Synthesis, Characterization and Properties Investigation of [4–(Dimethylsilyl)butyl]alkylferrocene Grafted HTPB as Novel Ferrocene Based Burning Rate Accelerator Catalysts for Composite Gas Generators

References

• Fink, B.; Lefumeux, A.; Perotto, C. Solid Pyrotechnic Compositions. GB Patent 2,285,256, July 6, 1995.
   Google Scholar
• Casiday, R.; Frey, R. Gas Laws Save Lives: The Chemistry Behind Airbags; Department of Chemistry, Washington University: St. Louis, USA, 2000.
   Google Scholar
• Yang, J. C.; Grosshandler, W. L.; Conference on Fire Research and Engineering. Building and Fire Research Laboratory, Maryland, USA, September 10-15,1995.
   Google Scholar
• (a); Teimuri-Mofrad, R.; Safa, D.; Rahimpour, K. Synthesis, Characterization and Electrochemical Properties of Novel Trinuclear Ferrocenyl Based Organosilane Compounds. J. Organomet. Chem 2014, 758, 36–44. (b) Teimuri-Mofrad, R.; Rahimpour, K.; Ghadari, R.; Synthesis, characterization, and electronic properties of novel Fc-DCM conjugated system; experimental and computational studies. J. Organomet. Chem. 2016, 811, 14-19. DOI: 10.1016/j.jorganchem.2016.03.007. DOI: 10.1016/j.jorganchem.2014.02.001;.
   Web of Science ®Google Scholar
• (a); D. Safa, K.; Abbasi, H.; Teimuri-Mofrad, R. Synthesis of Novel Ferrocenyl Silyl Ethers via Dehydrocoupling Reactions under Karstedt Catalyst. J. Organomet. Chem 2013, 740, 56–60. (b) D. Safa, K.; Abbasi, H.; Teimuri-Mofrad, R.; Charandabi, F.A.; [Tris(alkoxydimethylsilyl)methyl]alkylferrocenes as New Ferrocenyl Multifunctional Silyl Ethers. Aust. J. Chem. 2014, 67(5),784-789. DOI: 10.1071/CH13632. DOI: 10.1016/j.jorganchem.2013.04.027.
   Web of Science ®Google Scholar
• Kalenda, P.; Jarušek, J. Accelerating Effects of Ferrocene in Polymerization Reactions. Chem. Papers. 1991, 45(2), 119–132. DOI: 451a119.
   Google Scholar
• Ornelas, C.;. Application of Ferrocene and Its Derivatives in Cancer Research. New. J. Chem. 2011, 35(10), 1973–1985. DOI: 10.1039/C1NJ20172G.
   Web of Science ®Google Scholar
• Kazemizadeh, A. R.; Shajari, N.; Shapouri, R.; Adibpour, N.; Teimuri-Mofrad, R. Synthesis and Anti-Brucella Activity of Some New 1, 3, 4-Oxadiazole Derivatives Containing a Ferrocene Unit. J. Iran. Chem. Soc. 2016, 13(7), 1349–1355. DOI: 10.1007/s13738-016-0849-3.
   Web of Science ®Google Scholar
• Lanez, T.; Henni, M. Antioxidant Activity and Superoxide Anion Radical Interaction with 2-(Ferrocenylmethylamino) Benzonitrile and 3-(Ferrocenylmethylamino) Benzonitrile. J. Iran. Chem. Soc. 2016, 13(9), 1741–1748. DOI: 10.1007/s13738-016-0891-1.
   Web of Science ®Google Scholar
• (a); Wang, W. Y.; Wang, L.; Ma, N. N.; Zhu, C. L.; Qiu, Y. Q. Ferrocene/Fullerene Hybrids Showing Large Second-Order Nonlinear Optical Activities: Impact of the Cage Unit Size. Dalton. Trans. 2015, 44(21), 10078–10088. (b) Wu, K. L.; Zheng, J.; Ran, C. L.; Xu, Y.; Tang. M.S.; Synthesis, crystal structures, and electrochemical studies of ferrocenyl heterocyclic carbonylhydrazone receptors. J. Iran. Chem. Soc. 2013, 10(4),709-715. DOI: 10.1007/s13738-012-0204-2; (c) Constantinescu, C.; Matei, A.; Ion, V.; Mitu, B.; Ionita, I.; Dinescu, M.; Luculescu, C. R.; Vasiliu, C.; Emandi, A.; Ferrocene carboxaldehyde thin films grown by matrix-assisted pulsed laser evaporation for non linear optical applications. Appl. Surf. Sci. 2014, 302, 83-86. DOI: 10.1016/j.apsusc.2013.11.147. DOI: 10.1039/C5DT01134E;.
   Web of Science ®Google Scholar
• (a); Teimuri-Mofrad, R.; Rahimpour, K.; Ghadari, R. Design, Synthesis and Characterization of Ferrocene Based V-Shaped Chromophores with Modified Nonlinear Effect. J. Organomet. Chem 2017, 846, 397–406. (b) Teimuri-Mofrad, R.; Rahimpour, K.; Ghadari, R.; Ahmadi-Kandjani, S.; Ferrocene based nonlinear optical chromophores: synthesis, characterization and study of optical properties. J Mol Liq. 2017, 244, 322-329. DOI: 10.1016/j.molliq.2017.09.002. DOI: 10.1016/j.jorganchem.2017.07.023.
   Web of Science ®Google Scholar
• (a); Teimuri-Mofrad, R.; Rahimpour, K.; Vaez, A. R. Isophorone‐Based Organometallic Chromophores: Synthesis, Characterization and Investigation of Electro‐Optical Properties. Appl. Organomet. Chem. 2018, 32(2), e4031. (b) Teimuri-Mofrad, R.; Rahimpour, K.; Poursadegh, A.; Investigation of 5, 6-dimethoxy-1-indanone derivatives in optical applications: Synthesis, characterization and study of linear and nonlinear optical properties. Mater. Chem. Phys. 2017, 200, 384-394. DOI: 10.1016/j.matchemphys.2017.08.012. DOI: 10.1002/aoc.4031.
   Web of Science ®Google Scholar
• Hod, I.; Bury, W.; Gardner, D. M.; Deria, P.; Roznyatovskiy, V.; Wasielewski, M. R.; Farha, O. K.; Hupp, J. T. Bias-Switchable Permselectivity and Redox Catalytic Activity of a Ferrocene-Functionalized, Thin-Film Metal–Organic Framework Compound. J. Phys. Chem. Lett. 2015, 6(4), 586–591. DOI: 10.1021/acs.jpclett.5b00019.
   Web of Science ®Google Scholar
• Putzien, S.; Nuyken, O.; Kühn, F. E. Functionalized Polysilalkylene Siloxanes (Polycarbosiloxanes) by hydrosilylation—Catalysis and Synthesis. Prog. Polym. Sci. 2010, 35(6), 687–713. DOI: 10.1016/j.progpolymsci.2010.01.007.
   Web of Science ®Google Scholar
• Xiang, J.; Burges, R.; Häupler, B.; Wild, A.; Schubert, U. S.; Ho, C. L.; Wong, W. Y. Synthesis, Characterization and Charge–Discharge Studies of Ferrocene-Containing Poly (Fluorenylethynylene) Derivatives as Organic Cathode Materials. Polymer. 2015, 68, 328–334. DOI: 10.1016/j.polymer.2015.01.054.
   Web of Science ®Google Scholar
• Şenel, M.; Çevik, E.; Abasıyanık, M. F. Amperometric Hydrogen Peroxide Biosensor Based on Covalent Immobilization of Horseradish Peroxidase on Ferrocene Containing Polymeric Mediator. Sens. Actuators B Chem. 2010, 145(1), 444–450. DOI: 10.1016/j.snb.2009.12.055.
   Web of Science ®Google Scholar
• Fu, X. L.; Fan, X. Z.; Ju, X. H.; Qi, X. F.; Li, J. Z.; Yu, H. J. Molecular Dynamic Simulations on the Interaction between an HTPE Polymer and Energetic Plasticizers in a Solid Propellant. RSC Adv. 2015, 5(65), 52844–52851. DOI: 10.1039/C5RA05312A.
   Web of Science ®Google Scholar
• Cho, B. S.; Noh, S. T. Thermal Properties of Polyurethane Binder with 2‐(Ferrocenylpropyl) Dimethylsilane‐Grafted Hydroxyl‐Terminated Polybutadiene. J. Appl. Polym. Sci. 2011, 121(6), 3560–3568. DOI: 10.1002/app.34151.
   Web of Science ®Google Scholar
• Kishore, K.; Gayathri, V. Fundamentals of Solid- Propellant Combustion. Eds. Kuo, K. K., Summerfield, M. American Institute of Aeronautics and Astronautics: New York, 1984, Vol. 90; pp 53.
   Google Scholar
• Menke, K.; Gerber, P.; Geißler, E.; Bunte, G.; Kentgens, H.; Schöffl, R. Ammonium Nitrate: A Promising Rocket Propellant Oxidizer. Prop. Exp. Pyrotech. 1999, 24(3), 126–133. DOI: 10.1016/S0304-3894(99)00039-4.
   Google Scholar
• Gore, G. M.; Tipare, K. R.; Bhatewara, R. G.; Prasad, U. S.; Gupta, M.; Mane, S. K. Evaluation of Ferrocene Derivatives as Burn Rate Modifiers in AP/HTPB-based Composite Propellants. Dsj. 1999, 49(2), 151–158. DOI: 10.14429/dsj.49.3800.
   Google Scholar
• Doriath, G.;. Energetic Insensitive Propellants for Solid and Ducted Rockets. J. Propuls. Power. 1995, 11(4), 870–882. DOI: 10.2514/3.23912.
   Web of Science ®Google Scholar
• Abdin, Z. U.; Yu, H.; Wang, L.; Saleem, M.; Khalid, H.; Abbasi, N. M.; Akram, M. Synthesis, Anti‐Migration and Burning Rate Catalytic Mechanism of Ferrocene‐Based Compounds. Appl. Organomet. Chem. 2014, 28(8), 567–575. DOI: 10.1002/aoc.3166.
   Web of Science ®Google Scholar
• Saravanakumar, D.; Sengottuvelan, N.; Narayanan, V.; Kandaswamy, M.; Varghese, T. L. Burning‐Rate Enhancement of a High‐Energy Rocket Composite Solid Propellant Based on Ferrocene‐Grafted Hydroxyl‐Terminated Polybutadiene Binder. J. Appl. Polym. Sci. 2011, 119(5), 2517–2524. DOI: 10.1002/app.32859.
   Web of Science ®Google Scholar
• Teimuri-Mofrad, R.; D. Safa, K.; Abedinpour, S.; Rahimpour, K. Synthesis of 5-(Dimethylsilyl) Pentylalkylferrocene-Grafted HTPB (Alkylfc-HTPB) via Platinum-Catalyzed Hydrosilylation. J. Iran. Chem. Soc. 2017, 14(10), 2177–2185. DOI: 10.1007/s13738-017-1154-5.
   Web of Science ®Google Scholar
• Teimuri-Mofrad, R.; Mirzaei, F.; Abbasi, H.; D. Safa, K. Synthesis of New Binuclear Ferrocenyl Compounds by Hydrosilylation Reactions. C. R. Chim. 2017, 20(2), 197–205. DOI: 10.1016/j.crci.2016.06.011.
   Web of Science ®Google Scholar
• Teimuri-Mofrad, R.; Abbasi, H.; D. Safa, K.; Tahmasebi, B. Synthesis of Novel Bis [(Tris (Dimethylsilyl) Methyl) Alkyl] Ferrocene Derivatives as New Ferrocenyl Multi-Functional Silyl Ether Compounds. Arkivoc. 2016, 4, 371–384. DOI: 10.3998/ark.5550190.p009.596.
   Google Scholar
• Swarts, P. J.; Immelman, M.; Lamprecht, G. J.; Greyling, S. E.; Swarts, J. C. Ferrocene Derivatives as High Burning Rate Catalysts in Composite Propellants. S. Afr. J. Chem. 1997, 50, 208–216.
   Web of Science ®Google Scholar
• Graindorge, H.; Mondet, J. C.; Vincent, C. H.; Process for the Synthesis of Haloalkylferrocenes. US Patent 5550267, Aug 27, 1995.
   Google Scholar