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Journal of Nuclear Science and Technology Volume 44, 2007 - Issue 2
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ARTICLE

Separation of Americium(III) from Europium(III) by Extraction Based on in situ Formation of Dioctylammonium Dioctyldithiocarbamate Extractant

Sunao MIYASHITA Radiochemistry Research Laboratory, Faculty of Science, Shizuoka University, 836 Ohya, Suruga-ku, Shizuoka-shi, 422-8529, Japan
,
Makoto YANAGA Radiochemistry Research Laboratory, Faculty of Science, Shizuoka University, 836 Ohya, Suruga-ku, Shizuoka-shi, 422-8529, Japan
,
Isamu SATOH Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai-shi, 980-8577, Japan
&
Hideo SUGANUMA Radiochemistry Research Laboratory, Faculty of Science, Shizuoka University, 836 Ohya, Suruga-ku, Shizuoka-shi, 422-8529, Japan
Pages 233-237 | Received 15 Mar 2006, Accepted 31 Oct 2006, Published online: 05 Jan 2012

References

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  • Mirvaliev , R. , Watanabe , M. Matsumura , T. 2004 . “Selective separation of Am(III) from Ln(III) with a novel synergistic extraction system, N,N,N',N'-tetrakis(2-methylpyridyl)ethylendiamine (TPEN) and carboxylic acid in 1-octanol” . J. Nucl. Sci. Technol. , 41 : 1122
  • Kolarik , Z. , Mülliich , U. and Gassner , F. 1999 . “Selective extraction of Am(III) over Eu(III) by 2,6-ditriazolyl- and 2,6-ditriazinylpyridines” . Solvent Extr. Ion Exch. , 17 : 23
  • Zhu , Y. , Chen , J. and Jiao , R. 1996 . “Extraction of Am(III) and Eu(III) from nitrate solution with purified cyanex 301” . Solvent Extr. Ion Exch. , 14 : 61
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  • Miyashita , S. , Yanaga , M. Satoh , I. 2006 . “Separation of Americium(III) from Europium(III) by dioctylammonium dioctyldi-thiocarbamate/nitrobenzene extraction” . Chem. Lett. , 35 : 236
  • Fujinaga , K. , Fukai , M. Seike , Y. 1999 . “Solvent extraction of transition metals by an in situ extractant formation method: Utilization of an easily-solidifying solvent” . Anal. Sci. , 15 : 333
  • Hulanicki , A. 1967 . “Complexation reactions of dithiocarbamates” . Talanta , 14 : 1371
  • Voden , V. G. , Obukhova , M. E. and Pushlenkov , M. F. 1969 . “Complex formation in Americium with caprinohydroxamic acid” . Sov. Radiochem. , 11 : 633

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