Solubility and Solubility-Limiting Solid Phase in M(IV)-OH-Dicarboxylate Ternary Aqueous System

References

• Hummel , W. , Anderegg , G. , Rao , L. , Puigdomènech , I. and Tochiyama , O. 2005 . Chemical Thermodynamics Edited by: Mompean , F. J. Vol. 9 , North-Holland, Amsterdam : Elsevier . Chemical Thermodynamics of Compounds and Complexes of U, Np, Pu, Am, Tc, Se, Ni and Zr with Selected Organic Ligands, in:
   Google Scholar
• Babko , A. K. and Dubovenko , L. I. 1960 . “Zirconium oxalate complexes” . Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol. , 3 : 226
   Google Scholar
• Shvedov , V. and Maslov , E. 1962 . “Determination of the composition and stability constants of complex compounds by electromigration. I. Determination of the composition and stability constants of oxalate complexes of zirconium” . Sov. Radiochem. , 4 : 376
   Google Scholar
• Caletka , R. , Kyrs , M. and Rais , J. 1964 . “Sorption of zirconium by silica gel from nitrate medium in the presence of oxalic acid, EDTA and Arsenazo I” . J. Inorg. Nucl. Chem. , 26 : 1443
   Web of Science ®Google Scholar
• Bagawde , S. V. , Ramakrishna , V. V. and Patil , S. K. 1976 . “Oxalate complexing of tetravalent actinides” . J. Inorg. Nucl. Chem. , 38 : 1669
   Google Scholar
• Erten , H. N. , Mohammed , A. K. and Choppin , G. R. 1994 . “Variation of stability constants of thorium and uranium oxalate complexes with ionic strength” . Radiochim. Acta , 66/67 : 123
   Google Scholar
• Bernardo , P. Di. , Dinapoli , V. , Cassol , A. and Magon , L. 1977 . “Thermodynamic properties of actinide complexes. 4. Thorium(IV)-malonate system and uranyl(VI)-malonate system” . J. Inorg. Nucl. Chem. , 39 : 1659
   Google Scholar
• Tomat , G. , Magon , L. , Portanova , R. and Cassol , A. 1972 . “Complexes of thorium(IV)” . Z. Anorg. Allq. Chem. , 393 : 184
   Google Scholar
• Baes , C. F. and Mesmer , R. E. 1976 . The Hydrolysis of Cations New York : John Wiley & Sons .
   Google Scholar
• Guillaumont , R. , Fanghänel , Th. , Fuger , J. , Grenthe , I. , Neck , V. , Palmer , D. and Rand , M. 2003 . Chemical Thermodynamics Edited by: Mompean , F. J. Vol. 5 , North-Holland, Amsterdam : Elsevier . Update on the Chemical Thermodynamics of Uranium, Neptunium, Plutonium, Americium and Technetium, in:
   Google Scholar
• Brown , P. , Curti , E. , Grambow , B. and Ekberg , C. 2005 . Chemical Thermodynamics Edited by: Mompean , F. J. Vol. 8 , North-Holland, Amsterdam : Elsevier . Chemical Thermodynamics of Zirconium, in:
   Google Scholar
• Kobayashi , T. , Sasaki , T. , Takagi , I. and Moriyama , H. 2009 . “Solid phase precipitates in (Zr, Th)-OH-(oxalate, malonate) ternary aqueous system” . Radiochim. Acta , 97 : 237
   Google Scholar
• Kobayashi , T. , Sasaki , T. , Takagi , I. and Moriyama , H. 2009 . “Zirconium solubility in ternary aqueous system of Zr(IV)-OH-carboxylates” . J. Nucl. Sci. Technol. , 46 : 142
   Web of Science ®Google Scholar
• Kobayashi , T. , Sasaki , T. , Takagi , I. and Moriyama , H. 2009 . “Solubility of thorium(IV) in the presence of oxalic and malonic acids” . J. Nucl. Sci. Technol. , 46 : 1085
   Web of Science ®Google Scholar
• D'Eye , R. W.M. and Sellman , P. G. 1955 . “The thermal decomposition of thorium oxalate” . J. Inorg. Nucl. Chem. , 1 : 143
   Web of Science ®Google Scholar
• Pazukhin , E. , Smirnova , E. , Pazurkhina , Y. and Kiselev , P. 1988 . “Optimization of conditions for precipitation of thorium oxalate. 4. State of thorium in oxalate solutions” . Soviet Radiochim. , 30 : 308
   Web of Science ®Google Scholar
• Aybers , M. 1998 . “Kinetic study of the thermal decomposition of thorium oxalate dihydrate” . J. Nucl. Mater. , 252 : 28
   Web of Science ®Google Scholar
• Sasaki , T. , Kobayashi , T. , Takagi , I. and Moriyama , H. 2006 . “Solubility measurement of zirconium(IV) hydrous oxide” . Radiochim. Acta , 94 : 489
   Web of Science ®Google Scholar
• Sasaki , T. , Takaoka , Y. , Kobayashi , T. , Fujii , T. , Takagi , I. and Moriyama , H. 2008 . “Hydrolysis constants and complexation of Th(IV) with carboxylates” . Radiochim. Acta , 96 : 79
   Google Scholar
• Felmy , A. R. , Rai , D. and Mason , M. J. 1991 . “The solubility of hydrous thorium(IV) oxide in chloride media: Development of an aqueous ion-interaction model” . Radiochim. Acta , 55 : 177
   Web of Science ®Google Scholar
• Moon , H. 1989 . “Equilibrium ultrafiltration of hydrolyzed thorium(IV) solutions” . Bull. Korean Chem. Soc. , 10 : 270
   Web of Science ®Google Scholar
• Bilinski , H. and Brničevič , N. 1983 . “Precipitation and complex formation of zirconium(IV) with malonic, succinic and adipic acids at 298 K” . Croatica Chemica Acta , 56 : 53
   Google Scholar
• Cho , H. , Walther , C. , Roche , J. , Neck , V. , Denecke , M. A. , Dardenne , K. and Fanghänel , Th. 2005 . “Combined LIBD and XAFS investigation of the formation and structure of Zr(IV) colloids” . Anal. Bioanal. Chem. , 383 : 28
   PubMed Web of Science ®Google Scholar
• Smith , R. M. 1988 . NIST Critically Selected Stability Constants of Metal Complexes Database Version 5.0, National Institute of Standards & Technology, U.S. Secretary of Commerce, Gaithersburg
   Google Scholar
• Sasaki , T. , Kobayashi , T. , Takagi , I. and Moriyama , H. 2008 . “Hydrolysis constant and coordination geometry of zirconium(IV)” . J. Nucl. Sci. Technol. , 45 : 735
   Web of Science ®Google Scholar
• Ekberg , C. , Kallvenius , G. , Albinsson , Y. and Brown , P. 2004 . “Studies on the hydrolytic behavior of zirconium(IV)” . J. Solution Chem. , 33 : 47
   Web of Science ®Google Scholar
• Curti , E. 2001 . Paul Scherrer Institut Rep. TM-44–01-01
   Google Scholar
• Fujiwara , K. , Yamana , H. , Fujii , T. and Moriyama , H. 2003 . “Determination of uranium(IV) hydrolysis constants and solubility product of UO2·xH2O” . Radiochim. Acta , 91 : 345
   Web of Science ®Google Scholar
• Dash , S. , Krishnan , R. , Kamruddin , M. , Tyagi , A. K. and Raj , B. 2001 . “Temperature programmed decomposition of thorium oxalate hexahydrate” . J. Nucl. Mater. , 295 : 281
   Google Scholar
• Neck , V. and Kim , J. I. 2001 . “Solubility and hydrolysis of tetravalent actinides” . Radiochim. Acta , 89 : 1
   Web of Science ®Google Scholar