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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 39, 2009 - Issue 13
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Original Articles

Novel Synthesis of Phosphinates by the Microwave-Assisted Esterification of Phosphinic Acids

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Pages 2392-2404 | Received 22 Oct 2008, Published online: 01 Jun 2009

Keep up to date with the latest research on this topic with citation updates for this article.

Read on this site (12)

Réka Herbay, Nikolett Péczka, Gábor Györke, Péter Bagi, Elemér Fogassy & György Keglevich. (2019) Isomerization and application of phospholene oxides. Phosphorus, Sulfur, and Silicon and the Related Elements 194:4-6, pages 610-613.
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György Keglevich, Nóra Zsuzsa Kiss, Erika Bálint, Réka Henyecz, Alajos Grün & Zoltán Mucsi. (2019) Microwave irradiation and catalysis in organophosphorus chemistry. Phosphorus, Sulfur, and Silicon and the Related Elements 194:4-6, pages 391-395.
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Nóra Zsuzsa Kiss, Zita Gabriella Rádai & György Keglevich. (2016) Derivatization of phosphinic acids in the presence of ionic liquids. Phosphorus, Sulfur, and Silicon and the Related Elements 191:11-12, pages 1494-1496.
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György Keglevich, Nóra Z. Kiss, Erika Bálint, Péter Bagi, Alajos Grün, Tamara Kovács, Réka Henyecz & Péter Ábrányi-Balogh. (2016) Milestones in microwave-assisted organophosphorus chemistry. Phosphorus, Sulfur, and Silicon and the Related Elements 191:11-12, pages 1416-1420.
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Nóra Zsuzsa Kiss, Réka Henyecz, Erzsébet Jablonkai & György Keglevich. (2016) Synthesis of n-butyl ester and n-butylamide of methyl-phenylphosphinic acid: Two case studies. Synthetic Communications 46:9, pages 766-774.
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György Keglevich. (2014) Microwave-Assisted Synthesis of P-Heterocycles*. Phosphorus, Sulfur, and Silicon and the Related Elements 189:7-8, pages 1266-1278.
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Alajos Grün, Mátyás Milen, Tamás Földesi, Péter Ábrányi-Balogh, László Drahos & György Keglevich. (2013) Microwave-Assisted Amidation of Arylacetic Acids by Reaction with 2-Aryl-ethylamines. Synthetic Communications 43:11, pages 1491-1498.
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György Keglevich, Nóra Zsuzsa Kiss, Tamás Körtvélyesi & Zoltán Mucsi. (2013) Direct Estirification and Amidation of Phosphinic Acids Under Microwave Conditions. Phosphorus, Sulfur, and Silicon and the Related Elements 188:1-3, pages 29-32.
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Erzsébet Jablonkai, Erika Bálint, GyörgyT. Balogh, László Drahos & György Keglevich. (2012) Cyclic Phosphinates by the Alkylation of a Thermally Unstable 1-Hydroxy-1,2- Dihydrophosphinine 1-Oxide and A 3-Hydroxy-3-Phosphabicyclo[3.1.0]Hexane 3-Oxide. Phosphorus, Sulfur, and Silicon and the Related Elements 187:3, pages 357-363.
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György Keglevich, Alajos Grün, Erika Bálint, NóraZs. Kiss, Rita Kovács, IstvánG. Molnár, Zsófia Blastik, R.Viola Tóth, András Fehérvári & István Csontos. (2011) Green Chemical Tools in Organophosphorus Chemistry—Organophosphorus Tools in Green Chemistry. Phosphorus, Sulfur, and Silicon and the Related Elements 186:4, pages 613-620.
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György Keglevich, NóraZs. Kiss, Erika Bálint, Erzsébet Jablonkai, Alajos Grün, Mátyás Milen, Dávid Frigyes & István Greiner. (2011) Microwave-Assisted Esterification of Phosphinic Acids by Alcohols, Phenols, and Alkyl Halogenides. Phosphorus, Sulfur, and Silicon and the Related Elements 186:4, pages 802-803.
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Articles from other publishers (33)

Zhenyu Zhao, Hong Li & Xin Gao. (2023) Microwave Encounters Ionic Liquid: Synergistic Mechanism, Synthesis and Emerging Applications. Chemical Reviews 124:5, pages 2651-2698.
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Nikoletta Harsági, Nóra Zsuzsa Kiss, László Drahos & György Keglevich. (2021) Synthesis of Cyclic Phosphinates by Microwave-Assisted Ionic-Liquid-Promoted Alcoholysis. Synthesis 54:17, pages 3899-3905.
Crossref
Valmir B. Silva, Yane H. Santos, Renata Hellinger, Sergui Mansour, Antonin Delaune, Julien Legros, Sergey Zinoviev, Evandro S. Nogueira & Elisa S. Orth. (2022) Organophosphorus chemical security from a peaceful perspective: sustainable practices in its synthesis, decontamination and detection. Green Chemistry 24:2, pages 585-613.
Crossref
Ahmed Numan & Matthew Brichacek. (2021) Asymmetric Synthesis of Stereogenic Phosphorus P(V) Centers Using Chiral Nucleophilic Catalysis. Molecules 26:12, pages 3661.
Crossref
György Keglevich. (2021) Microwaves as “Co-Catalysts” or as Substitute for Catalysts in Organophosphorus Chemistry. Molecules 26:4, pages 1196.
Crossref
György Keglevich. 2021. Green Synthetic Approaches for Biologically Relevant Heterocycles. Green Synthetic Approaches for Biologically Relevant Heterocycles 111 142 .
Péter Bagi, Réka Herbay, Nikolett Péczka, Zoltán Mucsi, István Timári & and György Keglevich. (2020) Preparation of 2-phospholene oxides by the isomerization of 3-phospholene oxides. Beilstein Journal of Organic Chemistry 16, pages 818-832.
Crossref
Nóra Zsuzsa Kiss, Réka Henyecz & György Keglevich. (2020) Continuous Flow Esterification of a H-Phosphinic Acid, and Transesterification of H-Phosphinates and H-Phosphonates under Microwave Conditions. Molecules 25:3, pages 719.
Crossref
György Keglevich. (2019) Newer Developments in the Synthesis of P-Heterocycles. Current Organic Chemistry 23:12, pages 1342-1355.
Crossref
Moaz M. Abdou & Rasha A. El-Saeed. (2019) Potential chemical transformation of phosphinic acid derivatives and their applications in the synthesis of drugs. Bioorganic Chemistry 90, pages 103039.
Crossref
Erika Bálint, Ádám Tajti & György Keglevich. (2019) Application of the Microwave Technique in Continuous Flow Processing of Organophosphorus Chemical Reactions. Materials 12:5, pages 788.
Crossref
Nóra Zsuzsa Kiss & György Keglevich. (2019) Direct esterification of phosphinic and phosphonic acids enhanced by ionic liquid additives. Pure and Applied Chemistry 91:1, pages 59-65.
Crossref
György Keglevich. (2018) The Impact of Microwaves on Organophosphorus Chemistry. The Chemical Record 19:1, pages 65-76.
Crossref
Biquan Xiong, Chenghong Hu, Haotian Li, Congshan Zhou, Pangliang Zhang, Yu Liu & Kewen Tang. (2017) CDI-promoted direct esterification of P(O)-OH compounds with phenols. Tetrahedron Letters 58:25, pages 2482-2486.
Crossref
György Keglevich, Alajos Grün, Erika Bálint, Nóra Zsuzsa Kiss, Péter Bagi & László Tőke. (2016) Green chemical syntheses and applications within organophosphorus chemistry. Structural Chemistry 28:2, pages 431-443.
Crossref
György Keglevich, Nóra Zs. Kiss & Zoltán Mucsi. (2016) Milestones in microwave-assisted organophosphorus chemistry. Pure and Applied Chemistry 88:10-11, pages 931-939.
Crossref
Erika Bálint, Regina Eszter Tóth & György Keglevich. (2016) Synthesis of alkyl α‐aminomethyl‐phenylphosphinates and N,N ‐bis(alkoxyphenylphosphinylmethyl)amines by the microwave‐assisted Kabachnik–Fields reaction . Heteroatom Chemistry 27:5, pages 323-335.
Crossref
Nóra Zsuzsa Kiss & György Keglevich. (2016) Microwave-assisted direct esterification of cyclic phosphinic acids in the presence of ionic liquids. Tetrahedron Letters 57:9, pages 971-974.
Crossref
György Keglevich, Erika Bálint & Nóra Zs. Kiss. 2016. Milestones in Microwave Chemistry. Milestones in Microwave Chemistry 47 76 .
Biquan Xiong, Kui Zeng, Shanshan Zhang, Yongbo Zhou, Chak-Tong Au & Shuang-Feng Yin. (2015) Copper-catalyzed direct esterification of P(O)–OH compounds with phenols. Tetrahedron 71:49, pages 9293-9298.
Crossref
György Keglevich. 2015. Green Synthetic Approaches for Biologically Relevant Heterocycles. Green Synthetic Approaches for Biologically Relevant Heterocycles 559 570 .
Gheorghe Ilia, Mihaela Petric, Erika Bálint & György Keglevich. (2014) Synthesis of the Mixed Alkyl Esters of Phenylphosphonic Acid by Two Variations of the Atherton–Todd Protocol. Heteroatom Chemistry 26:1, pages 29-34.
Crossref
Erzsébet Jablonkai, Réka Henyecz, Mátyás Milen, János Kóti & György Keglevich. (2014) T3P®-assisted esterification and amidation of phosphinic acids. Tetrahedron 70:44, pages 8280-8285.
Crossref
Nóra Zsuzsa Kiss, Róbert Örkényi, Zoltán Mucsi & György Keglevich. (2014) The Synthesis of 3-Phosphabicyclo[3.1.0]- hexane 3-Oxides and 1,2-Dihydrophosphinine 1-Oxides with Lipophilic P-Alkoxy Substituents by Ring Enlargement. Heteroatom Chemistry 25:4, pages 265-273.
Crossref
Zoltán Mucsi, Nóra Zsuzsa Kiss & György Keglevich. (2014) A quantum chemical study on the mechanism and energetics of the direct esterification, thioesterification and amidation of 1-hydroxy-3-methyl-3-phospholene 1-oxide. RSC Advances 4:23, pages 11948.
Crossref
György Keglevich, Erzsébet Jablonkai & László B. Balázs. (2014) A “green” variation of the Hirao reaction: the P–C coupling of diethyl phosphite, alkyl phenyl- H -phosphinates and secondary phosphine oxides with bromoarenes using a P-ligand-free Pd(OAc) 2 catalyst under microwave and solvent-free conditions . RSC Adv. 4:43, pages 22808-22816.
Crossref
Erzsébet Jablonkai, Mátyás Milen, László Drahos & György Keglevich. (2013) Esterification of five-membered cyclic phosphinic acids under mild conditions using propylphosphonic anhydride (T3P®). Tetrahedron Letters 54:44, pages 5873-5875.
Crossref
Nóra Zsuzsa Kiss, Éva Böttger, László Drahos & György Keglevich. (2013) Microwave-Assisted Direct Esterification of Cyclic Phosphinic Acids. Heteroatom Chemistry 24:4, pages 283-288.
Crossref
György Keglevich, Nóra Zsuzsa Kiss & Tamás Körtvélyesi. (2013) Microwave‐Assisted Functionalization of Phosphinic Acids: Amidations versus Esterifications. Heteroatom Chemistry 24:2, pages 91-99.
Crossref
György Keglevich, Nóra Zsuzsa Kiss, László Drahos & Tamás Körtvélyesi. (2013) Direct esterification of phosphinic acids under microwave conditions: extension to the synthesis of thiophosphinates and new mechanistic insights. Tetrahedron Letters 54:6, pages 466-469.
Crossref
György Keglevich, Nóra Zsuzsa Kiss, Zoltán Mucsi & Tamás Körtvélyesi. (2012) Insights into a surprising reaction: The microwave-assisted direct esterification of phosphinic acids. Organic & Biomolecular Chemistry 10:10, pages 2011.
Crossref
Christelle Petit, Fabien Fécourt & Jean‐Luc Montchamp. (2011) Synthesis of Disubstituted Phosphinates via Palladium‐Catalyzed Hydrophosphinylation of H ‐Phosphinic Acids . Advanced Synthesis & Catalysis 353:11-12, pages 1883-1888.
Crossref
Erika Bálint, Erzsébet Jablonkai, Mária Bálint & György Keglevich. (2010) Alkylating esterification of 1‐hydroxy‐3‐phospholene oxides under solventless MW conditions. Heteroatom Chemistry 21:4, pages 211-214.
Crossref

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