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Original Articles

Properties of Starch Blends with Biodegradable Polymers

, &
Pages 385-409 | Published online: 07 Feb 2007

References

  • Albertsson , A.C. and Karlsson , S. 1994 . Chemistry and Technology of Biodegradable Polymers 48 pp. Glasgow : Blackie . Chapter 2
  • Suvorova , A.I. , Tyukova , I.S. and Trufanova , E.I. 2000 . Biodegradable starch-based polymeric materials . Russ. Chem. Rev. , 69 ( 5 ) : 451 – 459 .
  • Decriaud , A.C. , Maurel , V.B. and Silvestre , F. 1998 . Standard methods for testing the aerobic biodegradation of polymeric materials. Review and perspectives . Adv. Polym. Sci. , 135 : 207 – 226 .
  • Nayak , P. 1999 . Biodegradable polymer: opportunities and challenges . J.M.S.-Rev. Macromol. Phys. , C39 ( 3 ) : 481 – 505 .
  • Roper , H. and Koch , H. 1990 . The role of starch in biodegradable thermoplastic materials . Starch/Staerke , 42 : 123 – 130 .
  • Vonrecum , H.A. , Cleek , R.L. , Eskin , S.G. and Mokos , A.G. 1995 . Degradation of polydispersed poly(l-lactic acid) to modulate lactic-acid release . Biomaterials , 16 ( 6 ) : 441 – 447 .
  • Lefebvre , F. , Daro , A. and David , C. 1995 . Biodegradation of polycaprolactone by microorganisms from all industrial compost of household refuse 2 . J. Macromol. Sci. , A32 : 867 – 873 .
  • Doi , Y. , Kanesawa , Y. , Kunioka , M. and Saito , T. 1990 . Biodegradation of microbial copolymer: poly(3-hydroxybutyrate-co-3-hydroxyvalerate) and poly(3-hydroxybutyrate-co-4-hydroxyvalerate) . Macromolecules , 23 : 26 – 31 .
  • Young , A.H. 1984 . “ Classification of starch ” . In Starch: Chemistry and Technology, , 2nd Ed. Edited by: Whistler , R.L. , Bemiller , J.N. and Paschall , E.F. 289 pp. Orlando : Academic Press .
  • Jane , J. 1995 . Starch properties, modifications, and applications . J. M. S. –Pure Appl. Chem. , A32 ( 4 ) : 751 – 757 .
  • Griffin , G.J.L. 1974 . Biodegradable filler in thermoplastics . Adv. Chem. Ser. , 134 : 159 – 170 . (Fillers Reinf. Plast., Symp. 1973)
  • Griffin , G.J.L. Synthetic Rein-Based Compositions . US Patent 4,125,495 . November 14, 1978 .
  • Otey , F.H. , Westhoff , R.P. and Doane , W.M. 1980 . Starch-based blown films . Ind. Eng. Chem. Prod. Res. Dev. , 19 ( 4 ) : 592 – 595 .
  • Chudnovsky , A. , Shulkin , Y. , Baron , D. and Lin , K.P. 1995 . New method of lifetime prediction for brittle fracture of polyethylene . J. Appl. Polym. Sci. , 56 : 1465 – 1478 .
  • Arvanitoyannis , I. , Biliaderis , C. , Ogawa , H. and Kawasaki , N. 1998 . Biodegradable films made from low density polyethylene (LDPE) and rice starch for food packaging uses; part 1 . Carbohydr. Polym. , 36 ( 2/3 ) : 89 – 104 .
  • Jana , T.T. and Maiti , S.K. 1999 . A biodegradable film. Part 1. Pilot plant investigation for production of the biodegradable film . Angew. Makromol. Chem. , 267 : 16 – 19 .
  • French , D. 1984 . “ The formation of starch granules ” . In Starch: Chemistry and Technology, , 2nd Ed. Edited by: Whistler , R.L. , Bemiller , J.N. and Paschall , E.F. 219 pp Orlando : Academic Press .
  • Roper , H. and Koch , H. 1990 . The role of starch in biodegradable thermoplastic materials . Starch/Staerke , 42 : 123 – 130 .
  • Swanson , C.L. , Shogren , R.L. , Fanta , G.F. and Iman , S.H. 1993 . Starch-plastic materials-preparation, physical properties, and biodegradability (a review of recent USDA research) . J. Environ. Polym. Degrad. , 1 ( 2 ) : 155 – 166 .
  • Lai , L.S. and Kokini , J.L. 1991 . Physicochemical changes and rheological properties of starch during extrusion . Biotechnol. Prog. , 7 : 251 – 266 .
  • Loercks , J. , Pommeranz , W. , Heuer , J. , Klenke , K. and Schmidt , H. Producing Biodegradable Films from Vegetable Raw Materials . PCT Int. Appl. WO 94,04,600 . March 03, 1994 .
  • Schennink , G.G.J. , Feil , H. and Van Leuven , R.A.H. Preparation of Biodegradable Three-Dimensional Thermoplastic Starch Foam Molding for Packing and Filling Materials . PCT WO 98,51,466 . November 19 1998 .
  • Nakamura , A.J. Production of Biodegradable Starch-Based Cushion Molding . Jpn. Kokai Tokyo Koho JP 200,052,437 . February 22, 2000 .
  • Hino , J. , Nakaya , N. and Shimoohzono , T. Starch-Based Biodegradable Powders and their Manufactures . Jpn. Kokai Tokyo Koho JP 200,086,733 . March 28, 2000 .
  • Iwasaki , K. , Hisasue , O. , Nagai , M. , Tokugawa , Y. and Shinomiya , T. Manufacture of Starch-Based Biodegradable Foams . Jpn. Kokai Tokyo Koho JP 200,053,793 . February 22, 2000 .
  • Ogawa , Y. Manufacture Spontaneously Degradable Starch Molding . Jpn. Kokai Tokyo Koho JP 200,202,844 . July 25, 2000 .
  • Kesselring , A. , Kaiser , N. and Koblitz , T. Process for Producing a Shaped Body made of Biodegradable Material . PCT Int. Appl. WO 00,39,213 . July 6, 2000 .
  • Zobel , H.F. 1988 . Molecules to granules: a comprehensive starch review . Starch/Staerke , 40 : 44 – 50 .
  • Zeleznak , K.J. and Hoseney , R.C. 1987 . The glass transition in starch . Cereal Chem. , 64 : 121 – 124 .
  • Doane , W.M. 1992 . USDA research on starch-based biodegradable plastics . Starch/Staerke , 44 : 293 – 295 .
  • Stepto , R.F.T. 2000 . Thermoplastic starch . Macromol. Symp. , 152 : 73 – 82 .
  • Shogren , R.L. , Swanson , C.L. and Thompson , A.R. 1992 . Extrudates of cornstarch with urea and glycol: structure/mechanical property relations . Starch/Staerke , 44 : 335 – 338 .
  • Yu , L. , Christov , V. , Gray , G. , Dutt , U. , Harvey , T. , Halley , P. , Coombs , S. , Jayasekara , R. and Lonergan , G. 1999 . Effect of additives on gelatiniztion, rheological properties, and biodegradability of thermoplastic starch . Macromol. Symp. , 144 : 371 – 374 .
  • Gattin , R. , Copinet , A. , Bertrand , C. and Coutuier , Y. 2001 . Comparative biodegradation study of starch- and polylactic acid-based materials . J. Polym. Environ. , 1 : 11 – 17 .
  • Van Soest , J.J.G. , Benes , K. , de Wit , D. and Vliegenthart , J.F.G. 1996 . The influence of starch molecular mass on the properties of extruded thermoplastic starch . Polymer , 37 : 3543 – 3552 .
  • Van Soest , J.J.G. , Benes , K. and de Wit , D. 1995 . The influence of acid-hydrolysis of potato starch on the stress-strain properties of thermoplastic starch . Starch/Starke , 47 : 429 – 434 .
  • Kirby , A.R. , Clark , S.A. , Parker , R. and Smith , A.C. 1991 . The deformation and failure behavior of water starch plasticized with glucose and water . J. Mater. Sci. , 26 : 1351 – 1356 .
  • Kirby , A.R. , Clark , S.A. , Parker , R. and Smith , A.C. 1993 . The deformation and failure behavior of wheat starch plasticized with water . J. Mater. Sci. , 28 : 5937 – 5942 .
  • Loudin , D. , Bizot , H. and Colonna , P. 1997 . “Antiplasticization” in starch–glycerol films? . J. Appl. Polym. Sci. , 63 : 1047 – 1052 .
  • Liu , Z.Q. , Yi , X.S. and Feng , Y. 2001 . Effects of glycerin and glycerol monostearate on performance of thermoplastic starch . J. Mater. Sci. , 36 : 1809 – 1815 .
  • Forssell , P. , Mikkila , J. and Suortti , T. 1996 . Plasticization of barley starch with glycol and water . J. M. S.—Pure Appl. Chem. , A33 ( 5 ) : 703 – 715 .
  • Van Soest , J.J.G. , Wit , D.D. and Vliegenthart , J.F.G. 1996 . Mechanical properties of thermoplastic waxy maize starch . J. Appl. Polym. Sci. , 61 : 1927 – 1937 .
  • Van Soest , J.J.G. , Benes , K. , de Wit , D. and Vliegenthart , J.F.G. 1996 . Changes in the mechanical properties of thermoplastic potato starch in relation with changes in B-type crystallinity . Carbohydr. Polym. , 29 : 225 – 232 .
  • Van Soest , J.J.G. and Essers , P. 1997 . Influence of amylose–amylopectin ratio on properties of extruded starch plastic sheets . J. Macromol. Sci.—Pure Appl. Chem. , A34 : 1665 – 1689 .
  • Van Soest , J.J.G. and Borger , D.E. 1997 . Structure and properties of compression-molded thermoplastic starch materials from normal and high-amylose maize starches . J. Appl. Polym. Sci. , 64 : 631 – 644 .
  • Chinnaswamy , R. and Hanna , M.A. 1990 . Macromolecular and functional properties of native and extrusion-cooked corn starch . Cereal Chem. , 67 : 491 – 498 .
  • Park , H.M. , Li , X.C. , Jin , C.Z. , Park , C.Y. , Cho , W.J. and Ha , C.S. 2002 . Preparation and properties of biodegradable thermoplastic starch/clay hybrids . Macroml. Mater. Eng. , 287 : 553 – 558 .
  • Chiellini , E. , Corti , A. , D'Antone , S. and Solaro , R. 1999 . Biodegradation of PVA-based formulations . Macromol. Symp. , 144 : 127 – 139 .
  • Mao , L.J. , Imam , S. , Gordon , S. , Cinelli , P. and Chiellini , E. 2000 . Extruded cornstarch-glycerol-polyvinyl alcohol blends: mechanical properties, morphology, and biodegradability . J. Polym. Environ. , 4 : 205 – 211 .
  • Chen , L. , Imam , S.H. , Gordon , S.H. and Greene , R.V. 1997 . Starch-polyvinyl alcohol crosslinked film-performance and biodegradation . J. Environ. Polym. Degrad. , 5 ( 2 ) : 111 – 117 .
  • Lenk , R.S. and Merrall , R.E. 1981 . Starch/poly(vinyl alcohol) heatsealable film: 2 . Polymer , 22 : 1279 – 1282 .
  • Hiroshi , Y. Polyvinyl Alcohol-Starch Film and Use Thereof . JP 2,252,744 . October 11, 1990 .
  • Hiroshi , Y. Agricultural Mulching Film . JP 3,262,421 . November 22, 1991 .
  • Shogren , R.L. , Lawton , T.W. , Tiefenbacher , K.F. and Chen , L. 1998 . Starch-poly(vinylalcol) foamed articles prepared by a baking process . J. Appl. Polym. Sci. , 68 : 2129 – 2140 .
  • Roesser , D.S. , Nevling , J. , Rawlins , D.C. and Billmer , R.L. Biodegradable Expanded Starch Products, Their Production and Their Use . European Patent Appl. EP 965,609 . December 22, 1999 .
  • Saito , H. and Murasaka , K. Starch-Containing Swellable Foams Having Biodegradable Property . Jpn Kokai Tokyo Koho JP 2000,109,592 . Apri 18, 2000 .
  • Alfani , R. , Iannace , S. and Nicolais , L. 1998 . Synthesis and characterization of starch-based polyurethane foam . J. Appl. Polym. Sci. , 68 : 739 – 745 .
  • Chen , L. , Iman , S.H. , Stein , T.M. , Gordon , S.H. , Hou , C.T. and Greene , R.V. 1996 . Starch-polyvinyl alcohol cast film-performance and biodegradation . Polym. Prepr. , 37 : 461 – 462 .
  • Lawton , J.W. and Fanta , G.F. 1994 . Glycerol-plasticized films prepared from starch-poly (vinyl alcohol) mixtures: effect of poly(ethylene-co-acrylic acid) . Carbohydr. Polym. , 23 ( 4 ) : 275 – 280 .
  • Liu , Z.Q. , Feng , Y. and Yi , X.S. 1999 . Thermoplastic starch/PVAl compounds: preparation, processing, and properties . J. Appl. Polym. Sci. , 74 : 2667 – 2673 .
  • Myllymaki , O. , Myllarinen , P. , Forssell , P. , Suortti , T. , Lahteenkorva , K. , Ahvenainen , R. and Poutanen , K. 1998 . Mechanical and permeability properties of biodegradable extruded starch/polycaprolacton films . Packag. Technol. Sci. , 11 ( 6 ) : 265 – 274 .
  • Kweon , D.K. and Lim , S.T. 2001 . Substitution of corn starch with polycaprolactone via chlorination and water resistance of the substituted starch . J. Appl. Polym. Sci. , 81 : 2197 – 2202 .
  • Shin , C.H. , Kim , Y.I. , Kim , B.S. and Shin , B.Y. 2000 . Mechanical properties and biodegradability of PCL/TPS blend . Polymer (Korea) , 24 ( 1 ) : 48 – 57 .
  • Chechian , K. 1998 . Processing-induced effects on rheological behavior of biodegradable starch/polycaprolactone blends . Annu. Tech. Conf.-Soc. Plast. Eng. , 3 : 3557 – 3561 .
  • Paranamuda , H. , Tokiwa , Y. and Tanaka , H. 1996 . Physical properties and biodegradability of blends containing poly (ε-caprolactone) and tropical starch . J. Environ. Polym. Degrad. , 4 ( 1 ) : 1 – 7 .
  • Wang , L. , Shogren , R.L. and Carrier , C. 2000 . Preparation and thermoplastic starch-polyester laminate sheets by coextrusion . Polym. Eng. Sci. , 40 ( 2 ) : 499 – 506 .
  • Oduasnya , O.S. , Ishiaku , U.S. and Azsmi , B.M.N. 2000 . On mechanical properties of sago starch/poly (ε-caprolactone) composites . Polym. Eng. Sci. , 40 ( 6 ) : 1298 – 1305 .
  • Bastioli , C. 1998 . Properties and applications of Mater-Bi starch-based materials . Polym. Degrad. Stab. , 59 ( 1–3 ) : 263 – 272 .
  • Bastioli , C. , Bellotti , V. , Del , G.L. and Gilli , G. 1993 . Mater-Bi: properties and biodegradability . J. Environ. Polym. Degrad. , 1 ( 3 ) : 181 – 191 .
  • Bastioli , C. , Bellotti , V. , Del , T.G. and Lombi , R. Biodegradable Polymeric Compositions Based on Starch and Thermoplastic Polymers . PCT Int. Appl. WO 2,147,82 . March 09, 1992 .
  • Bastioli , C. , Bellotti , V. and Montino , A. Biodegradable polymeric compositions Based on Starch and Thermoplastic Polymers . PCT Int. Appl. WO 92,196,80 . November 11, 1992 .
  • 1997 . “ Product Information ” . Warrington : Solvay Interox Ltd. .
  • Goldberg , D. 1995 . A review of the biodegradability and utility of poly(caprolactone) . J. Environ. Polym. Degrad. , 3 : 61 – 67 .
  • Amass , W. , Amass , A. and Tighe , B. 1998 . A review of biodegradable polymers: uses, current development in the synthesis and characterization of biodegradable polyesters, blends of biodegradable polymers and recent advances in biodegradation studies . Polym. I. , 47 : 89 – 144 .
  • Bastioli , C. , Cerutti , A. , Guanella , I. , Romano , G.C. and Tosin , M. 1995 . Physical state and biodegradation behavior of starch-polycaprolactone systems . J. Environ. Polym. Degrad. , 3 ( 2 ) : 81 – 95 .
  • Narayan , R. and Krishnan , M. 1995 . Biodegradable composites and blends of starch with poly(ε-caprolactone) ACS polym . Mater. Sci. Eng. , 72 : 186 – 187 .
  • Kim , C.H. , Cho , K.Y. and Park , J.K. 2001 . Reactive blends of gelatinized starch and polycaprolactone-g-glycidyl methacrylate . J. Appl. Polym. Sci. , 81 : 1507 – 1516 .
  • Avella , M. , Errico , M.E. , Laurienzo , P. , Martudcelli , E. , Raimo , M. and Rimedio , R. 2000 . Preparation and characterization of compatibilized polycaprolactone/starch composites . Polymer , 41 : 3875 – 3881 .
  • Kim , C.H. , Choi , E.J. and Park , J.K. 2000 . Effect of PEG molecular weight on the tensile toughness of starch/PCL/PEG blends . J. Appl. Polym. Sci. , 77 : 2049 – 2056 .
  • Choi , E.J. , Kim , C.H. and Park , J.K. 1999 . Structure-property relationship in PCL/starch blend compatibilized with starch-g-PCL copolymer . J. Poly. Sci.: Part B: Polym. Physics , 37 : 2430 – 2438 .
  • Kim , C.H. , Cho , K.Y. and Park , J.K. 2001 . Effect of poly(acrylic acid)-g-PCL microstructure on the mechanical properties of starch/PCL blend compatibilized with poly(acrylic acid)-g-PCL . Polym. Eng. Sci. , 41 : 542 – 553 .
  • Koenig , M.F. and Huang , S.T. 1995 . Biodegradable blends and composites of polycaprolactone and starch derivatives . Polymer , 36 : 1877 – 1882 .
  • Vikman , M. , Hulleman , S.H.D. , Van Der Zee , M. , Myllarinen , P. and Feil , H. 1999 . Morphology and enzymatic degradation of thermoplastic starch-PCL blends . J. Appl. Polym. Sci. , 74 : 2594 – 2604 .
  • Averous , L. , Moro , L. , Dole , P. and Fringant , C. 2000 . Properties of thermoplastic blends: starch-polycaprolactone . Polymer , 41 : 4157 – 4167 .
  • Matzinos , P. , Tserki , V. , Kontoyiannis , A. and Panayiotou , C. 2002 . Processing and characterization of starch/polycaprolactone products . Polym. Degrad. And Stab. , 77 : 17 – 24 .
  • Reeve , M.S. , McCarthy , S.P. , Downey , M.J. and Gross , R.A. 1994 . Polylactide stereochemistry: effect on enzymic degradability . Macromolecules , 27 : 825 – 831 .
  • Reed , A.M. and Gilding , D.K. 1981 . Biodegradable polymers for use in surgery-poly (glycolic acid)/poly(lactic acid) homo and copolymers: 2 . In vitro degradation. Polymer , 22 : 494 – 498 .
  • Fang , Q. and Hanna , M.A. 2000 . Functional properties of polylactic acid starch-based loose-fill packaging foams . Cereal Chem. , 77 ( 6 ) : 779 – 783 .
  • Jacobsen , S. and Fritz , H.G. 1996 . Filling of poly(lactic acid) with native starch . Polym. Eng. Sci. , 36 : 2799 – 2804 .
  • Park , J.W. , Lee , D.J. , Yoo , E.S. , Im , S.S. , Kim , S.H. and Kim , Y.H. 1999 . Biodegradable polymer blends of poly(lactic acid) and starch . Korea Polym. J. , 7 ( 2 ) : 93 – 101 .
  • Kim , S.H. , Chin , I.J. , Yoon , J.S. , Kim , S.H. and Huang , J.S. 1998 . Mechanical properties of biodegradable blends of poly(l-lactic acid) with starch . Korea Polym. J. , 6 : 422 – 427 .
  • Martin , O. and Averous , L. 2001 . Poly(lactic acid): plasticization and properties of biodegradable multiphase systems . Polymer , 42 : 6209 – 6219 .
  • Ke , T.Y. and Sun , X.Z. 2000 . Physical properties of poly(lactic acid) and starch composites with various blending ratios . Cereal Chem. , 77 : 232 – 236 .
  • Park , J.W. and Im , S.S. 2000 . Biodegradable polymer blends of poly(l-lactic acid) and gelatinized starch . Polym. Eng. Sci. , 40 : 2539 – 2550 .
  • Wang , H. , Sun , X.Z. and Seib , P. 2002 . Mechanical properties of poly(lactic acid) and wheat starch blends with methylenediphenyl diisocyanate . J. Appl. Polym. Sci. , 84 : 1257 – 1262 .
  • Imam , S.H. , Gordon , S.H. , Shogren , R.L. , Tosteson , T.R. , Govind , N.S. and Greene , R.V. 1999 . Degradation of starch-poly(β-hydroxybutyrate-co-β-hydroxyvalerate) bioplastic in tropical coastal waters . App. Environ. Microbil. , 65 ( 2 ) : 431 – 437 .
  • Imam , S.H. , Chen , L. , Gordon , S.H. , Shogren , R.L. , Weisleader , D. and Greene , R.V. 1998 . Biodegradation of injection molded starch-poly(3- hydroxybutyrate-co-3-hydroxyvalerate) blends in natural compost environment . J. Environ. Polym. Degrad. , 6 ( 2 ) : 91 – 98 .
  • Ramsay , B.A. , Langlada , V. , Carrean , P.J. and Ramsay , J.A. 1993 . Biodegradability and mechanical properties of poly(β-hydroxybutyrate-co-β-hydroxyvalerate)-starch blends . Appl. Environ. Microbiol. , 59 : 1242 – 1246 .
  • Gordon , S.H. , Imam , S.H. , Shorgen , R.L. , Govind , N.S. and Greene , R.V. 2000 . A semiempirical model for predicting biodegradation profiles of individual polymers in starch-poly(β-hydroxybutyrate-co-β-hydroxyvalerate) bioplastic . J. Appl. Polym. Sci. , 76 : 1767 – 1776 .
  • Seves , A. , Beltrame , P.L. , Selli , E. and Bergamasco , L. 1998 . Morphology and thermal behavior of poly(3-hydroxybutyrate-co-3-hydroxyvalerate)/starch valerate blends . Angew. Makromol. Chem. , 260 : 65 – 70 .
  • Ceccorulli , G. , Pizzoli , M. and Scandola , M. 1993 . Effect of a low molecular weight plasticizer on the thermal and viscoelastic properties of miscible blends of bacterial poly(3-hydroxybutyrate) with cellulose acetate butyrate . Macromolecules , 26 : 6722 – 6756 .
  • Avella , M. and Errico , M.E. 2000 . Preparation of PHBV/starch blends by reactive blending and their characterization . J. Appl. Polym. Sci. , 77 : 232 – 236 .
  • Lotti , N. and Scandola , M. 1992 . Miscibility of bacterial poly(3-hydroxybutyrate-co-3-hydroxyvalerate) with ester substituted celluloses . Polym. Bull. , 29 : 407 – 413 .
  • Scandola , M. , Ceccorulli , G. and Pizzoli , M. 1992 . Miscibility of bacterial poly(3-hydroxybutyrate) with cellulose ester . Macromolecules , 25 : 6441 – 6446 .
  • Kotnis , M.A. , O'Brien , G.S. and Willett , J.L. 1995 . Processing and mechanical properties of biodegradation poly(hydroxybutyrate-co-valerate)-starch compositions . J. Environ. Polym. Degrad. , 3 ( 2 ) : 97 – 105 .
  • Shogren , R.L. 1995 . Poly (ethylene-oxide)-coated granular starch-poly(hydroxybutyrate-co-hydroxyvalerate) composite materials . J. Environ. Polym. Degrad. , 3 ( 2 ) : 75 – 80 .
  • Imam , S.H. , Gordon , S.H. , Shogren , R.L. and Greene , R.V. 1995 . Biodegradation of starch-poly(β-hydroxybutyrate-co-β-hydroxyvalerate) composites in municipal activated sludge . J. Environ. Polym. Degrad. , 3 : 205 – 213 .
  • Willett , J.L. , Kotnis , M.A. , O'Brien , G.S. , Fanta , G.F. and Gordon , S.H. 1998 . Properties of starch-graft-poly(glycidylmethacrylate)-PHBV composites . J. Appl. Polym. Sci. , 70 : 1121 – 1127 .
  • Ha , C.S. and Cho , W.J. 2002 . Miscibility, properties, and biodegradability of microbial polyester containing blends . Prog. Polym. Sci. , 27 : 759 – 809 .
  • Kim , M.N. , Lee , A.R. , Yoon , J.S. and Chin , I.J. 2000 . Biodegradation of poly(3-hydrobutyrate), sky-green and mater-bi by fungi isolated from soils . Eur. Polym. J. , 36 : 1677 – 1685 .
  • Park , H.M. , Lee , S.R. , Chowdhury , S.R. , Kong , T.K. , Kim , H.K. , Park , S.H. and Ha , C.S. 2002 . Tensile properties, morphology, and biodegradability of blends of starch with various thermoplastics . J. Appl. Polym. Sci. , 86 : 2907 – 2915 .
  • Averous , L. and Fringant , C. 2001 . Association between plasticized starch and polyesters: processing and performance of injected biodegradable systems . Polym. Eng. Sci. , 41 : 727 – 734 .
  • Shioozono , T. and Hino , J. Biodegradable Composition . Jpn. JP 9,137,069 . May 27, 1997 . and Biodegradable Pot for Raising Seedling. Jpn. JP 9,294,482, November 18, 1997
  • Ratto , J.A. and Stenhouse , P.J. 1995 . Investigation of biodegradable thermoplastic polyester/starch blends . Ann. Tech. Conf.—Soc. Plast. Eng. , 53 ( 2 ) : 1824 – 1828 .
  • Mani , R. and Bhattacharya , M. 2000 . Properties of injection moulded blends of starch and modified biodegradable polyesters . Eur. Polym. J. , 37 : 515 – 526 .
  • Ratto , J.A. , Stenhouse , P.J. , Auerbach , M. , Mitchell , J. and Farrell , R. 1999 . Processing, performance, and biodegradability of a thermoplastic aliphatic polyester/starch system . Polymer , 40 : 6777 – 6788 .

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