106
Views
10
CrossRef citations to date
0
Altmetric
Original Articles

Modeling of the Extraction of Lanthanide Nitrates from Aqueous Solutions Over a Wide Range of Activities by CMPO

, , , , &
Pages 791-811 | Received 06 Jan 2004, Accepted 10 Apr 2004, Published online: 24 Aug 2007

References

  • Horwitz , E. P. , Kalina , D. G. , Kaplan , L. , Mason , G. W. and Diamond , H. 1982 . Selected alkyl(phenyl)‐N,N‐dialkylcarbamoylmethylphosphine oxides as extractants for Am(III) from nitric acid media . Sep. Sci. Technol. , 17 ( 10 ) : 1261 – 1279 .
  • Horwitz , E. P. , Diamond , H. and Kalina , D. G. 1983 . Carbamoylmethylphosphoryl Derivatives as Actinide Extractants in Plutomium Chemistry , ACS Symposium Series (216) Edited by: Carnall , W. T. and Choppin , G. Washington, D.C. : American Chemical Society . Chap 27
  • Horwitz , E. P. and Kalina , D. G. 1984 . The extraction of Am(III) from nitric acid by octyl(phenyl)‐N,N‐diisobutylcarbamoylmethylphosphine oxide – tri‐n‐butyl phosphate mixtures . Solvent Extr. Ion Exch. , 2 ( 2 ) : 179 – 200 . [CSA]
  • Horwitz , E. P. , Kalina , D. G. , Diamond , H. and Vandegrift , G. F. 1985 . The TRUEX process—a process for the extraction of the transuranic elements from nitric acid wastes utilizing modified purex solvent . Solvent Extr. Ion Exch. , 3 ( 1, 2 ) : 75 – 109 . [CSA]
  • Horwitz , E. P. , Martin , K. A. , Diamond , H. and Kaplan , L. 1986 . Extraction of Am from nitric acid by carbamoyl–phosphoryl extractants: the influence of substituents on the selectivity of Am over Fe and selected fission products . Solvent Extr. Ion Exch. , 4 ( 3 ) : 449 – 494 .
  • Diamond , H. , Horwitz , E. P. and Danesi , P. R. 1986 . Activity coefficients of carbamoylmethylphosphoryl extractants in toluene . Solvent Extr. Ion Exch. , 4 ( 5 ) : 1009 – 1027 .
  • Horwitz , E. P. , Diamond , H. and Martin , K. A. 1987 . The extraction of selected actinides in the (III), (IV) and (VI) oxidation states from hydrochloric acid by OφD(iB)CMPO: the TRUEX‐chloride process . Solvent Extr. Ion Exch. , 5 ( 3 ) : 447 – 470 . [CSA]
  • Chiarizia , R. and Horwitz , E. P. 1987 . The solvent extraction of selected organic complexants by TRUEX process solvent . Solvent Extr. Ion Exch. , 5 ( 1 ) : 175 – 194 .
  • Mathur , J. , Murali , M. and Natarajan , P. 1991 . Extraction of actinides and fission products by octyl(phenyl)‐N,N‐diisobutylcarbamoylmethyl‐phosphine oxide from nitric acid media . Talanta , 39 ( 5 ) : 493 – 496 . [CROSSREF]
  • Horwitz , E. P. and Chiarizia , R. 1992 . Diluent effects in the extraction of Am(III) from nitric acid solution by selected carbamoyl–phosphoryl extractants and related monofunctional compounds . Solvent Extr. Ion Exch. , 10 ( 1 ) : 101 – 118 .
  • Mincher , B. 1992 . A slope analysis investigation of the trivalent f‐series metal CMPO complex . Solvent Extr. Ion Exch. , 10 ( 4 ) : 615 – 622 .
  • Reddy , M. , Damodaran , A. , Mathur , J. , Murali , M. S. , Balarama Krishna , M. V. and Iyer , R. H. 1996 . The itinerant extraction behavior of f‐elements and yttrium with octyl(phenyl)‐N,N‐diisobutylcarbamoyl‐methylphosphine oxide . Solvent Extr. Ion Exch. , 14 ( 5 ) : 793 – 816 .
  • Mickael , K. M. , Rizvi , G. H. , Mathur , J. N. , Kapoor , S. C. , Ramanujam , A. and Iyer , R. H. 1997 . Recovery of plutonium and americium from laboratory acidic waste solutions using tri‐n‐octylamine and octylphenyl‐N‐N‐diisobutylcarbamoylmethylphosphine oxide . Talanta , 44 : 2095 – 2102 . [CROSSREF]
  • Koma , Y. , Watanabe , M. , Nemoto , S. and Tanaka , Y. 1998 . Trivalent f‐element intra‐group separation by solvent extraction with CMPO–complexant system . J. Nucl. Sci. Technol. , 35 ( 2 ) : 130 – 136 .
  • Rao , L. , Xia , Y. , Rapko , B. M. and Martin , P. F. 1998 . Synergistic extraction of Eu(III) and Am(III) by thenoyltrifluoroacetone and neutral donor extractants: (carbamoylmethyl)phosphine oxide and 2,6‐bis((diphenylphosphino)methyl)pyridine N,P,P‐trioxide . Solvent Extr. Ion Exch. , 16 ( 4 ) : 913 – 929 .
  • Koma , Y. , Koyama , T. and Tanaka , Y. 1999 . Enhancement of the mutual separation of lanthanide elements in the solvent extraction based on the CMPO–TBP mixed solvent by using a DTPA‐nitrate solution . J. Nucl. Sci. Technol. , 36 ( 10 ) : 934 – 939 . [CSA]
  • Rozen , A. M. , Volk , V. I. , Vakhrushin , A. , Zakharkin , B. S. , Kartasheva , N. A. , Krupnov , B. V. and Nikolotova , Z. I. 1999 . Extractants for exhaustive recovery of TPEs from radiochemical production waste . Radiochemistry , 41 ( 3 ) : 215 – 221 .
  • Kalina , D. G. , Horwitz , E. P. , Kaplan , L. and Muscatello , A. C. 1981 . The extraction of Am(III) and Fe(III) by selected dihexyl N,N‐dialkylcarbamoylmethyl‐phosphonates, ‐phosphinates and ‐phosphine oxides from nitrate media . Sep. Sci. Technol. , 16 ( 9 ) : 1127 – 1145 .
  • Horwitz , E. P. , Muscatello , A. , Kalina , D. G. and Kaplan , L. 1981 . The extraction of selected transplutonium(III) and lanthanide(III) ions by dihexyl‐N,N‐diethylcarbamoylmethylphosphonate from aqueous nitrate media . Sep. Sci. Technol. , 16 ( 4 ) : 417 – 437 .
  • Litvina , M. N. , Chmutova , M. K. , Myasoedov , B. F. and Kabachnik , M. I. 1996 . Extraction and separation factors of lanthanides and americium in aqueous nitric acid–diaryl(dialkyl)‐(dialkylcarbamoylmethyl)phosphine oxide systems . Radiochemistry , 38 ( 6 ) : 494 – 499 .
  • Garcia‐Carrera , A. 2000 . “ Extraction des Lanthanides et des Actinides au Moyen de Calixarènes Portant des Groupements CMPO ” . Catalogne : Université Polytechnique . Ph.D. Thesis
  • Hill , C. 1994 . “ Application des Calixarènes Fonctionnalisés au Traitement des Effluents Radioactifs par Membranes Liquides Supportées ” . Université Louis Pasteur de Strasbourg . Ph.D. Thesis
  • Bonnesen , P. V. , Delmau , L. H. , Haverlock , T. J. and Moyer , B. A. 1998 . Alkaline‐Side Extraction of Cesium from Savannah River Tank Waste Using a Calixarene‐Crown Ether Extractant ORNL/TM‐13704
  • Mokili , B. and Poitrenaud , C. 1995 . Modeling of nitric acid and water from aqueous solutions containing a salting‐out agent by tri‐butylphosphate . Solvent Extr. Ion Exch. , 13 ( 4 ) : 731 – 754 .
  • Mokili , B. and Poitrenaud , C. 1996 . Modeling of the extraction of neodymium and praseodymium nitrates from aqueous solutions containing a salting‐out agent or nitric acid by tri‐N‐butylphosphate . Solvent Extr. Ion Exch. , 14 ( 4 ) : 617 – 634 .
  • Dannus , P. 1991 . “ Modélisation Physico‐Chimique de l'Extraction de Constituants Inorganiques par des Réactifs Solvatants ” . Paris : Université Pierre et Marie Curie . Ph.D. Thesis
  • Schulz , W. W. , Navratil , J. D. and Kertes , A. S. 1991 . Science and Technology of Tributylphosphate Vol. IV , CRC Press .
  • Frolov , Y. G. , Sergievskii , V. V. and Zuev , A. P. 1973 . Influence of the hydration of amine salts on the extraction equilibrium . Sov. Atom. Energy , 35 ( 2 ) : 731 – 739 .
  • Rard , J. A. , Miller , D. and Speddindg , F. H. 1979 . Isopiestic determination of the activity coefficients of some aqueous rare‐earth electrolyte solutions at 25°C. 4. La(NO3)3, Pr(NO3)3 and Nd(NO3)3 . J. Chem. Eng. Data , 24 ( 4 ) : 348 – 354 .
  • Libus , Z. , Sadowska , T. and Traskowski , J. 1979 . Osmotic coefficient of aqueous rare‐earth perchlorates and nitrates . J. Chem. Themodyn. , 11 : 1151 [CROSSREF]
  • Rard , J. A. and Spedding , F. H. 1982 . Isopiestic determination of the activity coefficients of some aqueous rare‐earth electrolyte solutions at 25°C. 6. Eu(NO3)3, Yb(NO3)3 and YCl3 . J. Chem. Eng. Data , 27 ( 4 ) : 454 – 461 .
  • Rard , J. A. , Shiers , L. E. , Heiser , D. J. and Spedding , F. H. 1977 . Isopiestic determination of the activity coefficients of some aqueous rare‐earth electrolyte solutions at 25°C. 3. The rare earth nitrates . J. Chem. Eng. Data , 22 ( 3 ) : 337 – 350 .
  • Mikulin , G. I. 1968 . Voprosy Fizicheskoï Khimii Rastvorov Electrolitov (Problems in Physical Chemistry of Electrolyte Solutions) . Izdatelstvo “Khimiya” Leningrad Otdelenie ,
  • Vdovenko , V. M. and Ryazanov , M. A. 1965 . Coefficients d'activité dans les systèmes à plusieurs constituents I . Radiochimie , 7 ( 1 ) : 40
  • Zdanovskii , A. B. 1936 . Zakonomernosti v Izmenenii Svoistv. Smeshannykh Rastvorov (Regularities in the Variation of the Properties of Mixed Solutions) . Trudy Solyanoï Lab. Akad. Nauk. , 6 SSSR
  • Stokes , R. and Robinson , R. 1966 . Interactions in aqueous nonelectrolyte solutions. I. Solute–solvent equilibria . J. Phys. Chem. , 70 : 2126 – 2130 .
  • Chen , H. , Sangster , J. , Teng , T. T. and Lenzi , F. 1973 . A general method of predicting the water activity of ternary aqueous solutions from binary data . Can. J. Chem. Eng. , 51 : 234
  • Frolov , Y. G. and Nikolaev , V. P. 1971 . Symposium “Materialy Vsesoyuznogo Simpozium po Termokhimii Rastvorov Elektrolitov I Neelektrolitov,” . All‐Union Symposium on the Thermochemistry of Solution of Electrolytes and Non‐Electrolytes . 1971 , Ivanoro. pp. 161
  • Awakura , Y. , Kawasaki , Y. , Uno , A. , Sato , K. and Majima , H. 1987 . Activities of water and HCl in system of HCl–MCl n including CuCl2, NiCl2 and FeCl3 . Hydrometallurgy , 19 : 137 [CROSSREF] [CSA]
  • Majima , H. , Awakura , Y. and Kawasaki , Y. 1988 . Activities of Water and Solutes in the Aqueous Solution Systems H2SO4–M x (SO4) y and HCl–MCl x Tokyo : Agne Shofu Publishing Inc. .
  • Mokili , B. 1992 . “ Modélisation de l'Extraction Liquide–Liquide de l'Acide Nitrique et de Nitrates de lanthanides par le phosphate de Tributyle ” . Paris : Université Pierre et Marie Curie . Ph.D. Thesis
  • Scholz , E. 1984 . Karl Fischer Titration Berlin : Springer Verlag .

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.