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Original Articles

Methods for the determination of European Union-permitted added natural colours in foods: a review

Pages 527-596 | Received 07 Sep 2010, Accepted 11 Jan 2011, Published online: 18 Mar 2011

References

  • Abramov , VV , Chesnokova , SM , Andreev , PA and Sapalova , OI . 1982 . Determination of iron (II) and (III) oxides in glasses . J Analyt Chem USSR , 37 ( 11 ) : 1579 – 1581 .
  • Airs , RL , Atkinson , JE and Keely , BJ . 2001 . Development and application of a high resolution liquid chromatographic method for the analysis of complex pigment distributions . J Chromatogr A , 917 : 167 – 177 .
  • Airs , RL and Keely , BJ . 2000 . A novel approach for sensitivity enhancement in atmospheric pressure chemical ionisation liquid chromatography/mass spectrometry of chlorophylls . Rapid Comm Mass Spectrom , 14 : 125 – 128 .
  • Akyilmaz , E and Kozgus , O . 2009 . Determination of calcium in milk and water samples by using catalase enzyme electrode . Food Chem , 115 : 347 – 351 .
  • Alghamdi , AH , Alshammery , HH and Abdalla , MA . 2009 . Determination of carmine food dye (E120) in foodstuffs by stripping voltammetry . J AOAC Int , 92 ( 5 ) : 1454 – 1459 .
  • Almela , L , Fernández-Lopez , JA and Roca , MJ . 2000 . High-performance liquid chromatographic screening of chlorophyll derivatives produced during fruit screening . J Chromatogr A , 870 : 483 – 489 .
  • Amakawa , E , Ogiwara , T , Takeuchi , M , Ohnishi , K and Kano , I . 1993 . Determination of sodium copper chlorophyllin in foods . Ann Rep Tokyo Metropolitan Res Lab Public Health , 44 : 131 – 137 .
  • Ames , JL , Inns , EL and Nursten , HE . 2000 . Development of a surveillance method for Class III caramel in foods , Report: Project Number A02006 London : Food Standards Agency .
  • Ames , JM , Nursten , HE , Castle , L , Gapps , TR , Royle , L , Apriyantono , A and Radcliffe , CM . 2001 . Food colorant analysis: characterisation of caramel colours I and IV and discrimination of malts from malt extracts , Report: Project Number A01001 London : Food Standards Agency .
  • Andersen , OM and Jordheim , M . 2006 . “ The anthocyanins ” . In Flavanoids: chemistry biochemistry and applications , Edited by: Andersen , OM and Markham , KR . 471 – 473 . Boca Raton, FL : CRC Press .
  • Andrzejewska , E . 1981 . Detection of natural organic dye cochineal in meat products . Roczniki Panstwowego Zakladu Higieny , 32 : 315 – 318 .
  • Aparnathi , KD and Sharma , RS . 1991 . Annatto colour for food: a review . Indian Food Packer , March–April : 13 – 27 .
  • Aranda , M and Morlock , G . 2006 . Simultaneous determination of riboflavin, pyridoxine, nicotinamide, caffeine and taurine in energy drinks by planar chromatography-multiple detection with confirmation by electrospray ionization mass spectrometry . J Chromatogr A , 1131 : 253 – 260 .
  • Arella , F , Lahély , S , Bourguignon , JB and Hasselmann , C . 1996 . Liquid chromatographic determination of vitamins B1 and B2 in foods . A collaborative study. Food Chem , 56 ( 1 ) : 81 – 86 .
  • Association of Analytical Communities (AOAC). 1970. Official methods of analysis. 11th ed. Section 34.019. Washington (DC): AOAC.
  • Association of Analytical Communities (AOAC) . 1980 . Association of Official Analytical Chemists official methods of analysis, , 11th , Washington (DC) : AOAC .
  • Association of Analytical Communities (AOAC). 1995. Official method 930.17: Marsh test – first action. Chapter 26, distilled liquors. Official Methods of Analysis of AOAC International. 16th ed. Vol. II. Arlington (VA): AOAC International.
  • Aulenta , F , Burch , R , Haines , J and Patel , PD . 2001 . Novel approaches to the identification and quantification of Class III and Class IV caramels in food , Report: Project Number A01005 London : Food Standards Agency .
  • Azeredo , HMC . 2009 . Betalains: properties, sources, applications, and stability – a review . Int J Food Sci Tech , 44 : 2365 – 2376 .
  • Bakker , J and Timberlake , CF . 1985 . The distribution and content of anthocyanins in young port wines as determine by high-performance liquid chromatography . J Sci Food Agricult , 36 : 1325 – 1333 .
  • Bareth , A , Strohmar , W and Kitzelmann , E . 2002 . HPLC and spectrophotometric determination of annatto in cheese . Eur Food Res Tech , 215 : 359 – 364 .
  • Barth , MM , Zhou , C , Kute , KM and Rosenthal , GA . 1995 . Determination of optimum conditions for supercritical-fluid extraction of carotenoids from carrot (Daucus carota L) tissue . J Agricult Food Chem , 43 ( 11 ) : 2876 – 2878 .
  • Belitz , H-D , Grosch , W and Schierberle , P . 2004 . Food Chemistry, , 3rd revd , 793 – 795 . New York, NY : Springer .
  • Bertrand , M and Schoefs , B . 1997 . “ Working with photosynthetic pigments: problems and precautions ” . In Handbook of photosynthesis , Edited by: Pessarakli , M . 151 – 172 . New York, NY : Marcel Dekker .
  • Bertrand , M , Weber , G and Schoefs , B . 2003 . Metal determination and quantification in biological material using particle induces X-ray emission . Trends Analyt Chem. , 22 : 254 – 262 .
  • Berzas Nevado , JJ , Guiberteau Cabanillas , C and Contento Salcedo , AM . 1999 . method development and validation for the simultaneous determination of dyes in foodstuffs by capillary zone electrophoresis . Analytica Chimica Acta , 378 : 63 – 71 .
  • Bicard , V , Fougerousse , A and Brouillard , R . 1999 . Analysis of natural anthocyanins by capillary zone electrophoresis in acidic media . J Liquid Chromatogr Rel Tech , 22 ( 4 ) : 541 – 550 .
  • Biehler , E , Mayer , F , Hoffmann , L , Krause , E and Bohn , T . 2010 . Comparison of 3 spectrophotometric methods for carotenoid determination in frequently consumed fruit and vegetables . J Food Sci , 75 ( 1 ) : C55 – C61 .
  • Bilyk , A . 1981 . Thin-layer chromatographic separation of beet pigments . J Food Sci , 46 : 298 – 299 .
  • Boguhn , J , Baumgärtel , T , Dieckmann , A and Rodehutscord , M . 2009 . Determination of titanium dioxide supplements in different matrices using two methods involving photometer and inductively coupled plasma optical emission spectrometer measurements . Archiv Anim Nutr , 63 ( 4 ) : 337 – 342 .
  • Bosch Reig , F , Peris Martinez , V , Gimeno Adelantado , JV , Sánchez Ramos , S , Yusá Marco , DJ and Bosch Mossi , F . 1998 . X-ray fluorescence analysis of iron (III), potassium and sulfur oxides in cements with a hyperbolic addition-dilution model and using a single multicomponent standard . J Analyt Atom Spectrom , 13 : 583 – 585 .
  • Boscolo , M , Andrade-Sobrinho , LG , Lima-Neto , BS and Franco , DW . 2002 . Spectrophotometric determination of caramel content in spirits aged in oak casks . J AOAC Int , 85 ( 3 ) : 744 – 750 .
  • Breithaupt , D . 2004 . Simultaneous HPLC determination of carotenoids used as food colouring additives: applicability of accelerated solvent extraction . Food Chem , 86 : 449 – 456 .
  • Britton , G . 1992 . “ Carotenoids ” . In Natural food colorants , Edited by: Hendry , GAF and Haughton , JD . 141 – 182 . London, , UK : Blackie .
  • Britton , G . 1995 . “ UV/visible spectroscopy ” . In Carotenoids volume 1B: Spectroscopy , Edited by: Britton , G , Liaaen-Jensen , S and Pfander , H . 13 – 62 . Basel, , Switzerland : Birkhäuser .
  • Brockman , R . 1998 . Detection of natural colourings in raw sausage . Fleischwirtschaft , 78 ( 2 ) : 143 – 145 .
  • Bueno , M . 1997 . Collaborative study: determination of retinol and carotene by high-performance liquid chromatography . Food Chem , 59 ( 1 ) : 165 – 170 .
  • Burch , R . 2005 . Development and validation of an HPLC method for measurement of Class III caramels in foods , Report: Project Number A01037 London : Food Standards Agency .
  • Burch , R , Haines , J and Patel , P . 2002 . Development and validation of methods for the analysis of Class III and Class IV caramels , Report: Project Number A01025 London : Food Standards Agency .
  • Burch , R , Topping , J and Haines , J . 2007 . Review of literature relating to the extraction of additives from complex food matrices , Report: Project Number A01058 London : Food Standards Agency .
  • Burkhardt , S and Böhm , V . 2007 . Development of a new method for the complete extraction of carotenoids from cereals with special reference to Durum wheat (Triticum durum Desf.) . J Agricult Food Chem , 55 : 8295 – 8301 .
  • Bushway , RJ . 1985 . Separation of carotenoids in fruits and vegetables by high-performance liquid-chromatography . J Liq Chromatogr , 8 : 1527 – 1547 .
  • Caelen , I , Kalman , A and Wahlström , L . 2004 . Biosensor-based determination of riboflavin in milk samples . Analyt Chem , 76 : 137 – 143 .
  • Canjura , FL and Schwartz , SJ . 1991 . Separation of chlorophyll compounds and their polar derivatives by high-performance liquid chromatography . J Agricult Food Chem , 39 : 1102 – 1105 .
  • Canjura , FL , Schwartz , SJ and Nunes , RV . 1991 . Degradation kinetics of chlorophylls and chlorophyllides . J Food Sci , 56 : 1639 – 1643 .
  • Cano , MP . 1991 . HPLC separation of chlorophyll and carotenoid pigments of four kiwi fruit cultivars . J Agricult Food Sci , 39 : 1786 – 1791 .
  • Careri , M , Elviri , L and Mangia , A . 1999 . Liquid chromatography-electrospray mass spectrometry of b-carotene and xanthophylls: validation of the analytical method . J Chromatogr A , 854 : 233 – 244 .
  • Caroli , S . 2007 . The determination of chemical elements in food: applications for atomic and mass spectrometry , Hoboken : Wiley .
  • Carvalho , PRN and Collins , CH . 1997 . HPLC determination of carminic acid in foodstuffs and beverages using diode array and fluorescence detection . Chromatographia , 45 : 63 – 66 .
  • Castellar , MR , Obon , JM and Fernandez-Lopez , J . 2006 . The isolation and properties of a concentrated red–purple betacyanin food colourant from Opuntia stricta fruits . J Sci Food Agricult , 86 ( 1 ) : 122 – 128 .
  • Chandra , A , Rana , J and Li , Y . 2001 . Separation, identification, quantification and method validation of anthocyanins in botanical supplement raw materials by HPLC and HPLC-MS . J Agricult Food Chem , 49 : 3515 – 3521 .
  • Chernomorsky , S , Rancourt , R , Sahai , D and Poretz , R . 1997 . Evaluation of commercial chlorophyllin copper complex preparations by liquid chromatography with photodiode array detection . J AOAC Int , 80 : 433 – 435 .
  • Chethana , S , Nayak , CA and Raghavarao , KSMS . 2007 . Aqueous two phase extraction for purification and concentration of betalains . J Food Eng , 81 : 679 – 687 .
  • Ciolino , LA . 1998 . Determination and classification of added caramel color in adulterated acerola juice formulations . J Agricult Food Chem , 46 : 1746 – 1753 .
  • Coffey , JS and Castle , L . 1994 . Analysis for caramel colour (Class III) . Food Chem , 51 : 413 – 416 .
  • Coffey , JS , Nursten , HE , Ames , JM and Castle , L . 1997 . A liquid chromatographic method for the estimation of Class III caramel added to foods . Food Chem , 58 ( 3 ) : 259 – 267 .
  • Corradi , C and Micheli , G . 1981 . A rapid research and identification method for the natural colorant E160b bixin, norbixin (Oriana, annatto) in food products . Industrie Alimentari May , 20 : 372 – 375 .
  • Coultate , TP . 2002 . Food: the chemistry of its components, , 4th , 175 – 178 . Cambridge, , UK : The Royal Society of Chemistry .
  • Coultate , TP . 2009 . Food: the chemistry of its components, , 5th , 318 – 321 . Cambridge, , UK : The Royal Society of Chemistry .
  • Craft , NE , Wise , SA and Soares Jr , JH . 1992 . Optimization of an isocratic high-performance liquid chromatographic separation of carotenoids . J Chromatogr , 589 : 171 – 176 .
  • Cubadda , F . 2007 . “ Applications of inductively coupled mass spectrometry to trace element research and control ” . In The determination of chemical elements in food: applications for atomic and mass spectrometry , Edited by: Caroli , S . 225 – 295 . Hoboken : Wiley .
  • da Costa , CT , Horton , D and Margolis , SA . 2000 . Analysis of anthocyanins in foods by liquid chromatography, liquid chromatography-mass spectrometry and capillary electrophoresis . J Chromatogr A , 881 : 403 – 410 .
  • da Costa , CT , Nelson , BC , Margolis , SA and Horton , J . 1998 . Separation of blackcurrant anthocyanins by capillary zone electrophoresis . J Chromatogr A , 799 : 321 – 327 .
  • Daood , HG , Czinkotai , B , Hoschke , A and Biacs , P . 1989 . High performance liquid chromatography of chlorophylls and carotenoids from vegetables . J Chromatogr , 472 : 296 – 302 .
  • Darko , E , Schoefs , B and Lemoine , Y . 2000 . Improved liquid chromatographic method for the analysis of photosynthetic pigments of higher plants . J Chromatogr A , 876 : 111 – 116 .
  • Davídek , J , Velíšek , J and Pokornŷ , J . 1990 . “ Chemical changes during food processing ” . In Developments in food science 21 , 324 – 327 . Oxford, , UK : Elsevier .
  • de Quirós , ARB and Costa , HS . 2006 . Analysis of carotenoids in vegetable and plasma samples: a review . J Food Composition Anal , 19 : 97 – 111 .
  • Delgado-Vargas , F , Jiménez , AR and Paredes-López , O . 2000 . Natural pigments: carotenoids, anthocyanins, and betalaines – characteristics, biosynthesis, processing and stability . Critical Rev Food Sci Nutr , 40 ( 3 ) : 173 – 289 .
  • Dias , MG , Camões , MF and Oliveira , L . 2008 . Uncertainty estimation and in-house method validation of HPLC analysis of carotenoids for food composition data production . Food Chem , 109 : 815 – 824 .
  • Dionex. 2010. Dionex Application Note 120. Determination of calcium and magnesium in brine [Internet]. Available from: http://www.dionex.com/en-us/webdocs/4205-An120.pdf/
  • Dos Santos , LMG , Araujo , RGO , Welz , B , Jacob , S , do , C , Vale , MGR and Becker-Ross , H . 2009 . Simultaneous determination of Cd and Fe in grain products using direct solid sampling and high-resolution continuum source electrothermal atomic absorption spectrometry . Talanta , 78 : 577 – 583 .
  • Edelenbos , M , Christensen , LP and Grevsen , K . 2001 . HPLC determination of chlorophyll and carotenoid pigments in processed pea cultivars (Psium sativum L.) . J Agricult Food Chem , 49 : 4768 – 4774 .
  • Eder , R . 2000 . “ Pigments ” . In Food analysis by HPLC. 2nd revd ed , Edited by: Nollet , LML . 825 – 880 . New York, NY : Marcel Dekker .
  • Egginger , R . 1985 . Determination of red beet color additive in frankfurters and dry sausage – a single rapid qualitative test . Fleischwirtschaft , 65 ( 8 ) : 917 – 921 .
  • El Gharras , H , Hasib , A , Jaouad , A , El-bouadili , A and Schoefs , B . 2008 . Stability of vacuolar betaxanthin pigments in juices from Moroccan yellow Opuntia ficus indica fruits . Int J Food Sci Tech , 43 : 351 – 356 .
  • Epler , KS , Sander , LC , Ziegler , RG , Wise , SA and Craft , NE . 1992 . Evaluation of reversed-phase liquid-chromatographic columns for recovery and selectivity of selected carotenoids . J Chromatogr , 595 : 89 – 101 .
  • European Union . 1994 . European Parliament and Council Directive 94/36/EC of 30 June 1994 on colours for use in foodstuffs . Off J Eur Union L , 237 : 13 – 29 .
  • European , Union . 2002 . Commission Decision 2002/657/EC of 12 August 2002 implementing Council Directive 96/23/EC concerning the performance of analytical methods and interpretation of results . Off J Eur Union , L221 : 8 – 36 .
  • European Union . 2008 . Commission Directive 2008/128/EC of 22 December 2008 laying down specific purity criteria concerning colours for use in foodstuffs (Codified version) . Off J Eur Union , L6 : 20 – 63 .
  • Faud , MYA and Moh , ZISL . 1997 . Determination of carbon black content in HDPE – purge gas buoyancy effect . Thermochimica Acta , 298 : 115 – 118 .
  • Feltl , L , Pacáková , V , Štulík , K and Volka , K . 2005 . Reliability of carotenoid analyses: a review . Current Analyt Chem , 1 : 93 – 102 .
  • Fernandez , RXE , Shier , NW and Watkins , BA . 2000 . Effect of alkali saponification, enzymatic hydrolysis and storage time on the total carotenoid concentration of Costa Rican crude palm oil . J Food Composition Anal , 13 : 179 – 187 .
  • Food Standards Agency (FSA). 2006. Study on illegal dyes in imported foods [Internet]. 12th December; [cited 2009 Jan 8]. Available from: http://www.food.gov.uk/
  • Food Standards Agency (FSA). 2010. Canthaxanthin: your questions answered [Internet]. Available from: http://www.food.gov.uk/multimedia/webpage/canthaxanthin_qanda/
  • Francis , FH . 1989 . Food colorants: anthocyanins . Critical Rev Food Sci Nutr , 28 ( 4 ) : 273 – 314 .
  • Francis , FJ . 1982 . “ Analysis of anthocyanins ” . In Anthocyanins as food colors , Edited by: Markakis , P . 181 – 207 . London, , UK : Academic Press .
  • Fukushi , K , Takeda , S , Wakida , S-I , Higashi , K and Hiiro , K . 1997 . Determination of free calcium in vegetables by capillary zone electrophoresis . J Chromatogr A , 759 : 211 – 216 .
  • Gao , H-W . 2002 . Spectrophotometric determination of trace amounts of calcium using the calcium complex with alizarin . J Brazilian Chem Soc , 13 ( 1 ) : 78 – 81 .
  • Garciá Barrera , FA , Reynoso , CR and González de Mejía , E . 1998 . Estabilidad de las betalínas extraídas del garambullo (Myrtillocactus geometrizans) . Food Sci Tech Int , 4 : 115 – 120 .
  • Gauthier-Jaques , A , Bortlik , K , Hau , J and Fay , LB . 2001 . Improved method to track chlorophyll degradation . J Agricult Food Chem , 49 : 1117 – 1122 .
  • Giusti , MM , Rodriguez-Saona , LE , Griffin , D and Wrolstad , RE . 1999 . Electrospray and tandem mass spectroscopy as tools for anthocyanin characterization . J Agricult Food Chem , 47 : 4657 – 4664 .
  • Gnayfeed , MH , Daood , HG , Illes , V and Biacs , PA . 2001 . supercritical CO2 and subcritical propane extraction of pungent paprika and quantification of carotenoids, tocopherols, and capsaicinoids . J Agricult Food Chem , 49 ( 6 ) : 2761 – 2766 .
  • Goiffon , JP , Mouly , PP and Gaydou , EM . 1999 . Anthocyanic pigment determination in red fruit juices, concentrated juices and syrups using liquid chromatography . Analytica Chimica Acta , 382 : 39 – 50 .
  • Gong , Q , Wei , X , Zhang , X , Yi , N and Wu , J . 2000 . Study on the determination of free iron oxide in soil extract by FIA-ICP-AES . Spectroscopy Spectral Anal , 20 ( 2 ) : 229 – 231 .
  • González , M , Gallego , M and Valcárcel , M . 2003 . Determination of natural and synthetic colorants in prescreened dairy samples using liquid chromatography-diode array detection . Analyt Chem , 75 : 685 – 693 .
  • Gottelt , U , Henrion , G , Kalähne , R and Stoyke , M . 1996 . Simultaneous determination of the elements copper, zinc, iron, manganese as well as sodium, potassium and magnesium by flame atomic absorption spectrometry (F-AAS) . Nahrung – Food , 40 ( 6 ) : 313 – 318 .
  • Gross , J . 1980 . A rapid separation of citrus carotenoids by thin-layer chromatography . Chromatographia , 13 : 572 – 573 .
  • Haas , U and Vinha , CA . 1995 . Qualitative and semiquantitative analysis of annatto and its content in food additives by photoacoustic spectrometry . Analyst , 120 : 351 – 354 .
  • Haddad , PR and Jackson , PE . 1990 . “ Ion chromatography principles and applications ” . In J Chromatogr Library , Vol. 46 , 605 – 607 . Oxford, , UK : Elsevier .
  • Hamano , T , Mitusuhashi , Y , Aoki , N , Yamamoto , S , Tsuji , S , Ito , Y and Oji , Y . 1990 . Colorimetric micro-determination of titanium dioxide in foods . J Japanese Soc Food Sci Tech , 37 ( 2 ) : 162 – 166 .
  • Hammond , EG , Chang , J and Reinbold , GW . 1975 . Colorimetric method for residual annatto in dry whey . J Dairy Sci , 58 : 1365
  • Hayashi , T , Hayashi , K , Fujita , J , Ono , M , Oka , H , Ito , Y , Matsumoto , H , Ozeki , N , Itakura , Y and ang Nakazawa , H . 2001 . An HPLC method for the analysis of paprika color in food using capsanthin as an indicator . J Liquid Chromatogr Related Tech , 24 ( 15 ) : 2347 – 2361 .
  • Heath , DD , Pruitt , MA , Brenner , DE and Rock , CL . 2003 . Curcumin in plasma and urine: quantitation by high-performance liquid chromatography . J Chromatogr B , 783 : 287 – 295 .
  • Hebrero , E , Garcia Rodriguez , C , Santos Buelga , C and Rivas Gonzalo , JC . 1989 . Analysis of anthocyanins by high-performance liquid chromatography diode array spectroscopy in a hybrid grape variety (Vitis vinifera × Vitis berlandieri 141B) . Am J Enology Viticult , 40 ( 4 ) : 283 – 291 .
  • Hendry , GA . 1992 . “ Chlorophylls and chlorophyll derivatives ” . In Natural food colorants , Edited by: Hendry , GAF and Haughton , JD . 79 – 103 . London, , UK : Blackie .
  • Henning , W . 1983 . Detection and evaluation of the addition of betanin to foodstuffs . Deutsche Lebensmittel-Rundschau , 79 ( 12 ) : 407 – 410 .
  • Henry , BA . 1992 . “ Natural food colours ” . In Natural food colorants , Edited by: Hendry , GAF and Houghton , JD . 39 London, , UK : Blackie .
  • Hirokado , M , Kimura , K , Suzuki , K , Sadamasu , Y , Katsuki , Y , Yasuda , K and Nishijima , M . 1999 . Detection of madder color, cochineal extract, lac color, carthamus yellow and carthamus red in processed foods by TLC . Shokuhin Eiseigaku Zasshi , 40 ( 6 ) : 488 – 493 .
  • Hiserodt , R , Hartman , TG , Ho , C-T and Rosen , RT . 1996 . Characterization of powdered turmeric by liquid chromatography-mass spectrometry and gas chromatography-mass spectrometry . J Chromatogr A , 740 : 51 – 63 .
  • Hong , V and Wrolstad , RE . 1990a . Use of HPLC separation/photodiode array detection for characterization of anthocyanins . J Agricult Food Chem , 38 : 708 – 715 .
  • Hong , V and Wrolstad , RE . 1990b . Characterization of anthocyanin-containing colorants and fruit juices by HPLC/photodiode array detection . J Agricult Food Chem , 38 : 698 – 708 .
  • Hou , X , Li , Y , Wu , G , Wang , L , Hong , M and Wu , Y . 2010 . Determination of para red, Sudan dyes, canthaxanthin, and astaxanthin in animal feeds using UPLC . J Chromatogr Sci , 48 : 22 – 25 .
  • Hsieh , J-PC and Karel , M . 1983 . Rapid extraction and determination of alpha-carotenes and beta-carotenes in foods . J Chromatogr , 259 : 515 – 518 .
  • Huang , H-Y , Chuang , C-L , Chiu , C-W and Chung , M-C . 2005 . Determination of food colorants by microemulsion electrokinetic chromatography . Electrophoresis , 26 : 867 – 877 .
  • Huang , H-Y , Shih , Y-C and Chen , Y-C . 2002 . Determining eight colorants in milk beverages by capillary electrophoresis . J Chromatogr A , 959 : 317 – 325 .
  • Ichiyanagi , T , Tateyama , C , Oikawa , K and Konishi , T . 2000 . Comparison of anthocyanin distribution in different blueberry sources by capillary zone electrophoresis . Biol Pharmaceut Bull , 23 : 492 – 497 .
  • Inoue , H , Furuya , K , Watanabe , K , Tanaka , K , Shirai , T and Miyoshi , E . 1988 . Separation and determination of copper(II) chlorophylls by reverse-phase high performance liquid chromatography . Analyt Sci , 4 : 599 – 603 .
  • Inoue , H , Yamashita , H , Furuya , K , Nonomura , Y , Yoshioka , N and Li , S . 1994 . Determination of copper(II) chlorophyllin by reverse-phase high-performance liquid-chromatography . J Chromatogr A , 679 : 99 – 104 .
  • Inoue , K , Hamasaki , S , Yoshimura , Y , Yamada , M , Nakamura , M , Ito , Y and Nakazawa , H . 2003 . Validation of LC/electrospray-MS for determination of major curcuminoids in foods . J Liquid Chromatogr Related Tech , 26 ( 1 ) : 53 – 62 .
  • International Carbon Black Association (ICBA). 2004. Carbon black user’s guide: safety, health and environmental information. ICBA. Available from: http://www.carbon-black.org
  • Isaksen , M and Francis , GW . 1986 . Reverse-phase thin-layer chromatography of carotenoids . J Chromatogr , 355 : 356 – 362 .
  • Itakura , Y , Ueno , E , Ito , Y , Oka , H , Ozeki , N , Hayashi , T , Yamada , S , Kagami , T , Miyazaki , Y Otsuji , Y . 1999 . Analysis of lac and cochineal colors in foods using reversed-phase thin-layer chromatography/scanning densitometry . Shokuhin Eiseigaku Zasshi , 40 ( 3 ) : 183 – 188 .
  • Jackman , RL and Smith , JK . 1992 . “ Anthocyanins and betalains ” . In Natural food colorants , Edited by: Hendry , GAF and Haughton , JD . 183 – 241 . London, , UK : Blackie .
  • Jackman , RL , Yamada , RY , Tung , MA and Speers , RA . 1987 . Anthocyanins as food colorants – a review . J Food Biochem , 11 : 201 – 247 .
  • Jakobsen , J . 2008 . Optimisation of the determination of thiamin, 2-(1-hydroxyethyl)thiamin, and riboflavin in food samples by use of HPLC . Food Chem , 106 : 1209 – 1217 .
  • Jalón , M , Peña , MJ and Rivas , JC . 1989 . Liquid chromatographic determination of carminic acid in yoghurt . J Assoc Off Analyt Chem , 72 ( 2 ) : 231 – 234 .
  • Jayaprakasha , GK , Rao , LJM and Sakariah , KK . 2002 . Improved HPLC method for the determination of curcumin, demethoxycurcumin and bisdemethoxycurcumin . J Agricult Food Chem , 50 : 3668 – 3672 .
  • JECFA. 2010a. Monograph 1, 2006. Curcumin [Internet]. Available from: http://www.fao.org/ag/agn/jecfa-additives/specs/Monograph1/Additive-140.pdf/
  • JECFA. 2010b. Specification for riboflavin [Internet]. Available from: http://www.fao.org/ag/agn/jecfa-additives/specs/Monograph1/Additive-377.pdf/
  • JECFA. 2010c. Purity specifications for cochineal extract [Internet]. Available from: http://www.fao.org/ag/agn/jecfa-additives/specs/Monograph1/Additive-137.pdf/
  • JECFA. 2010d. Purity specifications for carmines [Internet]. Available from: http://www.fao.org/ag/agn/jecfa-additives/specs/Monograph1/additive-108-m1.pdf/
  • JECFA. 2010e. Purity specifications for chlorophylls [Internet]. Available from: http://www.fao.org/ag/agn/jecfa-additives/specs/Monograph1/Additive-128.pdf/
  • JECFA. 2010f. Purity specifications for chlorophyllins, copper complexes sodium and potassium salts [Internet]. Available from: http://www.fao.org/ag/agn/jecfa-additives/specs/monograph5/additive-127-m5.pdf/
  • JECFA. 2010h. Purity specifications for caramels [Internet]. Available from: http://www.fao.org/ag/agn/jecfa-additives/specs/Monograph1/Additive-102.pdf/
  • JECFA. 2010i. Purity specifications for carotenes (vegetable) [Internet]. Available from: http://www.fao.org/ag/agn/jecfa-additives/specs/Monograph1/Additive-115.pdf/
  • JECFA. 2010j. Purity specifications for carotenes (algae) [Internet]. Available from: http://www.fao.org/ag/agn/jecfa-additives/specs/monograph4/additive-114-m4.pdf/
  • JECFA. 2010k. Purity specifications for paprika oleoresin [Internet]. Available from: http://www.fao.org/ag/agn/jecfa-additives/specs/Monograph1/Additive-303.pdf/
  • JECFA. 2010l. Purity specifications for paprika extract [Internet]. Available from: http://www.fao.org/ag/agn/jecfa-additives/specs/monograph5/additive-510-m5.pdf/
  • JECFA. 2010m. Purity specifications for lycopene extract from tomato [Internet]. Available from: http://www.fao.org/ag/agn/jecfa-additives/specs/monograph7/additive-517-m7.pdf/
  • JECFA. 2010n. Purity specifications for β-apo-8′-carotenal [Internet]. Available from: http://www.fao.org/ag/agn/jecfa-additives/specs/Monograph1/Additive-111.pdf/
  • JECFA. 2010o. Purity specifications for β-apo-8′-carotenoic acid ethyl ester [Internet]. Available from: http://www.fao.org/ag/agn/jecfa-additives/specs/Monograph1/Additive-116.pdf/
  • JECFA. 2010p. Purity specifications for lutein from Tagetes erecta [Internet]. Available from: http://www.fao.org/ag/agn/jecfa-additives/specs/monograph3/additive-255.pdf/
  • JECFA. 2010q. Purity specifications for Tagetes extract [Internet]. Available from: http://www.fao.org/ag/agn/jecfa-additives/specs/monograph3/additive-452.pdf/
  • JECFA. 2010r. Purity specifications for canthaxanthin [Internet]. Available from: http://www.fao.org/ag/agn/jecfa-additives/specs/monograph5/additive-101-m5.pdf/
  • JECFA. 2010s. Purity specifications for annatto [Internet]. Available from: http://www.fao.org/ag/agn/jecfa-additives/results.html?additiveName=annatto&ins=&cas1=&cas2=&cas3=&techFunction=-1&searchBy=aname/
  • JECFA. 2010t. [Internet]. Available from: http://www.fao.org/ag/agn/jecfa-additives/specs/Monograph1/Additive-052.pdf/
  • JECFA. 2010u. Specifications for blackcurrant extract [Internet]. Available from: http://www.fao.org/ag/agn/jecfa-additives/specs/Monograph1/Additive-056.pdf/
  • JECFA. 2010v. Specifications for grape skin extract [Internet]. Available from: http://www.fao.org/ag/agn/jecfa-additives/specs/Monograph1/Additive-214.pdf/
  • JECFA. 2010w. Specification for vegetable carbon [Internet]. Available from: http://www.fao.org/ag/agn/jecfa-additives/specs/Monograph1/Additive-486.pdf/
  • JECFA. 2010x. Specification for calcium carbonate [Internet]. Available from: http://www.fao.org/ag/agn/jecfa-additives/specs/Monograph1/Additive-075.pdf/
  • JECFA. 2010y. Specification for titanium dioxide [Internet]. Available from: http://www.fao.org/ag/agn/jecfa-additives/specs/monograph7/additive-466-m7.pdf/
  • JECFA. 2010z. Specification for iron oxides [Internet]. Available from: http://www.fao.org/ag/agn/jecfa-additives/specs/monograph5/additive-238-m5.pdf/
  • Johnson-Flanagan , AM and Thiagarajah , MR . 1990 . Degreening in canola (Brassica napus cv. Westar) embryos under optimum conditions . J Plant Physiol , 136 ( 2 ) : 180 – 186 .
  • Jubert , C and Bailey , G . 2007 . Isolation of chlorophylls a and b from spinach by counter-current chromatography . J Chromatogr A , 1140 : 95 – 100 .
  • Julshamn , K , Maage , A and Wallin , HC . 1998 . Determination of magnesium and calcium in foods by atomic absorption spectrometry after microwave digestion: NMKL collaborative study . J AOAC Int , 81 ( 6 ) : 1202 – 1208 .
  • Kamuf W, Nixon A, Parker O. 2010. Caramel colour – the science and art [Internet]. Available from: http://www.caramel.com/EditorUpload/File/mso29F.pdf/
  • Kanai , Y . 1990 . Simultaneous determination of iron(II) and iron(III) oxides in geological materials by ion chromatography . Analyst , 115 : 809 – 812 .
  • Kani , T , Dobashi , K , Kato , F , Yuasa , Y and Miyazawa , F . 1986 . Comparisons of platinum crucible ashing and porcelain crucible ashing for the colorimetric determination of titanium dioxide in food and the real situation of titanium dioxide in market foods . Eisei Kagaku , 32 ( 1 ) : 54 – 56 .
  • Kanias , GD . 1987 . Instrumental neutron activation analysis of iron and zinc in compact cosmetic products . Fresenius J Analyt Chem , 327 : 351 – 354 .
  • Karasz , AB , DeCocca , F and Bokus , L . 1973 . Detection of turmeric in foods by rapid fluorometric method and by improved spot test . J Assoc Off Analyt Chem , 56 : 626 – 628 .
  • Khalyfa , A , Kermasha , S and Ali , I . 1992 . Extraction, purification, and characterization of chlorophylls from spinach leaves . J Agricult Food Chem , 40 : 215 – 220 .
  • Khayatian , G and Pouzesh , S . 2007 . Solid phase extraction and flame atomic absorption spectroscopic determination of trace amounts of iron(III) using octadecyl silica membrane disks modified with 2-mercaptopyridine-1-oxide . J Iranian Chem Soc , 4 ( 4 ) : 490 – 496 .
  • Kiattanavith , N and Hummel , K . 1993 . Determination of carbon black filler in natural rubber vulcanizates by olefin metathesis degradation . Polymer Degradat Stabil , 41 : 1 – 3 .
  • Kirk , RS and Sawyer , R . 1991 . Pearson’s composition and analysis of foods, , 9th , Vol. 519 , 298 – 300 . Harlow, , UK : Longman .
  • Knuthsen , P . 1981 . Investigations on beetroot colours for the purpose of regulation . Zeitschrift Lebensmittel Untersuchung Forschung , 172 : 195 – 200 .
  • Konings , EJM and Roomans , HHS . 1997 . Evaluation of an LC method for the analysis of carotenoids in vegetables and fruit . Food Chem , 59 ( 4 ) : 599 – 603 .
  • Kostousova , TI and Osokina , GN . 1989 . Determination of iron (III) oxide Wustite in finely dispersed sludges . Industr Lab , 54 ( 12 ) : 1361 – 1363 .
  • Kouřil , R , Ilík , P , Nauš , J and Schoefs , B . 1999 . On the limits of applicability of spectrophotometric and spectrofluorimetric methods for the determination of chlorophyll a/b ratio . Photosynth Res , 62 : 107 – 116 .
  • Kravchenko , OV , Shvets , DI , Strelko , VV and Mironyuk , TI . 2001 . ESR characterization of vegetable carbon materials . Russian J Appl Chem , 75 ( 4 ) : 540 – 542 .
  • Kugler , F , Stintzing , FC and Carle , R . 2007 . Characterization of betalain patterns of differently coloured inflorescences from Gomphrena globosa L. and Bougainvillea sp. By HPLC-DAD-ESI-MS . Analyt Bioanalyt Chem , 387 : 637 – 648 .
  • Kujala , T , Loponen , J and Pihlaja , K . 2001 . Betalains and phenolics in red beetroot (Beta vulgaris) peel extracts: extraction and characterisation . J Biosci Bangalore , 56 ( 5–6 ) : 343 – 348 .
  • Lacker , T , Strohschein , S and Albert , K . 1999 . Separation and identification of various carotenoids by C-30 reversed-phase high-performance liquid chromatography coupled to UV and atmospheric pressure chemical ionization mass spectrometric detection . J Chromatogr A , 854 : 37 – 44 .
  • Lancaster , FE and Lawrence , JF . 1995 . Determination of annatto in high-fat dairy products, margarine and hard candy by solvent extraction followed by high-performance liquid chromatography . Food Addit Contam , 12 : 9 – 19 .
  • Lancaster , FE and Lawrence , JF . 1996 . High performance liquid chromatographic separation of carminic acid, α-bixin, and α- and β-norbixin, and the determination of carminic acid in foods . J Chromatogr A , 732 : 394 – 398 .
  • Lauro , GJ . 1991 . A primer on natural colours . Cereal Foods World , 36 : 949 – 953 .
  • Lea , AGH . 1988 . “ HPLC of natural pigments in foodstuffs ” . In HPLC in food analysis, , 2nd , Edited by: Macrae , R . 277 – 333 . London : Academic Press .
  • Lee , HS and Hong , V . 1992 . Chromatographic analysis of anthocyanins . J Chromatogr A , 624 : 221 – 234 .
  • Lee , J , Rennaker , C and Wrolstad , RE . 2008 . Correlation of two anthocyanin quantification methods: HPLC and spectrophotometric methods . Food Chem , 110 : 782 – 786 .
  • Lei , Y-J , Liu , W-P , Wang , X-H and Kang , H-L . 2007 . Determination of Sudan, amaranth and carmine in foods by high performance liquid chromatography . Fenxi Shiyanshi , 26 ( 4 ) : 85 – 88 .
  • Leisen , J , Breidt , J and Kelm , J . 1999 . 1 H NMR relaxation studies of cured natural rubbers with different carbon black fillers . Rubber Chem Tech , 72 ( 1 ) : 1 – 14 .
  • Leone , JL . 1973 . Collaborative study of the quantitative determination of titanium dioxide in cheese . J Assoc Off Analyt Chem , 56 : 535 – 537 .
  • Levy , LW and Rivadeneira , DM . 2000 . “ Annatto ” . In Natural food colorants: science and technology , Edited by: Lauro , GJ and Francis , FJ . 115 – 152 . New York, NY : Marcel Dekker .
  • Licht , BH , Shaw , K , Smith , C , Mendoza , M , Orr , J and Myers , DV . 1992a . Characterisation of caramel colour IV . Food Chem Toxicol , 30 : 365 – 373 .
  • Licht , BH , Shaw , K , Smith , C , Mendoza , M , Orr , J and Myers , DV . 1992b . Characterisation of caramel colours I, II and III . Food Chem Toxicol , 30 : 375 – 382 .
  • Licht , BH , Shaw , K , Smith , C , Mendoza , M , Orr , J and Myers , DV . 1992c . Development of specifications for caramel colours . Food Chem Toxicol , 30 : 383 – 387 .
  • Ling , YH , Ren , C , Mallery , SR , Ugalde , CM , Pei , P , Saradhi , UVRV , Stoner , GD , Chan , KK and Liu , ZF . 2009 . A rapid and sensitive LC-MS/MS method for quantification of four anthocyanins and iots application to a clinical pharmacology study of a bioadhesive black raspberry gel . J Chromatogr B , 877 : 4027 – 4034 .
  • Lomer , MCE , Thompson , RPH , Commisso , J , Keen , CL and Powell , JJ . 2000 . Determination of titanium dioxide in foods using inductively coupled plasma optical emission spectrometry . Analyst , 125 ( 12 ) : 2339 – 2343 .
  • López , N , Puértolas , E , Condón , S , Raso , J and Alvarez , I . 2009 . Enhancement of the extraction of betanine from red beetroot by pulsed electric fields . J Food Eng , 90 : 60 – 66 .
  • Lopez-Hernandez , J , Vazquez-Oderiz , L , Vazquez-Blanco , E , Romero-Rodriguez , A and Simal-Lozano , J . 1993 . HPLC determination of major pigments in the bean Phaseolus vulgaris . J Agricult Food Chem , 41 : 1613 – 1615 .
  • Luf , W and Brandl , E . 1988 . The detection of the annatto dyestuff norbixin/bixin in cheese using derivative spectroscopy and high-performance liquid chromatography . Zeitschrift Lebensmittel-Untersuchung Forschung , 186 : 327 – 332 .
  • Marczylo , TH , Steward , WP and Gescher , AJ . 2009 . Rapid analysis of curcumin and curcumin metabolites in rat biomatrices using a novel ultraperformance liquid chromatography (UPLC) method . J Agricult Food Chem , 57 : 797 – 803 .
  • Marshall , PN and Horobin , RW . 1974 . A simple assay procedure for carmine and carminic acid samples . Stain Tech , 49 : 19 – 28 .
  • Mazza , G , Cacace , JE and Kay , CD . 2004 . method of analysis for anthocyanins in plants and biological fluids . J AOAC Int , 87 ( 1 ) : 129 – 145 .
  • McNeal , JE . 1976 . Qualitative tests for added colouring matter in meat products . J Assoc Off Analyt Chem , 59 : 570
  • Mercadante , AZ , Steck , A and Pfander , H . 1997 . Isolation and identification of new apocarotenoids from annatto (Bixa orellana) seeds . J Agricult Food Chem , 45 : 1050 – 1054 .
  • Merino , L , Edberg , U and Tidriks , H . 1997 . Development and validation of a quantitative method for the determination of carmine (E120) in foodstuffs by liquid chromatography: NMKL collaborative study . J AOAC Int , 80 ( 5 ) : 1044 – 1051 .
  • Merken , HM and Beecher , GR . 2000 . measurement of food flavanoids by high-performance liquid chromatography: a review . J Agricult Food Chem , 48 ( 3 ) : 577 – 599 .
  • Mínguez-Mosquera , MI , Gandul-Rojas , B and Gallardo-Guerrero , ML . 1992 . Rapid method of quantification of chlorophylls and carotenoids in virgin olive oil by high performance liquid chromatography . J Agricult Food Chem , 40 : 60 – 63 .
  • Mínguez-Mosquera , MI , Gandul-Rojas , B , Montaño-Asquerino , A and Garrido-Fernández , J . 1991 . Determination of chlorophylls and carotenoids by high-performance liquid chromatography during olive lactic fermentation . J Chromatogr , 585 : 259 – 266 .
  • Mínguez-Mosquera , MI , Garrido-Fernández , J and Gandul-Rojas , B . 1990 . Quantification of pigments in fermented manzanilla and hojiblanca olives . J Agricult Food Chem , 36 : 1662 – 1666 .
  • Mínguez-Mosquera , MI , Hornero-Méndez , D and Garrido-Fernández , J . 1995 . Detection of bixin, lycopene, canthaxanthin and β-apo-8′-carotenal in products derived from red pepper . J AOAC Int , 78 : 491 – 496 .
  • Monajjemzadeh , F , Hassanzadeh , D , Valizadeh , H , Siahi-Shadbad , MR , Mojarrad , JS , Robertson , T and Roberts , MS . 2009 . Assessment of feasibility of Maillard reaction between Baclofen and lactose by liquid chromatography and tandem mass spectrometry, application to pre formulation studies . AAPS PharmScitech , 10 ( 2 ) : 649 – 659 .
  • Mortensen , A and Geppel , A . 2007 . HPLC-MS analysis of the green food colorant sodium copper chlorophyllin . Innovative Food Sci Emerging Tech , 8 : 419 – 425 .
  • Myers , WD , Ludden , PA , Nayigihugu , V and Hess , BW . 2004 . Technical Note: A procedure for the preparation and quantitative analysis of samples for titanium dioxide . J Anim Sci , 82 : 179 – 183 .
  • Navas-Diaz , A and Ramon-Peinado , MC . 1992 . Fluorimetric determination of curcumin in yogurt and mustard . J Agricult Food Chem , 40 : 56 – 59 .
  • Ndaw , S , Bergaentzlé , M , Aoudé-Werner , D and Hasselmann , C . 2000 . Extraction procedures for the liquid chromatographic determination of thiamin, riboflavin and vitamin B6 in foodstuffs . Food Chem , 71 : 129 – 138 .
  • Nilsson , T . 1970 . Studies into the pigments in beetroot . Lantbrukshögskolans Annaler , 36 : 179 – 219 .
  • Njaa , LR . 1961 . Determination of protein digestibility with titanium oxide as indicator substance . Acta Agriculturae Scandinavica , 11 : 227 – 241 .
  • Nonomura , Y , Yamaguchi , Y , Hara , K , Furuya , K , Yoshioka , N and Inoue , H . 1996 . High-performance liquid chromatographic separation of iron(III) chlorophyllin . J Chromatogr A , 721 : 350 – 354 .
  • Noppe , H , Abuin Martinez , S , Verheyden , K , van Loco , J , Companyó Beltran , R and de Brabander , HF . 2009 . Determination of bixin and norbixin in meat using liquid chromatography and photodiode array detection . Food Addit Contam , 26 : 17 – 24 .
  • Oliver , J and Palou , A . 2000 . Chromatographic determination of carotenoids in foods . J Chromatogr A , 881 : 543 – 555 .
  • Oshima , H , Ueno , E , Saito , I and Matsumoto , H . 2004 . Development of a solid-phase method for determination of phaeophorbide a and pyropheophorbide a in health foods by liquid chromatography . J AOAC Int , 87 ( 4 ) : 937 – 942 .
  • Ozeki , N , Ueno , E , Ito , Y , Oka , H , Hayashi , T , Itakura , Y , Yamada , S , Matsumoto , H , Ito , T Maruyama , T . 2000 . Analysis of turmeric oleoresin, gardenia yellow, and annatto extracts in foods using reverse-phase thin-layer chromatography/scanning densitometry . J Food Hygienic Soc Japan , 41 ( 6 ) : 347 – 352 .
  • Page , GI and Davies , SJ . 2007 . Tissue astaxanthin and canthaxanthin distribution in rainbow trout (Oncorhynchus mykiss) and Atlantic salmon (Salmo salar) . Comparative Biochem Physiol A , 143 : 125 – 132 .
  • Paramasivam , M , Poi , R , Banerjee , H and Bandyopadhyay , A . 2009 . High-performance thin layer chromatographic method for quantitative determination of curcuminoids in Curcuma longa germplasm . Food Chem , 113 : 640 – 644 .
  • Patey , AL , Shearer , G , Knowles , ME and Denner , WHB . 1985 . Development and use of a gas chromatographic method of analysis for low molecular weight compounds in glucose syrups and caramel colourings . Food Addit Contam , 2 ( 4 ) : 237 – 246 .
  • Péret-Almeida , L , Cherubino , APF , Alves , RJ , Dufossé , L and Glória , MBA . 2005 . Separation and determination of the physico-chemical characteristics of curcumin, demethoxycurcumin and bisdemethoxycurcumin . Food Res Int , 38 : 1039 – 1044 .
  • Pfander , H and Niggli , U . 1995 . “ Chromatography: Part V. Supercritical-fluid chromatography ” . In Carotenoids Volume 1A: Isolation and analysis , Edited by: Britton , G , Liaaen-Jensen , S and Pfander , H . 191 – 198 . Basel, , Switzerland : Birkhäuser .
  • Phattanawasin , P , Sotanaphun , U and Sriphong , L . 2009 . Validated TLC-image analysis method for simultaneous quantification of curcuminoids in Curcuma longa . Chromatographia , 69 : 397 – 400 .
  • Poitevin , E , Nicolas , M , Graveleau , L , Richoz , J , Andrey , D and Monard , F . 2009 . Improvement of AOAC official method 984.27 for the determination of nine nutritional elements if food products by inductively coupled plasma-atomic emission spectroscopy after microwave digestion: single laboratory validation and ring trial . J AOAC Int , 92 ( 5 ) : 1484 – 1518 .
  • Pourrat , A , Lejeune , B , Grand , A and Pourrat , H . 1988 . Betalains assay of fermented red beet root extract by high-performance liquid chromatography . J Food Sci , 53 ( 1 ) : 294 – 295 .
  • Preston , HD and Rickard , MD . 1980 . Extraction and chemistry of annatto . Food Chem , 5 : 47 – 56 .
  • Price , LC and Buescher , RW . 1997 . Kinetics of alkaline degradation of the food pigments curcumin and curcuminoids . J Food Sci , 62 ( 2 ) : 267 – 269 .
  • Rehbein , J , Dietrich , B , Grynbaum , MD , Hentschel , P , Kuehnle , M , Schuler , P , Bayer , M and Albert , K . 2007 . Characterization of bixin by LC-MS and LC-NMR . J Separation Sci , 30 : 2382 – 2390 .
  • Reith , JF and Gielen , JW . 1971 . Properties of bixin and norbixin and the composition of annatto extracts . J Food Sci , 36 : 861 – 864 .
  • Řezanka , T , Olšovská , J , Sobotka , M and Sigler , K . 2009 . The use of APCI-MS with HPLC and other separation techniques for identification of carotenoids and related compounds . Current Analyt Chem , 5 : 1 – 25 .
  • Richter , N , Jarmer , T , Chabrillat , S , Oyonarte , C , Hostert , P and Kaufmann , H . 2009 . Free iron oxide determination in Mediterranean soils using diffuse reflectance spectroscopy . Soil Sci Soc Am J , 73 ( 1 ) : 72 – 81 .
  • Rios , ADO and Mercadante , AZ . 2004 . Novel method for the determination of added annatto colour in extruded corn snack products . Food Addit Contam , 21 : 125 – 133 .
  • Rouseff , RL . 1988 . High performance liquid chromatographic separation and spectral characterization of the pigments in turmeric and annatto . J Food Sci , 53 : 1823 – 1826 .
  • Roy , S . 1987 . High-performance liquid chromatographic analysis of chloropigments . J Chromatogr , 391 : 19 – 34 .
  • Royle , L , Ames , JM , Castle , L and Nursten , HE . 2002 . Analysis of malts by capillary electrophoresis . J Sci Food Agricult , 82 : 443 – 451 .
  • Royle , L , Ames , JM , Castle , L , Nursten , HE and Radcliffe , CM . 1998 . Identification and quantification of Class IV caramels using capillary electrophoresis and its application to soft drinks . J Sci Food Agricult , 76 : 579 – 587 .
  • Royle , L and Radcliffe , CM . 1999 . Analysis of caramels by capillary electrophoresis and ultrafiltration . J Sci Food Agricult , 79 : 1709 – 1714 .
  • Saag , K . 1982 . “ Determination of food colorants ” . In HPLC in food analysis. Food Science and Technology Monographs , Edited by: Macrae , R . 264 – 267 . London, , UK : Academic Press .
  • Salgado-Roman , M , Botello-Álvarez , E , Rico-Martínez , R , Jiménez-Islas , H , Cárdenas-Manríquez , M and Navarette-Bolaños , JJ . 2008 . Enzymatic treatment to improve extraction of capsaicinoids and carotenoids from chilli (Capsicum anuum) fruits . J Agricult Food Chem , 56 : 10012 – 10018 .
  • Salvador , A , de la Guardia , M and Mauri , A . 1988 . Direct determination of calcium in food slurries by flame atomic absorption spectroscopy . Atom Spectrosc , 9 ( 6 ) : 195 – 197 .
  • Saxena , RJ , Gilmour , MI and Hays , MD . 2008 . Isolation and quantitative estimation of diesel exhaust and carbon black particles ingested by lung epithelial cells and alveolar macrophages in vitro . Biotechniques , 44 ( 6 ) : 799 – 805 .
  • Schiedt , K . 1995 . “ Chromatography: Part III. Thin-layer chromatography ” . In Carotenoids Volume 1A: Isolation and analysis , Edited by: Britton , G , Liaaen-Jensen , S and Pfander , H . 131 – 144 . Basel, , Switzerland : Birkhäuser .
  • Schiedt , K and Liaaen-Jensen , S . 1995 . “ Isolation and analysis ” . In Carotenoids Volume 1A: Isolation and analysis , Edited by: Britton , G , Liaaen-Jensen , S and Pfander , H . 81 – 108 . Basel, , Switzerland : Birkhäuser .
  • Schlatterer , J and Breithaupt , DE . 2006 . Xanthophylls in commercial egg yolks: quantitation and identification by HPLC and LC-(APCI)MS using a C30 phase . J Agricult Food Chem , 54 ( 6 ) : 2267 – 2273 .
  • Schoefs , B . 1998 . Photosynthetic pigments as food colorants: preparation, analysis and conservation, Francis JF, editor. Proceedings of the 3rd International Symposium on Natural Colorants for Foods, Neutraceuticals, Beverages, Confectionery and Cosmetics. Hamden: SIC. p. 314–334
  • Schoefs , B . 2001 . Analysis of terapyrrole pigments in foodstuffs . Int Lab , 33 : 34 – 39 .
  • Schoefs , B . 2002 . Chlorophyll and carotenoid analysis in food products. Properties of the pigments and methods of analysis . Trend Food Sci Tech , 13 : 361 – 371 .
  • Schoefs , B . 2003 . Chlorophyll and carotenoid analysis in food products . A practical case-by-case view. Trend Analyt Chem , 22 ( 6 ) : 335 – 339 .
  • Schoefs , B . 2004 . Determination of pigments in vegetables . J Chromatogr A , 1054 : 217 – 226 .
  • Schoefs , B . 2005 . Plant pigments: properties, analysis, degradation . Advan Food Nutr Res , 49 : 41 – 91 .
  • Schoefs , B , Bertrand , M and Lemoine , Y . 1995 . Separation of photosynthetic pigments and their precursors by reversed-phase high-performance liquid chromatography using a photodiode-array detector . J Chromatogr A , 692 : 239 – 245 .
  • Schwartz , SJ and von Elbe , JH . 1980 . Quantitative determination of individual betacyanin pigments by high-performance liquid chromatography . J Agricult Food Chem , 28 : 540 – 543 .
  • Schwartz , SJ , Hildenbrand , BE and von Elbe , JH . 1981 . Comparison of spectrophotometric and HPLC methods to quantify betacyanins . J Food Sci , 46 : 296 – 297 .
  • Schwartz , SJ , Woo , SL and von Elbe , JH . 1981 . High performance liquid chromatography of chlorophylls and their derivatives in fresh and processed spinach . J Agricult Food Chem , 29 : 533 – 535 .
  • Scott , KJ . 1992 . Observations on some problems associated with the analysis of carotenoids in foods by HPLC . Food Chem , 45 : 357 – 364 .
  • Scott , KJ , Finglas , PM , Seale , R , Hart , DJ and de Froidmont Gortz , I . 1996 . Interlaboratory studies of HPLC procedures for the analysis of carotenoids in foods . Food Chem , 57 ( 1 ) : 85 – 90 .
  • Scotter MJ. 1997. Analytical methods for natural food colour specifications. CSL Report No. FD 96/147. Project FS 1628. Food Standards Agency, London.
  • Scotter , MJ . 2009a . Synthesis and chemical characterisation of curcuminoid colouring principles for their potential use as HPLC standards for the determination of curcumin colour in foods . LWT Food Sci Tech , 42 : 1345 – 1351 .
  • Scotter , MJ . 2009b . The chemistry and analysis of annatto food colouring: a review . Food Addit Contamin A , 26 ( 8 ) : 1123 – 1145 .
  • Scotter , MJ , Castle , L and Roberts , D . 2005 . Method development and HPLC analysis of retail foods and beverages for copper chlorophyll (E141(i)) and chlorophyllins (E141(ii)) food colouring materials . Food Addit Contam , 22 ( 12 ) : 1163 – 1175 .
  • Scotter , MJ , Castle , L , Croucher , JM and Olivier , L . 2003 . Method development and analysis of retail foods and beverages for carotenoid food colouring materials E160a(ii) and E160e . Food Addit Contam , 20 ( 2 ) : 115 – 126 .
  • Scotter , MJ , Castle , L , Honeybone , C and Nelson , C . 2002 . Method development and analysis of retail foods for annatto food colouring material . Food Addit Contam , 19 : 205 – 222 .
  • Scotter , MJ , Thorpe , SA , Reynolds , SL , Wilson , LA and Strutt , PR . 1994 . Characterization of the principal colouring components of annatto using high performance liquid chromatography with photodiode array detection . Food Addit Contam , 11 : 301 – 315 .
  • Sérino , S , Gomex , L , Costagliola , G and Gautier , H . 2009 . HPLC assay of tomato carotenoids: validation of a rapid microextraction technique . J Agricult Food Chem , 57 : 8753 – 8760 .
  • Shah , NM and Chapman , JM . 2009 . Rapid separation of anthocyanins and flavanol glycosides utilizing Discovery ®DSC-MCAX solid phase extraction. Analytix, Issue 4 , Buchs, CH : Sigma-Aldrich .
  • Sharma , AK and Singh , I . 2009 . Spectrophotometric trace determination of iron in food, milk and tea samples using a new bis-azo dye as analytical reagent . Food Analyt Method , 2 ( 3 ) : 221 – 225 .
  • Shen , Y , Hu , Y , Huang , K , Yin , S , Chen , B and Yao , S . 2009 . Solid-phase extraction of carotenoids . J Chromatogr A , 1216 : 5763 – 5768 .
  • Short , FJ , Gorton , P , Wiseman , J and Boorman , KN . 1996 . Determination of titanium dioxide added as an inert marker in chicken digestibility studies . Anim Feed Sci Tech , 59 : 215 – 221 .
  • Smith PR, Blake CJ, Porter DC. 1983. Determination of added natural colours in foods. III. Annatto. Leatherhead Food R.A. Research Report No. 431. Leatherhead (UK): British Food Manufacturing Industries Research Association.
  • Smith , RM and Witowska , BA . 1984 . Comparison of detectors for the determination of curcumin in turmeric by high-performance liquid chromatography . Analyst , 109 : 259 – 261 .
  • Sowbhagya , HB and Chitra , VN . 2010 . Enzyme-assisted extraction of flavorings and colorants from plant materials . Critical Rev Food Sci Nutr , 50 : 146 – 161 .
  • Stintzing , FC , Trichterborn , J and Carle , R . 2006 . Characterization of anthocyanin-betalain mixtures for food colouring by chromatic and HPLC-DAD-MS analyses . Food Chem , 94 : 293 – 309 .
  • Streck , D , Steglich , W and Wray , V . 1993 . “ Betalains ” . In Methods in plant biochemistry , Vol. 8 , 421 – 450 . Orlando, FL : Academic Press .
  • Suzuki , N , Saitoh , K and Adachi , K . 1987 . Reverse-phase high-performance thin-layer chromatography and column liquid chromatography of chlorophylls and their derivatives . J Chromatogr , 408 : 181 – 190 .
  • Suzuki , Y and Shioi , Y . 2003 . Identification of chlorophylls and carotenoids in major teas by high-performance liquid chromatography with photodiode array detection . J Agricult Food Chem , 51 : 5307 – 5314 .
  • Tang , X , Cronin , DA and Brunton , NP . 2006 . A simplified approach to the determination of thiamine and riboflavin in meats using reverse phase HPLC . J Food Composition Anal , 19 : 831 – 837 .
  • Tarter , JG . 1987 . Ion chromatography , Chromatographic Sciences Series Vol. 37 382 – 386 . New York, NY : Marcel Dekker .
  • Taungbodhitham , AK , Jones , GP , Wahlqvist , ML and Briggs , DR . 1998 . Evaluation of extraction method for the analysis of carotenoids in fruits and vegetables . Food Chem , 63 ( 4 ) : 577 – 584 .
  • The Food and Environment Research Agency (Fera). 2010a. Internal communication. DEFRA Food and Environment Research Agency, York.
  • The Food and Environment Research Agency (Fera). 2010b. Food contaminant analysis [Internet]; [cited 2010 Nov 8]. Available from: http://www.fera.defra.gov.uk/foodDrink/foodAnalysis/foodContaminants.cfm/
  • Tian , Q , Giusti , MM , Stoner , GD and Schwartz , SJ . 2005 . Screening for anthocyanins using high-performance liquid chromatography coupled to electrospray ionization tandem mass spectrometry with precursor-ion analysis, product-ion analysis, common neutral loss analysis, and selected reaction monitoring . J Chromatogr A , 1091 : 72 – 82 .
  • Titgemeyer , EC , Armendariz , CK , Bindel , DJ , Greenwood , RH and Loest , CA . 2001 . Evaluation of titanium dioxide as a digestibility marker in cattle . J Anim Sci , 79 : 1059 – 1063 .
  • Tønnesen , HJ and Karlsen , J . 1983 . Quantitative determination of curcuma dyes in food . Zeitschrift Lebensmittel Untersuchung Forschung , 177 : 348 – 349 .
  • Tsunoda , K , Inoue , N , Tachibana , M and Aoyama , M . 1993 . Discriminitive determination of copper, iron and magnesium in chlorophyll and chlorophyllin complexes and their contents in foods . J Hyg Soc Japan , 34 ( 1 ) : 25 – 31 .
  • Valverde , J and This , H . 2008 . 1H NMR quantitative determination of photosynthetic pigments from green beans (Phaseolus vulgaris L.) . J Agricult Food Chem , 56 : 314 – 320 .
  • van Breemen , RB . 1996 . Innovations in carotenoid analysis using LC/MS . Analyt Chem , 68 : A299 – A304 .
  • van Breemen , RB . 1997 . Liquid chromatography mass spectrometry of carotenoids . Pure Appl Chem , 69 : 2061 – 2066 .
  • van Breemen , RB , Canjura , FK and Schwartz , SJ . 1991 . Identification of chlorophyll derivatives by mass spectrometry . J Agricult Food Chem , 39 : 1452 – 1456 .
  • van den Berg , H , van Schaik , F , Finglas , PM and de Froidmont-Görtz , I . 1996 . Third EU MAT intercomparison on methods for the determination of vitamins B-1, B-2 and B-6 in food . Food Chem , 57 ( 1 ) : 101 – 108 .
  • van Niekerk , PJ . 1988 . “ Chapter 5: Determination of vitamins ” . In HPLC in food analysis, , 2nd , Edited by: Macrea , R . 133 – 184 . London, , UK : Academic Press .
  • Vincent , KR and Scholz , RG . 1978 . Separation and quantification of red beet betacyanins and betaxanthins by high-performance liquid chromatography . J Agricult Food Chem , 26 : 812 – 816 .
  • Watanabe , T , Yamamoto , A , Nagai , S and Terabe , S . 1998 . Analysis of elderberry pigments in commercial food samples by micellar electrokinetic chromatography . Analyt Sci , 14 ( 4 ) : 839 – 844 .
  • Watson , DJ , Bushway , AA and Bushway , RJ . 2004 . Separation of peonidin and cyaniding, two anthocyanidins, in cranberries by capillary electrophoresis . J Liquid Chromatogr Related Tech , 27 ( 1 ) : 113 – 121 .
  • Wellnitz , MB . 1986 . Detection of cochineal in dry sausage . Fleischwirtschaft , 66 : 1001 – 1003 .
  • White , MM , Chejlava , M , Fried , B and Sherma , J . 2007 . The concentration of calcium carbonate in shells of freshwater snails . Am Malacological Bull , 22 ( 1 ) : 139 – 142 .
  • Wichitnithad , W , Jongaroonngamsang , N , Pummangura , S and Rojsitthisak , P . 2009 . A simple isocratic HPLC method for the simultaneous determination of curcuminoids in commercial turmeric extracts . Phytochem Anal , 20 : 314 – 319 .
  • Wood JE, Inns EL, Frazier RA, Nursten HE, Ames JM. 2002. Development of methods to determine levels of caramel in foodstuffs. Project Number A02002. Food Standards Agency Report, London.
  • Xu , Y-H , Tang , Y-J and Wu , M-J . 2007 . Determination of carminic acid in sweet by capillary electrophoresis using internal standard method . Fenxi Ceshi Xuebao , 26 ( 1 ) : 136 – 138 .
  • Yamada , S , Noda , N , Mikami , E and Hayakawa , J . 1993 . Analysis of colouring matters in food. 4. Methylation of cochineal color with diazomethane for the analysis of food products . J Agricult Food Chem , 41 : 1071 – 1075 .
  • Yasuda , K , Tadano , K , Ushiyama , H , Ogawa , H , Kawai , Y and Nishima , T . 1995 . Investigation to find an indicator substance for the analysis of sodium copper chlorophyllin in foods . J Food Hygienic Soc Japan , 36 : 710 – 716 .
  • Yoshida , A , Takagaki , Y and Nishimune , T . 1995 . Enzyme immunoassay for carminic acid in foods . J AOAC Int , 78 ( 3 ) : 807 – 811 .
  • Yu , L-H , Su , L-K and Mu , D-H . 2008 . Determination of carminic acid in carbohydrate foods and meat products by high-performance liquid chromatography . Fenxi Ceshi Xuebao , 27 ( 6 ) : 648 – 650 .
  • Zandomeneghi , M , Carbonaro , L and Zandomeneghi , G . 2007 . Biochemical flurometric method for the determination of riboflavin in milk . J Agricult Food Chem , 55 : 5990 – 5994 .
  • Zhang , J , Jinnai , S , Ikeda , R , Wada , M , Hayashida , S and Nakashima , K . 2009 . A simple HPLC-fluorescence method for the quantitation of curcuminoids and its application to turmeric products . Analyt Sci , 25 : 385 – 388 .
  • Zhang , H , Yang , X , Ma , Y , Dong , AJ and Zhang , YC . 2008 . Determination of canthaxanthin in feed ingredients by high performance liquid chromatography . Fenxi Ceshi Xuebao , 27 ( 7 ) : 785 – 787 .
  • Zougagh , M and Rios , A . 2008 . Supercritical fluid extraction as an on-line clean-up technique for the determination of riboflavin vitamins in food samples by capillary electrophoresis with fluorimetric detection . Electrophoresis , 29 : 3213 – 3219 .

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