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Review

Microextraction in Urine Samples for Gas Chromatography: A Review

, &
Pages 2663-2684 | Published online: 20 Nov 2014

References

  • Stanley SMR , FooHC. Screening for basic drugs in equine urine using direct-injection differential-gradient LC–LC coupled to hybrid tandem MS/MS. J. Chromatogr. B836 (1–2), 1–14 (2006).
  • Jiménez C , TorreRdl, VenturaM, SeguraJ, VenturaR. Stability studies of amphetamine and ephedrine derivatives in urine. J. Chromatogr. B843 (1), 84–93 (2006).
  • Gan SH , IsmailR. Validation of a high-performance liquid chromatography method for tramadol and o-desmethyltramadol in human plasma using solid-phase extraction. J. Chromatogr. B759 (2), 325–335 (2001).
  • Ahmadi-Jouibari T , FattahiN, ShamsipurM, PirsahebM. Dispersive liquid-liquid microextraction followed by high-performance liquid chromatography-ultraviolet detection to determination of opium alkaloids in human plasma. J. Pharm. Biomed. Anal. 85, 14–20 (2013).
  • Ahmadi-Jouibari T , FattahiN, ShamsipurM. Rapid extraction and determination of amphetamines in human urine samples using dispersive liquid–liquid microextraction and solidification of floating organic drop followed by high performanceliquid chromatography. J. Pharm. Biomed. Anal. 94, 145–151 (2014).
  • Rezaee M , AssadiY, MillaniMR, AghaeeE, AhmadiF, BerijaniS. Determination of organic compounds in water using dispersive liquid–liquid microextraction. J. Chromatogr. A1116 (1–2), 1–9 (2006).
  • Regueiro J , LlompartM, Garcia-JaresC, Garcia-MonteagudoJC, CelaR. Ultrasound-assisted emulsification–microextraction of emergent contaminants and pesticides in environmental waters. J. Chromatogr. A1190 (1–2), 27–38 (2008).
  • Moradi M , YaminiY, EsrafiliA, SeidiS. Application of surfactant assisted dispersive liquid–liquid microextraction for sample preparation of chlorophenols in water samples. Talanta82 (5), 1864–1869 (2010).
  • Saleh A , YaminiY, FarajiM, RezaeeM, GhambarianM. Ultrasound-assisted emulsification microextraction method based on applying low density organic solvents followed by gas chromatography analysis for the determination of polycyclic aromatic hydrocarbons in water samples. J. Chromatogr. A1216 (39), 6673–6679 (2009).
  • Mashayekhi HA , RezaeeM. Determination of ecstasy components in human urine by gas chromatography using a dispersive liquid–liquid microextraction procedure. Talanta J. Braz. Chem. Soc. 23 (9), 1698–1703 (2012).
  • Cunha SC , FernandesJO. Quantification of free and total bisphenol A and bisphenol B in human urine by dispersive liquid–liquid microextraction (DLLME) and heart-cutting multidimensional gas chromatography–mass spectrometry (MD–GC/MS). Talanta83 (1), 117–125 (2010).
  • Ito R , UshiroM, TakahashiYet al. Improvement and validation the method using dispersive liquid–liquid microextraction with in situ derivatization followed by gas chromatography–mass spectrometry for determination of tricyclic antidepressants in human urine samples. J. Chromatogr. B879 (31), 3714–3720 (2011).
  • Mudiam MKR , ChauhanA, JainRet al. Development, validation and comparison of two microextraction techniques for the rapid and sensitive determination of pregabalin in urine and pharmaceutical formulations after ethyl chloroformate derivatization followed by gas chromatography–mass spectrometric analysis. J. Pharm. Biomed. Anal. 70, 310–319 (2012).
  • Mudiam MKR , RatnasekharC. Ultra sound assisted one step rapid derivatization and dispersive liquid–liquid microextraction followed by gas chromatography–mass spectrometric determination of amino acids in complex matrices. J. Chromatogr. A1291, 10–18 (2013).
  • Mudiam MKR , ChR, ChauhanA, ManickamN, JainR, MurthyRC. Optimization of UA-DLLME by experimental design methodologies for the simultaneous determination of endosulfan and its metabolites in soil and urine samples by GC–MS. Anal. Methods4 (11), 3855–3863 (2012).
  • Shamsipur M , NaseriMT, BabriM. Quantification of candidate prostate cancer metabolite biomarkers in urine using dispersive derivatization liquid–liquid microextraction followed by gas and liquid chromatography–mass spectrometry. J. Pharm. Biomed. Anal. 81–82, 65–75 (2013).
  • Ghobadi M , YaminiY, EbrahimpourB. SPE coupled with dispersive liquid–liquid microextraction followed by GC with flame ionization detection for the determination of ultra-trace amounts of benzodiazepines. J. Sep. Sci. 37 (3), 287–294 (2014).
  • Djozan D , FarajzadehMA, SorouraddinSM, BaheriT. Molecularly imprinted-solid phase extraction combined with simultaneous derivatization and dispersive liquid–liquid microextraction for selective extraction and preconcentration of methamphetamine and ecstasy from urine samples followed by gas chromatography. J. Chromatogr. A1248, 24–31 (2012).
  • Mudiam MKR , ChauhanA, SinghKPet al. Determination of t, t-muconic acid in urine samples using a molecular imprinted polymer combined with simultaneous ethyl chloroformate derivatization and pre-concentration by dispersive liquid–liquid microextraction. Anal. Bioanal. Chem. 405 (1), 341–349 (2013).
  • Seidi S , YaminiY, RezazadehM. Combination of electromembrane extraction with dispersive liquid–liquid microextraction followed by gas chromatographic analysis as a fast and sensitive technique for determination of tricyclic antidepressants. J. Chromatogr. B913–914, 138–146 (2013).
  • Xu L , BasheerC, LeeHK. Developments in single-drop microextraction. J. Chromatogr. A1152, 184–192 (2007).
  • Yangcheng L , QuanL, GuangshengL, YouyuanD. Directly suspended droplet microextraction. Anal. Chim. Acta566 (2), 259–264 (2006).
  • Fakhari AR , TabaniH, NojavanS. Immersed single-drop microextraction combined with gas chromatography for the determination of sufentanil and alfentanil in urine and wastewater samples. Anal. Methods3 (4), 951–956 (2011).
  • Sarafraz Yazdi A , RazaviN. Separation and determination of amitriptyline and nortriptyline in biological samples using single-drop microextraction with GC. Chromatographia73 (5–6), 549–557 (2011).
  • Kardani F , DaneshfarA, SahraiR. Determination of nicotine, anabasine, and cotinine in urine and saliva samples using single-drop microextraction. J. Chromatogr. B878 (28), 2857–2862 (2010).
  • Fiamegos YC , StalikasCD. In-drop derivatisation liquid-phase microextraction assisted by ion-pairing transfer for the gas chromatographic determination of phenolic endocrine disruptors. Anal. Chim. Acta597 (1), 32–40 (2007).
  • Fiamegos YC , NanosCG, StalikasCD. Ultrasonic-assisted derivatization reaction of amino acids prior to their determination in urine by using single-drop microextraction in conjunction with gas chromatography. J. Chromatogr. B813 (1–2), 89–94 (2004).
  • Agrawal K , WuHF. Drop-to-drop solvent microextraction coupled with gas chromatography/mass spectrometry for rapid determination of trimeprazine in urine and blood of rats: application to pharmacokinetic studies. Rapid. Commun. Mass Spectrom. 21 (20), 3352–3356 (2007).
  • Liu BM , MalikP, WuHF. Single-drop microextraction and gas chromatography/mass spectrometric determination of anisaldehyde isomers in human urine and blood serum. Rapid Commun. Mass Spectrom. 18 (18), 2059–2064 (2004).
  • Fiamegos YC , StalikasCD. Gas chromatographic determination of carbonyl compounds in biological and oil samples by headspace single-drop microextraction with in-drop derivatisation. Anal. Chim. Acta609 (2), 175–183 (2008).
  • Hu M , ChenH, JiangY, ZhuH. Headspace single-drop microextraction coupled with gas chromatography electron capture detection of butanone derivative for determination of iodine in milk powder and urine. Chem. Pap. 67 (10), 1255–1261 (2013).
  • Saraji M , MehrafzaN, Hajialiakbari BidgoliAA, JafariMT. Determination of desipramine in biological samples using liquid–liquid–liquid microextraction combined with in-syringe derivatization, gas chromatography, and nitrogen/phosphorus detection. J. Sep. Sci. 35 (19), 2637–2644 (2012).
  • Chiang JS , HuangSD. Simultaneous derivatization and extraction of amphetamine and methylenedioxyamphetamine in urine with headspace liquid-phase microextraction followed by gas chromatography–mass spectrometry. J. Chromatogr. A1185 (1), 19–22 (2008).
  • Zhurba OM , AlekseenkoAN. Gas-chromatographic determination of thiodiglycolic acid in urine using derivatization and liquid microextraction. J. Anal. Chem. 68 (9), 809–814 (2013).
  • Rezaee M , MashayekhiHA, GarmaroudiSS. Simultaneous determination of amphetamine and related compounds in human urine using ultrasound-assisted emulsification microextraction and gas chromatography. Anal. Methods4 (10), 3212–3218 (2012).
  • Anizan S , BichonE, MonteauF, CesbronN, AntignacJP, Le BizecB. A new reliable sample preparation for high throughput focused steroid profiling by gas chromatography–mass spectrometry. J. Chromatogr. A1217 (43), 6652–6660 (2010).
  • Sobhi HR , YaminiY, EsrafiliA, AdibM. Extraction and determination of 2-pyrazoline derivatives using liquid phase microextraction based on solidification of floating organic drop. J. Pharm. Biomed. Anal. 48 (4), 1059–1063 (2008).
  • Sarafraz-Yazdi A , Raouf-YazdinejadS, Es’haghiZ. Directly suspended droplet microextraction and analysis of amitriptyline and nortriptyline by GC. Chromatographia66 (7–8), 613–617 (2007).
  • Pedersen-Bjergaard S , RasmussenKE. Liquid−liquid−liquid microextraction for sample preparation of biological fluids prior to capillary electrophoresis. Anal. Chem. 71 (14), 2650–2656 (1999).
  • Ghambarian M , YaminiY, EsrafiliA. Developments in hollow fiber based liquid-phase microextraction: principles and applications. Microchim. Acta177 (3–4), 271–294 (2012).
  • Ghambarian M , YaminiY, EsrafiliA, YazdanfarN, MoradiM. A new concept of hollow fiber liquid–liquid–liquid microextraction compatible with gas chromatography based on two immiscible organic solvents. J. Chromatogr. A1217, 5652–5658 (2010).
  • Ebrahimpour B , YaminiY, EsrafiliA. Extraction of azole antifungal drugs from milk and biological fluids using a new hollow fiber liquid-phase microextraction and analysis by GC-FID. Chromatographia74 (3–4), 281–289 (2011).
  • Lin CH , YanCT, KumarPV, LiHP, JenJF. Determination of pyrethroid metabolites in human urine using liquid phase microextraction coupled in-syringe derivatization followed by gas chromatography/electron capture detection. Anal. Bioanal. Chem. 401 (3), 927–937 (2011).
  • Ghambarian M , YaminiY, EsrafiliA. Three-phase hollow fiber liquid-phase microextraction based on two immiscible organic solvents for determination of tramadol in urine and plasma samples. J. Pharm. Biomed. Anal. 56 (5), 1041–1045 (2011).
  • Rasmussen KE , Pedersen-BjergaardS, KroghM, UglandHG, Gr⊘nhaugT. Development of a simple in-vial liquid-phase microextraction device for drug analysis compatible with capillary gas chromatography, capillary electrophoresis and high-performance liquid chromatography. J. Chromatogr. A873 (1), 3–11 (2000).
  • Ugland HG , KroghM, RasmussenKE. Liquid-phase microextraction as a sample preparation technique prior to capillary gas chromatographic-determination of benzodiazepines in biological matrices. J. Chromatogr. B749 (1), 85–92 (2000).
  • De Jager LS , AndrewsARJ. Preliminary studies of a fast screening method for cocaine and cocaine metabolites in urine using hollow fibre membrane solvent microextraction (HFMSME). Analyst126 (8), 1298–1303 (2001).
  • Kramer KE , AndrewsARJ. Screening method for 11-nor-Δ9-tetrahydrocannabinol-9-carboxylic acid in urine using hollow fiber membrane solvent microextraction with in-tube derivatization. J. Chromatogr. B760 (1), 27–36 (2001).
  • Lai BW , LiuBM, MalikPK, WuHF. Combination of liquid-phase hollow fiber membrane microextraction with gas chromatography-negative chemical ionization mass spectrometry for the determination of dichlorophenol isomers in water and urine. Anal. Chim. Acta576 (1), 61–66 (2006).
  • Kawaguchi M , ItoR, OkanouchiN, SaitoK, NakazawaH. Miniaturized hollow fiber assisted liquid-phase microextraction with in situ derivatization and gas chromatography-mass spectrometry for analysis of bisphenol A in human urine sample. J. Chromatogr. B870 (1), 98–102 (2008).
  • Ito R , KawaguchiM, HondaHet al. Hollow-fiber-supported liquid phase microextraction with in situ derivatization and gas chromatography–mass spectrometry for determination of chlorophenols in human urine samples. J. Chromatogr. B872 (1–2), 63–67 (2008).
  • Kawaguchi M , ItoR, HondaHet al. Miniaturized hollow fiber assisted liquid-phase microextraction and gas chromatography-mass spectrometry for determination of benzophenone and derivates in human urine sample. J. Chromatogr. B877 (3), 298–302 (2009).
  • Cui S , TanS, OuyangG, PawliszynJ. Automated polyvinylidene difluoride hollow fiber liquid-phase microextraction of flunitrazepam in plasma and urine samples for gas chromatography/tandem mass spectrometry. J. Chromatogr. A1216 (12), 2241–2247 (2009).
  • Prichodko A , JonusaiteK, VickackaiteV. Hollow fibre liquid phase microextraction of parabens. Cent. Eur. J. Chem. 7 (3), 285–290 (2009).
  • Ito R , KawaguchiM, KoganeiYet al. Development of miniaturized hollow-fiber assisted liquid-phase microextraction with in situ acyl derivatization followed by gc–MS for the determination of benzophenones in human urine samples. Anal. Sci. 25 (8), 1033–1037 (2009).
  • Xiao Q , HuB. Hollow fiber-liquid phase microextraction combined with gas chromatography for the determination of phenothiazine drugs in urine. J. Chromatogr. B878 (19), 1599–1604 (2010).
  • Xiong J , ChenJ, HeM, HuB. Simultaneous quantification of amphetamines, caffeine and ketamine in urine by hollow fiber liquid phase microextraction combined with gas chromatography-flame ionization detector. Talanta82 (3), 969–975 (2010).
  • Leinonen A , VuorensolaK, LepolaLMet al. Liquid-phase microextraction for sample preparation in analysis of unconjugated anabolic steroids in urine. Anal. Chim. Acta559 (2), 166–172 (2006).
  • Wang X , LiuJ, WangY, ZhaoX, GaoL, XuD. Hollow fiber liquid phase microextraction of tramadol from water and biological samples. Chin. J. Chromatogr. 24 (6), 641–644 (2006).
  • Saraji M , BoroujeniMK. Analysis of narcotic drugs in biological samples using hollow fiber liquid-phase microextraction and gas chromatography with nitrogen phosphorus detection. Microchim. Acta174 (1), 159–166 (2011).
  • Fakhari AR , TabaniH, NojavanS. Miniaturized hollow fibre assisted liquid-phase microextraction and gas chromatography for determination of trace concentration of sufentanil and alfentanil in biological samples. Drug Test Anal. 5 (7), 589–595 (2013).
  • Rasmussen KE , Pedersen-BjergaardS. Developments in hollow fibre-based, liquid-phase microextraction. Trends Anal. Chem. 23 (1), 1–10 (2004).
  • Pedersen-Bjergaard S , RasmussenKE. Electrokinetic migration across artificial liquid membranes: new concept for rapid sample preparation of biological fluids. J. Chromatogr. A1109 (2), 183–190 (2006).
  • Hosseiny Davarani SS , Morteza-NajarianA, NojavanS, PourahadiA, Beigzadeh AbbassiM. Two-phase electromembrane extraction followed by gas chromatography–mass spectrometry analysis. J. Sep. Sci. 36 (4), 736–743 (2013).
  • Gjelstad A , JensenH, RasmussenKE, Pedersen-BjergaardS. Kinetic aspects of hollow fiber liquid-phase microextraction and electromembrane extraction. Anal. Chim. Acta742, 10–16 (2012).
  • Rezazadeh M , YaminiY, SeidiS, EbrahimpourB. Electromembrane surrounded solid phase microextraction: A novel approach for efficient extraction from complicated matrices. J. Chromatogr. A1280, 16–22 (2013).
  • Jiang X , LeeHK. Solvent bar microextraction. Anal. Chem. 76 (18), 5591–5596 (2004).
  • Ghasemi E . Optimization of solvent bar microextraction combined with gas chromatography mass spectrometry for preconcentration and determination of tramadol in biological samples. J. Chromatogr. A1251, 48–53 (2012).
  • Liu W , ZhangL, FanLet al. An improved hollow fiber solvent-stir bar microextraction for the preconcentration of anabolic steroids in biological matrix with determination by gas chromatography–mass spectrometry. J. Chromatogr. A1233, 1–7 (2012).
  • Huang G , LiHF, ZhangBT, MaY, LinJM. Vortex solvent bar microextraction for phthalate esters from aqueous matrices. Talanta100, 64–70 (2012).
  • Hu Y , WangY, HuY, LiG. Liquid–liquid–solid microextraction based on membrane-protected molecularly imprinted polymer fiber for trace analysis of triazines in complex aqueous samples. J. Chromatogr. A1216 (47), 8304–8311 (2009).
  • Sarafraz-Yazdi A , AmiriA, RounaghiG, Eshtiagh-HosseiniH. Determination of non-steroidal anti-inflammatory drugs in urine by hollow-fiber liquid membrane-protected solid-phase microextraction based on sol-gel fiber coating. J. Chromatogr. B908, 67–75 (2012).
  • Ghambarian M , YaminiY, EsrafiliA. Three-phase hollow fiber microextraction based on two immiscible organic solvents for determination of tricyclic antidepressant drugs: comparison with conventional three-phase hollow fiber microextraction. J. Chromatogr. A1222, 5–12 (2012).
  • Liu W , ZhangL, WeiZ, ChenS, ChenG. Analysis of β-agonists and β-blockers in urine using hollow fibre-protected liquid-phase microextraction with in situ derivatization followed by gas chromatography/mass spectrometry. J. Chromatogr. A1216 (28), 5340–5346 (2009).
  • Malecky M , BroudiscouA, BroudiscouLP. Optimisation of headspace solid-phase microextraction for quantitative analysis of monoterpenes in caprine blood. Anim. Feed Sci. Tech. 173 (3–4), 261–267 (2012).
  • Melo LP , QueirozRHC, QueirozMEC. Automated determination of rifampicin in plasma samples by in-tube solid-phase microextraction coupled with liquid chromatography. J. Chromatogr. B879 (24), 2454–2458 (2011).
  • Naccarato A , GionfriddoE, SindonaG, TagarelliA. Simultaneous determination of benzothiazoles, benzotriazoles and benzosulfonamides by solid phase microextraction-gas chromatography-triple quadrupole mass spectrometry in environmental aqueous matrices and human urine. J. Chromatogr. A1338, 164–173 (2014).
  • Emídio ES , PrataVdeM, DóreaHS. Validation of an analytical method for analysis of cannabinoids in hair by headspace solid-phase microextraction and gas chromatography–ion trap tandem mass spectrometry. Anal. Chim. Acta670 (1–2), 63–71 (2010).
  • Yu H , XuL, WangP. Solid phase microextraction for analysis of alkanes and aromatic hydrocarbons in human breath. J. Chromatogr. B826 (1–2), 69–74 (2005).
  • Ho TD , CanestraroAJ, AndersonJL. Ionic liquids in solid-phase microextraction. Anal. Chim. Acta695 (1–2), 18–43 (2011).
  • Wu J , MullettWM, PawliszynJ. Electrochemically controlled solid-phase microextraction based on conductive polypyrrole films. Anal. Chem. 74 (18), 4855–4859 (2002).
  • Bagheri H , AyaziZ, NaderiM. Conductive polymer-based microextraction methods. Anal. Chim. Acta767 (12), 1–13 (2013).
  • Centini F , MastiA, CompariniIB. Quantitative and qualitative analysis of MDMA, MDEA, MA and amphetamine in urine by head-space/solid phase micro-extraction (SPME) and GC/MS. Forensic Sci. Int. 83 (3), 161–166 (1996).
  • Zachariadis GA , RosenbergE. Determination of butyl- and phenyltin compounds in human urine by HS-SPME after derivatization with tetraethylborate and subsequent determination by capillary GC with microwave-induced plasma atomic emission and mass spectrometric detection. Talanta78 (2), 570–576 (2009).
  • Kapsimali DC , ZachariadisGA. Headspace and direct immersion solid phase microextraction procedures for selenite determination in urine, saliva and milk by gas chromatography mass spectrometry. J. Chromatogr. B877 (27), 3210–3214 (2009).
  • Zachariadis GA , KapsimaliDC. Effect of sample matrix on sensitivity of mercury and methylmercury quantitation in human urine, saliva, and serum using GC-MS. J. Sep. Sci. 31 (22), 3884–3894 (2008).
  • Wu JC , PawliszynJ. Preparation and applications of polypyrrole films in solid-phase microextraction. J. Chromatogr. A909 (1), 37 (2001).
  • Bagheri H , SarajiM. New polymeric sorbent for the solid-phase extraction of chlorophenols from water samples followed by gas chromatography–electron-capture detection. J. Chromatogr. A910 (1), 87–93 (2001).
  • Wu J , YuX, LordH, PawliszynJ. Solid phase microextraction of inorganic anions based on polypyrrole film. Analyst125 (3), 391 (2000).
  • Wu J , LordHL, PawliszynJ, KataokaH. Polypyrrole-coated capillary in-tube solid phase microextraction coupled with liquid chromatography–electrospray ionization mass spectrometry for the determination of β-blockers in urine and serum samples. J. Microcolumn Sep. 12 (4), 255 (2000).
  • Lin YH , CuiXL, BonthaJR. Electrically controlled anion exchange based on polypyrrole and carbon nanotubes nanocomposite for perchlorate removal. Environ. Sci. Technol. 40 (12), 4004–4009 (2006).
  • Huang MJ , TaiC, ZhouQF, JiangGB. Preparation of polyaniline coating on a stainless-steel wire using electroplating and its application to the determination of six aromatic amines using headspace solid-phase microextraction. J. Chromatogr. A1048 (2), 257–262 (2004).
  • Bagheri H , MirA, BabanezhadE. An electropolymerized aniline-based fiber coating for solid phase microextraction of phenols from water. Anal. Chim. Acta532 (1), 89–95 (2005).
  • Lord H , PawliszynJ. Evolution of solid-phase microextraction technology. J. Chromatogr. A885 (1–2), 153–193 (2000).
  • Ugland HG , KroghM, RasmussenKE. Aqueous alkylchloroformate derivatisation and solid-phase microextraction: determination of amphetamines in urine by capillary gas chromatography. J. Chromatogr. B701 (1), 29–38 (1997).
  • M Koster EH , HofmanNSK, De JongGJ. Direct solid-phase microextraction combined with gas and liquid chromatography for the determination of lidocaine in human urine. Chromatographia47 (11–12), 678–684 (1998).
  • Luo Y , PanL, PawliszynJ. Determination of five benzodiazepines in aqueous solution and biological fluids using solid-phase microextraction with carbowaxTM/DVB fiber coating. J. Microcolumn Sep. 10 (2), 193–201 (1998).
  • Mester Z , PawliszynJ. Speciation of dimethylarsinic acid and monomethylarsonic acid by solid-phase microextraction–gas chromatography–ion trap mass spectrometry. J. Chromatogr. A873 (1), 129–135 (2000).
  • Freire IA , BarreraAM, SilvaPC, DuqueMJ, GómezPF, EijoPL. Microwave assisted extraction for the determination of ethyl glucuronide in urine by gas chromatography-mass spectrometry. J. Appl. Toxicol. 28 (6), 773–778 (2008).
  • Chia J , LeeTY, HuangSD. Simple device for the solid-phase microextraction screening of polychlorodibenzo-p-dioxins and polychlorodibenzofurans in heavily contaminated soil samples. Anal. Chim. Acta527 (2), 157–162 (2004).
  • Seidi S , YaminiY. Analytical sonochemistry; developments, applications, and hyphenations of ultrasound in sample preparation and analytical techniques. Cent. Eur. J. Chem. 10 (4), 938–976 (2012).
  • Özcan L , ŞahinM, ŞahinY. Electrochemical preparation of a molecularly lmprinted polypyrrole-modified pencil graphite electrode for determination of ascorbic acid. Sensors8 (9), 5792–5805 (2008).
  • Liu X , WangX, TanFet al. An electrochemically enhanced solid-phase microextraction approach based on molecularly imprinted polypyrrole/multi-walled carbon nanotubes composite coating for selective extraction of fluoroquinolones in aqueous samples. Anal. Chim. Acta727, 26–33 (2012).
  • Yamini Y , SeidiS, RezazadehM. Electrical field-induced extraction and separation techniques: promising trends in analytical chemistry-A review. Anal. Chim. Acta814, 1–22 (2014).
  • Collins CJ , ArriganDWM. A review of recent advances in electrochemically modulated extraction methods. Anal. Bioanal. Chem. 393, 835–845 (2009).
  • Morales-Cid G , CárdenasS, SimonetBM, ValcárcelM. Sample treatments improved by electric fields. Trend. Anal. Chem. 29 (2), 158–165 (2010).
  • Pedersen-Bjergaard S , RasmussenKE. Electrical potential can drive liquid–liquid extraction for sample preparation in chromatography. Trend. Anal. Chem. 27 (10), 934–941 (2008).
  • Kubáň P , ŠlampováA, BočekP. Electric field-enhanced transport across phase boundaries and membranes and its potential use in sample pretreatment for bioanalysis. Electrophoresis31, 768–785 (2010).
  • Deore B , ChenZ, NagaokaT. Potential-induced enantioselective uptake of amino acid into molecularly imprinted overoxidized polypyrrole. Anal. Chem. 72 (17), 3989–3994 (2000).
  • Syritski V , ReutJ, MenakerA, GyurcsányiRE, ÖpikA. Electrosynthesized molecularly imprinted polypyrrole films for enantioselective recognition of l-aspartic acid. Electrochim. Acta53 (6), 2729–2736 (2008).
  • Bianchi F , DugheriS, MusciMet al. Fully automated solid-phase microextraction–fast gas chromatography–mass spectrometry method using a new ionic liquid column for high-throughput analysis of sarcosine and N-ethylglycine in human urine and urinary sediments. Anal. Chim. Acta707 (1–2), 197–203 (2010).
  • Ahmadi F , AsgharlooH, SadeghiS, Gharehbagh-AghababaV, AdibiH. Post-derivatization procedure for determination of hippuric acid after extraction by an automated micro solid phase extraction system and monitoring by gas chromatography. J. Chromatogr. B877 (27), 2945–2951 (2009).
  • De Martinis BS , Martins RuzzeneMA, Santos MartinCC. Determination of ethanol in human blood and urine by automated headspace solid-phase microextraction and capillary gas chromatography. Anal. Chim. Acta522 (2), 163–168 (2004).
  • Wooten JV , AshleyDL, CalafatAM. Quantitation of 2-chlorovinylarsonous acid in human urine by automated solid-phase microextraction–gas chromatography–mass spectrometry. J. Chromatogr. B772 (1), 147–153 (2002).
  • De Martinis BS , MartinCCS. Automated headspace solid-phase microextraction and capillary gas chromatography analysis of ethanol in postmortem specimens. Forensic Sci. Int. 128 (3), 115–119 (2002).
  • Grefslie Ugland H , KroghM, RasmussenKE. Automated determination of ‘Ecstasy’ and amphetamines in urine by SPME and capillary gas chromatography after propylchloroformate derivatization. J. Pharm. Biomed. Anal. 19 (3–4), 463–475 (1999).
  • Ahuja S . Derivatization in gas chromatography. J. Pharm. Sci. 65 (2), 163–182 (1976).
  • Sarrión MN , SantosFJ, GalceranMT. In situ derivatization/solid-phase microextraction for the determination of haloacetic acids in water. Anal. Chem. 72 (20), 4865–4873 (2000).
  • Mattarozzi M , MusciM, CareriMet al. A novel headspace solid-phase microextraction method using in situ derivatization and a diethoxydiphenylsilane fibre for the gas chromatography–mass spectrometry determination of urinary hydroxy polycyclic aromatic hydrocarbons. J. Chromatogr. A1216 (30), 5634–5639 (2009).
  • Zachariadis GA , TzollasNM, NikolaouM, RosenbergE. Storage stability studies for tributyltin determination in human urine samples using headspace solid-phase microextraction and gas chromatography mass spectrometry. Biomed. Chromatogr. 27 (3), 299–305 (2013).
  • Tan TY , BasheerC, Yan AngMJ, LeeHK. Electroenhanced solid-phase microextraction of methamphetamine with commercial fibers. J. Chromatogr. A1297, 12–16 (2013).
  • Sarafraz-Yazdi A , ArdakiMS, AmiriA. Determination of monocyclic aromatic amines using headspace solid-phase microextraction based on sol-gel technique prior to GC. J. Sep. Sci. 36 (9–10), 1629–1635 (2013).
  • Racamonde I , RodilR, QuintanaJB, CelaR. In-sample derivatization-solid-phase microextraction of amphetamines and ecstasy related stimulants from water and urine. Anal. Chim. Acta770, 75–84 (2013).
  • Moreno I , Da FonsecaB, OppolzerDet al. Analysis of Salvinorin A in urine using microextraction in packed syringe and GC–MS/MS. Bioanalysis5 (6), 661–668 (2013).
  • Monteleone M , NaccaratoA, SindonaG, TagarelliA. A reliable and simple method for the assay of neuroendocrine tumor markers in human urine by solid-phase microextraction-gas chromatography–triple quadrupole mass spectrometry. Anal. Chim. Acta759, 66–73 (2013).
  • Campo L , FustinoniS, ConsonniDet al. Urinary carcinogenic 4–6 ring polycyclic aromatic hydrocarbons in coke oven workers and in subjects belonging to the general population: role of occupational and environmental exposure. Int. J. Hyg. Environ. Health217 (2–3), 231–238 (2014).
  • Zachariadis GA , LangioliAV. Headspace solid phase microextraction for terpenes and volatile compounds determination in mastic gum extracts, mastic oil and human urine by GC–MS. Anal. Lett. 45 (9), 993–1003 (2012).
  • Sarafraz-Yazdi A , DizavandiZR, AmiriA. Determination of phenolic compounds in water and urine samples using solid-phase microextraction based on sol-gel technique prior to GC-FID. Anal. Methods4 (12), 4316–4325 (2012).
  • Rastkari N , AhmadkhanihaR, YunesianM. Simultaneous determination of trichloroethylene, perchloroethylene and trichloroacetic acid in human urine using solid-phase microextraction fibre coated with single-walled carbon nanotubes. Int. J. Environ. Anal. Chem. 92 (14), 1650–1665 (2012).
  • Rani S , MalikAK. A novel microextraction by packed sorbent-gas chromatography procedure for the simultaneous analysis of antiepileptic drugs in human plasma and urine. J. Sep. Sci. 35 (21), 2970–2977 (2012).
  • Nielsen K , LauritsenFR, NissiläT, KetolaRA. Rapid screening of drug compounds in urine using a combination of microextraction by packed sorbent and rotating micropillar array electrospray ionization mass spectrometry. Rapid Commun. Mass Spectrom. 26 (3), 297–303 (2012).
  • Mudiam MKR , ChR, JainR, SaxenaPN, ChauhanA, MurthyRC. Rapid and simultaneous determination of twenty amino acids in complex biological and food samples by solid-phase microextraction and gas chromatography–mass spectrometry with the aid of experimental design after ethyl chloroformate derivatization. J. Chromatogr. B Anal. Technol. Biomed. Life Sci. 907, 56–64 (2012).
  • Mochalski P , AgapiouA, StatheropoulosM, AmannA. Permeation profiles of potential urine-borne biomarkers of human presence over brick and concrete. Analyst137 (14), 3278–3285 (2012).
  • Liu Y , XinQ, LiuDet al. The application of HS-SPME-GC/MS in detecting chemical components in giant panda (Ailuropoda melanoleuca) urine. Acta Theriol. Sin. 32 (1), 48–57 (2012).
  • Ebrahimzadeh H , MehdiniaA, KamareiF, MoradiE. A sensitive method for the determination of methadone in biological samples using nano-structured α-carboxy polypyrrol as a sorbent of SPME. Chromatographia75 (3–4), 149–155 (2012).
  • Barnes BB , SnowNH. Analysis of Salvinorin A in plants, water, and urine using solid-phase microextraction-comprehensive two-dimensional gas chromatography–time of flight mass spectrometry. J. Chromatogr. A1226, 110–115 (2012).
  • Zeng J , ZouJ, SongXet al. A new strategy for basic drug extraction in aqueous medium using electrochemically enhanced solid-phase microextraction. J. Chromatogr. A1218 (2), 191–196 (2011).
  • Rani S , KumarA, MalikAK, SinghB. Quantification of tricyclic and nontricyclic antidepressants in spiked plasma and urine samples using microextraction in packed syringe and analysis by LC and GC–MS. Chromatographia74 (3–4), 235–242 (2011).
  • Lee MR , LaiFY, DouJ, LinKL, ChungLW. Determination of trace leaching phthalate esters in water and urine from plastic containers by solid-phase microextraction and gas chromatography–mass spectrometry. Anal. Lett. 44 (4), 676–686 (2011).
  • Kusano M , MendezE, FurtonKG. Development of headspace SPME method for analysis of volatile organic compounds present in human biological specimens. Anal. Bioanal. Chem. 400 (7), 1817–1826 (2011).
  • Koryagina NL , UkolovaES, Savel’EvaEIet al. High-sensitivity determination of 2-chlorovinylarsonous acid in biomedical samples for retrospective detection of exposure to lewisite upon antidotal therapy. Spectroscopy26 (1), 1–10 (2011).
  • Guadagni R , MiragliaN, SimonelliAet al. Solid-phase microextraction-gas chromatography-mass spectrometry method validation for the determination of endogenous substances: urinary hexanal and heptanal as lung tumor biomarkers. Anal. Chim. Acta701 (1), 29–36 (2011).
  • Cui Z , ZhangK, ZhouQ, LiuJ, JiangG. Determination of methyltin compounds in urine of occupationally exposed and general population by in situ ethylation and headspace SPME coupled with GC-FPD. Talanta85 (2), 1028–1033 (2011).
  • Cavaliere B , MacChioneB, MonteleoneM, NaccaratoA, SindonaG, TagarelliA. Sarcosine as a marker in prostate cancer progression: a rapid and simple method for its quantification in human urine by solid-phase microextraction-gas chromatography–triple quadrupole mass spectrometry. Anal. Bioanal. Chem. 400 (9), 2903–2912 (2011).
  • Campo L , FustinoniS, BertazziP. Quantification of carcinogenic 4- to 6-ring polycyclic aromatic hydrocarbons in human urine by solid-phase microextraction gas chromatography–isotope dilution mass spectrometry. Anal. Bioanal. Chem. 401 (2), 625–634 (2011).
  • Bianchi F , DugheriS, MusciMet al. Fully automated solid-phase microextraction-fast gas chromatography-mass spectrometry method using a new ionic liquid column for high-throughput analysis of sarcosine and N-ethylglycine in human urine and urinary sediments. Anal. Chim. Acta707 (1–2), 197–203 (2011).
  • Qiu L , LiuW, HuangM, ZhangL. Preparation and application of solid-phase microextraction fiber based on molecularly imprinted polymer for determination of anabolic steroids in complicated samples. J. Chromatogr. A1217 (48), 7461–7470 (2010).
  • Li X , ZhouH, LiPet al. Rapid detection of methamphetamine in urine by SPME-GC-MS. Chin. J. Forensic Med. 25 (4), 252–254 (2010).
  • Lafay F , VullietE, Flament-WatonMM. Contribution of microextraction in packed sorbent for the analysis of cotinine in human urine by GC–MS. Anal. Bioanal. Chem. 396 (2), 937–941 (2010).
  • Kapsimali DC , ZachariadisGA. Comparison of tetraethylborate and tetraphenylborate for selenite determination in human urine by gas chromatography mass spectrometry, after headspace solid phase microextraction. Talanta80 (3), 1311–1317 (2010).
  • Horst K , RychlikM. Quantification of 1,8-cineole and of its metabolites in humans using stable isotope dilution assays. Mol. Nut. Food Res. 54 (10), 1515–1529 (2010).
  • Dugheri S , PacentiM, TraldiPet al. New automated and high-throughput quantitative analysis of urinary ketones by multifiber exchange-solid phase microextraction coupled to fast gas chromatography/negative chemical-electron ionization/mass spectrometry. J. Autom. Methods Manage. Chem. 2010, 972926 (2010).
  • De Lima Gomes PCF , D’AndreaED, MendesCB, De SiquegMEPB. Determination of benzene, toluene and n-hexane in urine and blood by headspace solid-phase microextration/gas-chromatography for the biomonitoring of occupational exposure. Talanta J. Braz. Chem. Soc. 21 (1), 119–126 (2010).
  • Anizan S , BichonE, MonteauF, CesbronN, AntignacJP, Le BizecB. A new reliable sample preparation for high throughput focused steroid profiling by gas chromatography–mass spectrometry. J. Chromatogr. A1217 (43), 6652–6660 (2010).
  • Zhang Z , DuanH, ZhangL, ChenX, LiuW, ChenG. Direct determination of anabolic steroids in pig urine by a new SPME–GC–MS method. Talanta78 (3), 1083–1089 (2009).
  • Sobus JR , WaidyanathaS, McCleanMDet al. Urinary naphthalene and phenanthrene as biomarkers of occupational exposure to polycyclic aromatic hydrocarbons. Occup. Environ. Med. 66 (2), 99–104 (2009).
  • Rossella F , CampoL, PavanelloS, KapkaL, SiwinskaE, FustinoniS. Urinary polycyclic aromatic hydrocarbons and monohydroxy metabolites as biomarkers of exposure in coke oven workers. Occup. Environ. Med. 66 (8), 509–516 (2009).
  • Raikos N , TheodoridisG, AlexiadouEet al. Analysis of anaesthetics and analgesics in human urine by headspace SPME and GC. J. Sep. Sci. 32 (7), 1018–1026 (2009).
  • Oliveira AFF , MaiaPP, PaivaMJN, SiqueiraMEPB. Determination of 2,5-hexanedione in urine by headspace solid-phase microextraction and gas chromatography. J. Anal. Toxicol. 33 (4), 223–228 (2009).
  • Kwak J , OpiekunMC, MatsumuraK, PretiG, YamazakiK, BeauchampGK. Major histocompatibility complex-regulated odortypes: peptide-free urinary volatile signals. Physiol. Behav. 96 (1), 184–188 (2009).
  • Kapsimali DC , ZachariadisGA. Headspace and direct immersion solid phase microextraction procedures for selenite determination in urine, saliva and milk by gas chromatography mass spectrometry. J. Chromatogr. B Anal. Technol. Biomed. Life Sci. 877 (27), 3210–3214 (2009).
  • He Y , PohlJ, EngelR, RothmanL, ThomasM. Preparation of ionic liquid based solid-phase microextraction fiber and its application to forensic determination of methamphetamine and amphetamine in human urine. J. Chromatogr. A1216 (24), 4824–4830 (2009).
  • Campo L , MercadanteR, RossellaF, FustinoniS. Quantification of 13 priority polycyclic aromatic hydrocarbons in human urine by headspace solid-phase microextraction gas chromatography–isotope dilution mass spectrometry. Anal. Chim. Acta631 (2), 196–205 (2009).
  • Bueno M , PannierF. Quantitative analysis of volatile selenium metabolites in normal urine by headspace solid phase microextraction gas chromatography–inductively coupled plasma mass spectrometry. Talanta78 (3), 759–763 (2009).
  • Zachariadis GA , KapsimaliDC. Effect of sample matrix on sensitivity of mercury and methylmercury quantitation in human urine, saliva, and serum using GC-MS. J. Sep. Sci. 31 (22), 3884–3893 (2008).
  • Pacenti M , DugheriS, VillanelliFet al. Determination of organic acids in urine by solid-phase microextraction and gas chromatography-ion trap tandem mass spectrometry previous ‘in sample’ derivatization with trimethyloxonium tetrafluoroborate. Biomed. Chromatogr. 22 (10), 1155–1163 (2008).
  • Netto DC , ReisRM, MendesCB, GomesPCFL, MartinsI, SiqueiraMEPB. Headspace solid-phase microextraction procedure for gas-chromatography analysis of toluene in urine. Talanta J. Braz. Chem. Soc. 19 (6), 1201–1206 (2008).
  • Jun Hj , LeeKG, LeeYK, WooGJ, ParkYS, LeeSJ. Correlation of urinary furan with plasma γ-glutamyltranspeptidase levels in healthy men and women. Food Chem. Toxicol. 46 (5), 1753–1759 (2008).
  • Heidari HR , ShahtaheriSJ, GolbabaeiF, AlimohammadiM, Rahimi-FroushaniA. Optimization of headspace solid phase microextraction procedure for trace analysis of toluene. Int. J. Occup. Saf. Ergonomics14 (4), 395–405 (2008).
  • Scibetta L , CampoL, MercadanteR, FoàV, FustinoniS. Determination of low level methyl tert-butyl ether, ethyl tert-butyl ether and methyl tert-amyl ether in human urine by HS-SPME gas chromatography/mass spectrometry. Anal. Chim. Acta581 (1), 53–62 (2007).
  • Matin AA , MalekiR, FarajzadehMA, FarhadiK, HosseinzadehR, JouybanA. Headspace SPME-GC method for acetone analysis and its biomedical application. Chromatographia66 (5–6), 383–387 (2007).
  • Li N , DengC, ZhangX. Determination of methylmalonic acid and glutaric acid in urine by aqueous-phase derivatization followed by headspace solid-phase microextraction and gas chromatography-mass spectrometry. J. Sep. Sci. 30 (2), 266–271 (2007).
  • Karačonji IB , SkenderL. Comparison between dynamic headspace and headspace solid-phase microextraction for gas chromatography of BTEX in urine. Arh. Hig. Rada Toksikol. 58 (4), 421–427 (2007).
  • El-Beqqali A , Abdel-RehimM. Quantitative analysis of methadone in human urine samples by microextraction in packed syringe-gas chromatography-mass spectrometry (MEPS-GC-MS). J. Sep. Sci. 30 (15), 2501–2505 (2007).
  • De Paiva MJN , MartinsI, DeSiqueira MEPB. Analysis of ortho-cresol in urine by solid phase microextraction-capillary gas chromatography. Talanta J. Braz. Chem. Soc. 18 (5), 1034–1039 (2007).
  • Brown SD , RhodesDJ, PritchardBJ. A validated SPME-GC-MS method for simultaneous quantification of club drugs in human urine. Forensic Sci. Int. 171 (2–3), 142–150 (2007).
  • Brčić Karačonji I , SkenderL, KaračićV. Determination of nicotine and cotinine in urine by headspace solid phase microextraction gas chromatography with mass spectrometric detection. Acta Chim. Slov. 54 (1), 74–78 (2007).
  • Zhou J , ZengZ. Novel fiber coated with β-cyclodextrin derivatives used for headspace solid-phase microextraction of ephedrine and methamphetamine in human urine. Anal. Chim. Acta556 (2), 400–406 (2006).
  • Zeng D , ChenB, YaoS, YingJ. Determination of tetramethylenedisulfotetramine in human urine with gas chromatograph-flame thermionic detection coupling with direct immersed solid-phase micro-extraction. Forensic Sci. Int. 159 (2–3), 168–174 (2006).
  • Yonamine M , SavianoAM. Determination of cocaine and cocaethylene in urine by solid-phase microextraction and gas chromatography-mass spectrometry. Biomed. Chromatogr. 20 (10), 1071–1075 (2006).
  • Maleki R , FarhadiK, MatinAA. Analysis of ethanol and methanol in human body fluids by headspace solid phase microextraction coupled with capillary gas chromatography. Anal. Sci. 22 (9), 1253–1255 (2006).
  • Lourenço ELB , FerreiraA, PintoE, YonamineM, FarskySHP. On-fiber derivatization of SPME extracts of phenol, hydroquinone and catechol with GC–MS detection. Chromatographia63 (3–4), 175–179 (2006).
  • Liu Z , HaraK, KashimuraSet al. Two simple methods for enantiomeric analyses of urinary amphetamines by GC/MS using deuterium-labeled L-amphetamines as internal standards. Forensic Toxicol. 24 (1), 2–7 (2006).
  • Kuriki A , KumazawaT, LeeXPet al. Simultaneous determination of selegiline and desmethylselegiline in human body fluids by headspace solid-phase microextraction and gas chromatography–mass spectrometry. J. Chromatogr. B Anal. Technol. Biomed. Life Sci. 844 (2), 283–291 (2006).
  • Gallardo E , BarrosoM, MargalhoC, CruzA, VieiraDN, López-RivadullaM. Determination of quinalphos in blood and urine by direct solid-phase microextraction combined with gas chromatography–mass spectrometry. J. Chromatogr. B Anal. Technol. Biomed. Life Sci. 832 (1), 162–168 (2006).
  • Gallardo E , BarrosoM, MargalhoC, CruzA, VieiraDN, López-RivadullaM. Solid-phase microextraction for gas chromatographic/mass spectrometric analysis of dimethoate in human biological samples. Rapid Commun. Mass Spectrom. 20 (5), 865–869 (2006).
  • Gallardo E , BarrosoM, MargalhoC, CruzA, VieiraDN, López-RivadullaM. Determination of parathion in biological fluids by means of direct solid-phase microextraction. Anal. Bioanal. Chem. 386 (6), 1717–1726 (2006).

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