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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 30, 2000 - Issue 2
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Original Articles

A Simple and Efficient Procedure for Oxidation of Sulfides to Sulfoxides by Hexamethylenetetramine-Bromine Complex(Hmtab)

Ahmad Shaabani Chemistry Department, Shahid Beheshti University, P.O. Box 19396--4716, Tehran, Iran
,
Mohammad B. Teimouri Chemistry Department, Shahid Beheshti University, P.O. Box 19396--4716, Tehran, Iran
&
Hamid R. Safaei Chemistry Department, Shahid Beheshti University, P.O. Box 19396--4716, Tehran, Iran
Pages 265-271 | Received 22 Jan 1999, Published online: 04 Dec 2007

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Read on this site (13)

Weifeng Wang & Yanqing Peng. (2023) Mechanochemical organic synthesis in a rotary evaporator beyond conventional application: Proof-of-concept reactions. Synthetic Communications 53:9, pages 625-639.
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Ahmad Shaabani, Elham Farhangi & Abbas Rahmati. (2010) An Efficient and Selective Oxidation of Sulfides and Thiols with Silica-Supported 1,1,3,3-Tetramethylguanidine/Br2 Complex. Phosphorus, Sulfur, and Silicon and the Related Elements 185:2, pages 463-468.
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Ahmad Shaabani, Abbas Rahmati & Soheila Naderi. (2007) Ultrasound‐Promoted Rapid Oxidative Cleavage of Oximes with NaBrO3/Ion Exchange Resin. Synthetic Communications 37:22, pages 4035-4042.
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AbdolR. Hajipour, Lian-Wang Guo & ArnoldE. Ruoho. (2006) Nitric Acid in the Presence of Supported P2O5 On Silica Gel Affords an Efficient and Mild System for Oxidation of Organic Compounds Under Solvent-Free Conditions. Molecular Crystals and Liquid Crystals 456:1, pages 85-93.
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Ahmad Shaabani, Abbas Rahmati & Elham Farhangi. (2006) Selective and efficient oxidation of sulfides and thiols with a 1,1,3,3-tetramethylguanidine/Br2 complex. Journal of Sulfur Chemistry 27:4, pages 287-291.
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Iraj Mohammadpoor-Baltork, Hamid Reza Memarian, Kiumars Bahrami & Karim Esmayilpour. (2005) Selective Oxidation of Sulfides to Sulfoxides and Sulfones Using -Butyltriphenylphosphonium Dichromate (Bu PPh3)2Cr2O7 in the Presence of Aluminium Chloride in Solution and Under Microwave Irradiation. Phosphorus, Sulfur, and Silicon and the Related Elements 180:12, pages 2751-2766.
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Mohammad Bagher Teimouri & Houri Mivehchi. (2005) Efficient Hexamethylenetetramine‐Bromine (HMTAB)‐Catalyzed Synthesis of Bis(indolyl)methanes in Water. Synthetic Communications 35:13, pages 1835-1843.
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N. Grayaa Jaoued, R. Oueslati & A. Hedhli. (2005) Synthesis and Pummerer Reaction of α,ω‐Bis(Fluoroalkylsulfinylmethyl)Polyethylene Glycols. Synthetic Communications 35:4, pages 543-556.
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Ahmad Shaabani, Kamal Soleimani & Ayoob Bazgir. (2004) Silica Sulfuric Acid Catalysis the Oxidation of Organic Compounds with Sodium Bromate. Synthetic Communications 34:18, pages 3303-3315.
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Ahmad Shaabani, Ayoob Bazgir, Kamal Soleimani & Peyman Salehi. (2003) Solvent Effects in the Oxidation of Sulfides with NaBrO3/Mg(HSO4)2 . Synthetic Communications 33:17, pages 2935-2944.
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Satya Paul, Varinder Gupta & Rajive Gupta. (2003) A Simple and Selective Procedure for α-Bromination of Alkanones Using Hexamethylenetetramine-bromine Complex and Basic Alumina in Solvent-Free Conditions. Synthetic Communications 33:11, pages 1917-1922.
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Ahmad Shaabani & Donald G. Lee. (2003) Cerium(III) Bromate as a New Reagent in Oxidation of Organic Compounds. Synthetic Communications 33:11, pages 1845-1854.
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Ahmad Shaabani & Donald G. Lee. (2003) Solvent Free Ion Exchange Catalysis in the Oxidation of Organic Compounds with Sodium Bromate. Synthetic Communications 33:8, pages 1255-1260.
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Somayeh Molaei & Mohammad Ghadermazi. (2019) Immobilization of cerium (IV) and erbium (III) in mesoporous MCM‐41: Two novel and highly active heterogeneous catalysts for the synthesis of 5‐substituted tetrazoles, and chemo‐ and homoselective oxidation of sulfides. Applied Organometallic Chemistry 33:7.
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A. Lattanzi. 2014. Comprehensive Organic Synthesis II. Comprehensive Organic Synthesis II 837 879 .
Mohammad Bagher Teimouri, Peyman Akbari-Moghaddam & Mahnaz Motaghinezhad. (2013) Urotropine–bromine promoted synthesis of functionalized oxaspirotricyclic furopyrimidines via a domino Knoevenagel condensation/Michael addition/α-bromination/Williamson cycloetherification sequence in water. Tetrahedron 69:33, pages 6804-6809.
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Abbas Shockravi, Ali Javadi & Ebrahim Abouzari-Lotf. (2013) Binaphthyl-based macromolecules: a review. RSC Advances 3:19, pages 6717.
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Bo Zhang, Ming-Dong Zhou, Mirza Cokoja, János Mink, Shu-Liang Zang & Fritz E. Kühn. (2012) Oxidation of sulfides to sulfoxides mediated by ionic liquids. RSC Advances 2:22, pages 8416.
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Kerstin A. Stingl & Svetlana B. Tsogoeva. (2010) Recent advances in sulfoxidation reactions: a metal-free approach. Tetrahedron: Asymmetry 21:9-10, pages 1055-1074.
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Ahmad Shaabani, Elham Farhangi & Abbas Rahmati. (2008) Ionic liquid promoted selective oxidation of organic compounds with NaBrO3. Monatshefte für Chemie - Chemical Monthly 139:8, pages 905-908.
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. (2008) An Environmentally Benign Synthesis of 1-Benzyl-4-aza-1-azonia-bicyclo[2.2.2]octane Tribromide and Its Application as an Efficient and Selective Reagent for Oxidation of Sulfides to Sulfoxides in Solution and Solvent-free Conditions. Bulletin of the Korean Chemical Society 29:7, pages 1332-1334.
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Moslem Mansour Lakouraj, Mahmood Tajbakhsh & Hamed Tashakkorian. (2006) Ion Exchange Resin Catalyzed Selective Oxidation of Sulfides to Sulfoxides Using Hydrogen Peroxide. Monatshefte für Chemie - Chemical Monthly 138:1, pages 83-88.
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K. Bahrami. (2006) Selective oxidation of sulfides to sulfoxides and sulfones using hydrogen peroxide (H2O2) in the presence of zirconium tetrachloride. Tetrahedron Letters 47:12, pages 2009-2012.
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Abdol R. Hajipour, Behzad Kooshki & Arnold E. Ruoho. (2005) Nitric acid in the presence of supported P2O5 on silica gel: an efficient and novel reagent for oxidation of sulfides to the corresponding sulfoxides. Tetrahedron Letters 46:33, pages 5503-5506.
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Iraj Mohammadpoor-Baltork, Hamid R Memarian & Kiumars Bahrami. (2005) 3-Carboxypyridinium chlorochromate aluminium chloride An efficient and inexpensive reagent system for the selective oxidation of sulfides to sulfoxides and sulfones in solution and under microwave irradiation. Canadian Journal of Chemistry 83:2, pages 115-121.
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Piotr Kowalski, Katarzyna Mitka, Katarzyna Ossowska & Zofia Kolarska. (2005) Oxidation of sulfides to sulfoxides. Part 1: Oxidation using halogen derivatives. Tetrahedron 61:8, pages 1933-1953.
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Michael B. Smith. 2003. Compendium of Organic Synthetic Methods. Compendium of Organic Synthetic Methods 470 482 .
Abdol R. Hajipour, Shadpour E. Mallakpour & Hadi Adibi. (2002) Selective and Efficient Oxidation of Sulfides and Thiols with Benzyltriphenylphosphonium Peroxymonosulfate in Aprotic Solvent. The Journal of Organic Chemistry 67:24, pages 8666-8668.
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Ahmad Shaabani, Mohammad B. Teimouri & Hamid R. Safaei. (2010) ChemInform Abstract: A Simple and Efficient Procedure for Oxidation of Sulfides to Sulfoxides by Hexamethylenetetramine‐Bromine Complex (HMTAB).. ChemInform 31:22.
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