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Original Articles

Development of an analytical method for the simultaneous analysis of MCPD esters and glycidyl esters in oil-based foodstuffs

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Pages 985-994 | Received 13 Dec 2013, Accepted 28 Feb 2014, Published online: 02 May 2014

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Nur Aainaa Syahirah Ramli, Nur Azmina Roslan, Fadzlina Abdullah, Bahriah Bilal, Razmah Ghazali, Raznim Arni Abd Razak & Azmil Haizam Ahmad Tarmizi. (2023) Determination of process contaminants 2- and 3-MCPD esters and glycidyl esters in palm-based glycerol by indirect analysis using GC-MS. Food Additives & Contaminants: Part A 0:0, pages 1-15.
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Siti Hajar Muhamad Rosli, Mei Siu Lau, Tasnim Khalid, Siti Khuzaimah Maarof, Suganthi Jeyabalan, Syazwani Sirdar Ali, Norhayati Mustafa Khalid, Mohd Fairulnizal Md Noh, Ruhaya Salleh, Lalitha Palaniveloo, Mohamad Hasnan Ahmad, Nurul Izzah Ahmad, Laila Rabaah Ahmad Suhaimi, Zawiyah Sharif, Nurhazwani Abd Rahman, Ros Suzanna Ahmad Bustamam, Rohan Malek, Boon Wei Teoh, Say Chuan Khoo, Chun Sen Lim, Nurul Huda Razali & Ami Fazlin Syed Mohamed. (2023) Association between dietary 3-monochloropropane-1,2-diol esters (3-MCPDE) and renal cancer in Peninsular Malaysia: exposure assessment and matched case-control study. Food Additives & Contaminants: Part A 40:4, pages 475-492.
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Friederike Wöhrlin, Hildburg Fry, Monika Lahrssen-Wiederholt & Angelika Preiß-Weigert. (2015) Occurrence of fatty acid esters of 3-MCPD, 2-MCPD and glycidol in infant formula. Food Additives & Contaminants: Part A 32:11, pages 1810-1822.
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Muhamad Roddy Ramli, Wai Lin Siew, Nuzul Amri Ibrahim, Ainie Kuntom & Raznim Arni Abd. Razak. (2015) Other factors to consider in the formation of chloropropandiol fatty esters in oil processes. Food Additives & Contaminants: Part A 32:6, pages 817-824.
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Articles from other publishers (27)

Fa Wang, Yixi Sun, Shanshan Li, Jing Yan, Wen Qin, Ahmed S.M. Saleh & Qing Zhang. (2023) Plant phenolic extracts for the quality protection of frying oil during deep frying: Sources, effects, and mechanisms. Grain & Oil Science and Technology 6:3, pages 148-161.
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Nur Aainaa Syahirah Ramli, Nur Azmina Roslan, Fadzlina Abdullah, Razmah Ghazali, Raznim Arni Abd Razak, Azmil Haizam Ahmad Tarmizi & Bahriah Bilal. (2023) Analytical method for the determination of 2- and 3-monochloropropanediol esters and glycidyl ester in palm-based fatty acids by GC-MS. Food Control 151, pages 109824.
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Zhengchao Shen, Xin Ma, Muhammad Mujahid Ali, Jiang Liang, Haixia Sui & Zhenxia Du. (2023) Study of the evolution of 3-MCPDEs and GEs in the infant formula production chain employing a modified indirect method based on magnetic solid phase extraction. Food Chemistry 399, pages 134018.
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Kinuko MIYAZAKI. (2022) Development and Application of New Analytical Methods for Compounds Concerned about Potential Health Risks in Edible Fats and Oils.油脂中の2-/3-MCPD脂肪酸エステル類及びグリシドール脂肪酸エステル類の新規分析法開発とその応用. KAGAKU TO SEIBUTSU 60:8, pages 410-419.
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Shihuan Li, Jinhui Li, Senwei Feng, Linlin Bian, Zhuoting Liu, Yunfang Ping, Xu Wang & Ann Van Schepdael. (2022) Headspace solid-phase microextraction and on-fiber derivatization for the determination of 3-/2-MCPDE and GE in breast milk and infant formula by gas chromatography tandem mass spectrometry. LWT 154, pages 112575.
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Karel Hrnčiřík. 2022. Processing Contaminants in Edible Oils. Processing Contaminants in Edible Oils 65 108 .
Shaun MacMahon, Jessica Beekman & Michael Granvogl. 2022. Processing Contaminants in Edible Oils. Processing Contaminants in Edible Oils 195 219 .
Helle Lochmann Knudsen, Rasmus Leth Miller & Annette Tjørnelund Jensen. (2021) Glycidol and 3‐MCPD Analysis Methods for Mono‐ and Diglycerides. European Journal of Lipid Science and Technology 123:11, pages 2000266.
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Maria Beatriz Abreu Gloria, Lilia Masson, Jaime Amaya-Farfan & Delia B. Rodriguez-Amaya. 2021. Chemical Changes During Processing and Storage of Foods. Chemical Changes During Processing and Storage of Foods 453 535 .
Shaun MacMahon & Jessica Beekman. (2019) 3-Chloro-1,2-propanediol (3-MCPD), 2-chloro-1,3-propanediol (2-MCPD) and glycidyl esters in infant formula: a review. Current Opinion in Food Science 30, pages 67-72.
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Jessica K. Beekman, Michael Granvogl & Shaun MacMahon. 2019. Mitigating Contamination from Food Processing. Mitigating Contamination from Food Processing 75 107 .
Perci O.B. Homrich, Láisa G. Dias, Lilian R.B. Mariutti, Neura Bragagnolo & Roberta Ceriani. (2019) Liquid-liquid equilibria and density data for pseudoternary systems of refined soybean oil + (hexanal, or heptanal, or butyric acid, or valeric acid, or caproic acid, or caprylic acid) + dimethyl sulfoxide at 298.15 K. The Journal of Chemical Thermodynamics 131, pages 149-158.
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Kinuko MIYAZAKIKazuo KOYAMA. (2019) Development and Application of an Enzymatic Indirect Method for Simultaneous Analysis of 3-MCPD Esters, 2-MCPD Esters and Glycidyl Esters2-/3-MCPD脂肪酸エステル,グリシドール脂肪酸エステル間接分析法(酵素法)の開発とその応用. Oleoscience 19:12, pages 489-496.
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J.A. Custodio-Mendoza, A.M. Carro, M.A. Lage-Yusty, A. Herrero, I.M. Valente, J.A. Rodrigues & R.A. Lorenzo. (2019) Occurrence and exposure of 3-monochloropropanediol diesters in edible oils and oil-based foodstuffs from the Spanish market. Food Chemistry 270, pages 214-222.
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Shaun MacMahon. 2019. Encyclopedia of Food Chemistry. Encyclopedia of Food Chemistry 569 577 .
Sook Chin Chew & Kar Lin Nyam. 2019. Fruit Oils: Chemistry and Functionality. Fruit Oils: Chemistry and Functionality 451 494 .
J.A. Custodio-Mendoza, R.A. Lorenzo, I.M. Valente, P.J. Almeida, M.A. Lage, J.A. Rodrigues & A.M. Carro. (2018) Development of a partitioned liquid-liquid extraction- dispersive solid phase extraction procedure followed by liquid chromatography-tandem mass spectrometry for analysis of 3-monochloropropane-1,2-diol diesters in edible oils. Journal of Chromatography A 1548, pages 19-26.
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Wei-wei Cheng, Guo-qin Liu, Li-qing Wang & Zeng-she Liu. (2017) Glycidyl Fatty Acid Esters in Refined Edible Oils: A Review on Formation, Occurrence, Analysis, and Elimination Methods. Comprehensive Reviews in Food Science and Food Safety 16:2, pages 263-281.
Crossref
Jessica K. Leigh & Shaun MacMahon. (2016) Extraction and Liquid Chromatography–Tandem Mass Spectrometry Detection of 3-Monochloropropanediol Esters and Glycidyl Esters in Infant Formula. Journal of Agricultural and Food Chemistry 64:49, pages 9442-9451.
Crossref
Renata Jędrkiewicz, Agnieszka Głowacz-Różyńska, Justyna Gromadzka, Adam Kloskowski & Jacek Namieśnik. (2016) Indirect Determination of MCPD Fatty Acid Esters in Lipid Fractions of Commercially Available Infant Formulas for the Assessment of Infants’ Health Risk. Food Analytical Methods 9:12, pages 3460-3469.
Crossref
Vasilios G. Samaras, Anupam Giri, Zuzana Zelinkova, Lubomir Karasek, Gerhard Buttinger & Thomas Wenzl. (2016) Analytical method for the trace determination of esterified 3- and 2-monochloropropanediol and glycidyl fatty acid esters in various food matrices. Journal of Chromatography A 1466, pages 136-147.
Crossref
Weiwei Cheng, Guoqin Liu & Xinqi Liu. (2016) Formation of Glycidyl Fatty Acid Esters Both in Real Edible Oils during Laboratory-Scale Refining and in Chemical Model during High Temperature Exposure. Journal of Agricultural and Food Chemistry 64:29, pages 5919-5927.
Crossref
Kinuko Miyazaki & Kazuo Koyama. (2016) Application of Indirect Enzymatic Method for Determinations of 2-/3-MCPD-Es and Gly-Es in Foods Containing fats and Oils. Journal of the American Oil Chemists' Society 93:7, pages 885-893.
Crossref
Corinne Marc, Valérie Drouard-Pascarel, Cécile Rétho, Patrice Janvion & Frédéric Saltron. (2016) Determination of 3-Monochloropropane-1,2-diol and 2-Monochloropropane-1,3-diol (MCPD) Esters and Glycidyl Esters by Microwave Extraction in Different Foodstuffs. Journal of Agricultural and Food Chemistry 64:21, pages 4353-4361.
Crossref
R. Jędrkiewicz, A. Głowacz, J. Gromadzka & J. Namieśnik. (2016) Determination of 3-MCPD and 2-MCPD esters in edible oils, fish oils and lipid fractions of margarines available on Polish market. Food Control 59, pages 487-492.
Crossref
Richard H Stadler. (2015) Monochloropropane-1,2-diol esters (MCPDEs) and glycidyl esters (GEs): an update. Current Opinion in Food Science 6, pages 12-18.
Crossref
Thomas Wenzl, Vasilios Samaras, Anupam Giri, Gerhard Buttinger, Lubomir Karasek & Zuzana Zelinkova. (2015) Development and validation of analytical methods for the analysis of 3‐MCPD (both in free and ester form) and glycidyl esters in various food matrices and performance of an ad‐hoc survey on specific food groups in support to a scientific opinion on comprehensive risk assessment on the presence of 3‐MCPD and glycidyl esters in food. EFSA Supporting Publications 12:3.
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