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Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry Volume 33, 2003 - Issue 9
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Original Articles

Synthesis and Labile Ligand‐Substitution Reactions of tetrakis(Benzylisocyanide)bis‐(tri‐p‐tolylarsine‐oxide)cobalt(III) Perchlorate

Clifford A. L. Becker Department of Chemistry, University of Botswana, P/Bag 0022, Gaborone, BotswanaCorrespondence[email protected]
&
Otlaadisa Clifford Malete Department of Chemistry, University of Botswana, P/Bag 0022, Gaborone, Botswana
Pages 1635-1645 | Received 28 May 2002, Accepted 27 May 2003, Published online: 15 Feb 2007

References

  • Becker , C. A.L. 1993 . Synthesis of paramagnetic tetrakis(benzylisocyanide)bis(tri‐p‐tolylarsineoxide)cobalt(III) tetrafluoroborate. An example of oxidation of ligand and metal in reaction of pentakis(arylisocyanide)cobalt(II) with triarylarsine . Inorg. Chim. Acta , 203 : 175 – 178 .
  • Becker , C. A.L. and Motladiile , S. 2001 . Ligand substitution reactions in tetrakis‐(benzylisocyanide)bis(tri‐p‐tolylarsineoxide)cobalt(III) tetrafluoroborate: an example of a labile six‐coordinate cobalt(III) complex . Synth. React. Inorg. Met.‐Org. Chem. , 31 ( 9 ) : 1545 – 1552 .
  • Becker , C. A.L. 1993 . Reactions of isopropylisocyanide and t‐butylisocyanide with cobalt(II) perchlorate and tetrafluoroborate . J. Coord. Chem. , 28 : 147 – 153 .
  • Becker , C. A.L. , Anisi , A. , Myer , G. and Wright , J. D. 1986 . Preparation of tetrakis(t‐butylisocyanide)aquacobalt(II) perchlorate and reaction with tertiary phosphine ligands . Inorg. Chim. Acta , 111 : 11 – 18 .
  • Becker , C. A.L. 1978 . Magnetic moments for pentakis(aromatic isocyanide)‐cobalt(II) complexes . Inorg. Chim. Acta , 27 : L105 – L107 .
  • Becker , C. A.L. and Cooper , J. C. 1989 . Preparation of tetrakis(2,6‐dimethylphenylisocyanide)cobalt(II) perchlorate in novel reactions . Inorg. Chim. Acta , 158 : 141 – 149 .
  • Becker , C. A.L. and Cooper , J. C. 1991 . Synthesis, characterization and molecular structure of tetrakis(2,6‐diethylphenylisocyanide)bis(perchlorato)cobalt(II). An example of dissimilarity between perchlorate and tetrafluoroborate salts . Inog. Chim. Acta , 182 : 25 – 32 .
  • Becker , C. A.L. 1992 . Synthesis of tetrakis(2,6‐di‐isopropylphenylisocyanide)bis(perchlorato) cobalt(II) and hexakis(2,6‐di‐isopropylphenylisocyanide)cobalt(II) tetrafluoroborate. An example of dissimilarity between perchlorate and tetrafluoroborate salts . Synth. React. Inorg. Met.‐Org. Chem. , 22 ( 4 ) : 437 – 446 .
  • Becker , C. A.L. 1995 . Reactions of pentakis(arylisocyanide)cobalt(II) perchlorate with triphenylarsine and triphenylstibine . Synth. React. Inorg. Met.‐Org. Chem. , 25 ( 9 ) : 1455 – 1467 .
  • Becker , C. A.L. and Biswas , M. A.S. 1993 . Synthesis and characterization of tetrakis(alkylisocyanide) bis(trialkylphosphine)cobalt(III) complexes . J. Coord. Chem. , 29 : 277 – 286 .
  • Becker , C. A.L. 1997 . Synthesis of tris(cyclohexylisocyanide)bis(triphenyl‐phosphine)cobalt(II) perchlorate. An example of unusual stabilization of the cobalt(II) oxidation state . Synth. React. Inorg. Met.‐Org. Chem. , 27 ( 10 ) : 1527 – 1542 .
  • Becker , C. A.L. , Sebobi , G. S. and Simane , N. T. 2002 . Synthesis of tetrakis(alkylisocyanide)bis(triphenylstibine)cobalt(II) and tetrakis(alkylisocyanide)bis(triphenylstibineoxide)cobalt(III) complexes. Ligand substitution and oxidation in pentakis(alkylisocyanide)cobalt(II) . Inorg. Chim. Acta , 334 : 327 – 333 .

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