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Articles

Bis(cyclopentadienyl) lanthanide benzylthiolate: synthesis, molecular structure and catalytic property for ε-caprolactone –polymerization

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Pages 233-239 | Received 04 Nov 2018, Accepted 23 Dec 2018, Published online: 10 Jan 2019

References

  • Wehr-Candler T, Henderson W. Coordination chemistry of the thiosalicylate ligand. Coord Chem Rev. 2016;313:111–155. doi: 10.1016/j.ccr.2016.01.011
  • Mashima K, Nakayama Y, Shibahara T, et al. Synthesis of arenethiolate complexes of divalent and trivalent lanthanides from metallic lanthanides and diaryl disulfides: crystal structures of [{Yb(hmpa)3}2(μ-SPh)3][SPh] and Ln(SPh)3(hmpa)3 (Ln = Sm, Yb; hmpa = Hexamethylphosphoric Triamide). Inorg Chem. 1996;35:93–99. doi: 10.1021/ic950050i
  • Wu ZZ, Huang ZE, Cai RF, et al. Synthesis and thermal stability of binuclear biscyclopentadienyl lanthanide thiolates, X-ray crystal structure of [(C5H5)2Yb(μ-SCH2CH2CH2CH3)]2. J Organomet Chem. 1996;506:25–30. doi: 10.1016/0022-328X(95)05677-H
  • Tiekink E RT, Henderson W. Coordination chemistry of 3- and 4-mercaptobenzoate ligands: versatile hydrogen-bonding isomers of the thiosalicylate (2-mercaptobenzoate) ligand. Coord Chem Rev. 2017;341:19–52. doi: 10.1016/j.ccr.2017.03.025
  • Evans WJ, Miller KA, Lee DS, et al. Synthesis, structure, and ligand-based reduction reactivity of trivalent organosamarium benzene chalcogenolate complexes (C5Me5)2Sm(EPh)(THF) and [(C5Me5)2Sm(μ-EPh)]2. Inorg Chem. 2005;44:4326–4332. doi: 10.1021/ic0502170
  • Kumar GA, Riman RE, Brennan JG. NIR emission from molecules and clusters with lanthanide-chalcogen bonds. Coord Chem Rev. 2014;273–274:111–124. doi: 10.1016/j.ccr.2014.04.009
  • Cheng ML, Li HX, Zhang WH, et al. Protonolysis reactions of [(Me3Si)2N]3Ln(μ-Cl)Li(THF)3 with tBuSH or EtSH: isolation, structures and catalytic properties of dinuclear complexes [{(Me3Si)2N}2Ln(μ-StBu)]2 and tetranuclear complexes [Li(thf)4][{(Me3Si)2N}4Ln4(μ4-SEt)(μ-SEt)8] (Ln = Pr, Sm). Eur J Inorg Chem. 2007;2007:1889–1896. doi: 10.1002/ejic.200601132
  • Nakayama Y, Shibahara T, Fukumoto H, et al. Syndiospecific polymerization of methyl methacrylate catalyzed by lanthanoid thiolate complexes bearing a hexamethylphosphoric triamide ligand. Macromolecules. 1996;29:8014–8016. doi: 10.1021/ma960387j
  • Sun HM, Li HR, Yao CS, et al. Lanthanide thiolate complexes: novel initiators for ring-opening polymerization of ε-caprolactone. Chin J Chem. 2005;23:1541–1544. doi: 10.1002/cjoc.200591541
  • Yuan F, Zhou Y, Li L, et al. Synthsis and structures of amine bis(phenolate) lanthanide thiolates and their application in the polymerization of ε-caprolactone. Inorg Chim Acta. 2013;408:33–38. doi: 10.1016/j.ica.2013.08.019
  • Wu ZZ, Ma WW, Huang ZE, et al. Synthesis and crystal structure of binuclear biscyclopentadienyl ytterbium N-propyl thiolate [(C5H5)2Yb(μ-SCH2CH2CH3)]2. Polyhedron. 1996;15:3427–3432. doi: 10.1016/0277-5387(96)00026-5
  • Zhang Z, Zhang L, Li Y, et al. Activation of bis(guanidinate)lanthanide alkyl and aryl complexes on elemental sulfur: synthesis and characterization of bis(guanidinate)lanthanide thiolates and disulfides. Inorg Chem. 2010;49:5715–5722. doi: 10.1021/ic100617n
  • Zhang ZX, Li YR, Liu RT, et al. Insertion reaction of elemental sulfur into the Ln-C bond: synthesis and characterization of [(C5H4SiMe2tBu)2Ln(μ-SR)]2 (R = Me, Ln = Yb, Er, Dy, Y; R = nBu, Ln = Yb, Dy). Polyhedron. 2007;26:4986–4992. doi: 10.1016/j.poly.2007.07.010
  • Zhang J, Ma L, Cai R, et al. Substituent effects on isocyanate insertion into a lanthanide-sulfur bond. Unexpected construction of a coordinated thiazolate ring. Organometallics. 2005;24:738–742. doi: 10.1021/om0492606
  • Poremba P, Noltemeyer M, Schmidt HG, et al. Monomere bis(η5-cyclopentadienyl) lanthanoid(III) komplexe mit raumerfullenden alkoxid- und thiolat-liganden: molekulstruktur von (C5H5)2Yb(THF)[SC6H2(CF3)3-2,4,6]. J Organomet Chem. 1995;501:315–319. doi: 10.1016/0022-328X(95)05703-R
  • Gu Z, Li L, Bao Q, et al. Lanthanocene diolate complexes: synthesis, structures and catalytic property for ε-caprolactone polymerization. Chin J Chem. 2015;33:563–567. doi: 10.1002/cjoc.201400826

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