Modeling of Waste Form Performance and System Release

References

• U.S. Nuclear Regulatory Commission Rules and Regulations, “Disposal of High-Level Radioactive Wastes in Geologic Repositories,” 10CFR60, para. 60.111-Performance Objectives, Federal Register (July 24, 1981).
   Google Scholar
• H. W. GODBEE and D. S. JOY, “Assessment of the Loss of Radioactive Isotopes from Waste Solids to the Environment. Part I: Background and Theory,” ORNL-TM-4333, Oak Ridge National Laboratory (1974).
   Google Scholar
• A. J. MACHIELS and C. PESCATORE, “Modeling of Waste Form Leaching. Part II: Mechanistic Modeling of Nuclear Waste Form Leaching by Aqueous Solutions,” Technical Report UILU-ENG-82-5360, University of Illinois, Urbana, Illinois (1974); see also ONWI/E512-06000-2, Office of Nuclear Waste Isolation (1982).
   Google Scholar
• W. L. KUHN and R. D. PETERS, “Leach Models for a Commercial Nuclear Waste Glass,” Scientific Basis for Nuclear Waste Management, Vol. VI, p. 167, D. G. BROOKINS, Ed., North-Holland Publishing Company (1982).
   Google Scholar
• K. HARVEY, “A Semiunified Approach to Leach Testing of Nuclear Waste Forms,” Nucl. Chem. Waste Manage., 4, 201 (1983).
   Google Scholar
• R. M. WALLACE and G. G. WICKS, “Leaching Chemistry of Defense Borosilicate Glass,” Scientific Basis for Nuclear Waste Management, Vol. VI, p. 23, D. G. BROOKINS, Ed., North-Holland Publishing Company (1982).
   Google Scholar
• M. J. PLODINEC, C. J. JANTZEN, and G. G. WICKS, “A Thermodynamic Approach to Prediction of the Stability of Proposed Radwaste Glasses,” DP-MS-82-66, Savannah River Laboratory (1982).
   Google Scholar
• B. GRAMBOW, “The Role of Metal Ion Solubility in the Leaching of Nuclear Waste Glasses,” Scientific Basis for Nuclear Waste Management, Vol. V, p. 93, W. LUTZE, Ed., North-Holland Publishing Company (1982).
   Google Scholar
• P. L. CHAMBRÉ, T. H. PIGFORD, A. FUJITA, T. KANKI, R. KOBAYASHI, H. LUNG, D. TING, Y. SATO, and S. J. ZAVOSHY, “Analytical Performance Models for Geologic Repositories,” LBL-14842, Lawrence Berkeley Laboratory, University of California (1982).
   Google Scholar
• P. B. MACEDO, A. BARKATT, and J. H. SIMMONS, “A Flow Model for the Kinetics of Dissolution of Nuclear Waste Glasses,” Nucl. Chem. Waste Manage., 3, 13 (1982).
   Google Scholar
• A. BARKATT, P. B. MACEDO, W. SOUSANPOUR, A. O. BARKATT, M. A. BOROOMAND, C. F. FISHER, J. J. SHIRRON, P. SZOKE, and V. L. ROGERS, “The Use of a Flow Test and a Flow Model in Evaluating the Durability of Various Nuclear Waste-Form Materials,” Nucl. Chem. Waste Manage., 4, 153 (1983).
   Google Scholar
• A. E. HUGHES, J. A. C. MARPLES, and A. M. STONEHAM, “The Significance of Leach Rates in Determining the Release of Radioactivity from Vitrified Nuclear Waste,” Nucl. Technol., 61, 496 (1983).
   Web of Science ®Google Scholar
• C. J. MONTROSE, P. B. MACEDO, and A. BARKATT, “Phenomenological Models of Nuclear Waste Glass Leaching,” Nucl. Technol. (to be published).
   Google Scholar
• A. BARKATT, W. SOUSANPOUR, A. O. BARKATT, M. A. BOROOMAND, and P. B. MACEDO, “Leach Behavior of SRL TDS-131 Defense Waste Glass in Water at High/Low Flow Rates,” Scientific Basis for Nuclear Waste Management, Vol. VII, p. 643, G. L. McVAY, Ed., North-Holland Publishing Company (1984).
   Google Scholar
• M.J. APTED and R. ADIGA, “The Role of Ground-Water Flow in Determining Release Rate Behavior of Borosilicate Glass,” Scientific Basis for Nuclear Waste Management, Vol. VIII, C. M. JANTZEN, J. A. STONE, and R. C. EWING, Eds., North-Holland Publishing Company (1985).
   Google Scholar
• A. BARKATT, P. B. MACEDO, W. SOUSANPOUR, A. O. BARKATT, M. A. BOROOMAND, V. L. ROGERS, A. NAZARI, G. PIMENOV, and J. J. SHIRRON, “Leach Mechanisms of Borosilicate Glass Defense Waste Forms—Effects of Composition,” Waste Management ’84, Vol. 1, p. 627, Arizona Board of Regents, Tucson, Arizona (1984).
   Google Scholar
• M. J. APTED, “Overview of Hydrothermal Testing of Waste Package Barrier Materials at the Basalt Waste Isolation Project,” Proc. Workshop on Leaching Mechanisms of Nuclear Waste Forms, Gaithersburg, Maryland, May 19–21, 1982, PNL-4382, J. E. MENDEL, Ed., Pacific Northwest Laboratory (1982).
   Google Scholar
• A. BARKATT, P. B. MACEDO, W. SOUSANPOUR, M. A. BOROOMAND, P. SZOKE, and V. L. ROGERS, “Aluminosilicate Saturation as a Solubility Control in Leaching of Nuclear Waste-Form Materials,” Proc. Workshop on Leaching Mechanisms of Nuclear Waste Forms, Gaithersburg, Maryland, May 19–21, 1982, PNL-4382, p. 20, J. E. MENDEL, Ed., Pacific Northwest Laboratory (1982).
   Google Scholar
• J. K. BATES and M. J. STEINDLER, “Alteration of Nuclear Waste Glass by Hydration,” Scientific Basis for Nuclear Waste Management, Vol. VI, p. 83, D. G. BROOKINS, Ed., North-Holland Publishing Company (1983).
   Google Scholar
• A. B. HARKER and J. F. FLINTOFF, “Mechanisms of Enhanced Dissolution in Nuclear Waste Glasses,” Scientific Basis for Nuclear Waste Management, Vol. VIII, C. M. JANTZEN, J. A. STONE, and R. C. EWING, North-Holland Publishing Company (1985).
   Google Scholar
• A. BARKATT, B. C. GIBSON, and M. BRANDYS, “Kinetic Model of Nuclear Waste Glass Dissolution in Flowing Water Environments,” Scientific Basis for Nuclear Waste Management, Vol. VIII, C. M. JANTZEN, J. A. STONE, and R. C. EWING, Eds., North-Holland Publishing Company (1985).
   Google Scholar
• W. J. GRAY, G. L. McVAY, J. O. BARNER, J. W. SHADE, and R. W. COTE, “Evaluation of Spent Fuel as a Waste Form in a Salt Repository,” Scientific Basis for Nuclear Waste Management, Vol. VII, p. 437, G. L. McVAY, Ed., North-Holland Publishing Company (1984).
   Google Scholar
• W. P. FREEBORN, B. E. SCHEETZ, and W. B. WHITE, “The Role of Boron in Monitoring the Leaching of Borosilicate Glass Waste Forms,” Scientific Basis for Nuclear Waste Management, Vol. VIII, C. M. JANTZEN, J. A. STONE, and R. C. EWING, Eds., North-Holland Publishing Company (1985).
   Google Scholar
• M. J. PLODINEC, G. G. WICKS, and N. E. BIBLER, “An Assessment of Savannah River Borosilicate Glass in the Repository Environment,” DP-1629, Savannah River Laboratory (1982).
   Google Scholar
• W. A. ROSS, J. H. WESTSIK, Jr., F. P. ROBERTS, and C. O. HARVEY, “Comparative Leach Testing of Alternative Transuranic Waste Forms,” Bull. Am. Ceram. Soc., 62, 1026, 1035 (1983).
   Google Scholar
• P. K. SMITH and C. A. BAXTER, “Fracture During Cooling of Cast Borosilicate Glass Containing Nuclear Wastes,” DP-1602, Savannah River Laboratory (1981).
   Google Scholar
• “Interim Reference Repository Conditions for a Nuclear Waste Repository in Basalt,” NWTS-16, The Reference Repository Conditions Interface Working Group, Office of Nuclear Waste Isolation (1981).
   Google Scholar
• A. BARKATT et al., “Mechanisms of Defense Waste Glass Dissolution,” Nucl. Technol., 73, 140 (1986).
   Web of Science ®Google Scholar
• P. B. MACEDO and A. BARKATT, “Evaluation of Bulk Properties of Radwaste Glass and Ceramic Container Materials to Determine Long-Term Stability,” NUREG/CR-2737, U.S. Nuclear Regulatory Commission (1982).
   Google Scholar
• T. E. JONES, “Reference Material Chemistry-Synthetic Ground Water Formulation,” RHO-BW-ST-37 P, Rockwell Han ford Operations (1982).
   Google Scholar
• G. L. McVAY, “A Review of Recent PNL Research Activities Related to Glass Leaching Mechanism,” Proc. Workshop on the Leaching Mechanisms of Nuclear Waste Forms, Gaithersburg, Maryland, May 19–21, 1982, PNL-4382, p. 74, Pacific Northwest Laboratory (1982).
   Google Scholar
• G. L. McVAY, submitted to Nucl. Technol.
   Google Scholar