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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 44, 2014 - Issue 16
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Synthetic Communications Reviews

Selective Nitration of Phenolic Compounds by Green Synthetic Approaches

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Pages 2313-2335 | Received 18 Feb 2014, Published online: 13 Jun 2014

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Zafar Iqbal, Asha Joshi & Saroj Ranjan De. (2023) Metal nitrate promoted highly regiospecific ortho–nitration of phenols: Application to the synthesis of nitroxynil. Synthetic Communications 53:7-8, pages 557-567.
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M. Satish Kumar, Y. Hemanth Sriram, M. Venkateswarlu, K. C. Rajanna, M. Sai Sudhakar, Purugula Venkanna & P. K. Saiprakash. (2018) Silica-supported perchloric acid and potassium bisulfate as reusable green catalysts for nitration of aromatics under solvent-free microwave conditions. Synthetic Communications 48:1, pages 59-67.
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Başak Temur Ergan, Mahmut Bayramoğlu & Elif Şahin. (2017) Regioselective nitration of phenol under continuous microwave irradiation. Journal of Microwave Power and Electromagnetic Energy 51:4, pages 314-324.
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Małgorzata Wąsińska, Anna Korczewska, Mirosław Giurg & Jacek Skarżewski. (2015) Improved Protocol for Mononitration of Phenols with Bismuth(III) and Iron(III) Nitrates. Synthetic Communications 45:1, pages 143-150.
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Someshwar Dagduappa Dindulkar, Kwon Taek Lim, Byung Kwon Cho & Yeon Tae Jeong. (2014) Green Approach Toward One Pot Cascade Synthesis of 3-Aryl-3,4-Dihydro-1,2,4 Benzothiadiazine-1,1-Dioxides. Phosphorus, Sulfur, and Silicon and the Related Elements 189:1, pages 40-51.
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N. Iranpoor, H. Firouzabadi & S. Farahi. (2007) Sulfonated charcoal as a mild and efficient catalyst for esterification and trans-esterification reactions. Journal of Sulfur Chemistry 28:6, pages 581-587.
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Jitendra R. Satam, Manoj B. Gawande, Sameer S. Deshpande & Radha V. Jayaram. (2007) SO4 2−/SnO2: Efficient, Chemoselective, and Reusable Catalyst for Acylation of Alcohols, Phenols, and Amines at Room Temperature. Synthetic Communications 37:17, pages 3011-3020.
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Nasser Iranpoor, Habib Firouzabadi & Arezu Jamalian. (2006) Silphos [PCl3− (SiO2) ]: A Heterogeneous Phosphine Reagent for the Regioselective Synthesis of vic-Haloalcohols. Phosphorus, Sulfur, and Silicon and the Related Elements 181:11, pages 2615-2621.
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Wei Wang, Shu‐Xiang Wang, Xin‐Ying Qin & Ji‐Tai Li. (2005) Reaction of Aldehydes and Pyrazolones in the Presence of Sodium Dodecyl Sulfate in Aqueous Media. Synthetic Communications 35:9, pages 1263-1269.
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P. Manisankar, C. Vedhi, S. Viswanathan & H. G. Prabu. (2004) Investigation on the Usage of Clay Modified Electrode for the Electrochemical Determination of Some Pollutants. Journal of Environmental Science and Health, Part B 39:1, pages 89-100.
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Mohammad Ali Zolfigol, Farhad Shirini & Arash Ghorbani Chogamarani. (2003) Silica Chloride/NaNO2 as a Novel Heterogeneous System for the Nitration of Phenols Under Mild Conditions. Phosphorus, Sulfur, and Silicon and the Related Elements 178:9, pages 2019-2025.
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Abbas Shockravi, Hassan Valizadeh & MajidM. Heravi. (2003) A One-Pot and Convenient Synthesis of Coumarins in Solventless System. Phosphorus, Sulfur, and Silicon and the Related Elements 178:3, pages 501-504.
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Devendra D. Pathak & J. Joe Gerald. (2003) An Efficient and Convenient Method for the Synthesis of Dialkoxymethanes Using Kaolinite as a Catalyst. Synthetic Communications 33:9, pages 1557-1561.
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Abbas Shockravi, Hashem Shargi, Hassan Valizadeh & MajidM. Heravi. (2002) Solvent Free Synthesis of Coumarins. Phosphorus, Sulfur, and Silicon and the Related Elements 177:11, pages 2555-2559.
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Pan-Suk Kwon, Young-Mee Kim, Chul-Joong Kang, Tae-Woo Kwon, Sung-Kee Chung & Young-Tae Chang. (1997) Microwave Enhanced Knoevenagel Condensation of Malonic Acid on Basic Alumina. Synthetic Communications 27:23, pages 4091-4100.
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H. Firouzabadi, N. Iranpoor & M.A. Zolfigol. (1997) Dinitrogen Tetroxide Complexes of Iron and Copper Nitrates as New Reagents for Selective Mono- and Dinitration of Phenolic Compounds. Synthetic Communications 27:19, pages 3301-3311.
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H.M.Sampath Kumar, PradyumnaK. Mohanty, M. Suresh Kumar & J.S. Yadav. (1997) Microwave Promoted Rapid Dehydration of Aldoximes to Nitriles on a Solid Support . Synthetic Communications 27:8, pages 1327-1333.
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A.R.A.S. Deshmukh, V.K. Gumaste & B.M. Bhawal. (1995) Montmorillonite, an Efficient Catalyst for the Preparation of Dialkoxymethanes. Synthetic Communications 25:24, pages 3939-3944.
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Y.V. Subba Rao, P. Vijayanand, S.J. Kulkarni, M. Subrahmanyam & A.V. Rama Rao. (1995) Shape Selective Deacetylation Over Zeolites: A Simple Methodology. Synthetic Communications 25:6, pages 849-855.
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B.M. Choudary, V.L. K. Valli & A. Durga Prasad. (1991) A Novel Montmorillonite - KMnO4 System for the Oxidation of Alkenes Under Triphase Conditions. Synthetic Communications 21:20, pages 2007-2013.
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Elvira Gutierrez & Eduardo Ruiz-hitzky. (1988) Intracrystalline Pinacol Rearrangement in Layer Silicates. Molecular Crystals and Liquid Crystals Incorporating Nonlinear Optics 161:1, pages 453-458.
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Rumasha N. T. Kankanamage, Ben K. Ahiadu, Jie He & James F. Rusling. (2023) Biocatalytic Nitration of Phenols in Microemulsions at Elevated Temperatures Using Enzymes Stabilized on Magnetic Beads. ChemCatChem 15:15.
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Taku Kitanosono, Airu Hashidoko, Yasuhiro Yamashita & Shū Kobayashi. (2022) 2‐Methoxyethyl Nitrite as a Reagent for Chemoselective On‐Water Nitration. Chemistry – An Asian Journal 17:16.
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James H Clark, Anwar Jardine, Avtar Matharu & Christian Stevens. 2022. Greener Organic Transformations. Greener Organic Transformations 90 95 .
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Manmohan Reddy Depa, Suneetha Potla, Umesh C. Narkhede, Vinod D. Jadhav & Siddaiah Vidavalur. (2020) Copper-mediated regioselective efficient direct ortho-nitration of anilide derivatives. Tetrahedron Letters 61:33, pages 152223.
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Susmita Saikia & Ruli Borah. (2019) 2‐Methyl‐1,3‐disulfoimidazolium polyoxometalate hybrid catalytic systems as equivalent safer alternatives to concentrated sulfuric acid in nitration of aromatic compounds. Applied Organometallic Chemistry 33:10.
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Chandrashekar Mudithanapelli, Lama Prema Dhorma & Mi-hyun Kim. (2019) PIFA-Promoted, Solvent-Controlled Selective Functionalization of C(sp 2 )–H or C(sp 3 )–H: Nitration via C–N Bond Cleavage of CH 3 NO 2 , Cyanation, or Oxygenation in Water . Organic Letters 21:9, pages 3098-3102.
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Feng-Chao Guo, Min-Zun Ji, Pu Zhang & Zhi-Xin Guo. (2018) Facile nitration of aromatic compounds using Bi(NO3)3·5H2O/MgSO4 under mechanochemical conditions. Green Processing and Synthesis 7:5, pages 453-459.
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Xiaohe Xu, Jian Sun, Yuyan Lin, Jingya Cheng, Pingping Li, Yiyan Yan, Qi Shuai & Yuanyuan Xie. (2017) Copper nitrate-catalyzed oxidative coupling of unactivated C(sp 3 )–H bonds of ethers and alkanes with N -hydroxyphthalimide: synthesis of N -hydroxyimide esters . Organic & Biomolecular Chemistry 15:46, pages 9875-9879.
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Jixing Li, Hui Zhou, Jinlong Zhang, Huameng Yang & Gaoxi Jiang. (2016) AgNO 3 as nitrogen source for rhodium( iii )-catalyzed synthesis of 2-aryl-2H-benzotriazoles from azobenzenes . Chemical Communications 52:61, pages 9589-9592.
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Mingchun Gao, Yingying Li, Yuansheng Gan & Bin Xu. (2015) Copper Nitrate Mediated Regioselective [2+2+1] Cyclization of Alkynes with Alkenes: A Cascade Approach to Δ 2 ‐Isoxazolines . Angewandte Chemie International Edition 54:30, pages 8795-8799.
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Mingchun Gao, Yingying Li, Yuansheng Gan & Bin Xu. (2015) Copper Nitrate Mediated Regioselective [2+2+1] Cyclization of Alkynes with Alkenes: A Cascade Approach to Δ 2 ‐Isoxazolines . Angewandte Chemie 127:30, pages 8919-8923.
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Rajesh H. Vekariya, Kinjal D. Patel & Hitesh D. Patel. (2015) Melamine trisulfonic acid (MTSA): an efficient and recyclable heterogeneous catalyst in green organic synthesis. RSC Advances 5:110, pages 90819-90837.
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Rajesh H. Vekariya & Hitesh D. Patel. (2014) ChemInform Abstract: Selective Nitration of Phenolic Compounds by Green Synthetic Approaches. ChemInform 45:36.
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