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Research Article

Preparation and characterisation of multilayer films and microcapsules containing poly(N-isopropylacrylamide-co-sodium vinylsulphonate) and applicability on controlled release

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Pages 93-101 | Received 31 Jan 2012, Accepted 28 May 2012, Published online: 03 Jul 2012

References

  • Chen GH, Hoffman AS. Temperature-induced phase transition behaviors of random vs graft copolymers of N-isopropylacrylamide and acrylic acid. Macromol Rapid Commun 1995; 16(3)175–82
  • Chilklis CK, Grasshoff JM. Swelling of thin films. I. acrylamide-N-isopropylacrylamide copolymers in water. J Polym Sci Part A-2: Polym Phys 1970; 8: 1617–26
  • Decher G, Hong JD. Buildup of ultrathin multilayer films by a self-assembly process: II. Consecutive adsorption of anionic and cationic bipolar amphiphiles and polyelectrolytes on charged surfaces. Ber Bunsen Ges Phys Chem 1991; 95(11)1430–34
  • Didymus JM, Oliver P, Mann S. Influence of low molecular weight and macromolecular organic additives on the morphology of calcium carbonate. J Chem Soc, Faraday Trans 1993; 89(15)2891–900
  • Díez-Peña E, Quijada-Garrido I, Barrales-Rienda JM, Wilhelm M, Spiess HW. NMR studies of the structure and dynamics of polymer gels based on N-isopropylacrylamide (NiPAAm) and methacrylic acid (MAA). Macromol Chem Phys 2002; 203(3)491–502
  • Gao CY, Chen B, Möhwald H. Thermo-sensitive poly(allylamine)-g-poly(N-isopropylacrylamide) copolymers: Salt-tuned phase separation, particle formation and their applicability on curved surface. Colloids Surf A 2006; 272(3)203–10
  • Gao CY, Möhwald H, Shen JC. Thermo-sensitive poly(allylamine)-g-poly(N-isopropylacrylamide): Synthesis, phase separation and particle formation. Polymer 2005; 46(12)4088–97
  • Gao YX, Ji XM, Yin YH, Dong H, Zheng H. Poly(N-isopropylacrylamide), poly(methacrylic acid) and their copolymers for oral colon-specific drug delivery. J Wuhan Univ Technol Mater Sci Ed 2009; 24(4)571–4
  • Griffiths PC, Alexander C, Nilmini R, Pennadam SS, King SM, Heenan RK. Physicochemical characterization of thermoresponsive poly(N-isopropylacrylamide)-poly(ethylene imine) graft copolymers. Biomacromolecules 2008; 9(4)1170–8
  • Heskins M, Guillet JE. Solution properties of poly(N-isopropylacrylamide). J Macromol Sci Part A Pure Appl Chem 1968; A2(8)1441–55
  • Hong JD, Schmitt J. Buildup of ultrathin multilayer films by a self-assembly process: III. Consecutively alternating adsorption of anionic and cationic polyelectrolytes on charged surfaces. Thin Solid Films 1992; 210–211(2)831–5
  • Jaber JA, Schlenoff JB. Polyelectrolyte multilayers with reversible thermal responsivity. Macromolecules 2005; 38: 1300–6
  • Jones MS. Effect of pH on the lower critical solution temperatures of random copolymers of N-isopropylacrylamide and acrylic acid. Eur Polym J 1999; 35(5)795–801
  • Kato T, Suzuki T, Amamiya T, Irie T, Komiyama M. Effects of macromolecules on the crystallization of CaCO3 the formation of organic/inorganic composites. Supramol Sci 1998; 5(3–4)411–15
  • Kwak D, Han JT, Lee JH, Lim HS, Lee DH, Cho K. Face control of thermo-responsive wettability through an all-electrostatic self-assembling process. Surf Sci 2008; 602: 3100–5
  • Lu CH, Wei F, Wu NZ, Zhao XS, Luo CQ, Cao WX. Micropatterned self-assembled film based on temperature-responsive poly(N-isopropylacrylamide-co-acrylic acid). J Colloid Interface Sci 2004; 277: 172–5
  • Schild HG. Poly(N-isopropylacrylamide): Experiment, theory and application. Prog Polym Sci 1992; 17(2)163–249
  • Schilli CM, Zhang MF, Rizzardo E, Thang SH, Chong YK, Edwards K, Karlsson G, Muller AHE. A new double-responsive block copolymer synthesized via RAFT polymerization: Poly(N-isopropylacrylamide)-block-poly(acrylic acid). Macromolecules 2004; 37(21)7861–6
  • Serpe M, Jones C, Lyon L. Layer-by-layer deposition of thermoresponsive microgel thin films. Langmuir 2003; 19(21)8759–64
  • Tian P, Wu QL, Lian K. Preparation of temperature- and pH-sensitive, stimuli-responsive poly(N-isopropylacrylamide-co-methacrylic acid) nanoparticles. J Appl Polym Sci 2007; 108(4)2226–32
  • Wang F, Feng J, Tong WJ, Gao ChY. A facile pathway to fabricate microcapsules by in situ polyelectrolyte coacervation on poly(styrene sulfonate)-doped CaCO3 particles. J Mater Chem 2007; 17: 670–6
  • Wang F, Li LH, Gao CY. Poly(allylamine)-graft-poly(N-isopropylacrylamide)/poly(styrene sulfonate) sodium salt multilayers: Buildup, wettability, and mechanical properties. Macromol Chem Phys 2009; 210(23)2022–8
  • Yang CM, Cheng YL. RAFT synthesis of poly(N-isopropylacrylamide) and poly(methacrylic acid) homopolymers and block copolymers: Kinetics and characterization. J Appl Polym Sci 2006; 102(2)1191–201
  • Zavgorodnya O, Serpe MJ. Assembly of poly(N-isopropylacrylamide)-co-acrylic acid microgel thin films on polyelectrolyte multilayers: Effects of polyelectrolyte layer thickness, surface charge, and microgel solution pH. Colloid Polym Sci 2011; 289: 591–602

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