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Original Articles

PREPARATION, STRUCTURAL CHARACTERIZATION, AND PROPERTIES OF NIOBIUM PENTAARYLOXIDES, Nb(OAr)5

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Pages 1831-1842 | Received 28 Jun 2000, Accepted 09 Sep 2001, Published online: 15 Feb 2007

REFERENCES

  • Bradley , D. C. , Mehrotra , R. C. and Gaur , D. P. 1978 . Metal Alkoxides London, New York, San Francisco : Academic Press .
  • Cotton , F. A. , Diebold , M. P. and Roth , W. J. 1985 . Binuclear Alkoxides Complexes of Niobium and Tantalum in Lower Oxidation States . Inorg. Chem. , 24 : 3509 – 3510 .
  • Cotton , F. A. , Diebold , M. P. and Roth , W. J. 1987 . Dinuclear Niobium(IV). Complexes Nb2Cl4(OMe)4L2 (L = MeOH, CH3CN) and their Relation of Analogous W and Mo Compounds . Inorg. Chem. , 26 : 3319 – 3323 .
  • Cotton , F. A. , Diebold , M. P. and Roth , W. J. 1987 . Alkoxide Complexes of Niobium(III) . Inorg. Chem. , 26 : 3323 – 3327 .
  • Cotton , F. A. , Diebold , M. P. and Roth , W. J. 1988 . Further Studies of Low-Valent Alkoxide Complexes of Niobium(IV) Nonamethoxide . Inorg. Chem. , 27 : 3596 – 3600 .
  • Malhotra , K. C. and Martin , R. L. 1982 . Metal Phenoxides . J. Organomet. Chem. , 282 : 159 – 187 .
  • Chesnut , R. W. , Yu , J. S. , Fanwick , P. E. , Rothwell , I. P. and Huffman , J. C. 1990 . The Cyclometallation of 2,6-Diphenylphenoxide (OAr-2,6Ph2) Ligands at Niobium(V) and Tantalum(V) Metal Centres. The Solid State Structures of Monocylometallated Compounds. Ta(OC6H3Ph-C6H4)(OAr-2,6Ph2)2(R), (R = CH3, n-C4H9) and Nb(OC6H3Ph-C6H4)(OAr-2,6Ph2)2CL . Polyhedron , 9 : 1051 – 1058 .
  • Hubert-Pfalzgraf , L. G. and Riess , L. G. 1980 . The Obtention of Niobium Oxyalkoxide Derivatives by Direct Alkoxylation of the Oxychloride . Inorg. Chim. Acta , 41 : 111 – 117 .
  • Gibson , V. C. , Kee , T. P. and Shaw , A. 1988 . Convenient High Yield Synthesis of [Nb(O)Cl3], [Nb(O)Cl3(CH3CN)2] and [Nb(O)Cl3(THF)2]. Formation and Decomposition of Intermediate Alkoxo (and Siloxo) Derivatives of General Formula [Nb(Cl)4(OR)]2 (R = Me, Et, SiMe3) . Polyhedron , 7 : 2217 – 2219 .
  • Gibson , V. C. , Kee , T. P. and Clegg , W. 1990 . Synthesis and Characterization of Half Sandwitched Tantalum Compounds in Oxidation States I to V: Tertiary Phosphines, Acetylenes, Butadienes, Carbonyls and Oxo Derivatives. X-ray Crystal Structure of [Ta(C5Me5)Cl3(PMe3)3] . J. Chem. Soc. Dalton Trans. , : 3199 – 3210 .
  • Kee , T. P. and Gibson , V. C. 1992 . Four-Coordinate Oxo-Phenoxide Compounds of Niobium(V). Synthesis and Characterization of [Nb(O)(O-2,6-R2C6H3)3], R = Me (1), R = Bu (2) . Polyhedron , 6 : 587 – 589 .
  • Funk , V. H. and Baumann , W. 1937 . Reaction of a Few Metal Chlorides with Phenol and β-Naphthol . Z. Anorg. Allg. Chem. , 231 : 264 – 268 .
  • Malhotra , K. C. , Banerjee , U. K. and Chaudhry , S. C. 1980 . Nature of Phenoxides of Niobium(V) and Tantalum(V) . J. Ind. Chem. Soc. , 57 : 868 – 870 .
  • Wang , R. , Folting , K. , Huffman , J. C. , Chamberlain , L. R. and Rothwell , I. P. 1986 . Synthesis and Solid State Structure of Tetra(2,6-di-isopropylphenoxy)hexamethoxy-di-tantalum(V) Ta2(OC6H3Pr2 i)4-(OCH3)6 . Inorg. Chim. Acta. , 120 : 81 – 83 .
  • Lewis , L. N. and Garbauskas , M. E. 1985 . Structure of Tantalum Cresoxides . Inorg. Chem. , 24 : 363 – 366 .
  • Chamberlain , L. R. , Rothwell , I. P. and Huffman , J. C. 1984 . Chemistry of Sterically Crowded Aryloxide Ligands 4. Synthesis of Mixed Chloroaryloxides of Tantalum . Inorg. Chem. , 23 : 2575 – 2578 .
  • Simmons , W. W. 1978 . The Sadtler Handbook of Infrared Spectra 544 Sadtler Research Laboratories Inc .
  • Dyer , J. R. 1989 . Applications of Absorption Spectroscopy of Organic Compounds 37 Prentice-Hall of Indian Pvt. Ltd. .
  • Barraclough , C. G. , Bradley , D. C. , Lewis , J. and Thomas , I. M. 1961 . The Infrared Spectra of some Metal Alkoxides, Trialkylsilyloxides and Related Silanols . J. Chem. Soc. , : 2601 – 2605 .
  • Bradley , D. C. and Westlake , A. H. 1965 . Proceedings of the Tihany Symposium 309 Budapest : Hungarian Academy of Sciences .
  • Clark , R. J.H. 1965 . Metal-halogen Stretching Frequencies in Inorganic Complexes . Spectrochim. Acta , 21 : 955 – 963 .
  • Simmons , W. W. 1978 . The Sadtler Handbook of Proton NMR Spectra 303 Sadtler Research Laboratories. Inc .
  • Turevskaya , E. P. , Turova , N. Ya. , Korolev , A. V. , Yanovsky , A. I. and Struchkov , Yu. T. 1995 . Bimetallic Alkoxides of Niobium . Polyhedron , 14 : 1531 – 1542 .
  • Garg , G. , Dubey , R. K. , Singh , A. and Mehrotra , R. C. 1991 . Synthetic, Spectroscopic and Magnetic Studies of Hetro-metal Alkoxides of Cobalt- (II), Nickel(II) and Copper(II) Containing the Sterically Crowded Tetraalkoxoaluminate Ligand . Polyhedron , 10 : 1733 – 1739 .
  • 2000–2001 . Aldrich Handbook of Fine Chemicals and Laboratory Equipment Vol. B9 , 318 USA : Aldrich Chemical Company, Inc . 990-1
  • 2000–2001 . Aldrich Handbook of Fine Chemicals and Laboratory Equipment Vol. Ml , 1073 USA : Aldrich Chemical Company, Inc. . 865-5
  • Dubey , R. K. , Singh , A. and Mehrotra , R. C. 1987 . Synthesis and Characterization of Copper(II) Bis(dizirconium-ennea-alkoxides) . Polyhedron , 6 ( 3 ) : 427 – 423 .

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