2001;202:2750–2759.10.1002/(ISSN)1521-3935
  • Krishnan S, Klein A, El-Aasser MS, et al. Effect of surfactant concentration on particle nucleation in emulsion polymerization of n-butyl methacrylate. Macromolecules 2003;36:3152–3159.10.1021/ma021120p
  • Feeney PJ, Napper DH, Gilbert RG. Coagulative nucleation and particle size distributions in emulsion polymerization. Macromolecules 1984;17:2520–2529.10.1021/ma00142a010
  • Coen EM, Gilbert RG, Morrison BR, et al. Modelling particle size distributions and secondary particle formation in emulsion polymerisation. Polymer 1998;39:7099–7112.10.1016/S0032-3861(98)00255-9
  • Kemmere MF, Meuldijk J, Drinkenburg AAH, et al. Aspects of coagulation during emulsion polymerization of styrene and vinyl acetate. J. Appl. Polym. Sci. 1998;69:2409–2421.10.1002/(ISSN)1097-4628
  • Piirma I, Chen SR. Adsorption of ionic surfactants on latex particles. J. Colloid Interface Sci. 1980;74:90–102.10.1016/0021-9797(80)90173-3
  • Vijayendran BR. Polymer polarity and surfactant adsorption. J. Appl. Polym. Sci. 1979;23:733–742.10.1002/app.1979.070230308
  • Fitch RM, Tsai CH. Particle formation in polymer colloids, III: prediction of the number of particles by a homogeneous nucleation theory. In: Fitch RM, editor. Polymer colloids. Chicago, IL: Springer; 1971. p. 73–102.10.1007/978-1-4684-1920-7
  • Ganeva DE, Sprong E, de Bruyn H, et al. Particle formation in ab initio RAFT mediated emulsion polymerization systems. Macromolecules 2007;40:6181–6189.10.1021/ma070442w
  • Camli ST, Buyukserin F, Balci O, et al. Size controlled synthesis of sub-100nm monodisperse poly(methylmethacrylate) nanoparticles using surfactant-free emulsion polymerization. J. Colloid Interface Sci. 2010;344:528–532.10.1016/j.jcis.2010.01.041
  • Ohshima H. Approximate analytic expression for the stability ratio of colloidal dispersions. Colloid Polym. Sci. 2014;292:2269–2274.10.1007/s00396-014-3257-1
  • Li Z, Cheng H, Han CC. Mechanism of narrowly dispersed latex formation in a surfactant-free emulsion polymerization of styrene in acetone-water mixture. Macromolecules 2012;45:3231–3239.10.1021/ma202535j
  • Kim G, Lim S, Lee BH, et al. Effect of homogeneity of methanol/water/monomer mixture on the mode of polymerization of MMA: soap-free emulsion polymerization versus dispersion polymerization. Polymer 2010;51:1197–1205.10.1016/j.polymer.2009.12.038
  • Smeets NM, Hutchinson RA, McKenna TF. Determination of the critical chain length of oligomers in dispersion polymerization. ACS Macro Lett. 2011;1:171–174.
  • Nomura M, Tobita H, Suzuki K. Emulsion polymerization: kinetic and mechanistic aspects. In: Okubo M, editor. Polymer particles. Berlin: Springer; 2005. Vol. 175. p. 1–128. 10.1007/b14102
  • Liu BJ, Zhang MY, Gui Y, et al. Effect of aqueous phase composition on particle coagulation behavior in batch emulsion polymerization of styrene. J. Colloids Surf., A 2014;452:159–164.10.1016/j.jcis.2013.11.053
  • La Mer VK, Dinegar RH. Theory, production and mechanism of formation of monodispersed hydrosols. J. Am. Chem. Soc. 1950;72:4847–4854.10.1021/ja01167a001
  • Sajjadi S. Particle formation and coagulation in the seeded semibatch emulsion polymerization of butyl acrylate. J. Polym. Sci., Part A: Polym. Chem. 2000;38:3612–3630.10.1002/(ISSN)1099-0518
  • Herrera-Ordonez J, Rivera O, Maldonado-Textle H, et al. Kinetics of styrene emulsion polymerization above the critical micelle concentration: effect of the initial monomer concentration on the molecular weight. J. Polym. Sci., Part A: Polym. Chem. 2005;43:1963–1972.10.1002/(ISSN)1099-0518
  • Nagao D, Yamada Y, Inukai S, et al. Quantitative understanding of the self-sharpening of growing polymer particle size distributions in soap-free emulsion polymerization. Polymer 2015;68:176–182.10.1016/j.polymer.2015.05.020
  • Suwabe C, Nagao D, Ishii H, et al. Chemical bonding heterocoagulation of nanoparticles onto polymeric spheres by two-step addition of polymerizable coupling agent. Colloid Polym. Sci. 2015;293:2095–2100.10.1007/s00396-015-3603-y

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