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Articles

Trivalent Actinide and Lanthanide Separations by Dialkyl-Substituted Diphosphonic Acids

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Pages 69-90 | Published online: 09 Nov 2011

REFERENCES

  • Szymanski, A. (1987) Nobel Prize 200 Years Later. In 1787-1987, Two Hundred Years of Rare Earths; Gshneidner, K.A., Jr., and Capellen, J., Eds.; North-Holland: Amsterdam, The Netherlands; 14-16.
  • Nash, K.L. and Jensen, M.P. (2000) Analytical Separations of the Lanthanides: Basic Chemistry and Methods. In Handbook on the Physics and Chemistry of Rare Earths, Vol. 28 Gshneidner, K.A., Jr. and Eyring, L., Eds.; Elsevier Science B.V.: Amsterdam, The Netherlands; 311-371.
  • Sherrington, L. (1983) Commercial Processes for Rare Earths and Thorium. In Handbook of Solvent Extraction; Lo, T.C., Baird, M.H.I. and Hanson, C., Eds.; Wiley-Interscience: New York; 717-723.
  • Alstad, J., Auguston, J.H., and Farbu, L. (1974) Solvent Extraction of Rare-Earth Metal Ions with Thenoyltritluoroacetone in Carbon Tetrachloride., J. Inorg. Nucl. Chem., 36: 899–903.
  • Jordanov, V.M., Atanassova, M., and Dukov, I.L. (2002) Solvent Extraction of Lanthanides with l-Phenyl-3-methyl-4-benzoyl-5-pyrazolone. Sep. Sci. Technol., 37: 3349–3356.
  • Reddy, M.L.P. (2000) 4-Acylbis(1-phenyl-3-methy 1-5-pyrazolones) as Extractants for f-Elements. Solvent Extr. Ion Exch., 18: 1135–1153.
  • Ceccaroli, B. and Alstad, J. (1981) Trends in Separation Factors for the Lanthanum Series as Obtained in Solvent Extraction from an Aqueous Thiocyanate Solution. J. Inorg. Nucl. Chem., 43: 1881–1886.
  • Turanov, A.N., Karandashev, V.K., and Yarkevich, A.N. (2001) Extraction of Rare-Earth Elements and Yttrium from Nitric Acid Solutions by Butyl(diphenyl-phosphinyl-methyl)phenylphosphinate. Solvent Extr. Ion Exch., 20: 1–19.
  • Chu, D., Ma, G., and Li, D. (2001) Solvent Extraction of Lanthanides and Yttrium from Nitrate Solutions with Cyanex 923. In Solvent Extraction for the 21st Century. Proceedings of ISEC’99; Cox, M., Hidalgo, M., and Valiente, M., Ed.; Society of Chemical Industry: London, UK; 1109-1114.
  • Peppard, D.F., Mason, G.W., Maier, J.L., and Driscoll, W.J. (1957) Fractional Extraction of the Lanthanides as Their Di-alkyl Orthophosphates. J. Inorg. Nucl. Chem., 4: 333–343.
  • Pierce, T.B. and Peck, P.F. (1963) The Extraction of the Lanthanide Elements from Perchloric Acid by Di-(2-ethylhexyl) Hydrogen Phosphate. The Analyst, 88: 217–221.
  • Fidelis, I. and Siekierski, S. (1965) Use of 2-Ethylhexyl Phenylphosphonic Acid in Reversed Phase Partition Chromatography. J. Chromatog., 17: 542–548.
  • Fidelis, I. and Siekierski, S. (1966) The Regularities in Stability Constants of Some Rare Earth Complexes. J. Inorg. Nucl. Cliem., 28: 185–188.
  • Fidelis, I. and Siekierski, S. (1967) The Influence of Enthalpy and Entropy on the Separation Factor of the Lanthanides in the HFHΦP-HNO3 System. J. Inorg. Nucl. Chem., 29: 2629–2635.
  • Peppard, D.F., Mason, G.W., and Lewey, S. (1969) A Tetrad Effect in the Liquid-Liquid Ordering of Lanthanides(III). J. Inorg. Nucl. Chem., 31: 2271–2272.
  • Peppard, D.F., Bloomquist, C.A.A., Horwitz, E.P., Lewey, S., and Mason, G.W. (1970) Analogous Actinide(IlI) and Lanthanide(III) Effects. J. Inorg. Nucl. Chem., 32: 339–343.
  • Siekierski, S. (1970) Further Observations on the Regularities Associated with the Formation of the Lanthanide and Actinide Complexes. J. Inorg. Nucl. Chem., 32: 519–529.
  • Li, D. (2001) Rare Earths Separation Study. In Solvent Extraction for the 2181 Century. Proceedings of ISEC’99; Cox, M., Hidalgo, M., and Valiente, M., Eds.; Society of Chemical Industry: London, UK; 1081-1087.
  • Peppard, D.F., Mason, G.W., and Lewey, S. (1969) A Tetrad Grouping of Lantha-nides(III) in Their Liquid-Liquid Extraction Ordering. In Solvent Extraction Research; Kertes, A.S. and Marcus, Y.; Wiley-Interscience: New York; 49-57.
  • Fidelis, I. and Siekierski, S. (1971) On the Regularities or Tetrad Effect in Complex Formation by f-Electron Elements. A Double-Double Effect. J. Inorg. Nucl. Chem., 33: 3191–3194 (and references therein).
  • Nugent, L.J. (1970) Theory of the Tetrad Effect in the Lanthanide(III) and Actinide(III) Series. J. Inorg. Nucl. Cliem., 32: 3485–3491.
  • Jørgensen, C.K. (1970) The “Tetrad Effect” of Peppard is a Variation of the Nephelauxetic Ratio in the Third Decimal. J. Inorg. Nucl. Chem., 32: 3127–3128.
  • Siekierski, S. (1971) The Shape of the Lanthanide Contraction as Reflected in the Changes of the Unit Cell Volume, Lanthanide Radius and the Free Energy of Complex Formation. J. Inorg. Nucl. Chem., 33: 377–386.
  • Sinha, S.P. (1976) A Systematic Correlation of the Properties of the/-Transition Metal Ions. In Structure and Bonding, Vol. 30, Dunitz, J.D., Hemmerich, P., Ibers, J.A., Jørgensen, C.K., Neilands, J.B., Reinen, D., and Williams, R.J.P., Eds.; Springer-Verlag: Heidelberg, Germany; 1-65.
  • Fidelis, I.K. and Mioduski, T.J. (1981) Double-Double Effect of the Inner Transition Elements. In Structure and Bonding, Vol. 47; Dunitz, J.D., Hemmerich, P., Ibers, J.A., Jørgensen, C.K., Neilands, J.B., Reinen, D., and Williams, R.J.P., Ed.; Springer-Verlag: Heidelberg, Germany; 27-51.
  • Siekierski, S. (1992) Systematics of the 4/Electron Elements. Polish J. Chem., 66: 215–230.
  • Mioduski, T. (1997) The “Regular” and “Inverse” Tetrad Effect. Comments Inorg. Chem., 2: 93–119.
  • Kawabe, I. and Masuda, A. (2001) The Original Examples of Lanthanide Tetrad Effect in Solvent Extraction: A New Interpretation Compatible with Recent Progress in REE Geochemistry. Geochem. J., 35: 215–224.
  • Shannon, R.D. (1976) Revised Effective Ionic Radii and Systematic Studies of Interatomic Distances in Halides and Chalcogenides. Acta Crystallogr., 32A: 751–767.
  • Wakui, Y., Yokoyama, T., and Akiba, K. (2001) Solvent Extraction of Rare Earth Elements(III) with a Bifunctional Phosphinic Acid. In Solvent Extraction for the 21st Century. Proceedings of ISEC’99 Cox, M., Hidalgo, M., and Valiente, M., Ed.; Society of Chemical Industry: London, UK, 1103–1107.
  • Turanov, A.N., Karandashev, V.K., and Yarkevich, A.N. (2002) Metal Extraction from Nitric Acid Solutions by (Diphenyl-Phosphinylmethyl)Phenylphosphinic Acid. Solvent Extr. Ion Exch., 20: 633–663.
  • Chiarizia, R., Horwitz, E.P., Rickert, P.G., and Herlinger, A.W. (1996) Metal Extraction by Alkyl-Substituted Diphosphonic Acids. Part I: P,P’-di(2-ethylhexyl) Methanediphosphonic Acid. Solvent Extr. Ion Exch., 14: 773–792.
  • Herlinger, A.W., Ferraro, J.R., Chiarizia, R., and Horwitz, E.P. (1997) An Investigation of P,P’-Di(2-ethylhexyl) Methanediphosphonic Acid and Some of its Metal Complexes. Polyhedron, 16: 1843–1854.
  • Herlinger, A.W., Chiarizia, R., Ferraro, J.R., Rickert, P.G., and Horwitz, E.P. (1997) Metal Extraction by Alkyl Substituted Diphosphonic Acids. Part 2: P,P’-Di(2-ethylhexyl) Ethanediphosphonic Acid Aggregation and IR Study. Solvent Extr. Ion Exch., 15: 401–416.
  • Chiarizia, R., Herlinger, A.W., and Horwitz, E.P. (1997) Metal Extraction by Alkyl Substituted Diphosphonic Acids. Part 3: P,P′-Di(2-ethylhexyl) Ethanedi-phosphonic Acid Solvent Extraction Study. Solvent Extr. Ion Exch., 15: 417–431.
  • Chiarizia, R., Urban, V., Thiyagarajan, P., and Herlinger, A.W. (1998) Aggregation of P,P’-Di(2-ethylhexyl) Methanediphosphonic Acid and its Fe(III) Complexes. Solvent Extr. Ion Exch., 16: 1257–1278.
  • Chiarizia, R., Urban, V., Thiyagarajan, P., and Herlinger, A.W. (1999) SANS Study of Aggregation of Complexes Formed in the Extraction of Selected Metal Cations by P,P’-Di(2-ethylhexyl) Ethane- and Butane-Diphosphonic Acids. Solvent Extr. Ion Exch., 17: 1171–1194.
  • Peppard, D.F., Mason, G.W., McCarty, S., and Johnson, F.D. (1962) Extraction of Ca(II), Sr(II) and Ba(II) by Acidic Esters of Phosphorus Oxy Acids. J. Inorg. Nucl. Chem., 24: 321–332.
  • Chiarizia, R., McAlister, D.R., and Herlinger, A.W. (2001) Solvent Extraction by Dialkyl-Substituted Diphosphonic Acids in a Dcpolymerizing Diluent. Part II. Fe(III) and Actinide Ions. Solvent Extr. Ion Exch., 19: 415–440.
  • Smith, R.M., Martell, A.E., and Motekaitis, R.J. (1998) NIST Critical Stability Constants of Metal Complexes Database, Version 5.0; US Department of Commerce: Gaithersburg, Maryland.
  • Barrens, R.E., Jr., McAlister, D.R., Herlinger, A.W., Chiarizia, R., and Ferraro, J.R. (1999) Hydrogen Bonding in Aggregates of Dialkylsubstituted Diphosphonic Acids and Monofunctional Analogues. Solvent Extr. Ion Exclu, 17: 1195–1217.

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