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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 2, 1972 - Issue 4
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Original Articles

Curtius Degradation Utilizing Trimethylsilyl Azide. A facile isocyanate synthesis

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Pages 227-230 | Received 23 May 1972, Published online: 26 Jan 2007

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Tholappanavara H. Suresha Kumara, KittappaM. Mahadevan, HosanagaraN. Harishkumar, Basavaraj Padmashali & Gadada Naganagowda. (2009) Synthesis of Benzo[b]thiophene Substituted Carbamates, Ureas, Semicarbazides, and Pyrazoles and Their Antimicrobial and Analgesic Activity. Phosphorus, Sulfur, and Silicon and the Related Elements 184:7, pages 1866-1879.
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JamesD. Warren & JefferyB. Press. (1980) Trimethylsilylazide/KN3/18-Crown-6. Formation and Curtius Rearrangement of Acyl Azides from Unreactive Acid Chlorides. Synthetic Communications 10:2, pages 107-110.
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Grant Krow, KalyaniM. Damodaran, Edward Michener, StephenI. Miller & DavidR. Dalton. (1976) Nonsymmetric 9-Phenanthrylamines. An Improved Synthetic Procedure to a Useful Synthon. Synthetic Communications 6:4, pages 261-267.
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Articles from other publishers (23)

Vajihe Kishi, Behzad Chahkandi, Ehsan Zahedi & Sadegh Allameh. (2024) A theoretical assessment of Curtius rearrangement of malonyl azide: Molecular mechanism insight and solvent effects. Journal of Molecular Liquids 396, pages 124078.
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Tarek H. El-Assaad, Jayden Zhu, Anjitha Sebastian, Dominic V. McGrath, Ishita Neogi & Keshaba N. Parida. (2022) Dioxiranes: a half-century journey. Organic Chemistry Frontiers 9:20, pages 5675-5725.
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Kozaburo Nishiyama, Cheng Wang & Hélène Lebel. 2001. Encyclopedia of Reagents for Organic Synthesis. Encyclopedia of Reagents for Organic Synthesis 1 16 .
Kozaburo Nishiyama & Cheng Wang. 2001. Encyclopedia of Reagents for Organic Synthesis. Encyclopedia of Reagents for Organic Synthesis.
Louis F. Fieser, Mary Fieser & Tse‐Lok HoTse‐Lok Ho, Mary Fieser, Louis Fieser, Rick Danheiser, William Roush & Janice Smith. 2006. Fieser and Fieser's Reagents for Organic Synthesis. Fieser and Fieser's Reagents for Organic Synthesis.
Kozaburo Nishiyama. 2001. Encyclopedia of Reagents for Organic Synthesis. Encyclopedia of Reagents for Organic Synthesis.
Da-Jun Chen & Zhen-Chu Chen. (2000) Hypervalent iodine in synthesis. Part 54: One-step conversion of aryl aldehydes to aroyl azides using a combined reagent of (diacetoxyiodo)benzene with sodium azide. Tetrahedron Letters 41:38, pages 7361-7363.
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Viresh H. Rawal & Hua M. Zhong. (1994) One-step conversion of esters to acyl azides using diethylaluminum azide. Tetrahedron Letters 35:28, pages 4947-4950.
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A.M. Jouani, F. Sz?nyi & A. Cambon. (1992) Synth?se des isocyanates de 2-F-alkyl?thyle. Journal of Fluorine Chemistry 56:1, pages 85-92.
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Takayuki Shioiri. 1991. Comprehensive Organic Synthesis. Comprehensive Organic Synthesis 795 828 .
J. C. Madelmont, M. F. Moreau, D. Godeneche, P. Labarre & A. Veyre. (2006) Marquage par 14 C du Chloro‐2 Ethyl Isocyanate. Application au Marquage de Chloroethyl Tetrazinone et de Chloroethylnitrosourees . Journal of Labelled Compounds and Radiopharmaceuticals 25:10, pages 1135-1142.
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R.S. Atkinson. 1984. Azides and Nitrenes. Azides and Nitrenes 247 295 .
Ronald M. Pike, Nancy Sobinski & Patrick J. McManus. (1983) Organopseudohalosilanes II. Azidosilanes. Journal of Organometallic Chemistry 253:2, pages 183-216.
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John S. Broughton, Peter Lynch, Robert Stephens & John Colin Tatlow. (1983) Polyfluorobicyclo(2,2,1)heptanes. Part XII. 4H-decafluorobicyclo(2,2,1)hept-1-YL isocyanate, amine and alcohol, and derivatives therefrom. Journal of Fluorine Chemistry 22:2, pages 123-132.
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William P. WeberWilliam P. Weber. 1983. Silicon Reagents for Organic Synthesis. Silicon Reagents for Organic Synthesis 40 53 .
L. Birkofer & O. Stuhl. 1980. Organic Chemistry Syntheses and Reactivity. Organic Chemistry Syntheses and Reactivity 33 88 .
Stephen S. Washburne & Kwanghee K. Park. (2009) Synthesis of hydantoins transformable to 3‐alkylorotic acids from aminofumarate and isocyanates. Journal of Heterocyclic Chemistry 12:2, pages 369-371.
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Annemarie Closse & René Huguenin. (2004) Isolierung und Strukturaufklärung von Chlamydocin. Helvetica Chimica Acta 57:3, pages 533-545.
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Hans R. Kricheldorf & Walter Regel. (2006) Reaktionen mit Silylaziden, 4. Über Cyclopropylisocyanate. Chemische Berichte 106:11, pages 3753-3764.
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William R. PetersonJr.Jr., Jack Radell & Stephen S. Washburne. (1973) Interaction of carbonyl compounds with organomettalic azides IV. Perfluoroalkyl isocyanates. Journal of Fluorine Chemistry 2:4, pages 437-441.
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Herbert T. Nagasawa & Dwight S. Fullerton. 1973. 303 312 .
S. S. WASHBURNE & W. R. JUN. PETERSON. (2016) ChemInform Abstract: CURTIUS‐ABBAU UNTER VERWENDUNG VON TRIMETHYLSILYLAZID, EINE LEICHTE ISOCYANAT‐SYNTH.. Chemischer Informationsdienst 3:52.
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S. S. Washburne & W. R. PetersonJr.Jr.. (1972) Isocyanates derived from fatty acids by the trimethylsilyl azide modification of the curtius rearrangement. Journal of the American Oil Chemists' Society 49:12, pages 694-695.
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