Fundamental Studies Regarding Synergism Between Calix[4]arene‐bis(tert‐octylbenzo‐crown‐6) and Alcohol Modifiers in the Solvent Extraction of Cesium Nitrate

References

• Marcus , Y. and Kertes , A. S. 1969 . Ion Exchange and Solvent Extraction of Metal Complexes New York : Wiley Interscience .
   Google Scholar
• Sekine , T. and Hasegawa , Y. 1977 . Solvent Extraction Chemistry: Fundamentals and Applications New York : Marcel Dekker .
   Google Scholar
• Rydberg , J. , Musikas , C. and Choppin , G. R. 1992 . Principles and Practices of Solvent Extraction New York : Marcel Dekker .
   Google Scholar
• Sachleben , R. A. , Deng , Y. and Moyer , B. A. 1996 . Ring‐size and substituent effects in the solvent extraction of alkali metal nitrates by crown ethers in 1,2‐dichloroethane and 1‐octanol . Solvent Extr. Ion Exch , 14 ( 6 ) : 995 – 1015 .
   Google Scholar
• Levitskaia , T. G. , Bonnesen , P. V. , Chambliss , C. K. and Moyer , B. A. 2003 . Synergistic pseudohydroxide extraction: synergism and anion selectivity in sodium extraction using a crown ether and a series of weak lipophilic acids . Anal. Chem. , 75 ( 3 ) : 405 – 412 .
   PubMedGoogle Scholar
• Duchemin , C. R. , Engle , N. L. , Bonnesen , P. V. , Haverlock , T. J. , Delmau , L. H. and Moyer , B. A. 2001 . Solvatochromic solvent polarity measurements of alcohol solvent modifiers and correlation with cesium extraction strength . Solvent Extr. Ion Exch. , 19 ( 6 ) : 1037 – 1058 .
   Web of Science ®Google Scholar
• Kavallieratos , K. and Moyer , B. A. 2001 . Attenuation of Hofmeister bias in ion‐pair extraction by a disulfonamide anion host used in strikingly effective synergistic combination with a calix‐crown Cs+ host . Chem. Commun. , 17 : 1620 – 1621 .
   Google Scholar
• Bryan , J. C. , Delmau , L. H. , Hay , B. P. , Nicholas , J. B. , Rogers , L. M. , Rogers , R. D. and Moyer , B. A. 1999 . Cesium recognition by supramolecular assemblies of 2‐benzylphenol and 2‐benzylphenolate . Struct. Chem. , 10 ( 3 ) : 187 – 203 .
   Google Scholar
• Delmau , L. H. , Bryan , J. C. , Hay , B. P. , Engle , N. L. , Sachleben , R. A. and Moyer , B. A. 2000 . “ Benzyl phenol derivatives: extraction properties of calixarene fragments ” . In Calixarene Molecules for Separations , ACS Symposium Series Edited by: Lumetta , G. J. , Rogers , R. D. and Gopalan , A. S. Vol. 757 , 86 – 106 . Washington, D.C. : American Chemical Society . Chap. 7
   Google Scholar
• Bonnesen , P. V. , Delmau , L. H. , Moyer , B. A. and Lumetta , G. J. 2003 . Development of effective solvent modifiers for the solvent extraction of cesium from alkaline high‐level tank waste . Solvent Extr. Ion Exch. , 21 ( 2 ) : 141 – 170 .
   Web of Science ®Google Scholar
• Bonnesen , P. V. , Delmau , L. H. , Moyer , B. A. and Leonard , R. A. 2000 . A robust alkaline‐side CSEX solvent suitable for removing cesium from Savannah River high level waste . Solvent Extr. Ion Exch. , 18 ( 6 ) : 1079 – 1108 .
   Web of Science ®Google Scholar
• Leonard , R. A. , Conner , C. , Liberatore , M. W. , Sedlet , J. , Aase , S. B. , Vandegrift , G. F. , Delmau , L. H. , Bonnesen , P. V. and Moyer , B. A. 2001 . Development of a solvent extraction process for cesium removal from SRS tank waste . Sep. Sci. Technol. , 36 : 743 – 766 .
   Web of Science ®Google Scholar
• Bonnesen , P. V. , Haverlock , T. J. , Engle , N. L. , Sachleben , R. A. and Moyer , B. A. 2000 . “ Development of process chemistry for the removal of cesium from acidic nuclear waste by calix[4]arene‐crown‐6 ethers ” . In Calixarene Molecules for Separations , ACS Symposium Series Edited by: Lumetta , G. J. , Rogers , R. D. and Gopalan , A. S. Vol. 757 , 26 – 44 . Washington, D.C. : American Chemical Society . Chap. 3
   Google Scholar
• Moyer , B. A. , Sachleben , R. A. , Bonnesen , P. V. and Presley , D. J. Calixarene Crown Ether Solvent Composition and Use Thereof for Extraction of Cesium from Alkaline Waste Solutions . U.S. Patent 6,174,503 . 16 January 2001 .
   Google Scholar
• Bonnesen , P. V. , Moyer , B. A. and Sachleben , R. A. Fluoro‐alcohol Phase Modifiers and Process for Cesium Solvent Extraction . U.S. Patent 6,566,561 . 20 May 2003 .
   Google Scholar
• Baes , C. F. Jr. 2001 . Modeling solvent extraction systems with SXFIT . Solvent Extr. Ion Exch. , 19 : 193 – 213 .
   Web of Science ®Google Scholar
• Ritcey , G. M. and Ashbrook , A. W. 1980 . Solvent Extraction, Principles and Applications to Process Metallurgy New York : Elsevier .
   Google Scholar
• Ritcey , G. M. and Ashbrook , A. W. 1984 . Solvent Extraction, Principles and Applications to Process Metallurgy New York : Elsevier .
   Google Scholar
• Szymanowski , J. 1995 . Physicochemical modification of extractants . Crit. Rev. Anal. Chem. , 25 : 143 – 194 .
   Web of Science ®Google Scholar
• Sastre , A. and Szymanowski , J. Physicochemical discussion of the effect of modifiers on the extraction properties of hydroxyoximes . Solvent Extr. Ion Exch. , submitted
   Google Scholar
• Shmidt , V. S. 1971 . Amine Extraction Jerusalem : Keter Press .
   Google Scholar
• Kertes , A. S. 1965 . “ The Chemistry of the Formation and Elimination of a Third Phase in Organophosphorus and Amine Extraction Systems ” . In Solvent Extraction Chemistry of Metals Edited by: McKay , H. A. C. , Healy , T. V. , Jenkins , I. L. and Naylor , A. 377 – 399 . London : Macmillan .
   Google Scholar
• Verstegen , J. M. P. J. 1965 . The third phase in amine systems . J. Inorg. Nucl. Chem. , 27 : 201 – 207 .
   Web of Science ®Google Scholar
• Lipovskii , A. A. and Dem'yanova , T. A. 1966 . Nature of the interaction of tridecylammonium salts with aliphatic alcohol molecules . Radiokhimiya , 8 ( 1 ) : 112 – 114 .
   Google Scholar
• Muhammed , M. A. 1976 . The role of octanol in the extraction of hydrochloric acid by trilaurylamine dissolved in benzene . J. Radioanal. Chem. , 30 : 411 – 417 .
   Google Scholar
• Chiarizia , R. , Jensen , M. P. , Borkowski , M. , Ferraro , J. R. , Thiyagarajan , P. and Littrell , K. C. 2003 . Third phase formation revisited: The U(VI), HNO3‐TBP, n‐dodecane system . Solvent Extr. Ion Exch. , 21 ( 1 ) : 1 – 27 .
   Web of Science ®Google Scholar
• Asfari , Z. , Wenger , S. and Vicens , J. 1994 . Calixcrowns and related molecules . J. Incl. Phenom. Mol. Recogn. Chem. , 19 ( 1–4 ) : 137 – 148 .
   Web of Science ®Google Scholar
• Dozol , J.‐F. , Simon , N. , Lamare , V. , Rouquette , H. , Eymard , S. , Tournois , B. , De Marc , D. and Macias , R. M. 1999 . A solution for cesium removal from high salinity acidic or alkaline liquid waste: the crown calix[4]arenes . Sep. Sci. Technol. , 34 ( 6‐7 ) : 877 – 909 .
   Web of Science ®Google Scholar
• 17 October 2001 . Vol. 66, No. 201 , 17 October , 52752 – 52756 . U.S. Department of Energy, Department of Energy Record of Decision . Savannah River Site Salt Processing Alternatives, Federal Register
   Google Scholar
• Moyer , B. A. , Alexandratos , S. D. , Bonnesen , P. V. , Brown , G. M. , Caton , J. E. Jr. , Delmau , L. H. , Duchemin , C. R. , Haverlock , T. J. , Levitskaia , T. G. , Maskarinec , M. P. , Sloop , F. V. Jr. and Stine , C. L. February 2002 . Caustic‐side Solvent Extraction Chemical and Physical Properties: Progress in FY 2000 and FY 2001 February , Oak Ridge, TN : Oak Ridge National Laboratory . Report ORNL/TM‐2001/285
   Google Scholar
• Delmau , L. H. , Birdwell Jr. , Bonnesen , P. V. , Foote , L. J. , Haverlock , T. J. , Klatt , L. N. , Lee , D. D. , Leonard , R. A. , Levitskaia , T. G. , Maskarinec , M. P. , Moyer , B. A. , Sloop , F. V. Jr. and Tomkins , B. A. October 2002 . Caustic‐side Solvent Extraction: Chemical And Physical Properties of the Optimized Solvent October , Oak Ridge, Tennessee : Oak Ridge National Laboratory . ORNL/TM‐2002/190
   Google Scholar
• Bonnesen , P. V. , Delmau , L. H. , Haverlock , T. J. and Moyer , B. A. December 1998 . Alkaline‐side Extraction of Cesium from Savannah River Tank Waste using a Calixarene‐Crown Ether Extractant December , Oak Ridge, TN : Oak Ridge National Laboratory . Report ORNL/TM‐13704
   Google Scholar
• Harms , K. 1995 . XCAD4 Germany : Universität Marburg .
   Google Scholar
• 1995 . SHELXTL (Version 5, IRIX) Madison, Wisconsin : Siemens Analytical X‐ray Instruments, Inc. .
   Google Scholar
• Spek , A. L. 1996 . PLATON: A Multi‐Purpose Crystallographic Tool The Netherlands : Universiteit Utrecht .
   Google Scholar
• Jeffrey , G. A. 1997 . An Introduction to Hydrogen Bonding Edited by: Truhlar , D. G. Oxford : Oxford University Press .
   Google Scholar
• Delmau , L. H. , Van Berkel , G. J. , Bonnesen , P. V. and Moyer , B. A. 1999 . Improved Performance of the Alkaline‐Side Csex Process for Cesium Extraction from Alkaline High‐Level Waste Obtained by Characterization of the Effect of Surfactant Impurities Oak Ridge, TN : Oak Ridge National Laboratory . Report ORNL/TM‐1999/209
   Google Scholar
• Delmau , L. H. , Baes , C. F. Jr. , Bostick , D. A. , Haverlock , T. J. and Moyer , B. A. Solvent extraction system modeling using the program SXFIT . Hydrometallurgy 2003—Fifth International Conference in Honor of Professor Ian Ritchie, Vol. 1, Proceedings of the 2003 International Symposium on Hydrometallurgy . August 24–27 2003 , Vancouver, Canada. Leaching and Solution Purification , Edited by: Young , C. A. , Alfantazi , A. M. , Anderson , C. G. , Dreisinger , D. B. , Harris , B. and James , A. pp. 969 – 981 . Warrendale, PA : TMS (The Minerals, Metals, and Materials Society) .
   Google Scholar
• Baes , C. F. Jr. , McDowell , W. J. and Bryan , S. A. 1987 . The interpretation of equilibrium data from synergistic solvent extraction systems . Solvent Extr. Ion Exch. , 5 ( 1 ) : 1 – 2 .
   Web of Science ®Google Scholar
• Baes , C. F. Jr. , Moyer , B. A. , Case , G. N. and Case , F. I. 1990 . SXLSQA, a computer program for including both complex formation and activity effects in the interpretation of solvent extraction data . Sep. Sci. Technol. , 25 ( 13–15 ) : 1675 – 1688 .
   Web of Science ®Google Scholar
• Baes , C. F. Jr. December 1998 . SXLSQI: A Program for Modeling Solvent Extraction Systems December , Oak Ridge, TN : Oak Ridge National Laboratory . Oak Ridge National Laboratory Report ORNL/TM‐13604
   Google Scholar
• Hormadaly , J. and Marcus , Y. 1979 . Anion solvation properties of protic solvents. 1. Spectroscopic study . J. Phys. Chem. , 83 ( 22 ) : 2843 – 2848 .
   Google Scholar
• Reichardt , C. 1990 . Solvents and Solvent Effects in Organic Chemistry , 2nd Ed. Weinheim (Federal Republic of Germany) : VCH .
   Google Scholar
• Marcus , Y. , Pross , E. and Hormadaly , J. 1980 . Anion solvation properties of protic solvents. 2. Salt distribution study . J. Phys. Chem. , 84 : 2708 – 2715 .
   Web of Science ®Google Scholar
• Haverlock , T. J. , Bonnesen , P. V. , Sachleben , R. A. and Moyer , B. A. 2000 . Analysis of equilibria in the extraction of cesium nitrate by calix[4]arene‐bis(t‐octylbenzo‐crown‐6) in 1,2‐dichloroethane . J. Inclusion Phenom. Mol. Recognit. Chem. , 36 : 21 – 37 .
   Web of Science ®Google Scholar
• Barton , A. F.M. 1983 . Handbook of Solubility Parameters and other Cohesion Parameters , 2nd ed. Boca Raton : CRC Press .
   Google Scholar
• Millero , F. J. 1972 . Water and Aqueous Solutions Edited by: Horne , R. A. New York : Wiley‐Interscience .
   Google Scholar
• Pitzer , K. S. 1991 . Activity Coefficients in Electrolyte Solutions , 2nd Ed. Edited by: Pitzer , K. S. Boca Raton : CRC Press .
   Google Scholar
• Bure , C. and Lange , C. 2003 . Comparison of dissociation of ions in an electrospray source, or a collision cell in tandem mass spectrometry . Current Org Chem. , 7 ( 15 ) : 1613 – 1624 .
   Google Scholar