2,134
Views
20
CrossRef citations to date
0
Altmetric
Original Articles

Quantification of Diterpenes and Their Palmitate Esters in Coffee Brews by HPLC-DAD

, , , &
Pages 2284-2299 | Received 15 Dec 2013, Accepted 07 Jun 2014, Published online: 19 Jun 2015

REFERENCES

  • Speer, K.; Hruschka, A.; Kurzrock, T.; Kölling-Speer, I. Diterpenes in coffee. In Caffeinated Beverages; Parliament, T.H.; Ho, C.H; Schieberle, P.; Eds.; American Chemical Society, USA, 2000.
  • Campanha, F.G.; Dias, R.C.; Benassi, M.D. Discrimination of coffee species using kahweol and cafestol: Effect of roasting and of defects. Coffee Science, Lavras 2010, 5 (1), 87–96.
  • Araujo, J.M.A.; Sandi, D. Extraction of coffee diterpenes and coffee oil using supercritical carbon dioxide. Food Chemistry 2006, 101, 1087–1094.
  • Speer, K.; Kölling-Speer, I. The lipid fraction of the coffee bean. Brazilian Journal of Plant Physiology 2006, 18 (1), 201–216.
  • Urgert, R.; Weg, G.; Kosmeijer-Schuil, T.G.; Boverikamp, P.; Hovenier, R.; Katan, M.B. Levels of the cholesterol-elevating diterpenes cafestol and kahweol in various coffee brews. Journal of Agricultural and Food Chemistry 1995, 43, 2167–2172.
  • Gross, G.; Jaccaud, E.; Huggett, A.C. Analysis of the content of the diterpenes cafestol and kahweol in coffee brews. Food and Chemical Toxicology 1997, 35, 547–554.
  • Zhang, C.; Linforth, R.; Fisk, I.D. Cafestol extraction yield from different coffee brew mechanisms. Food Research International 2012, 49, 27–31.
  • De Roos, B.; Caslake, M.J.; Stalenhoef, A.F.H.; Bedford, D.; Demacker, P.M.N.; Katan, M.B.; Packard, C.J. The coffee diterpene cafestol increases plasma triacylglycerol by increasing the production rate of large VLDL apolipoprotein B in healthy normolipidemic subjects 1–3. The American Journal of Clinical Nutrition 2001, 73, 45–52.
  • Cavin, C.; Holzhauser, D.; Constable, A.; Huggett, A.C.; Schilter, B. The coffee-specific diterpenes cafestol and kahweol protect against aflatoxin B1-induced genotoxicity through a dual mechanism. Carcinogenesis 1998, 19 (8), 1369–1375.
  • Cavin, C.; Holzhaeuser, D.; Scharf, G.; Constable, A.; Huber, W.W.; Schilter, B. Cafestol and kahweol, two coffee specific diterpenes with anticarcinogenic activity. Food and Chemical Toxicology 2002, 40, 1155–1163.
  • Cárdenas, C.; Quesada, A.R.; Medina, M.A. Anti-angiogenic and anti-inflammatory properties of kahweol, a coffee diterpene. PLoS One 2011, 6 (8), e23407.
  • Oigman, S.S.; de Souza, R.O.M.A.; dos Santos Júnior, H.M.; Hovell, A.M.C.; Hamerski, L.; Rezende, C.M. Microwave-assisted methanolysis of green coffee oil. Food Chemistry 2012, 134, 999–1004.
  • Dias, R.C.E.; de Faria, A.F.; Mercadante, A.Z.; Bragagnolo, N.B.; Benassi, M.T. Comparison of extraction methods for kahweol and cafestol analysis in roasted coffee. Journal of the Brazilian Chemical Society 2013, 24 (3), 492–499.
  • Kurzrock, T.; Speer, K. Identification of kahweol fatty acid esters in arabica coffee by means of LC/MS. Journal of Separation Science 2001, 24, 843–848.
  • Dias, R.C.E.; Alves, S.T.; Benassi, M.T.; Spectrophotometric method for quantification of kahweol in coffee. Journal of Food Composition and Analysis 2013, 31, 137–143.
  • Chartier, A.; Beaumesnil, M.; de Oliveira, A.L.; Elfakir, C.; Bostyn, S. Optimization of the isolation and quantitation of kahweol and cafestol in green coffee oil. Talanta 2013, 117, 102–111.
  • Kitzberger, C.S.G.; dos Santos Scholz, M.B.; Pereira, L.F.P.; Vieira, L.G.; Sera, T.; Gonc, J.B.; Silva, A.D.; Benassi, M.T. Diterpenes in green and roasted coffee of Coffea arabica cultivars growing in the same edapho-climatic conditions. Journal of Food Composition and Analysis 2013, 30, 52–57.
  • Kurzrock, T.; Speer, K. Diterpenes and diterpene esters in coffee. Food Reviews International 2001, 17 (4), 433–450.
  • Dias, R.C.E.; Campanha, G.F.; Vieira, L.G.E.; Ferreira, L.P.; Pot, D.; Marraccini, P.; Benassi, M.T. Evaluation of kahweol and cafestol in coffee tissues and roasted coffee by a new high performance liquid chromatography methodology. Journal of Agricultural and Food Chemistry 2010, 58 (1), 88–93.
  • Silva, J.A.; Borges, N.; Santos, A.; Alves, A. Method validation for cafestol and kahweol quantification in brews by HPLC-DAD. Food Analytical Methods 2012, 5 (6), 1404–1410.
  • Speer, K.; Kölling-Speer, I. Lipids. In Coffee: Recent Developments; Clarke, R.J.; Vitzthum, O.G.; Eds.; BlackWell Science: UK, 2001, 33–49.
  • Lam, L.K.T.; Sparnins, V.L.; Wattenberg, L.W. Isolation and identification of kahweol palmitate and cafestol palmitate as active constituents of green coffee beans that enhance glutathione S-transferase activity in the mouse. Cancer Research 1982, 42, 1193–1198.
  • Pettitt, B.C. Identification of the diterpene esters in arabica and canephora coffees. Journal of Agricultural and Food Chemistry 1987, 35, 549–555.
  • Sehat, N.; Montag, A.; Speer, K. Lipids in the coffee brew. In Proceedings of the 15th ASIC Colloquium (Montpellier); ASIC Paris, France, June 6–11, 1993; 869–872.
  • Sehat, N.; Niedwetzki, G. Coffee lipids: Analysis of diterpene 16-O-methylcafestol as an indicator of admixing of coffee. In: New Techniques and Applications in Lipid Analysis; McDonald, R.E.; Mossoba, M.M.; Eds.; AOCS Press: Champaign, Illinois, USA, 1997, 356–379.
  • Huber, W.W.; Teitel, C.H.; Coles, B.F.; King, R.S.; Wiese, F.W.; Kaderlik, K.R.; … Kadlubar, F.F. Potential chemoprotective effects of the coffee components kahweol and cafestol palmitates via modification of hepatic N-acetyltransferase and glutathione S-transferase activities. Environmental and Molecular Mutagenesis 2004, 44, 265–276.
  • Huber, W.W.; McDaniel, L.P.; Kaderlik, K.R.; Teitel, C.H.; Lang, N.P.; Kadlubar, F.F. Chemoprotection against the formation of colon DNA adducts from the food-borne carcinogen 2-amino-1-methyl-6-phenylimidazow4,5-bxpyridine (PhIP) in the rat. Mutation Research 1997, 376, 115–122.
  • Majer, B.J.; Hofer, E.; Cavin, C.; Lhoste, E.; Uhl, M.; Glatt, H.R.; Meinl, W.; Knasmüller, S. Coffee diterpenes prevent the genotoxic effects of 2-amino-1-methyl-6-phenylimidazo[4,5-b]pyridine (PhIP) and N-nitrosodimethyl amine in a human derived liver cell line (HepG2). Food and Chemical Toxicology 2005, 43, 433–441.
  • Abdullah, M.; Koc, A.B. Oil removal from waste coffee grounds using two-phase solvent extraction enhanced with ultrasonication. Renewable Energy 2013, 50, 965–970.
  • Bertholet, R. Preparation of cafestol. United States Patent 1987, 4 (692), 534.

Reprints and Corporate Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

To request a reprint or corporate permissions for this article, please click on the relevant link below:

Academic Permissions

Please note: Selecting permissions does not provide access to the full text of the article, please see our help page How do I view content?

Obtain permissions instantly via Rightslink by clicking on the button below:

If you are unable to obtain permissions via Rightslink, please complete and submit this Permissions form. For more information, please visit our Permissions help page.