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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 42, 2012 - Issue 9
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Original Articles

Phosphomolybdic Acid: An Efficient and Recyclable Solid Acid Catalyst for the Synthesis of 4,4′-(Arylmethylene)bis(1H-pyrazol-5-ols)

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Pages 1349-1358 | Received 16 Aug 2010, Published online: 11 Jan 2012

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Read on this site (4)

Yongjun Zheng, Yong Zheng, Zhen Wang, Yana Cao, Qian Shao & Zhanhu Guo. (2018) Sodium dodecyl benzene sulfonate-catalyzed reaction for aromatic aldehydes with 1-phenyl-3-methyl-5-pyrazolone in aqueous media. Green Chemistry Letters and Reviews 11:3, pages 217-223.
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Bahareh Sadeghi & Maryam Ghorbani Rad. (2015) SbCl5/SiO2 Nanoparticles: An Efficient and Reusable Reagent for the Synthesis of 4,4′-(Arylmethylene)bis(1H-pyrazol-5-ol) Derivatives in Water. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 45:11, pages 1723-1727.
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Articles from other publishers (34)

Ganesh B. Pund, Sambhaji T. Dhumal, Tejshri R. Deshmukh, Diksha B. Wahul, Krishna R. Mandave, Sujeet A. Gaware, Santosh S. Chavan, Mazahar Farooqui, Bhagwansing S. Dobhal & Madhav J. Hebade. (2023) Greener Synthetic Approach for 4,4′‐(Arylmethylene)bis(3‐methyl‐1H‐pyrazol‐5‐ol) Derivatives in an Aqueous Medium using Theophylline as a Catalyst. ChemistrySelect 8:45.
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Tejas M. Dhameliya, Rutvi J. Patel, Rajvi H. Amin, Dipen K. Sureja & Kunjan B. Bodiwala. (2023) Comprehensive Review on Metal Nanoparticles Catalyzed Synthesis of Aza- and Oxa-Heterocycles Reported in 2021. Mini-Reviews in Organic Chemistry 20:8, pages 800-817.
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Andrzej Danel, Elżbieta Porębska, Kacper Markiel, Oleksii Havrysh, Mateusz Kucharek, Arkadiusz Gut & Tomasz Uchacz. (2023) Multicomponent Synthesis of 4-Aryl-4,9-dihydro-1H-pyrazolo[3,4-b]quinolines Using L-Proline as a Catalyst—Does It Really Proceed?. Molecules 28:22, pages 7612.
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Shivani Soni, Pankaj Teli, Nusrat Sahiba, Sunita Teli & Shikha Agarwal. (2023) Exploring the synthetic potential of a g-C 3 N 4 ·SO 3 H ionic liquid catalyst for one-pot synthesis of 1,1-dihomoarylmethane scaffolds via Knoevenagel–Michael reaction . RSC Advances 13:19, pages 13337-13353.
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Anant B. Kanagare, M.Sc.Ashok R. Yadav, Ashishkumar P. Katariya, Devidas S. Bhagat, Ajit K. Dhas, Dattatraya N. Pansare, Pratik A. Nagwade, Brajesh Kumar, Jaiprakash N. Sangshetti & Satish U. Deshmukh. (2023) Insights into 4,4′‐Arylmethylene‐Bis‐1 H ‐Pyrazol‐5‐Ols Scaffolds: Various Synthetic Routes and Their Applications . ChemistrySelect 8:4.
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Anamika Gupta, Safia Iqbal, Roohi, Mohd. Kamil Hussain, Mohd. Rehan Zaheer & Krapa Shankar. (2022) Visible Light-Promoted Green and Sustainable Approach for One-Pot Synthesis of 4,4’-(Arylmethylene)bis(1H-pyrazol-5-ols), In Vitro Anticancer Activity, and Molecular Docking with Covid-19 M pro . ACS Omega 7:38, pages 34583-34598.
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José Eduardo Cadena-Cruz, Luis M. Guamán-Ortiz, Juan Carlos Romero-Benavides, Natalia Bailon-Moscoso, Kevin E. Murillo-Sotomayor, Nadia V. Ortiz-Guamán & Jorge Heredia-Moya. (2021) Synthesis of 4,4′-(arylmethylene)bis(3-methyl-1-phenyl-1H-pyrazol-5-ols) and evaluation of their antioxidant and anticancer activities. BMC Chemistry 15:1.
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Taiebeh Tamoradi, Seyedeh Masoumeh Mousavi & Bikash Karmakar. (2021) In situ decorated Mn–lysine complex on magnetic nanoparticles as a novel and reusable nanocatalyst in the synthesis of 4,4′-(arylmethylene)-bis-(3-methyl-1-phenyl-1H-pyrazol-5-ols) derivatives. Journal of the Iranian Chemical Society 18:11, pages 2919-2929.
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Mahdieh Sadeghpour & Abolfazl Olyaei. (2021) Recent advances in the synthesis of bis(pyrazolyl)methanes and their applications. Research on Chemical Intermediates 47:11, pages 4399-4441.
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Bijeta Mitra & Pranab Ghosh. (2021) Humic acid: A Biodegradable Organocatalyst for Solvent‐free Synthesis of Bis(indolyl)methanes, Bis(pyrazolyl)methanes, Bis‐coumarins and Bis‐lawsones. ChemistrySelect 6:1, pages 68-81.
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Rezvan Kardooni & Ali Reza Kiasat. (2020) Polyethylene Glycol as a Green and Biocompatible Reaction Media for the Catalyst Free Synthesis of Organic Compounds. Current Organic Chemistry 24:12, pages 1275-1314.
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Adeleh Moshtaghi Zonouz, Masoumeh Beiranvand, Rahim Mohammad-Rezaei & Soheila Naderi. (2020) Green and Efficient Synthesis of Fluorescent Bis(pyrazolyl)methanes in Choline Chloride/Urea Deep Eutectic Solvent. Letters in Organic Chemistry 17:7, pages 548-554.
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Sharoni Gupta, Rukhsar Banu, Chetna Ameta, Rakshit Ameta & Pinki Bala Punjabi. (2019) Emerging Trends in the Syntheses of Heterocycles Using Graphene-based Carbocatalysts: An Update. Topics in Current Chemistry 377:3.
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Yuvaraj P. Sarnikar, Dhanraj O. Biradar, Yogesh D. Mane & Bhimrao C. Khade. (2019) Highly Efficient Direct Synthesis of Scaffold 9a,10,12,12a‐Tetrahydrobenzo[ b ]cyclopenta[ f ]pyrrolo[1,2‐ d ][1,4]diazepinone by Using Active Phoshomolybdic Acid . Journal of Heterocyclic Chemistry 56:3, pages 1111-1116.
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Mohammad Dashteh, Saeed Baghery, Mohammad Ali Zolfigol, Yadollah Bayat & Asiye Asgari. (2019) 1,10‐Phenanthrolin‐1‐ium Trinitromethanide (1,10‐PHTNM) as a Nano Molten Salt Catalyst With Y‐Aromatic Counter Ion: Applications for Synthesis of Organic Compounds. ChemistrySelect 4:1, pages 337-346.
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Ting Wang, Yang Yu, Xushun Qing, Chenlu Dai & Cunde Wang. (2018) Efficient Preparation of Potassium Arylmethylene-4-(1 H -Pyrazol-5-ol)-4′-(1 H -Pyrazol-5-Olate) Derivatives via a Four-Component Reaction . Journal of Chemical Research 42:6, pages 313-316.
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Mosadegh Keshavarz, Amanollah Zarei Ahmady, Luigi Vaccaro & Maryam Kardani. (2018) Non-Covalent Supported of l-Proline on Graphene Oxide/Fe3O4 Nanocomposite: A Novel, Highly Efficient and Superparamagnetically Separable Catalyst for the Synthesis of Bis-Pyrazole Derivatives. Molecules 23:2, pages 330.
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Roya Jahanshahi & Batool Akhlaghinia. (2017) Sulfonated Honeycomb Coral (HC-SO3H): a new, green and highly efficient heterogeneous catalyst for the rapid one-pot pseudo-five component synthesis of 4,4′-(aryl methylene) bis(3-methyl-1H-pyrazol-5-ol)s. Chemical Papers 71:7, pages 1351-1364.
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Hoda Banari, Hamzeh Kiyani & Alireza Pourali. (2016) Efficient synthesis of bis(indolyl)methanes, bispyrazoles and biscoumarins using 4-sulfophthalic acid. Research on Chemical Intermediates 43:3, pages 1635-1649.
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Cheng Yang, Peng‐Ze Liu & Da‐Zhen Xu. (2017) A Green and Efficient One‐Pot Pseudo‐Five‐Component Reaction for Synthesis of Bis(pyrazol‐5‐ol) Derivatives via Tandem Cyclocondensation‐Knoevenagel–Michael Reaction. ChemistrySelect 2:3, pages 1232-1236.
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Dawei Zhang, Yumin Zhang, Tianqi Zhao, Jing Li, Yaya Hou & Qiang Gu. (2016) A rapid and efficient solvent-free microwave-assisted synthesis of pyrazolone derivatives containing substituted isoxazole ring. Tetrahedron 72:22, pages 2979-2987.
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Moustafa A. Gouda. (2015) Chemistry of 4,4′‐(arylmethylene)‐bis(3‐methyl‐1‐phenyl‐1 H ‐pyrazol‐5‐ol)s . Journal of Heterocyclic Chemistry 53:2, pages 356-376.
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Mosadegh Keshavarz & Masoumeh Vafaei-Nezhad. (2015) Design and Characterization of l-Prolinate-Amberlite as a Novel Heterogeneous Organocatalyst and Its Catalytic Application in the Synthesis of Pyrazol-Derivates. Catalysis Letters 146:2, pages 353-363.
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Mahmood Tajbakhsh, Marzieh Heidary, Rahman Hosseinzadeh & Mohammadreza Azizi Amiri. (2016) FeCl 3 ·6H 2 O as a green and readily available catalyst for the synthesis of 1-oxo-hexahydroxanthenes by the condensation of salicylaldehydes with 1,3-diketones in aqueous media. Tetrahedron Letters 57:1, pages 141-145.
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Asieh Vafaee, Abolghasem Davoodnia & Mehdi Pordel. (2015) A rapid, efficient, and high-yielding synthesis of 4,4′-(arylmethylene)bis(3-methyl-1H-pyrazol-5-ol) derivatives catalyzed by 12-tungstophosphoric acid (H3PW12O40). Research on Chemical Intermediates 41:11, pages 8343-8354.
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Khalid Mohammed Khan, Munira Taj Muhammad, Imran Khan, Shahnaz Perveen & Wolfgang Voelter. (2015) Rapid cesium fluoride-catalyzed Knoevenagel condensation for the synthesis of highly functionalized 4,4′-(arylmethylene)bis(1H-pyrazol-5-ol) derivatives. Monatshefte für Chemie - Chemical Monthly 146:9, pages 1587-1590.
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Monireh Zarghani & Batool Akhlaghinia. (2015) Sulfonated nanohydroxyapatite functionalized with 2-aminoethyl dihydrogen phosphate (HAP@AEPH 2 -SO 3 H) as a new recyclable and eco-friendly catalyst for rapid one-pot synthesis of 4,4′-(aryl methylene)bis(3-methyl-1H-pyrazol-5-ol)s . RSC Advances 5:107, pages 87769-87780.
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Javad Safaei-Ghomi, Bahareh Khojastehbakht-Koopaei & Safura Zahedi. (2015) Copper chromite nanoparticles as an efficient and recyclable catalyst for facile synthesis of 4,4'-(arylmethanediyl)bis(3-methyl-1H-pyrazol-5-ol) derivatives. Chemistry of Heterocyclic Compounds 51:1, pages 34-38.
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Khalid Mohammed Khan, Imran Khan, Shahnaz Perveen & Muhammad Imran Malik. (2014) A rapid and efficient CsF catalyzed tandem Knoevenagel–Michael reaction. Journal of Fluorine Chemistry 158, pages 1-5.
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Javad Safaei-Ghomi, Bahareh Khojastehbakht-Koopaei & Hossein Shahbazi-Alavi. (2014) Pseudo five-component process for the synthesis of 4,4′-(arylmethylene)bis(3-methyl-1H-pyrazol-5-ol) derivatives using ZnAl 2 O 4 nanoparticles in aqueous media . RSC Adv. 4:86, pages 46106-46113.
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S. Bhavanarushi, V. Kanakaiah, Gandu Bharath, A. Gangagnirao & J. Vatsala Rani. (2013) Synthesis and antibacterial activity of 4,4′-(aryl or alkyl methylene)-bis(1H-pyrazol-5-ol) derivatives. Medicinal Chemistry Research 23:1, pages 158-167.
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Zahed KARIMI-JABERI, Baharak POOLADIAN, Masoud MORADI & Ehsan GHASEMI. (2012) 1,3,5-Tris(hydrogensulfato) Benzene: A New and Efficient Catalyst for Synthesis of 4,4′-(arylmethylene)bis(1H-pyrazol-5-ol) Derivatives. Chinese Journal of Catalysis 33:11-12, pages 1945-1949.
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Kiran R. Phatangare, Vikas S. Padalkar, Vinod D. Gupta, Vikas S. Patil, Prashant G. Umape & N. Sekar. (2012) ChemInform Abstract: Phosphomolybdic Acid: An Efficient and Recyclable Solid Acid Catalyst for the Synthesis of 4,4′‐(Arylmethylene)bis(1H‐pyrazol‐5‐ols).. ChemInform 43:36.
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Mithu Saha, Amarta Kumar Pal & Shibaji Nandi. (2012) Pd(0) NPs: a novel and reusable catalyst for the synthesis of bis(heterocyclyl)methanes in water. RSC Advances 2:16, pages 6397.
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