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Original Articles

N,N,N′,N′‐Tetraoctyl Diglycolamide (TODGA): A Promising Extractant for Actinide‐Partitioning from High‐Level Waste (HLW)

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Pages 463-479 | Received 05 Oct 2004, Accepted 26 Apr 2005, Published online: 18 Aug 2006

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Read on this site (69)

Alexander N. Turanov & Vasilii K. Karandashev. (2023) Triflimide Effect in Solvent Extraction of Rare-Earth Elements from Nitric Acid Solutions by TODGA. Solvent Extraction and Ion Exchange 41:7, pages 885-904.
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Bholanath Mahanty, Prasanta K. Mohapatra, Andrea Leoncini, Jurriaan Huskens & Willem Verboom. (2022) Liquid–Liquid Extraction and Supported Liquid Membrane Transport of Neptunium(IV) Across a Flat-Sheet Supported Liquid Membrane Containing a TREN-DGA Derivative. Solvent Extraction and Ion Exchange 40:7, pages 693-717.
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Bholanath Mahanty, Prasanta K. Mohapatra, Andrea Leoncini, Jurriaan Huskens & Willem Verboom. (2022) Unique Eu(III) transport selectivity seen using a supported liquid membrane containing a diglycolamide dendrimer ligand. Separation Science and Technology 57:11, pages 1775-1787.
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Yifu Hu, Chuan Lu, Qi Chen, Yaoyang Liu, Yu Zhou, Caishan Jiao, Meng Zhang, Hongguo Hou, Yang Gao & Guoxin Tian. (2022) Pertraction of Nd(III) and U(VI) Through Flat Sheet Supported Liquid Membrane Containing N, N’-Dimethyl-N, N’-Dioctyl-3-Oxadiglcolamide as Carrier. Solvent Extraction and Ion Exchange 40:3, pages 269-289.
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Laurence Berthon, Amaury Paquet, Georges Saint-Louis & Philippe Guilbaud. (2021) How Phase Modifiers Disrupt Third-phase Formation in Solvent Extraction Solutions. Solvent Extraction and Ion Exchange 39:2, pages 204-232.
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Andreas Geist, Laurence Berthon, Marie-Christine Charbonnel & Udo Müllich. (2020) Extraction of Nitric Acid, Americium(III), Curium(III), and Lanthanides(III) into DMDOHEMA Dissolved in Kerosene. Solvent Extraction and Ion Exchange 38:7, pages 681-702.
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K. Rama Swami, K. A. Venkatesan & M. P. Antony. (2019) Role of Phase Modifiers in Controlling the Third-phase Formation During the Solvent Extraction of Trivalent Actinides. Solvent Extraction and Ion Exchange 37:7, pages 500-517.
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Régis Mastretta, Rémi Poirot, Damien Bourgeois & Daniel Meyer. (2019) Palladium Isolation and Purification from Nitrate Media: Efficient Process Based on Malonamides. Solvent Extraction and Ion Exchange 37:2, pages 140-156.
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David Woodhead, Fiona McLachlan, Robin Taylor, Udo Müllich, Andreas Geist, Andreas Wilden & Giuseppe Modolo. (2019) Nitric Acid Extraction into a TODGA Solvent Modified with 1-Octanol. Solvent Extraction and Ion Exchange 37:2, pages 173-190.
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A. N. Turanov, V. K. Karandashev, A. V. Kharlamov, N. A. Bondarenko & V. A. Khvostikov. (2019) Extraction of lanthanides(III) from Perchlorate Solutions with Carbamoyl- and Phosphorylmethoxymethylphosphine Oxides and Tetrabutyldiglycolamide. Solvent Extraction and Ion Exchange 37:1, pages 65-80.
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Yasutoshi Ban, Hideya Suzuki, Shinobu Hotoku, Tomohiro Kawasaki, Hiroshi Sagawa, Nao Tsutsui & Tatsuro Matsumura. (2019) Extraction of Trivalent Rare Earths and Minor Actinides from Nitric Acid with N,N,N’,N’-Tetradodecyldiglycolamide (TDdDGA) by Using Mixer-Settler Extractors in a Hot Cell. Solvent Extraction and Ion Exchange 37:1, pages 27-37.
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Jérémy Dehaudt, Neil J. Williams, Huimin Luo & Sheng Dai. (2018) Extraction of Rare Earths in Ionic Liquids Via Competitive Ligand Complexation between TODGA and DTPA. Solvent Extraction and Ion Exchange 36:6, pages 574-582.
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Peter Zsabka, Karen Van Hecke, Lesley Adriaensen, Andreas Wilden, Giuseppe Modolo, Marc Verwerft, Koen Binnemans & Thomas Cardinaels. (2018) Solvent Extraction of Am(III), Cm(III), and Ln(III) Ions from Simulated Highly Active Raffinate Solutions by TODGA Diluted in Aliquat-336 Nitrate Ionic Liquid. Solvent Extraction and Ion Exchange 36:6, pages 519-541.
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Arunasis Bhattacharyya, Prasanta K. Mohapatra, Dhaval R. Raut, Andrea Leoncini, Jurriaan Huskens & Willem Verboom. (2018) Unusual Reversal in Pu and U Extraction in an Ionic Liquid Using Two Tripodal Diglycolamide Ligands: Experimental and DFT Studies. Solvent Extraction and Ion Exchange 36:6, pages 542-557.
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Meena B Singh, Suneha R Patil, Aishwarya A Lohi & Vilas G. Gaikar. (2018) Insight into nitric acid extraction and aggregation of N, N, N’, N’-Tetraoctyl diglycolamide (TODGA) in organic solutions by molecular dynamics simulation. Separation Science and Technology 53:9, pages 1361-1371.
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Daniel Whittaker, Andreas Geist, Giuseppe Modolo, Robin Taylor, Mark Sarsfield & Andreas Wilden. (2018) Applications of Diglycolamide Based Solvent Extraction Processes in Spent Nuclear Fuel Reprocessing, Part 1: TODGA. Solvent Extraction and Ion Exchange 36:3, pages 223-256.
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Elena Macerata, Annalisa Ossola, Walter Panzeri, Marco Giola, Federica Faroldi, Dario Alberto Tinonin, Andrea Mele, Alessandro Casnati & Mario Mariani. (2018) Actinide–lanthanide co-extraction by rigidified diglycolamides. Solvent Extraction and Ion Exchange 36:1, pages 41-53.
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Yingbo Xu, Yang Gao, Yu Zhou, Chenchen Fan, Hongguo Hou & Meng Zhang. (2017) Extraction behavior of strontium from nitric acid medium with N,N’-dimethyl-N,N’-dioctyldiglcolamide. Solvent Extraction and Ion Exchange 35:7, pages 507-518.
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A. N Turanov, V. K Karandashev & V. A Khvostikov. (2017) Synergistic Extraction of Lanthanides (III) with Mixtures of TODGA and Hydrophobic Ionic Liquid into Molecular Diluent. Solvent Extraction and Ion Exchange 35:7, pages 461-479.
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Arijit Sengupta & M. S. Murali. (2016) Effect of phase modifiers TBP and iso-decanol on the extraction and complexation of Eu3+ with CMPO. Separation Science and Technology 51:13, pages 2153-2163.
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Fiona McLachlan, Katie Greenough, Andreas Geist, Bliss McLuckie, Giuseppe Modolo, Andreas Wilden & Robin Taylor. (2016) Nitric Acid Extraction into the TODGA/TBP Solvent. Solvent Extraction and Ion Exchange 34:4, pages 334-346.
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Jammu Ravi, K. A. Venkatesan, M. P. Antony, T. G. Srinivasan & P. R. Vasudeva Rao. (2016) Solvent extraction behavior of trivalent metal ions in diglycolamides having same carbon to oxygen ratio. Separation Science and Technology 51:1, pages 32-40.
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S. Chapron, C. Marie, G. Arrachart, M. Miguirditchian & S. Pellet-Rostaing. (2015) New Insight into the Americium/Curium Separation by Solvent Extraction using Diglycolamides. Solvent Extraction and Ion Exchange 33:3, pages 236-248.
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A. S. Kanekar, P. N. Pathak & P. K. Mohapatra. (2015) Supercritical Fluid Dissolution and Extraction of Trivalent Metal Cations from Different Matrices. Separation Science and Technology 50:3, pages 471-477.
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Emanuel Makrlík, Vít Novák & Petr Vaňura. (2015) Lithium ionophore VIII as an extraordinarily strong receptor for the trivalent europium cation. Molecular Physics 113:1, pages 89-94.
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Youwen Zhang, Ziyi Liu, Fuyou Fan, Lun Zhu & Yinglin Shen. (2014) Extraction of Uranium and Thorium from Nitric Acid Solution by TODGA in Ionic Liquids. Separation Science and Technology 49:12, pages 1895-1902.
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Arijit Sengupta, Prasanta K. Mohapatra, Mudassir Iqbal, Jurriaan Huskens & Willem Verboom. (2014) Solvent systems containing diglycolamide-functionalised calix[4]arenes in room temperature ionic liquid for metal ion extraction: studies with simulated high-level wastes. Supramolecular Chemistry 26:7-8, pages 612-619.
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P. V. Vernekar, Y. D. Jagdale, A. W. Patwardhan, A. V. Patwardhan, S. A. Ansari & P. K. Mohapatra. (2014) Non-Dispersive Solvent Extraction of Neodymium using N,N,N’,N’-Tetraoctyl Diglycolamide (TODGA). Separation Science and Technology 49:10, pages 1541-1554.
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Prasad V. Vernekar, Yogesh D. Jagdale, Ajay D. Sharma, Ashwin W. Patwardhan, Anand V. Patwardhan, Seraj A. Ansari & Prasanta K. Mohapatra. (2014) Simultaneous Extraction of Neodymium and Uranium using Hollow Fiber Supported Liquid Membrane. Separation Science and Technology 49:10, pages 1509-1520.
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Jammu Ravi, K. A. Venkatesan, M. P. Antony, T. G. Srinivasan & P. R. Vasudeva Rao. (2014) Feasibility of Using Di-Dodecyl-Di-Octyl Diglycolamide for Partitioning of Minor Actinides from Fast Reactor High-Level Liquid Waste. Solvent Extraction and Ion Exchange 32:4, pages 424-436.
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P.K. Nayak, R. Kumaresan, K.A. Venkatesan, M.P. Antony & P.R. Vasudeva Rao. (2014) Extraction Behavior of Am(III) and Eu(III) from Nitric Acid Medium in Tetraoctyldiglycolamide-Bis(2-Ethylhexyl)Phosphoric Acid Solution. Separation Science and Technology 49:8, pages 1186-1191.
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S. A. Ansari, R. B. Gujar, D. R. Prabhu, P. N. Pathak & P. K. Mohapatra. (2014) Comparative Evaluation of CMPO and Diglycolamide Based Solvent Systems for Actinide Partitioning in Mixer-Settler Runs Using Tracer-Spiked PHWR Simulated High Level Waste. Solvent Extraction and Ion Exchange 32:1, pages 44-58.
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Y.D. Jagdale, P.V. Vernekar, A.W. Patwardhan, A.V. Patwardhan, S.A. Ansari, P.K. Mohapatra & V.K. Manchanda. (2013) Mathematical Model for the Extraction of Metal Ions using Hollow Fiber Supported Liquid Membrane Operated in a Recycling Mode. Separation Science and Technology 48:16, pages 2454-2467.
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Arijit Sengupta, Prasanta K. Mohapatra, Mudassir Iqbal, Jurriaan Huskens & Willem Verboom. (2013) Role of organic diluent on actinide ion extraction using a both-side diglycolamide-functionalised calix[4]arene. Supramolecular Chemistry 25:9-11, pages 688-695.
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M. J. Carrot, C. R. Gregson & R. J. Taylor. (2013) Neptunium Extraction and Stability in the GANEX Solvent: 0.2 M TODGA/0.5 M DMDOHEMA/Kerosene. Solvent Extraction and Ion Exchange 31:5, pages 463-482.
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Pankaj Kandwal & P.K. Mohapatra. (2013) A Novel Liquid Emulsion Membrane Containing TODGA as the Carrier Extractant for Am Recovery from Acidic Wastes. Separation Science and Technology 48:8, pages 1167-1176.
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P.V. Vernekar, A.W. Patwardhan, A.V. Patwardhan, S.A. Ansari, P.K. Mohapatra & V.K. Manchanda. (2013) Mathematical Model for the Extraction of Neodymium from Nitrate Media using Hollow Fiber Supported Liquid Membrane Operated in a Recycling Mode. Separation Science and Technology 48:7, pages 1003-1014.
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Wei Meng, Feng Xiaogui & Chen Jing. (2013) Studies on Stripping of Actinides, and Some Fission and Corrosion Products from Loaded TRPO by N,N,N′,N′-Tetramethyl Diglycolamide. Separation Science and Technology 48:5, pages 741-748.
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M. E. Mincher, D. L. Quach, Y. J. Liao, B. J. Mincher & C. M. Wai. (2012) The Partitioning of Americium and the Lanthanides Using Tetrabutyldiglycolamide (TBDGA) in Octanol and in Ionic Liquid Solution. Solvent Extraction and Ion Exchange 30:7, pages 735-747.
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S. A. Ansari, R. B. Gujar, D. R. Prabhu, P. N. Pathak & P. K. Mohapatra. (2012) Counter-Current Extraction of Neptunium from Simulated Pressurized Heavy Water Reactor High Level Waste Using N,N,N',N'-Tetraoctyl Diglycolamide. Solvent Extraction and Ion Exchange 30:5, pages 457-468.
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R. B. Gujar, S. A. Ansari, A. Bhattacharyya, A. S. Kanekar, P. N. Pathak, P. K. Mohapatra & V. K. Manchanda. (2012) Radiolytic Stability of N,N,N′,N′-Tetraoctyl Diglycolamide (TODGA) in the Presence of Phase Modifiers Dissolved in n-Dodecane. Solvent Extraction and Ion Exchange 30:3, pages 278-290.
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R. B. Gujar, S. A. Ansari, D. R. Prabhu, P. N. Pathak, A. Sengupta, S. K. Thulasidas, P. K. Mohapatra & V. K. Manchanda. (2012) Actinide Partitioning with a Modified TODGA Solvent: Counter-Current Extraction Studies with Simulated High Level Waste. Solvent Extraction and Ion Exchange 30:2, pages 156-170.
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Jamie Brown, Fiona McLachlan, Mark Sarsfield, Robin Taylor, Giuseppe Modolo & Andreas Wilden. (2012) Plutonium Loading of Prospective Grouped Actinide Extraction (GANEX) Solvent Systems based on Diglycolamide Extractants. Solvent Extraction and Ion Exchange 30:2, pages 127-141.
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P.R. Vasudeva Rao, K.A. Venkatesan, A. Rout, T.G. Srinivasan & K. Nagarajan. (2012) Potential Applications of Room Temperature Ionic Liquids for Fission Products and Actinide Separation. Separation Science and Technology 47:2, pages 204-222.
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Bo Yu, JasonR. Bell, Huimin Luo & Sheng Dai. (2012) Ionic Liquid and Silica Sol-Gel Composite Materials Doped with N,N,N′,N′-tetra(n-octyl)diglycolamide for Extraction of La3+ and Ba2+ . Separation Science and Technology 47:2, pages 244-249.
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JasonR. Bell, Huimin Luo & Sheng Dai. (2012) Solvent Extraction Separation of La3+ and Ba2+ Using Imidazolium Ionic Liquids and TODGA Extractant. Separation Science and Technology 47:14-15, pages 2002-2006.
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C.B. Patil, S.A. Ansari, P.K. Mohapatra, V. Natarajan & V.K. Manchanda. (2011) Non-Dispersive Solvent Extraction and Stripping of Neodymium (III) using a Hollow Fiber Contactor with TODGA as the Extractant. Separation Science and Technology 46:5, pages 765-773.
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Seraj A. Ansari, Priyanath Pathak, Prashanta K. Mohapatra & Vijay K. Manchanda. (2011) Aqueous Partitioning of Minor Actinides by Different Processes. Separation & Purification Reviews 40:1, pages 43-76.
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Jammu Ravi, A. S. Suneesh, T. Prathibha, K. A. Venkatesan, M. P. Antony, T. G. Srinivasan & P. R. Vasudeva Rao. (2011) Extraction Behavior of Some Actinides and Fission Products from Nitric Acid Medium by a New Unsymmetrical Diglycolamide. Solvent Extraction and Ion Exchange 29:1, pages 86-105.
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Surajit Panja, P.K. Mohapatra, S.C. Tripathi & V.K. Manchanda. (2010) Controlled Pertraction of Plutonium(III) Under Reducing Conditions From Acidic Feeds Using TODGA as the Carrier Extractant. Separation Science and Technology 46:1, pages 94-104.
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R. B. Gujar, S. A. Ansari, D. R. Prabhu, D. R. Raut, P. N. Pathak, A. Sengupta, S. K. Thulasidas, P. K. Mohapatra & V. K. Manchanda. (2010) Demonstration of T2EHDGA Based Process for Actinide Partitioning Part II: Counter-Current Extraction Studies. Solvent Extraction and Ion Exchange 28:6, pages 764-777.
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Sun Guoxin, Liu Min, Cui Yu, Yuan Meilong & Yin Shaohong. (2010) Synthesis of N,N′-Dimethyl-N,N′-Dioctyl-3-Oxadiglycolamide and its Extraction Properties for Lanthanides. Solvent Extraction and Ion Exchange 28:4, pages 482-494.
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S. Panja, P. K. Mohapatra, S. C. Tripathi & V. K. Manchanda. (2010) Transport of Thorium(IV) Across a Supported Liquid Membrane Containing N,N,N′,N′-Tetraoctyl-3-oxapentanediamide (TODGA) as the Extractant. Separation Science and Technology 45:8, pages 1112-1120.
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R. B. Gujar, S. A. Ansari, P. K. Mohapatra & V. K. Manchanda. (2010) Development of T2EHDGA Based Process for Actinide Partitioning. Part I: Batch Studies for Process Optimization. Solvent Extraction and Ion Exchange 28:3, pages 350-366.
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Tang Yang, Song-Dong Ding, Ning Liu, Li Zhang & Ying-Jia Sui. (2009) Synthesis of Extraction Resin Containing N,N,N′,N′-Tetraisobutyl Diglycolamide and its Application for Separation of Sr(II) from Rb(I). Separation Science and Technology 44:11, pages 2526-2540.
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María Teresa Murillo, AmparoG. Espartero, Jorge Sánchez‐Quesada, Javier de Mendoza$suffix/text()$suffix/text() & Pilar Prados. (2009) Synthesis of Pre‐Organized Bisdiglycolamides (BisDGA) and Study of their Extraction Properties for Actinides(III) and Lanthanides(III). Solvent Extraction and Ion Exchange 27:2, pages 107-131.
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A. Paulenova, M. Yu. Alyapyshev, V. A. Babain, R. S. Herbst & J. D. Law. (2008) Extraction of Lanthanides with Diamides of Dipicolinic Acid from Nitric Acid Solutions. I. Separation Science and Technology 43:9-10, pages 2606-2618.
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A. N. Turanov, V. K. Karandashev & V. E. Baulin. (2008) Effect of Anions on the Extraction of Lanthanides (III) by N,N′‐Dimethyl‐N,N′‐Diphenyl‐3‐Oxapentanediamide. Solvent Extraction and Ion Exchange 26:2, pages 77-99.
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Giuseppe Modolo, Hanna Asp, Christian Schreinemachers & Hendrik Vijgen. (2007) Development of a TODGA based Process for Partitioning of Actinides from a PUREX Raffinate Part I: Batch Extraction Optimization Studies and Stability Tests. Solvent Extraction and Ion Exchange 25:6, pages 703-721.
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B. Zielinska, C. Apostolidis, F. Bruchertseifer & A. Morgenstern. (2007) An Improved Method for the Production of Ac‐225/Bi‐213 from Th‐229 for Targeted Alpha Therapy. Solvent Extraction and Ion Exchange 25:3, pages 339-349.
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E. A. Mowafy & H. F. Aly. (2007) Synthesis of some N,N,N′,N′‐Tetraalkyl‐3‐Oxa‐Pentane‐1,5‐Diamide and their Applications in Solvent Extraction. Solvent Extraction and Ion Exchange 25:2, pages 205-224.
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Yuji Sasaki, Philippe Rapold, Makoto Arisaka, Masaru Hirata, Takaumi Kimura, Clément Hill & Gérard Cote. (2007) An Additional Insight into the Correlation between the Distribution Ratios and the Aqueous Acidity of the TODGA System. Solvent Extraction and Ion Exchange 25:2, pages 187-204.
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