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Review Article

Nanoscale zero-valent iron for remediation of toxicants and wastewater treatment

ORCID Icon
Pages 390-419 | Received 28 Jun 2022, Accepted 10 May 2023, Published online: 11 Jun 2023

References

  • Mazumder A, Bhattacharya S, Bhattacharjee C, et al. Role of nano-photocatalysis in heavy metal detoxification. In: Inamuddin, editor. Nanophotocatalysis and environmental applications, environmental chemistry for a sustainable world. Cham: Springer Nature Switzerland AG; 2020: 30. p. 1–33.
  • Qian H, Pretzer LA, Velazquez JC, et al. Gold nanoparticles for cleaning contaminated water. J Chem Technol Biotechnol. 2013;88:735–741.
  • Lin Y, Cao Y, Yao Q, et al. Engineering noble metal nanomaterials for pollutant decomposition. Ind Eng Chem Res. 2020;59:20561–20581.
  • Igiri BE, Okoduwa SIR, Idoko GO, et al. Toxicity and bioremediation of heavy metals contaminated ecosystem from tannery wastewater: a review. J Toxicol. 2018;2018:1–16.
  • Akpomie KG, Conradie J, Adegoke KA, et al. Adsorption mechanism and modeling of radionuclides and heavy metals onto ZnO nanoparticles: a review. Appl Water Sci. 2023;13:20.
  • Stefaniuk M, Oleszczuk P, Ok YS. Review on nano zerovalent iron (nZVI): from synthesis to environmental applications. Chem Eng J. 2016;287:618–632.
  • Gebre SH, Sendeku MG. Trimetallic nanostructures and their applications in electrocatalytic energy conversions. J Energ Chem. 2022;65:329–352.
  • Yunus IS, Harwin W, Kurniawan A, et al. Nanotechnologies in water and air pollution treatment. Environ Technol Rev. 2012;1:136–148.
  • Gebre SH. Recent developments of supported and magnetic nanocatalysts for organic transformations: an up–to–date review. Appl Nanosci [Internet]. 2023;13:15–63. doi:10.1007/s13204-021-01888-3.
  • Gebre SH. Bio-inspired synthesis of metal and metal oxide nanoparticles: the key role of phytochemicals. J Clust Sci. 2023;34:665–704.
  • Chekli L, Bayatsarmadi B, Sekine R, et al. Analytical characterisation of nanoscale zero-valent iron: A methodological review. Anal Chim Acta. 2016;903:13–35.
  • Wang Z, Choi F, Acosta E. Effect of surfactants on zero-valent iron nanoparticles (NZVI) reactivity. J Surfactants Deterg. 2017;20:577–588.
  • Kadhum ST, Alkindi GY, Albayati TM. Remediation of phenolic wastewater implementing nano zerovalent iron as a granular third electrode in an electrochemical reactor. Int J Environ Sci Technol. 2022;19:1383–1392.
  • Zou Y, Wang X, Khan A, et al. Environmental remediation and application of nanoscale zero-valent iron and its composites for the removal of heavy metal ions: a review. Environ Sci Technol. 2016;50:7290–7304.
  • Gong X-B, You S-J, Wang X-H, et al. Silver-tungsten carbide nanohybrid for efficient electrocatalysis of oxygen reduction reaction in microbial fuel cell. J Power Sources. 2013;225:330–337.
  • Li Q, Chen Z, Wang H, et al. Removal of organic compounds by nanoscale zero-valent iron and its composites. Sci Total Environ. 2021;792:148546.
  • Tang H, Wang J, Zhang S, et al. Recent advances in nanoscale zero-valent iron-based materials: characteristics, environmental remediation and challenges. J Clean Prod. 2021;319:128641.
  • Xu J, Li H, Lowry GV. Sulfidized nanoscale zero-valent iron: tuning the properties of this complex material for efficient groundwater remediation. Acc Mater Res. 2021;2:420–431.
  • Cao Z, Liu X, Xu J, et al. Removal of antibiotic florfenicol by sulfide-modified nanoscale zero-valent iron. Environ Sci Technol. 2017;51:11269–11277.
  • Dong H, Deng J, Xie Y, et al. Stabilization of nanoscale zero-valent iron (nZVI) with modified biochar for Cr(VI) removal from aqueous solution. J Hazard Mater. 2017;332:79–86.
  • Peng Z, Xiong C, Wang W, et al. Hydrophobic modification of nanoscale zero-valent iron with excellent stability and floatability for efficient removal of floating oil on water. Chemosphere. 2018;201:110–118.
  • Sabouri MR, Sohrabi MR, Moghaddam AZ. A novel and efficient dyes degradation using bentonite supported zero-valent iron-based nanocomposites. Mater Sci Inc Nanomater Polymer. 2020;5:369–378.
  • Mukherjee R, Kumar R, Sinha A, et al. A review on synthesis, characterization and applications of nano-zero valent iron (nZVI) for environmental remediation. Crit Rev Environ Sci Technol. 2015;46:443–466.
  • Torrey JD, Killgore JP, Bedford NM, et al. Oxidation behavior of zero-valent iron nanoparticles in mixed matrix water purification membranes. Environ Sci: Water Res Technol. 2015;1:146–152.
  • Lu H, Wang J, Ferguson S, et al. Mechanism, synthesis and modification of nano zerovalent iron in water treatment. Nanoscale. 2016;8:9962–9975.
  • Kim H, Kim MS, Kim H, et al. Nanoparticulate zero-valent iron coupled with polyphosphate: the sequential redox treatment of organic compounds and its stability and bacterial toxicityty. Environ Sci: Nano. 2017;4:396–405.
  • Shad S, Belinga-Desaunay-Nault M-FA, Sohail S, et al. Removal of contaminants from canal water using microwave synthesized zero valent iron. Environ Sci: Water Res Technol. 2020;6:3057–3065.
  • Alazaiza MYD, Albahnasawi A, Copty NK, et al. Nanoscale zero-valent iron application for the treatment of soil, wastewater and groundwater contaminated with heavy metals: a review. Desalination Water Treat. 2022;253:194–210.
  • Srivastava K, Srivastava A, Singh P, et al. Remediation of distillery waste water using zero valent iron nanoparticles. Curr Opin Green Sustain Chem. 2021;4:100072.
  • Monga Y, Kumar P, Sharma RK, et al. Sustainable synthesis of nanoscale zerovalent iron particles for environmental remediation. ChemSusChem. 2020;13:3288–3305.
  • Fu F, Dionysiou DD, Liu H. The use of zero-valent iron for groundwater remediation and wastewater treatment: A review. J Hazard Mater. 2014;267:194–205.
  • Curcio GM, Limonti C, Siciliano A, et al. Nitrate removal by zero-valent metals: a comprehensive review. Sustainability. 2022;14:4500.
  • Wang B, Deng C, Ma W, et al. Modified nanoscale zero-valent iron in persulfate activation for organic pollution remediation: a review. Environ Sci Pollut Res. 2021;28:34229–34247.
  • Kozma G, Rónavári A, Kónya Z, et al. Environmentally benign synthesis methods of zero-valent iron nanoparticles. ACS Sustain Chem Eng. 2015;4:291–297.
  • Bhakya S, Muthukrishnan S, Sukumaran M, et al. Catalytic degradation of organic dyes using synthesized silver nanoparticles: a green approach. Bioremediat Biodegrad. 2015;6:1–9.
  • Jyoti K, Singh A. Green synthesis of nanostructured silver particles and their catalytic application in dye degradation. J Genet Eng Biotechnol. 2016;14:311–317.
  • Veisi H, Azizi S, Mohammadi P. Green synthesis of the silver nanoparticles mediated by thymbra spicata extract and its application as a heterogeneous and recyclable nanocatalyst for catalytic reduction of a variety of dyes in water. J Clean Prod. 2018;170:1536–1543.
  • Raman CD, Kanmani S. Textile dye degradation using nano zero valent iron: A review. J Environ Manage. 2016;177:341–355.
  • Radini IA, Hasan N, Malik MA, et al. Biosynthesis of iron nanoparticles using trigonella foenum-graecum seed extract for photocatalytic methyl orange dye degradation and antibacterial applications. J Photochem Photobiol B. 2018;183:154–163.
  • Chen Z, Jin X, Chen Z, et al. Removal of methyl orange from aqueous solution using bentonite-supported nanoscale zero-valent iron. J Colloid Interface Sci. 2011;363:601–607.
  • Quan G, Yang M, Fan Q, et al. Palygorskite-supported sulfide-modified nanoscale zero-valent iron for Congo Red removal. Environ Pollut Bioavailab. 2019;31:233–239.
  • Sravanthi K, Ayodhya D, Swamy PY. Green synthesis, characterization of biomaterial-supported zero-valent iron nanoparticles for contaminated water treatment. J Anal Sci Technol. 2018;9:1–11.
  • Li X, Zhao Y, Xi B, et al. Decolorization of methyl orange by a new clay-supported nanoscale zero-valent iron: synergetic effect, efficiency optimization and mechanism. J Environ Sci. 2016;52:8–17.
  • Wang X, Wang P, Ma J, et al. Synthesis, characterization, and reactivity of cellulose modified nano zero-valent iron for dye discoloration. Appl Surf Sci. 2015;345:57–66.
  • Abdelfatah AM, Fawzy M, Eltaweil AS, et al. Green synthesis of nano-zero-valent iron using ricinus communis seeds extract: characterization and application in the treatment of methylene blue-polluted water. ACS Omega. 2021;6:25397–25411.
  • Xin H, Yang X, Liu X, et al. Biosynthesis of iron nanoparticles using tie guanyin tea extract for degradation of bromothymol blue. J Nanotechnol. 2016;2016:1–8.
  • Alshehri A, Malik MA, Khan Z, et al. Biofabrication of Fe nanoparticles in aqueous extract of hibiscus sabdariffa with enhanced photocatalytic activities. RSC Adv. 2017;7:25149–25159.
  • Dutta S, Ghosh A, Satpathi S, et al. Modified synthesis of nanoscale zero-valent iron and its ultrasound-assisted reactivity study on a reactive dye and textile industry effluents. Desalination Water Treat. 2015;57:19321–19332.
  • Barreto-rodrigues M, Silveira J, Zazo JA, et al. Synthesis, characterization and application of nanoscale zero-valent iron in the degradation of the azo dye disperse Red 1. Biochem Pharmacol. 2017;5:628–634.
  • Kerkez DV, Tomasˇevic DD, Kozma G, et al. Three different clay-supported nanoscale zero-valent iron materials for industrial azo dye degradation: a comparative study. J Taiwan Inst Chem Eng. 2014;45:2451–2461.
  • Khunjan U, Kasikamphaiboon P. Green synthesis of kaolin-supported nanoscale zero-valent iron using ruellia tuberosa leaf extract for effective decolorization of azo dye reactive black 5. Arab J Sci Eng. 2021;46:383–394.
  • Bhatti HN, Iram Z, Iqbal M, et al. Facile synthesis of zero valent iron and photocatalytic application for the degradation of dyes. Mater Res Express. 2020;7:015802.
  • Reza M, Moghri M, Amiri S, et al. Optimization of reactive blue 21 removal by nanoscale zero-valent iron using response surface methodology. Arab J Chem. 2016;9:518–525.
  • Xu H, Tian W, Zhang Y, et al. Reduced graphene oxide/attapulgite-supported nanoscale zero-valent iron removal of acid Red 18 from aqueous solution. Water Air Soil Pollut. 2018;229:388.
  • Hamdy A, Mostafa MK, Nasr M. Zero-valent iron nanoparticles for methylene blue removal from aqueous solutions and textile wastewater treatment, with cost estimation. Water Sci Technol. 2018;78:367–378.
  • Liu C, Li X, Ma B, et al. Removal of water contaminants by nanoscale zero-valent iron immobilized in PAN-based oxidized membrane. Appl Surf Sci. 2014;321:158–165.
  • Luo S, Qin P, Shao J, et al. Synthesis of reactive nanoscale zero valent iron using rectorite supports and its application for orange II removal. Chem Eng J. 2013;223:1–7.
  • Shu HY, Chang MC, Chen CC, et al. Using resin supported nano zero-valent iron particles for decoloration of acid blue 113 azo dye solution. J Hazard Mater. 2010;184:499–505.
  • Weng CH, Lin YT, Yuan HM. Rapid decoloration of reactive black 5 by an advanced fenton process in conjunction with ultrasound. Sep Purif Technol. 2013;117:75–82.
  • Huang D, Chen G, Zeng G, et al. Synthesis and application of modified zero-valent iron nanoparticles for removal of hexavalent chromium from wastewater. Water Air Soil Pollut. 2015;226:375.
  • Zhu K, Chen C. Application of nZVI and its composites into the treatment of toxic/radioactive metal ions. In: Changlun C., editor. Emerging natural and tailored nanomaterials for radioactive waste treatment and environmental remediation. 1st ed. Hefei: Elsevier Ltd.; 2019. p. 281–330.
  • Kumar KVA, Amanchi SR, Sreedhar B, et al. Phenol and Cr(VI) degradation with Mn ion doped ZnO under visible light photocatalysis. RSC Adv. 2017;7:43030–43039.
  • Fazlzadeh M, Rahmani K, Zarei A, et al. A novel green synthesis of zero valent iron nanoparticles (NZVI) using three plant extracts and their efficient application for removal of Cr(VI) from aqueous solutions. Adv Powder Technol. 2017;28:122–130.
  • Gao H, Lv S, Dou J, et al. The efficient adsorption removal of Cr(VI) by using Fe3O4 nanoparticles hybridized with carbonaceous materials. RSC Adv. 2015;5:60033–60040.
  • Lee LZ, Abbas M, Zaini A, et al. Porous nanomaterials for heavy metal removal. In: Martizez L, Kharissova O, Kharisov B, editor. Handbook of ecomaterials. Cham: Springer; 2019. p. 469–494.
  • Yang J, Hou B, Wang J, et al. Nanomaterials for the removal of heavy metals from wastewater. Nanomaterials. 2019;9:1–39.
  • Singh S, Kapoor D, Khasnabis S, et al. Mechanism and kinetics of adsorption and removal of heavy metals from wastewater using nanomaterials. Environ Chem Lett. 2021;19:2351–2381.
  • Wu Y, Guan CY, Griswold N, et al. Zero-valent iron-based technologies for removal of heavy metal(loid)s and organic pollutants from the aquatic environment: recent advances and perspectives. J Clean Prod. 2020;277:123478.
  • Dai L, Meng K, Zhao W, et al. Mechanism-Enhanced active attapulgite-supported nanoscale zero-valent iron for efficient removal of Pb2 + from aqueous solution. Nanomaterials. 2022;12:1591.
  • Akoto JD, Chai F, Repo E, et al. Polyethyleneimine stabilized nanoscale zero-valent iron-magnetite (Fe3O4@nZVI-PEI) for the enhanced removal of arsenic from acidic aqueous solution: performance and mechanisms. J Environ Chem Eng. 2022;10:108589.
  • Chai F, Zhang R, Min X, et al. Highly efficient removal of arsenic (III/V) from groundwater using nZVI functionalized cellulose nanocrystals fabricated via a bioinspired strategy. Sci Total Environ. 2022;842:156937.
  • Huang P, Ye Z, Xie W, et al. Rapid magnetic removal of aqueous heavy metals and their relevant mechanisms using nanoscale zero valent iron (nZVI) particles. Water Res. 2013;47:4050–4058.
  • Kumar R, Singh N, Pandey SN. Potential of green synthesized zero-valent iron nanoparticles for remediation of lead-contaminated water. Int J Environ Sci Technol. 2015;12:3943–3950.
  • Yang F, Xie S, Wang G, et al. Investigation of a modified metal-organic framework UiO-66 with nanoscale zero-valent iron for removal of uranium (VI) from aqueous solution. Environ Sci Poll Res. 2020;27:20246–20258.
  • Onal ES, Yatkın T, Aslanov T, et al. Biosynthesis and characterization of iron nanoparticles for effective adsorption of Cr(VI). Int J Chem Eng. 2019;2019:1–13.
  • Lv X, Xu J, Jiang G, et al. Chemosphere removal of chromium (VI) from wastewater by nanoscale zero-valent iron particles supported on multiwalled carbon nanotubes. Chemosphere. 2011;85:1204–1209.
  • Poguberovi´c SS, Krˇcmar DM, Maleti´ SP, et al. Removal of As(III) and Cr(VI) from aqueous solutions using “green” zero-valent iron nanoparticles produced by oak mulberry and cherry leaf extracts. Ecol Eng. 2016;90:42–49.
  • Zhang X, Lin S, Chen Z, et al. Kaolinite-supported nanoscale zero-valent iron for removal of Pb2 + from aqueous solution: reactivity, characterization and mechanism. Water Res. 2011;45:3481–3488.
  • Jiao C, Cheng Y, Fan W, et al. Synthesis of agar-stabilized nanoscale zero-valent iron particles and removal study of hexavalent chromium. Int J Environ Sci Technol. 2015;12:1603–1612.
  • Li S, Wang W, Yan W, et al. Nanoscale zero-valent iron (nZVI) for the treatment of concentrated Cu(II) wastewater: a field demonstration. Environ Sci: Processes Impacts. 2014;16:524–533.
  • Fan H, Ren H, Ma X, et al. High-gravity continuous preparation of chitosan-stabilized nanoscale zero-valent iron towards Cr(VI) removal. Chem Eng J. 2020;390:124639.
  • Hidalgo KTS, Guzm´an-Blas R, Ortiz-Quiles EO, et al. Highly organized nanofiber formation from zero valent iron nanoparticles after cadmium water remediation. RSC Adv. 2014;5:2777–2784.
  • Li J, Chen C, Zhu K, et al. Nanoscale zero-valent iron particles modified on reduced graphene oxides using a plasma technique for Cd(II) removal. J Taiwan Inst Chem Eng. 2015;59:389–394.
  • Jing C, Landsberger S, Li YL. The application of illite supported nanoscale zero valent iron for the treatment of uranium contaminated groundwater. J Environ Radioact. 2017;176:1–6.
  • Chen X, Li F, Xie XJ, et al. Nanoscale zero-valent iron and chitosan functionalized eichhornia crassipes biochar for efficient hexavalent chromium removal. Int J Environ Res Public Health. 2019;16:3046.
  • Quan G, Zhang J, Guo J, et al. Removal of Cr(VI) from aqueous solution by nanoscale zero-valent iron grafted on acid-activated attapulgite. Water Air Soil Pollut. 2014;225:1979.
  • Liu S, Gao H, Cheng R, et al. Study on influencing factors and mechanism of removal of Cr(VI) from soil suspended liquid by bentonite-supported nanoscale zero-valent iron. Sci Rep. 2020;10:8831.
  • Luo S, Lu T, Peng L, et al. Synthesis of nanoscale zero-valent iron immobilized in alginate microcapsules for removal of Pb(II) from aqueous solution. J Mater Chem A. 2014;2:15463–15472.
  • Du Q, Li G, Zhang S, et al. High-dispersion zero-valent iron particles stabilized by artificial humic acid for lead ion removal. J Hazard Mater. 2020;383:121170.
  • Madhavi V, Prasad TNVKV, Vijaya A, et al. Application of phytogenic zerovalent iron nanoparticles in the adsorption of hexavalent chromium. Spectrochim Acta A Mol Biomol Spectrosc. 2013;116:17–25.
  • Li S, Wang W, Liang F, et al. Heavy metal removal using nanoscale zero-valent iron (nZVI): theory and application. J Hazard Mater. 2017;322:163–171.
  • Dongsheng Z, Wenqiang G, Guozhang C, et al. Removal of heavy metal lead (II) using nanoscale zero-valent iron with different preservation methods. Adv Powder Technol. 2018;30:581–589.
  • Boubakri S, Djebbi MA, Bouaziz Z, et al. Nanoscale zero-valent iron functionalized posidonia oceanica marine biomass for heavy metal removal from water. Environ Sci Pollut Res. 2017;24:27879–27896.
  • Jabeen H, Chandra V, Jung S, et al. Enhanced Cr(vi) removal using iron nanoparticle decorated graphene. Nanoscale. 2011;3:3583–3585.
  • Shi L, Zhang X, Chen Z. Removal of Chromium (VI) from wastewater using bentonite-supported nanoscale zero-valent iron. Water Res. 2010;45:886–892.
  • Liu T, Wang Z, Yan X, et al. Removal of mercury (II) and chromium (VI) from wastewater using a new and effective composite: pumice-supported nanoscale zero-valent iron. Chem Eng J. 2014;245:34–40.
  • Zhang Q, Zhao D, Feng S, et al. Synthesis of nanoscale zero-valent iron loaded chitosan for synergistically enhanced removal of U(VI) based on adsorption and reduction. J Colloid Interface Sci. 2019;552:735–743.
  • Yang D, Wang L, Li Z, et al. Simultaneous adsorption of Cd(II) and As(III) by a novel biochar-supported nanoscale zero-valent iron in aqueous systems. Sci Total Environ. 2019;708:134823.
  • Zhang X, Lin S, Lu X, et al. Removal of Pb(II) from water using synthesized kaolin supported nanoscale zero-valent iron. Chem Eng J. 2010;163:243–248.
  • Bagbi Y, Sarswat A, Tiwari S, et al. Synthesis of L-cysteine stabilized zero-valent iron (nZVI) nanoparticles for lead remediation from water. Environ Nanotechnol Monit Manag. 2017;7:34–45.
  • Li Z, Wang L, Meng J, et al. Zeolite-supported nanoscale zero-valent iron: New findings on simultaneous adsorption of Cd(II), Pb(II), and As(III) in aqueous solution and soil. J Hazard Mater. 2018;344:1–11.
  • Kim SA, Kamala-kannan S, Lee K, et al. Removal of Pb(II) from aqueous solution by a zeolite-nanoscale zero-valent iron composite. Chem Eng J. 2013;217:54–60.
  • Liu M, Wang Y, Chen L, et al. Mg(OH)2 supported nanoscale zero valent iron enhancing the removal of Pb(II) from aqueous solution. ACS Appl Mater Interfaces. 2015;7:7961–7969.
  • Arshadi M, Soleymanzadeh M, Salvacion JWL, et al. Nanoscale zero-valent iron (NZVI) supported on sineguelas waste for Pb(II) removal from aqueous solution: kinetics, thermodynamic and mechanism. J Colloid Interface Sci. 2014;426:241–251.
  • Jung AV, Le CP, Roig B, et al. Microbial contamination detection in water resources: interest of current optical methods, trends and needs in the context of climate change. Int J Environ Res Public Health. 2014;11:4292–4310.
  • Ashbolt NJ. Microbial contamination of drinking water and disease outcomes in developing regions. Toxicology. 2004;198:229–238.
  • Gebre SH, Sendeku MG. New frontiers in the biosynthesis of metal oxide nanoparticles and their environmental applications: an overview. SN Appl Sci. 2019;1:928.
  • Moustafa MT. Removal of pathogenic bacteria from wastewater using silver nanoparticles synthesized by two fungal species. Water Science. 2017;31:164–176.
  • Elshorbagy A-iL, Maraqa W, A M, et al. Use of nanoparticles for the disinfection of desalinated water. Water (Basel). 2019;11:559.
  • Nguyen NHA, Špánek R, Kasalický V, et al. Different effects of nano-scale and micro-scale zero-valent iron particles on planktonic microorganisms from natural reservoir water. Environ Sci: Nano. 2018;5:1117–1129.
  • Xie Y, Dong H, Zeng G, et al. The interactions between nanoscale zero-valent iron and microbes in the subsurface environment: A review. J Hazard Mater. 2017;321:390–407.
  • Sadek AH, Aske MS, Abdelhamid SA. Bacteriostatic impact of nanoscale zero-valent iron against pathogenic bacteria in the municipal wastewater. Biologia (Bratisl). 2021;76:2785–2809.
  • Diao M, Yao M. Use of zero-valent iron nanoparticles in inactivating microbes. Water Res. 2009;43:5243–5251.
  • Cheng R, Li G, Cheng C, et al. Removal of bacteriophage f2 in water by nanoscale zero-valent iron and parameters optimization using response surface methodology. Chem Eng J. 2014;252:150–158.
  • Cheng R, Li G, Shi L, et al. The mechanism for bacteriophage f2 removal by nanoscale zero-valent iron. Water Res. 2016;105:429–435.
  • Chen H, Cao Y, Wei E, et al. Facile synthesis of graphene nano zero-valent iron composites and their efficient removal of trichloronitromethane from drinking water. Chemosphere. 2016;146:32–39.
  • Shih Y, Hsu C, Su Y. Reduction of hexachlorobenzene by nanoscale zero-valent iron: kinetics, pH effect, and degradation mechanism. Sep Purif Technol. 2011;76:268–274.
  • Zhang B, Tian Y, Liu J, et al. Nanoscale zero-valent iron particles supported on MIL-96: a novel material for adsorption-degradation of trichloronitromethane. Environ Sci Poll Res. 2021;28:68513–68522.
  • Kim H, Hong H, Jung J, et al. Degradation of trichloroethylene (TCE) by nanoscale zero-valent iron (nZVI) immobilized in alginate bead. J Hazard Mater. 2010;176:1038–1043.
  • Bhattacharjee S, Ghoshal S. Optimal design of sulfidated nanoscale zerovalent iron for enhanced trichloroethene degradation. Environ Sci Technol. 2018;52:11078–11086.
  • Ma L, He H, Zhu R, et al. Bisphenol A degradation by a new acidic nano zero-valent iron diatomite composite. Catal Sci Technol. 2016;6:6066–6075.
  • Wu J, Zhao J, Hou J, et al. Degradation of Tetrabromobisphenol A by sulfidated nanoscale zerovalent iron in a dynamic two-step anoxic/oxic process. Environ Sci Technol. 2019;53:8105–8114.
  • Zhang J, Chen L, Zhang X. Removal of P-nitrophenol by nano zero valent iron-cobalt and activated persulfate supported onto activated carbon. Water (Basel). 2022;14:1387.
  • Kadhum ST, Alkindi GY, Albayati TM. Eco friendly adsorbents for removal of phenol from aqueous solution employing nanoparticle zero-valent iron synthesized from modified green tea bio-waste and supported on silty clay. Chin J Chem Eng. 2021;36:19–28.
  • Bae S, Gim S, Kim H, et al. Effect of NaBH4 on properties of nanoscale zero-valent iron and its catalytic activity for reduction of p -nitrophenol. Appl Catal B. 2015;182:541–549.
  • Bao T, Jin J, Damtie MM, et al. Green synthesis and application of nanoscale zero-valent iron/rectorite composite material for P-chlorophenol degradation via heterogeneous Fenton reaction. J Saudi Chem Soc. 2019;23:864–878.
  • Jing Q, Qiao S, Xiao W, et al. Efficient removal of 2,4-DCP by nano zero-valent iron-reduced graphene oxide: statistical modeling and process optimization using RSM-BBD approach. Adsorpt Sci Technol. 2021;2021:1–11.
  • Xie J, Lei C, Chen W, et al. Catalytic properties of transition metals modified nanoscale zero-valent iron for simultaneous removal of 4-chlorophenol and Cr(VI): efficacy, descriptor and reductive mechanisms. J Hazard Mater. 2021;403:123827.
  • Qiao J, Jiao W, Liu Y. Degradation of nitrobenzene-containing wastewater by sequential nanoscale zero valent iron-persulfate process. Green Energy Environ. 2021;6:910–919.
  • Lee H, Kim BH, Park YK, et al. Application of recycled zero-valent iron nanoparticle to the treatment of wastewater containing nitrobenzene. J Nanomater. 2015;2015:1–8.
  • Li J, Zhou Q, Liu Y, et al. Recyclable nanoscale zero-valent iron-based magnetic polydopamine coated nanomaterials for the adsorption and removal of phenanthrene and anthracene. Sci Technol Adv Mater. 2017;18:3–16.
  • Zhang X, Wu Y. Application of coupled zero-valent iron/biochar system for degradation of chlorobenzene-contaminated groundwater. Water Sci Technol. 2017;75:571–580.
  • Vinod VTP, Wacławek S, Sena C, et al. Gum karaya (Sterculia urens) stabilized zero-valent iron nanoparticles: characterization and applications for the removal of chromium and volatile organic pollutants from water. RSC Adv. 2017;7:13997–14009.
  • Nakatsuji Y, Salehi Z, Kawase Y. Mechanisms for removal of p-nitrophenol from aqueous solution using zero-valent iron. J Environ Manage. 2015;152:183–191.
  • Bin Q, Lin B, Zhu K, et al. Superior trichloroethylene removal from water by sulfide-modified nanoscale zero-valent iron/graphene aerogel composite. J Environ Sci. 2019;8:90102.
  • Arvaniti OS, Hwang Y, Andersen HR, et al. Reductive degradation of perfluorinated compounds in water using Mg-aminoclay coated nanoscale zero valent iron. Chem Eng J J. 2015;262:133–139.
  • Li L, Zhang S, Lu B, et al. Nitrobenzene reduction using nanoscale zero-valent iron supported by polystyrene microspheres with different surface functional groups. Environ Sci Poll Res. 2018;25:7916–7923.
  • Wang H, Cai S, Shan L, et al. Adsorptive and reductive removal of chlorophenol from wastewater by biomass-derived mesoporous carbon-supported sulfide nanoscale zerovalent iron. Nanomaterials. 2019;9:1786.
  • Krawczyk K, Wacławek S, Silvestri D, et al. Surface modification of zero-valent iron nanoparticles with β-cyclodextrin for 4-nitrophenol conversion. J Colloid Interface Sci. 2021;586:655–662.
  • Shih Y, Tai Y. Chemosphere reaction of decabrominated diphenyl ether by zerovalent iron nanoparticles. Chemosphere. 2010;78:1200–1206.
  • Dong H, Zhang C, Hou K, et al. Removal of trichloroethylene by biochar supported nanoscale zero-valent iron in aqueous solution. Sep Purif Technol. 2017;188:188–196.
  • Zhang X, Lin Y, Shan X, et al. Degradation of 2, 4, 6-trinitrotoluene (TNT) from explosive wastewater using nanoscale zero-valent iron. Chem Eng J. 2010;158:566–570.
  • Taylor P, Lisha KP, Pradeep T. Enhanced visual detection of pesticides using gold nanoparticles. J Environ Sci Health B. 2009;44:697–705.
  • Khodabakhshi A, Mohammadi-moghadam F, Amin MM, et al. Comparison of paraquat herbicide removal from aqueous solutions using nanoscale zero-valent iron-pumice/diatomite composites. Int J Chem Eng. 2021;2021:1–12.
  • Sun Z, Zheng S, Ayoko GA, et al. Degradation of simazine from aqueous solutions by diatomite-supported nanosized zero-valent iron composite materials. J Hazard Mater [Internet]. 2013;263:768–777. doi:10.1016/j.jhazmat.2013.10.045.
  • Xing R, He J, Hao P, et al. Graphene oxide-supported nanoscale zero-valent iron composites for the removal of atrazine from aqueous solution. Colloids Surf A. 2020;589:124466.
  • Jiang Z, Li J, Jiang D, et al. Removal of atrazine by biochar-supported zero-valent iron catalyzed persulfate oxidation: reactivity, radical production and transformation pathway. Environ Res. 2020;184:109260.
  • Poursaberi T, Konoz E, Sarrafi AHM, et al. Application of nanoscale zero-valent iron in the remediation of DDT from contaminated water. Chem Sci Trans. 2012;1:658–668.
  • Zhu C, Fang G, Dionysiou DD, et al. Efficient transformation of DDTs with persulfate activation by zero-valent iron nanoparticles: A mechanistic study. J Hazard Mater. 2016;316:232–241.
  • Kang J, Wu W, Liu W, et al. Zero-valent iron (ZVI) activation of persulfate (PS) for degradation of para-chloronitrobenzene in soil. Bull Environ Contam Toxicol. 2019;103:140–146.
  • Cheng R, Cheng C, Liu G, et al. Removing pentachlorophenol from water using a nanoscale zero-valent iron/H2O2 system. Chemosphere. 2015;141:138–143.
  • Liu W, Sutton NB, Rijnaarts HHM, et al. Pharmaceutical removal from water with iron- or manganese-based technologies: A review manganese-based technologies: a review. Crit Rev Environ Sci Technol. 2016;46:1584–1621.
  • Zhou Y, Wang T, Zhi D, et al. Applications of nanoscale zero-valent iron and its composites to the removal of antibiotics: a review. J Mater Sci. 2019;54:12171–12188.
  • Leili M, Fazlzadeh M, Bhatnagar A. Green synthesis of nano-zero-valent iron from Nettle and Thyme leaf extracts and their application for the removal of cephalexin antibiotic from aqueous solutions. Envoronmental Technology. 2018;39:1158–1172.
  • Xia S, Gu Z, Zhang Z, et al. Removal of chloramphenicol from aqueous solution by nanoscale zero-valent iron particles. Chem Eng J J. 2014;257:98–104.
  • Wu G, Kong W, Gao Y, et al. Removal of chloramphenicol by sulfide-modified nanoscale zero-valent iron activated persulfate: performance, salt resistance, and reaction mechanisms. Chemosphere. 2022;286:131876.
  • Sulaiman S, Al-jabari M. Removal of spironolactone from aqueous solution using bentonite-supported nanoscale zero-valent iron and activated charcoal. Desalination Water Treat. 2020;173:283–293.
  • Abdel-Aziz HM, Farag RS, Abdel-Gawad SA. Carbamazepine removal from aqueous solution by green synthesis zero-valent iron/Cu nanoparticles with ficus benjamina leaves’ extract. Int J Environ Res. 2019;13:843–852.
  • Zhang Y, Zhao L, Yang Y, et al. Degradation of the antibiotic ornidazole in aqueous solution by using nanoscale zero-valent iron particles: kinetics, mechanism, and degradation pathway. RSC Adv. 2018;8:35062–35072.
  • Zhao J, Yang X, Liang G, et al. Effective removal of two fluoroquinolone antibiotics by PEG-4000 stabilized nanoscale zero-valent iron supported onto zeolite (PZ-NZVI). Sci Total Environ. 2020;710:136289.
  • Machado S, Pacheco JG, Nouws HPA, et al. Green zero-valent iron nanoparticles for the degradation of amoxicillin. Int J Environ Sci Technol. 2017;14:1109–1118.
  • Zha S, Cheng Y, Gao Y, et al. Nanoscale zero-valent iron as a catalyst for heterogeneous Fenton oxidation of amoxicillin. Chem Eng J. 2014;255:141–148.
  • Gao J, Han D, Xu Y, et al. Persulfate activation by sulfide-modified nanoscale iron supported by biochar (S-nZVI/BC) for degradation of ciprofloxacin. Sep Purif Technol. 2020;235:116202.
  • Wang X, Du Y, Ma J. Novel synthesis of carbon spheres supported nanoscale zero-valent iron for removal of metronidazole. Appl Surf Sci. 2016;390:50–59.
  • Cao Z, Xu J, Li H, et al. Dechlorination and defluorination capability of sulfidized nanoscale zerovalent iron with suppressed water reactivity. Chem Eng J. 2020;400:125900.
  • Deng J, Dong H, Li L, et al. Ca(OH)2 coated nanoscale zero-valent iron as a persulfate activator for the degradation of sulfamethazine in aqueous solution. Sep Purif Technol. 2019;227:115731.
  • Daneshkhah M, Hossaini H, Malakootian M. Removal of metoprolol from water by sepiolite-supported nanoscale zero-valent iron. J Environ Chem Eng. 2017;5:3490–3499.
  • Zhang Y, Zhao L, Yang Y, et al. Degradation of norfloxacin in an aqueous solution by the nanoscale zero-valent iron-activated persulfate process. J Nanomater. 2020;2020:1–12.
  • Conde-Cid M, Paíga P, Moreira MM, et al. Sulfadiazine removal using green zero-valent iron nanoparticles: A low-cost and eco-friendly alternative technology for water remediation. Environ Res. 2021;198:110451.
  • Fang Z, Chen J, Qiu X, et al. Effective removal of antibiotic metronidazole from water by nanoscale zero-valent iron particles. Desalination. 2011;268:60–67.
  • Linting H, Kun C, Huaping D, et al. Enhanced effect of pyrite on the removal of metronidazole by zero valent iron. J Colloid Interface Sci. 2021;600:775–783.
  • Tran ML, Deng S, Fu C, et al. Efficient removal of antibiotic oxytetracycline from water using optimized montmorillonite-supported zero-valent iron nanocomposites. Environ Sci Poll Res. 2020;27:30853–30867.
  • Guler UA. Removal of tetracycline from aqueous solutions using nanoscale zero valent iron and functional pumice modified nanoscale zero valent iron. J Environ Eng Landsc Manag. 2016;25:223–233.
  • Shao Y, Zhao P, Yue Q, et al. Preparation of wheat straw-supported nanoscale zero-valent iron and its removal performance on ciprofloxacin. Ecotoxicol Environ Saf. 2018;158:100–107.
  • Gao Y, Zhang J, Zhou J, et al. Persulfate activation by nano zero-valent iron for the degradation of metoprolol in water: influencing factors, degradation pathways and toxicity. RSC Adv. 2020;10:20991–20999.
  • Lin C, Chen Y. Feasibility of using nanoscale zero-valent iron and persulfate to degrade sulfamethazine in aqueous solutions. Sep Purif Technol. 2017;194:388–395.
  • Weng X, Cai W, Lin S, et al. Applied clay science degradation mechanism of amoxicillin using clay supported nanoscale zero-valent iron. Appl Clay Sci. 2017;147:137–142.
  • Dong H, Ning Q, Li L, et al. A comparative study on the activation of persulfate by bare and surface- stabilized nanoscale zero-valent iron for the removal of sulfamethazine. Sep Purif Technol. 2020;230:115869.
  • Kobayashi M, Kurosu S, Yamaguchi R, et al. Removal of antibiotic sulfamethoxazole by zero-valent iron under oxic and anoxic conditions: removal mechanisms in acidic, neutral and alkaline solutions. J Environ Manage. 2017;200:88–96.
  • Zhang W, Gao H, He J, et al. Removal of norfloxacin using coupled synthesized nanoscale zero-valent iron (nZVI) with H2O2 system: optimization of operating conditions and degradation pathway. Sep Purif Technol. 2016;172:158–167.
  • Gao Y, Gao N, Wang W, et al. Ultrasound-assisted heterogeneous activation of persulfate by nano zero-valent iron (nZVI) for the propranolol degradation in water. Ultrason Sonochem [Internet]. 2018;49:33–40. doi:10.1016/j.ultsonch.2018.07.001.
  • Kassaee MZ, Motamedi E, Mikhak A, et al. Nitrate removal from water using iron nanoparticles produced by arc discharge vs. reduction. Chem Eng J. 2011;166:490–495.
  • Vilardi G, De Caprariis B, Stoller M, et al. Intensified water denitrification by means of a spinning disk reactor and stirred tank in series: kinetic modelling and computational fluid dynamics. J Water Process Eng. 2020;34:101147.
  • Peng L, Liu Y, Gao S, et al. Evaluation on the nanoscale zero valent iron based microbial denitrification for nitrate removal from groundwater. Sci Rep. 2015;5:12331.
  • Ma F, Zhao B, Diao J, et al. Mechanism of phosphate removal from aqueous solutions by biochar supported nanoscale zero- valent iron. RSC Adv. 2020;10:39217–39225.
  • Chen D, Gao B, Wang H, et al. Effective removal of high concentration of phosphate by starch-stabilized nanoscale zerovalent iron (SNZVI). J Taiwan Inst Chem Eng. 2016;61:181–187.
  • Wen Z, Zhang Y, Dai C. Removal of phosphate from aqueous solution using nanoscale zerovalent iron (nZVI). Colloids Surf A Physicochem Eng Asp. 2014;457:433–440.
  • Wu D, Shen Y, Ding A, et al. Phosphate removal from aqueous solutions by nanoscale zero-valent iron. Environ Technol. 2013;34:2663–2669.
  • Almeelbi T, Bezbaruah A. Aqueous phosphate removal using nanoscale zero-valent iron. J Nanopart Res. 2012;14:900.
  • Singh AK, Singh KP. Optimization of phosphate removal from aqueous solution using activated carbon supported zero – valent iron nanoparticles: application of RSM approach. Appl Water Sci. 2018;8:226.
  • Eljamal O, Khalil AME, Sugihara Y, et al. Phosphorus removal from aqueous solution by nanoscale zero valent iron in the presence of copper chloride. Chem Eng J [Internet]. 2016. doi:10.1016/j.cej.2016.02.052.
  • Shubair T, Eljamal O, Khalil AME, et al. Multilayer system of nanoscale zero valent iron and Nano-Fe/Cu particles for nitrate removal in porous media. Sep Purif Technol. 2018;193:242–254.
  • Diao ZH, Qian W, Lei ZX, et al. Insights on the nitrate reduction and norfloxacin oxidation over a novel nanoscale zero valent iron particle: reactivity, products, and mechanism. Sci Total Environ. 2019;660:541–549.
  • Khoshro S, Mirbagheri NS, Sabbaghi S. Removal of nitrate from aqueous solution using nano zerovalent iron-reduced graphene oxide composite: optimization of parameters. Water Environ J. 2020;34:608–621.
  • Babaei AA, Azari A, Kalantary RR, et al. Enhanced removal of nitrate from water using nZVI@MWCNTs composite: synthesis, kinetics and mechanism of reduction. Water Sci Technol. 2015;72:1988–1999.
  • Siciliano A. Use of nanoscale zero-valent iron (NZVI) particles for chemical denitrification under different operating conditions. Metals (Basel). 2015;5:1507–1519.
  • Anbia M, Kamel L. Preparation of pyramids structured silicon as a support for nano sized zero valent iron particles for nitrate removal from water. Silicon. 2018;10:1851–1859.
  • Ziajahromi S, Zand AD, Khanizadeh M. Nitrate removal from water using synthesis nanoscale zero-valent iron (NZVI). Intech. 2012;11:105–110.
  • Abdel M, Fageeh O, SA A-t, et al. Removal of nitrate ions from aqueous solution using zero-valent iron nanoparticles supported on high surface area nanographenes. J Mol Liq. 2015;212:708–715.
  • Zhang Q, Liu H, Chen T, et al. The synthesis of NZVI and Its application to the removal of phosphate from aqueous solutions. Water Air Soil Pollut. 2017;228:321.
  • Nagoya S, Nakamichi S, Kawase Y. Mechanisms of phosphate removal from aqueous solution by zero-valent iron: A novel kinetic model for electrostatic adsorption, surface complexation and precipitation of phosphate under oxic conditions. Sep Purif Technol. 2019;218:120–129.
  • Zhang Y, Douglas GB, Pu L, et al. Zero-valent iron-facilitated reduction of nitrate: chemical kinetics and reaction pathways. Sci Total Environ. 2017;598:1140–1150.
  • Sparis D, Mystrioti C, Xenidis A, et al. Desalination and water treatment reduction of nitrate by copper-coated ZVI nanoparticles. Desalination Water Treat. 2013;51:2926–2933.
  • Jiang Z, Lv L, Zhang W, et al. Nitrate reduction using nanosized zero-valent iron supported by polystyrene resins: role of surface functional groups. Water . 2011;45:2191–2198.
  • Suzuki T, Moribe M, Oyama Y, et al. Mechanism of nitrate reduction by zero-valent iron: equilibrium and kinetics studies. Chem Eng J. 2012;183:271–277.
  • Kodikara J, Gunawardana B, Jayaweera M, et al. Nitrate removal in potable groundwater by nano zerovalent iron under oxic conditions. Water Pract Technol. 2020;15:1126–1143.
  • Liu HB, Chen TH, Chang DY, et al. Nitrate reduction over nanoscale zero-valent iron prepared by hydrogen reduction of goethite. Mater Chem Phys. 2012;133:205–211.
  • Khalil AME, Eljamal O, Saha BB, et al. Performance of nanoscale zero-valent iron in nitrate reduction from water using a laboratory-scale continuous-flow system. Chemosphere. 2018;197:502–512.
  • Zhang Y, Li Y, Li J, et al. Enhanced removal of nitrate by a novel composite: nanoscale zero valent iron supported on pillared clay. Chem Eng J. 2011;171:526–531.
  • Bhattacharjee S, Darwish N, Shanableh A. Phosphate removal using nanoscale zerovalent iron: impact of chitosan and humic acid. Biochem Pharmacol. 2020;8:104131.
  • Lin D, Hu L, Lo IMC, et al. Size distribution and phosphate removal capacity of nano zero-valent iron (nZVI): influence of pH and ionic strength. Water (Basel). 2020;12:2939.
  • Gebre SH. Synthesis and potential applications of trimetallic nanostructures. New J. 2022;46:5438–5459.

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